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1. 发明授权

US07732501B2 Fullerene based proton conductive materials 有权
公开(公告)号：US07732501B2
公开(公告)日：2010-06-08
申请号：US11551048
申请日：2006-10-19
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： C08J5/20
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.

2. 发明申请

US20100120927A1 FULLERENE BASED PROTON CONDUCTIVE MATERIALS 失效
标题翻译：富勒烯基导电材料
公开(公告)号：US20100120927A1
公开(公告)日：2010-05-13
申请号：US12652346
申请日：2010-01-05
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： C08J5/22
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.
摘要翻译：一种基于富勒烯的质子导体，其包括通过至少部分氟化的间隔分子与富勒烯连接的质子传导性官能团。此外，包含由连接分子连接的至少两个质子导体的聚合物。此外，使用该聚合物作为质子交换膜的电化学装置，由此该装置能够实现自加湿特性。

3. 发明授权

US07695706B2 Producing method of fullerene derivative, fullerene derivative, proton conductor and electrochemical device 有权
标题翻译：富勒烯衍生物，富勒烯衍生物，质子导体和电化学装置的生产方法
公开(公告)号：US07695706B2
公开(公告)日：2010-04-13
申请号：US11427909
申请日：2006-06-30
申请人： Berthold Nuber
发明人： Berthold Nuber
IPC分类号： B01J19/08
CPC分类号： C07C305/20 , C07C35/44 , C07C309/25 , C07C2604/00 , H01M8/1016 , H01M8/1023 , Y02E60/324 , Y02P70/56 , Y10S977/734 , Y10S977/735 , Y10S977/74
摘要： Provided are a method of efficiently procuding fullerene into which a OH group or a SO3H group is introduced, such as fullerenol, or a derivative thereof, the fullerene and its derivative being preferable as a proton conductor, and a novel and usable proton conductor obtained by the method. Further, provided is an electrochemical device using the proton conductor such as a fuel cell or the like. In the producing method of the fullerene derivative, halogated fullerene, which is obtained through halogating a fullerene molecule is used as a precursor, the fullerene derivative is produced through introducing one or more proton dissociative group into at least one carbon atom of a fullerene molecule. Moreover, in a producing method of a polymerized fullerene derivative, a plurality of fullerene derivatives are bonded to one another by an aromatic group of an aromatic compound through reacting the plurality of fullerene derivatives with the aromatic compound. The fullerene derivative obtained by any of these method functions as a proton conductor, and an electrochemical device using the proton conductor such as a fuel cell can be downsized and simplified without atmosphere constraints.
摘要翻译：本发明提供一种有效地制备引入了OH基团或SO 3 H基团的富勒烯如富勒烯醇或其衍生物，富勒烯及其衍生物优选作为质子导体的方法，以及由式方法。此外，提供了使用诸如燃料电池等的质子导体的电化学装置。在富勒烯衍生物的制造方法中，通过使富勒烯分子卤化获得的卤代富勒烯用作前体，富勒烯衍生物是通过将一个或多个质子离解基团引入富勒烯分子的至少一个碳原子而制备的。此外，在聚合的富勒烯衍生物的制造方法中，通过使多种富勒烯衍生物与芳香族化合物反应，多个富勒烯衍生物通过芳香族化合物的芳香族基团彼此键合。通过这些方法中的任何一种获得的富勒烯衍生物用作质子导体，并且使用诸如燃料电池的质子导体的电化学装置可以在没有气氛限制的情况下被小型化和简化。

4. 发明申请

US20070087247A1 FULLERENE BASED PROTON CONDUCTIVE MATERIALS 有权
标题翻译：富勒烯基导电材料
公开(公告)号：US20070087247A1
公开(公告)日：2007-04-19
申请号：US11551079
申请日：2006-10-19
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： H01M8/10
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.
摘要翻译：一种基于富勒烯的质子导体，其包括通过至少部分氟化的间隔分子与富勒烯连接的质子传导性官能团。此外，包含由连接分子连接的至少两个质子导体的聚合物。此外，使用该聚合物作为质子交换膜的电化学装置，由此该装置能够实现自加湿特性。

5. 发明授权

US07371479B2 Method for fullerene derivative and the fullerene derivative proton conductor and electrochemical device 失效
标题翻译：富勒烯衍生物和富勒烯衍生物质子导体和电化学装置的方法
公开(公告)号：US07371479B2
公开(公告)日：2008-05-13
申请号：US10451320
申请日：2001-12-25
申请人： Berthold Nuber
发明人： Berthold Nuber
IPC分类号： H01M8/10
CPC分类号： C07C305/20 , C07C35/44 , C07C309/25 , C07C2604/00 , H01M8/1016 , H01M8/1023 , Y02E60/324 , Y02P70/56 , Y10S977/734 , Y10S977/735 , Y10S977/74
摘要： Provided are a method of efficiently procuding fullerene into which a OH group or a SO3H group is introduced, such as fullerenol, or a derivative thereof, the fullerene and its derivative being preferable as a proton conductor, and a novel and usable proton conductor obtained by the method. Further, provided is an electrochemical device using the proton conductor such as a fuel cell or the like. In the producing method of the fullerene derivative, halogated fullerene, which is obtained through halogating a fullerene molecule is used as a precursor, the fullerene derivative is produced through introducing one or more proton dissociative group into at least one carbon atom of a fullerene molecule. Moreover, in a producing method of a polymerized fullerene derivative, a plurality of fullerene derivatives are bonded to one another by an aromatic group of an aromatic compound through reacting the plurality of fullerene derivatives with the aromatic compound. The fullerene derivative obtained by any of these method functions as a proton conductor, and an electrochemical device using the proton conductor such as a fuel cell can be downsized and simplified without atmosphere constraints.
摘要翻译：本发明提供一种有效地制备引入了OH基或SO 3 H基的富勒烯的方法，例如富勒烯醇或其衍生物，富勒烯及其衍生物优选作为质子导体，以及通过该方法获得的新型可用的质子导体。此外，提供了使用诸如燃料电池等的质子导体的电化学装置。在富勒烯衍生物的制造方法中，通过使富勒烯分子卤化获得的卤代富勒烯用作前体，富勒烯衍生物是通过将一个或多个质子离解基团引入富勒烯分子的至少一个碳原子而制备的。此外，在聚合的富勒烯衍生物的制造方法中，通过使多种富勒烯衍生物与芳香族化合物反应，多个富勒烯衍生物通过芳香族化合物的芳香族基团彼此键合。通过这些方法中的任何一种获得的富勒烯衍生物用作质子导体，并且使用诸如燃料电池的质子导体的电化学装置可以在没有气氛限制的情况下被小型化和简化。

6. 发明申请

US20070032678A1 Process for isolating vinyl acetate 有权
标题翻译：乙酸乙烯酯分离方法
公开(公告)号：US20070032678A1
公开(公告)日：2007-02-08
申请号：US11484419
申请日：2006-07-11
申请人： Johann Stamm , Bernd Rinne , Stefan Hess , Hans-Jochen Sachs , Michael Sehr , Michael Bayer , Berthold Nuber , Martin Wagner
发明人： Johann Stamm , Bernd Rinne , Stefan Hess , Hans-Jochen Sachs , Michael Sehr , Michael Bayer , Berthold Nuber , Martin Wagner
IPC分类号： C07C67/48
CPC分类号： C07C67/055 , C07C67/54 , C07C69/01 , C07C69/15
摘要： A process for isolating vinyl acetate from the gas mixture formed in the reaction of ethylene with acetic acid and oxygen in the gas phase over catalysts comprising palladium or palladium compounds, with recirculation of the acetic-acid solution obtained in the circulating gas scrubber to the first distillation column (predewatering column).
摘要翻译：从在循环气体洗涤器中获得的包含钯或钯化合物的催化剂的乙烯与乙酸和氧气在气相中形成的气体混合物中分离乙酸乙烯酯的方法，其中循环气体洗涤器中获得的乙酸溶液再循环到第一蒸馏塔（预抽塔）。

7. 发明授权

US06890676B2 Fullerene based proton conductive materials 失效
标题翻译：富勒烯基质子传导材料
公开(公告)号：US06890676B2
公开(公告)日：2005-05-10
申请号：US10115109
申请日：2002-04-01
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： C01B31/02 , H01M8/10
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.
摘要翻译：一种基于富勒烯的质子导体，其包括通过至少部分氟化的间隔分子与富勒烯连接的质子传导性官能团。此外，包含由连接分子连接的至少两个质子导体的聚合物。此外，使用该聚合物作为质子交换膜的电化学装置，由此该装置能够实现自加湿特性。

8. 发明申请

US20100075197A1 FULLERENE BASED PROTON CONDUCTIVE MATERIALS 失效
公开(公告)号：US20100075197A1
公开(公告)日：2010-03-25
申请号：US12615785
申请日：2009-11-10
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： H01M8/10
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.

9. 发明授权

US07301048B2 Process for isolating vinyl acetate 有权
公开(公告)号：US07301048B2
公开(公告)日：2007-11-27
申请号：US11484419
申请日：2006-07-11
申请人： Johann Stamm , Bernd Rinne , Stefan Hess , Hans-Jochen Sachs , Michael Sehr , Michael J. Bayer , Berthold Nuber , Martin Wagner
发明人： Johann Stamm , Bernd Rinne , Stefan Hess , Hans-Jochen Sachs , Michael Sehr , Michael J. Bayer , Berthold Nuber , Martin Wagner
IPC分类号： C07C67/48
CPC分类号： C07C67/055 , C07C67/54 , C07C69/01 , C07C69/15
摘要： A process for isolating vinyl acetate from the gas mixture formed in the reaction of ethylene with acetic acid and oxygen in the gas phase over catalysts comprising palladium or palladium compounds, with recirculation of the acetic-acid solution obtained in the circulating gas scrubber to the first distillation column (predewatering column).

10. 发明授权

US07198863B2 Fullerene based proton conductive materials 有权
标题翻译：富勒烯基质子传导材料
公开(公告)号：US07198863B2
公开(公告)日：2007-04-03
申请号：US10986551
申请日：2004-11-10
申请人： Berthold Nuber , Bjoern Pietzak
发明人： Berthold Nuber , Bjoern Pietzak
IPC分类号： H01M8/10
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/15 , C01B32/152 , C08J5/2225 , C08J5/2262 , C08J2365/00 , H01B1/122 , H01M8/1023 , H01M8/1025 , H01M8/103 , H01M8/1039 , H01M2300/0082 , Y10S977/737
摘要： A fullerene-based proton conductor including a proton conductive functional group connected to the fullerene by an at least partially fluorinated spacer molecule. Also, a polymer including at least two of the proton conductors that are connected by a linking molecule. Further, an electrochemical device employing the polymer as a proton exchange membrane, whereby the device is able to achieve a self-humidifying characteristic.
摘要翻译：一种基于富勒烯的质子导体，其包括通过至少部分氟化的间隔分子与富勒烯连接的质子传导性官能团。此外，包含由连接分子连接的至少两个质子导体的聚合物。此外，使用该聚合物作为质子交换膜的电化学装置，由此该装置能够实现自加湿特性。

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