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1. 发明授权

US5885331A Process for the adsorption of nitrogen from gas mixtures by means of pressure swing adsorption with zeolites 失效
标题翻译：通过利用沸石的变压吸附从气体混合物中吸附氮的方法
公开(公告)号：US5885331A
公开(公告)日：1999-03-23
申请号：US690415
申请日：1996-07-25
申请人： Gerhard Reiss , Lothar Puppe , Bruno Hees
发明人： Gerhard Reiss , Lothar Puppe , Bruno Hees
IPC分类号： B01D53/04 , B01D53/047 , B01J20/18 , C01B13/02 , C01B21/04
CPC分类号： C01B13/027 , B01D53/047 , B01D2253/108 , B01D2256/12 , B01D2257/102 , B01D2259/40052 , B01D53/0446 , B01D53/0476 , C01B2210/0046 , Y10S95/902
摘要： In the pressure swing adsorption of nitrogen from gas mixtures with less polar gas components at temperatures of between 20.degree. and 50.degree. C., wherein the gas mixture is passed through an adsorber which is filled with packings of zeolite pellets and has an inlet zone and an outlet zone, the improvement which comprises providing at least two packings in the adsorber, a packing of Li-zeolite X in the inlet zone of the adsorber and a packing of at least one of Ca-zeolite A and Ca-zeolite X in the outlet zone of the adsorber.
摘要翻译：在20至50℃的温度下，在具有极性较小的气体组分的气体混合物的氮气的变压吸附中，其中气体混合物通过填充有沸石颗粒的填料的吸附器，并具有入口区和出口区，其改进包括在吸附器中提供至少两个填料，在吸附器的入口区域中包含Li-沸石X，并且在该吸附器的至少一个Ca-沸石A和Ca-沸石X的填料中吸附器的出口区。

2. 发明授权

US07462286B2 Chelate exchanger 失效
标题翻译：螯合交换器
公开(公告)号：US07462286B2
公开(公告)日：2008-12-09
申请号：US10578728
申请日：2004-11-06
申请人： Reinhold Klipper , Bruno Hees , Olaf Halle , Wolfgang Podszun , Pierre Vanhoorne , Hubertus Mittag , Wolfgang Zarges
发明人： Reinhold Klipper , Bruno Hees , Olaf Halle , Wolfgang Podszun , Pierre Vanhoorne , Hubertus Mittag , Wolfgang Zarges
IPC分类号： C02F1/42
CPC分类号： C08F8/30 , B01J45/00
摘要： The present invention relates to novel ion exchangers comprising carboxyl groups and also —(CH2)mNR1R2 groups having improved exchange kinetics and selectivity, a method for their production and also use thereof for the adsorption of metals, in particular arsenic, when these are additionally loaded with iron oxide/iron oxyhydroxide.
摘要翻译：本发明涉及包含羧基的新型离子交换剂以及具有改进的交换动力学和选择性的 - （CH 2）m N R 1 R 2基团，其生产方法以及它们用于吸附金属，特别是砷时，当这些还附加时与氧化铁/羟基氧化铁。

3. 发明申请

US20070062878A1 Chelate exchanger 失效
标题翻译：螯合交换器
公开(公告)号：US20070062878A1
公开(公告)日：2007-03-22
申请号：US10578728
申请日：2004-11-06
申请人： Reinhold Klipper , Bruno Hees , Olaf Halle , Wolfgang Podszun , Pierre Vanhoorne , Hubertus Mittag , Wolfgang Zarges
发明人： Reinhold Klipper , Bruno Hees , Olaf Halle , Wolfgang Podszun , Pierre Vanhoorne , Hubertus Mittag , Wolfgang Zarges
IPC分类号： B01D15/00
CPC分类号： C08F8/30 , B01J45/00
摘要： The present invention relates to novel ion exchangers comprising carboxyl groups and also —(CH2)mNR1R2 groups having improved exchange kinetics and selectivity, a method for their production and also use thereof for the adsorption of metals, in particular arsenic, when these are additionally loaded with iron oxide/iron oxyhydroxide.
摘要翻译：本发明涉及包含羧基的新型离子交换剂，并且还涉及 - （CH 2）2 NR 1 R 2 R 2 具有改进的交换动力学和选择性的组，其制备方法，并且还用于当这些还附加氧化铁/羟基氧化铁时金属的吸附，特别是砷。

4. 发明授权

US5656066A Adsorptive oxygen enrichment of air with mixtures of molecular sieve zeolites 失效
标题翻译：吸附氧富集空气与分子筛沸石混合物
公开(公告)号：US5656066A
公开(公告)日：1997-08-12
申请号：US648524
申请日：1996-05-13
申请人： Gerhard Reiss , Lothar Puppe , Bruno Hees
发明人： Gerhard Reiss , Lothar Puppe , Bruno Hees
IPC分类号： B01D53/04 , B01D53/047 , B01J20/18 , C01B13/02
CPC分类号： C01B13/027 , B01D53/02 , B01D53/04 , B01D2253/108 , B01D2253/1085 , B01D2256/12 , B01D2257/102 , B01D2259/403 , B01D53/047 , B01D53/0476 , C01B2210/0046 , Y10S95/902
摘要： An improved process for the oxygen enrichment of air by vacuum swing adsorption, pressure swing adsorption or a combination thereof, wherein the improvement comprises providing at least one packing at each of the air inlet to and air outlet from the adsorber, the packing at the air inlet side of the adsorber comprising Na-Ca zeolite X with an SiO.sub.2 /Al.sub.2 O.sub.3 ratio of 2.0 to 2.5 and with a CaO/Al.sub.2 O.sub.3 ratio of 0.4 to 0.75, the ratio being dependent upon the air inlet temperature, at an air inlet temperature of 20.degree. to 30.degree. C., the CaO/Al.sub.2 O.sub.3 ratio of the Na-Ca zeolite X at the inlet zone being 0.4 to 0.6, at an air inlet temperature of 30.degree. to 40.degree. C., the CaO/Al.sub.2 O.sub.3 ratio of the Ca zeolite X at the inlet zone being 0.55 to 0.65 and at an air inlet temperature of 40.degree. to 50.degree. C., the CaO/Al.sub.2 O.sub.3 ratio of the Na-Ca zeolite X at the inlet zone being 0.6 to 0.75, the packing at the air outlet side of the adsorber comprising Na-Ca zeolite A with a CaO/Al.sub.2 O.sub.3 ratio of 0.5 to 1.0 or Na-Ca zeolite X with CaO/Al.sub.2 O.sub.3 ratio of 0.4 to 1.0, above the CaO/Al.sub.2 O.sub.3 ratio of the Na-Ca zeolite X at the inlet side.
摘要翻译：通过真空变压吸附，变压吸附或其组合来改善空气富氧的方法，其中改进包括在吸附器的空气入口和空气出口的每个处提供至少一个填料，空气中的填料吸附器的入口侧包含SiO 2 / Al 2 O 3比为2.0至2.5且CaO / Al 2 O 3比为0.4至0.75的Na-Ca沸石X，该比率取决于空气入口温度，入口温度为20℃ 在30〜40℃，进口温度为30〜40℃的Na-Ca沸石X的CaO / Al 2 O 3比为0〜30℃，CaO / Al 2 O 3比例为入口处的沸石X为0.55〜0.65，入口温度为40〜50℃，入口区Na-Ca沸石X的CaO / Al2O3比为0.6〜0.75，包含CaO / Al 2 O 3比例为0.5〜1.0的Na-Ca沸石A的吸附器的出气侧或Na-Ca zeo CaO / Al2O3比为0.4〜1.0，高于入口侧的Na-Ca沸石X的CaO / Al 2 O 3比例。

5. 发明授权

US4883565A Process for electrophoretic white and colored enamelling 失效
标题翻译：电泳白色和彩色搪瓷的工艺
公开(公告)号：US4883565A
公开(公告)日：1989-11-28
申请号：US159909
申请日：1988-02-24
申请人： Bruno Hees , Hans Hoffmann
发明人： Bruno Hees , Hans Hoffmann
IPC分类号： C03C8/02 , C23D5/00 , C23D5/02 , C25D13/00 , C25D13/02
CPC分类号： C03C8/02 , C23D5/02
摘要： An improved method comprises electrophoretic application of enamel to a sheet steel substrate by a two layer/single stoving wherein a first or base enamel layer is applied to the sheet steel and a second white or colored enamel layer is applied to the first layer and the first layer has the following properties:(a) a coefficient of expansion below 165.times.10.sup.-7 /K at 0.degree. to 100.degree. C.,(b) a surface tension higher than 300 mN/m,(c) a transformation temperature of from 480.degree. to 520.degree. C., preferably from 490.degree. to 510.degree. C., and(d) a yield value of 15 to 30.
摘要翻译：一种改进的方法包括通过两层/单一烘烤将搪瓷电泳施加到钢板基材上，其中将第一或基础搪瓷层施加到钢板上，并将第二白色或有色搪瓷层施加到第一层和第一层层具有以下特性：（a）在0℃至100℃下的膨胀系数低于165×10 -7 / K，（b）表面张力高于300mN / m，（c）转变温度为480℃ DEG至520℃，优选490℃至510℃，（d）收率值为15至30。

6. 发明申请

US20080229882A1 Process for Purifying Sulphuric Acids 审中-公开
标题翻译：纯化硫酸的方法
公开(公告)号：US20080229882A1
公开(公告)日：2008-09-25
申请号：US10570455
申请日：2004-08-23
申请人： Olaf Halle , Wolfgang Podszun , Bruno Hees , Rheinhold Klipper , Jean-Marc Vesselle
发明人： Olaf Halle , Wolfgang Podszun , Bruno Hees , Rheinhold Klipper , Jean-Marc Vesselle
IPC分类号： C25C1/12 , C22B9/00
CPC分类号： C01B17/904 , B01J45/00 , C01B17/907 , C01B17/908 , C25C1/12
摘要： The present invention relates to a process for purifying sulphuric acids, in particular metal-containing sulphuric acids, characterized in that monodisperse ion exchangers having chelating functional groups are used.
摘要翻译：本发明涉及一种纯化硫酸，特别是含金属硫酸的方法，其特征在于使用具有螯合官能团的单分散离子交换剂。

7. 发明授权

US06649663B1 Process for preparing monodisperse ion exchangers having chelating functional groups and the use thereof 有权
标题翻译：制备具有螯合官能团的单分散离子交换剂的方法及其用途
公开(公告)号：US06649663B1
公开(公告)日：2003-11-18
申请号：US09643049
申请日：2000-08-21
申请人： Reinhold Klipper , Werner Strüver , Ulrich Schnegg , Bruno Hees , Bernhard Lehmann , Holger Lütjens
发明人： Reinhold Klipper , Werner Strüver , Ulrich Schnegg , Bruno Hees , Bernhard Lehmann , Holger Lütjens
IPC分类号： C08F830
CPC分类号： C08F8/00 , B01J45/00 , C02F1/42 , C08F8/12 , C08F8/30 , C08F212/08 , C08F212/00
摘要： The present invention relates to a process for preparing novel, monodisperse ion exchangers having chelating functional groups, and their use for adsorbing metal compounds, in particular, heavy metal compounds and noble metal compounds, and also for extracting alkaline-earth metals from saline solutions from alkali metal chloride electrolysis.
摘要翻译：本发明涉及一种制备具有螯合官能团的新型单分散离子交换剂的方法及其用于吸附金属化合物，特别是重金属化合物和贵金属化合物的用途，并且还用于从盐溶液中提取碱土金属碱金属氯化物电解。

8. 发明授权

US5962358A Binder-free molecular sieve zeolite granules which contain zeolites of the type lithium zeolite A and lithium zeolite X 失效
公开(公告)号：US5962358A
公开(公告)日：1999-10-05
申请号：US969329
申请日：1997-11-13
申请人： Bruno Hees , Lothar Puppe , Gerhard Reiss
发明人： Bruno Hees , Lothar Puppe , Gerhard Reiss
IPC分类号： B01D53/02 , B01D53/04 , B01J20/18 , C01B39/14 , C01B39/22 , B01D53/047 , B01J29/06
CPC分类号： B01J20/183 , Y10S95/902
摘要： The present invention relates to binder-free molecular sieve zeolite granules of lithium zeolite A and lithium zeolite X, a process for preparing these molecular sieve zeolite granules and their use for preparing nitrogen or oxygen from air by pressure swing adsorption.

9. 发明授权

US4734316A Enamellings with heterogeneous structure 失效
标题翻译：具有异质结构的搪瓷
公开(公告)号：US4734316A
公开(公告)日：1988-03-29
申请号：US885939
申请日：1986-07-15
申请人： Bruno Hees , Hans Hoffmann , Matjaz Florjancic , Horst Richter , Karin Ruess , Stauros Smernos , Otto Thaidigsmann
发明人： Bruno Hees , Hans Hoffmann , Matjaz Florjancic , Horst Richter , Karin Ruess , Stauros Smernos , Otto Thaidigsmann
IPC分类号： C03C3/091 , C03C3/085 , C03C8/00 , C03C8/02 , C03C8/16 , C03C17/04 , C23D5/00 , C23D5/04 , C25D13/02 , H05K1/05 , B05D1/00
CPC分类号： C03C8/02 , H05K1/053 , Y10S428/901 , Y10T428/24926
摘要： An article of manufacture useful as the base for an electronic circuit board is a substrate with an enamel layer having a heterogeneous structure containing at least two different phases obtained by applying a homogeneous, alkali-containing enamel powder to the substrate followed by heating at 850.degree. C. to 1,000.degree. C. wherein the enamel power has the composition as follows:______________________________________ Si.sub.O2 40-50% by weight Al.sub.2 O.sub.3 8-15% by weight Na.sub.2 O + K.sub.2 O 4-16% by weight CaO + BaO 25-35% by weight MgO 0-3% by weight B.sub.2 O.sub.3 0-10% by weight. ______________________________________
摘要翻译：可用作电子电路板基底的制品是具有异质结构的搪瓷层，该搪瓷层含有至少两个不同相，其通过将均匀的含碱搪瓷粉末涂覆到基底上，然后在850℃加热其中搪瓷粉末的组成如下：-SiO 2 40-50重量％-Al 2 O 3 8-15重量％-Na 2 O + K 2 O 4-16重量％-CaO + BaO 25-35 重量％-MgO 0-3％（重量）-B2O3 0-10％（重量）。 -

10. 发明申请

US20090158896A1 Monodisperse, Macroporous Chelating Resins in Metal Winning 审中-公开
标题翻译：单分散，大孔螯合树脂在金属胜利
公开(公告)号：US20090158896A1
公开(公告)日：2009-06-25
申请号：US12087632
申请日：2007-01-26
申请人： Duilio Rossoni , Reinhold Klipper , Bruno Hees , Rudolf Wagner , Stefan Neumann , Olaf Halle , Wolfgang Podszun , Michael Schelhaas
发明人： Duilio Rossoni , Reinhold Klipper , Bruno Hees , Rudolf Wagner , Stefan Neumann , Olaf Halle , Wolfgang Podszun , Michael Schelhaas
IPC分类号： C22B11/00 , C22B5/00 , C08F8/32
CPC分类号： C22B3/42 , B01J45/00 , C22B3/24 , C22B23/0453 , Y02P10/234
摘要： The present invention relates to the use of monodisperse, macroporous chelating resins in the recovery of metals in hydrometallurgical processes, in particular in resin-in-pulp processes.
摘要翻译：本发明涉及单分散大孔螯合树脂在湿法冶金方法中回收金属的用途，特别是在树脂 - 纸浆法中。

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