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1. 发明授权

US09353195B2 Emulsifier for emulsion polymerization and emulsion polymerization method using same 有权
标题翻译：用于乳液聚合的乳化剂和使用其的乳液聚合方法
公开(公告)号：US09353195B2
公开(公告)日：2016-05-31
申请号：US14367002
申请日：2012-12-12
申请人： Dai-Ichi Kogyo Seiyaku Co., Ltd.
发明人： Asako Ogasawara , Masayuki Hashimoto
IPC分类号： C08F2/24 , C08G65/26 , C08F212/00 , C08F2/26 , C08F2/30 , C08F212/08 , C08F218/08 , C08F220/14 , C08F220/18 , C09D133/10 , C08F290/14
CPC分类号： C08F2/24 , C08F2/26 , C08F2/30 , C08F212/00 , C08F212/08 , C08F218/08 , C08F220/14 , C08F220/18 , C08F290/142 , C08G65/14 , C08G65/2612 , C08G65/326 , C08G65/327 , C08G2650/58 , C09D133/10 , C08F2220/1825 , C08F2216/145 , C08F220/06 , C08F216/1466 , C08F230/02 , C08F236/10 , C08F236/06
摘要： An emulsifier for emulsion polymerization includes a compound represented by the following general: X=H, —(CH2)a—SO3M, —(CH2)b—COOM, —PO3M2, —P(B)O2M, or —CO—CH2—CH(SO3M)-COOM Y= Z=
摘要翻译：用于乳液聚合的乳化剂包括由以下通式表示的化合物：X = H， - （CH 2）a -SO 3 M， - （CH 2）b -COOM，-PO 3 M 2，-P（B）O 2 M或-CO-CH 2 - CH（SO3M）-COOM Y = Z =

2. 发明申请

US20150183907A1 Ionomer Compositions and Methods of Making and Using Same 审中-公开
标题翻译：离子聚合物组合物和制备和使用方法
公开(公告)号：US20150183907A1
公开(公告)日：2015-07-02
申请号：US14643960
申请日：2015-03-10
申请人： FINA TECHNOLOGY, INC.
发明人： Olga Khabashesku
IPC分类号： C08F212/08 , C08J5/18 , C08L25/08 , C08J9/00 , C08L67/02 , C08L69/00
CPC分类号： C08F212/08 , C08F212/00 , C08J5/18 , C08J9/00 , C08J2325/06 , C08K5/00 , C08K5/0025 , C08K5/098 , C08L25/06 , C08L25/08 , C08L67/02 , C08L69/00 , C08L25/14
摘要： A method comprising contacting at least one metal salt of an organic acid with at least one aromatic compound in a reaction zone under conditions suitable for the formation of a polymer, wherein the metal salt of an organic acid comprises a metal and at least one unsaturated organic acid moiety. A composition comprising polystyrene and a metal salt of cinnamic acid. An article made from a composition comprising polystyrene and a metal salt of cinnamic acid. A composition comprising polystyrene and a salt of a fatty acid. An article made from a composition comprising polystyrene and a salt of a fatty acid.
摘要翻译：一种方法，其包括使有机酸的至少一种金属盐与至少一种芳族化合物在反应区中在适于形成聚合物的条件下接触，其中有机酸的金属盐包含金属和至少一种不饱和有机物酸部分。包含聚苯乙烯和肉桂酸的金属盐的组合物。由包含聚苯乙烯和肉桂酸的金属盐的组合物制成的制品。包含聚苯乙烯和脂肪酸盐的组合物。由包含聚苯乙烯和脂肪酸的盐的组合物制成的制品。

3. 发明申请

US20110144220A1 INTERPOLYMER RESIN PARTICLES 有权
标题翻译：内嵌树脂颗粒
公开(公告)号：US20110144220A1
公开(公告)日：2011-06-16
申请号：US13020962
申请日：2011-02-04
申请人： Steven M. Krupinski
发明人： Steven M. Krupinski
IPC分类号： C08J9/18 , C08F12/08 , C08F10/00
CPC分类号： C08L25/00 , C08F255/00 , C08F255/02 , C08L23/02 , C08L25/06 , C08L2666/06 , C08F212/08 , C08L2666/04 , C08F212/00
摘要： Interpolymer resin particles comprised of 20% to 60% by weight of uncross-linked polyolefin e.g. polyethylene, polypropylene, and from 40% to 80% by weight based on the weight of the particles of a vinyl aromatic monomer, e.g. styrene, that is polymerized in a suspension process to form an interpenetrating network of polyolefin with polymerized vinyl aromatic monomer particles and having a gel content of 0 to 1.5% by weight based on the weight of the particles for improved processability in end-use applications and improved ESCR properties. The interpolymer resin particles have a VICAT softening temperature from about 90° C. to about 115° C., and a melt index from 0.2 to 35.0 g/10 minutes (Condition G). The particles can be mixed with a blowing agent to form extruded foam articles, such as foam board, and can be used in extrusion, injection molding, rotomolding, and thermoforming processes to form a layer, e.g. sheet, film, and as a tie layer in multi-layer structures to bind adjacent layers consisting of incompatible polymers, i.e. polystyrene and polyethylene for improved rigidity in multi-layer structures.
摘要翻译：包含20重量％至60重量％的未交联聚烯烃的共聚物树脂颗粒聚乙烯，聚丙烯，和40重量％至80重量％，基于乙烯基芳族单体颗粒的重量，例如乙烯基芳族聚合物。苯乙烯，其在悬浮方法中聚合以形成具有聚合的乙烯基芳族单体颗粒的聚烯烃的互穿网络，并且基于颗粒的重量具有0至1.5重量％的凝胶含量，以改善最终用途应用中的加工性能，改善ESCR性能。互聚物树脂颗粒的VICAT软化温度为约90℃至约115℃，熔体指数为0.2至35.0g / 10分钟（条件G）。颗粒可以与发泡剂混合以形成挤出的泡沫制品，例如泡沫板，并且可以用于挤出，注射成型，滚塑成型和热成型工艺以形成层，例如泡沫板。片，薄膜和多层结构中的粘结层，以结合由不相容的聚合物组成的相邻层，即聚苯乙烯和聚乙烯，以提高多层结构的刚度。

4. 发明申请

US20110105638A1 POLYFUNCTIONAL VINYL AROMATIC COPOLYMER, PROCESS FOR PRODUCING THE SAME, AND RESIN COMPOSITION 有权
标题翻译：多官能乙烯芳族共聚物，其制备方法和树脂组合物
公开(公告)号：US20110105638A1
公开(公告)日：2011-05-05
申请号：US12736055
申请日：2009-03-03
申请人： Masanao Kawabe , Hiroko Terao , Natsuko Okazaki
发明人： Masanao Kawabe , Hiroko Terao , Natsuko Okazaki
IPC分类号： C08L33/06 , C08G63/66 , C08L35/02 , B05D3/06
CPC分类号： C08F290/124 , C08F212/00 , C08F212/08 , C08F212/12 , C08F212/36 , C08F220/30 , G03F7/033 , C08F4/14 , C08F212/04 , C08F2220/301
摘要： An end-modified soluble polyfunctional vinyl aromatic copolymer, which is improved in heat resistance, thermal stability, solvent solubility, and compatibility with acrylate compounds, and a curable resin composition using the same are disclosed. The end-modified soluble polyfunctional vinyl aromatic copolymer is obtained by allowing a divinyl aromatic compound (a), a monovinyl aromatic compound (b), and an aromatic ether compound (c) to react with each other, and has, at an end, an end group derived from the aromatic ether compound and having an acrylate bond. The copolymer has a number average molecular weight Mn of 500 to 100,000, an introduction amount (c1) of the end group derived from the aromatic ether compound satisfies (c1)≧1.0 (group/molecule), a molar fraction a′ of a structural unit derived from the divinyl aromatic compound and a molar fraction b′ of a structural unit derived from the monovinyl aromatic compound in the copolymer satisfy 0.05≦a′/(a′+b′)≦0.95. Besides, the curable resin composition includes the copolymer and an unsaturated acrylate monomer.
摘要翻译：公开了一种改进的耐热性，热稳定性，溶剂溶解性和与丙烯酸酯化合物的相容性的可溶性多官能乙烯基芳族共聚物，以及使用其的可固化树脂组合物。通过使二乙烯基芳香族化合物（a），单乙烯基芳香族化合物（b）和芳香族醚化合物（c）彼此反应，得到末端改性的可溶性多官能乙烯基芳香族共聚物，衍生自芳族醚化合物并具有丙烯酸酯键的端基。共聚物的数均分子量Mn为500〜100,000，衍生自芳香族醚化合物的端基的导入量（c1）满足（c1）≥1.0（分组/分子），结构式来自二乙烯基芳香族化合物的单元和来自共聚物中的单乙烯基芳香族化合物的结构单元的摩尔分数b'满足0.05＆lt; nlE; a'/（a'+ b'）＆nlE; 0.95。此外，可固化树脂组合物包括共聚物和不饱和丙烯酸酯单体。

5. 发明申请

US20090163668A1 Conjugated Diene Polymer and Process for Production Thereof 有权
标题翻译：共轭二烯聚合物及其制备方法
公开(公告)号：US20090163668A1
公开(公告)日：2009-06-25
申请号：US11992306
申请日：2006-09-19
申请人： Haruo Yamada , Keiichi Toda , Norifusa Ishimura
发明人： Haruo Yamada , Keiichi Toda , Norifusa Ishimura
IPC分类号： C08F8/42
CPC分类号： C08C19/44 , C08F8/42 , C08L19/006 , C08F212/00
摘要： A process for producing a conjugated diene polymer composition, which comprises of polymerizing a conjugated diene compound or a conjugated diene compound and an aromatic vinyl compound in a hydrocarbon solvent in the presence of at least one compound selected from the group consisting of organoalkali metals and organoalkaline earth metals as an initiator and then reacting the active end of the resulting polymer with a low molecular compound represented by the following formula (1) or the following formula (2): (wherein in the formula (1), R1 represents an organic group containing an N atom not adjacent to the N atom of the aminosilyl group and having a molecular weight not greater than 1000, R2 represents a C1-10 hydrocarbon group or a C1-10 hydrocarbon group having no active hydrogen and substituted with an Si, O, N or S atom, R3 and R4 each independently represents a C1-20 alkyl group or aryl group, R5, R6, and R7 each represents a C1-20 alkyl group or aryl group or a C1-12 alkoxy group and g stands for an integer from 1 to 3, and in the formula (2), R8 and R9 each represents a C1-10 hydrocarbon group, a C1-10 hydrocarbon group having no active hydrogen and substituted with an Si, O, N or S atom, or an organic group containing an N atom not adjacent to the N atom of an aminosilyl group and having a molecular weight not greater than 1000, and R3, R4, R5, R6, R7 and g have the same meanings as defined in the formula (1)).
摘要翻译：一种共轭二烯聚合物组合物的制备方法，其包括在烃溶剂中在至少一种选自有机碱金属和有机碱金属的化合物存在下，使共轭二烯化合物或共轭二烯化合物和芳香族乙烯基化合物聚合然后使所得聚合物的活性末端与下式（1）或下式（2）表示的低分子化合物反应：（式（1）中，R 1表示有机基团含有不与氨基甲硅烷基的N原子相邻并且分子量不大于1000的N原子，R2表示不具有活性氢且被Si，O取代的C1-10烃基或C1-10烃基，N或S原子，R 3和R 4各自独立地表示C 1-20烷基或芳基，R 5，R 6和R 7各自表示C 1-20烷基或芳基或C 1-12烷氧基 g，g表示1〜3的整数，式（2）中，R 8，R 9分别表示碳原子数为1〜10的烃基，不具有活性氢并被Si，O， N或S原子，或含有不与氨基甲硅烷基的N原子相邻并且分子量不大于1000的N原子的有机基团，并且R3，R4，R5，R6，R7和g具有与在公式（1）中定义）。

6. 发明申请

US20090018296A1 Norbornene Addition Copolymer and Moldings 审中-公开
标题翻译：降冰片烯加成共聚物和木线条
公开(公告)号：US20090018296A1
公开(公告)日：2009-01-15
申请号：US11886672
申请日：2006-03-24
申请人： Shintaro Ikeda , Kei Nishii , Yasuo Tsunogae
发明人： Shintaro Ikeda , Kei Nishii , Yasuo Tsunogae
IPC分类号： C08F132/08
CPC分类号： C08F210/02 , C08F212/08 , C08F232/08 , C08F212/00 , C08F232/00 , C08F2500/25 , C08F2500/03
摘要： A norbornene addition copolymer obtained by subjecting a norbornene monomer (A), an aromatic vinyl compound (B), and an α-olefin having 2 to 20 cabon atoms (C) to addition copolymerization, the sum of the content of repeating units derived from the norbornene monomer (A) and the content of repeating units derived from the aromatic vinyl compound (B) being 25 to 90 mol % based on the total repeating units, and the content of repeating units derived from the aromatic vinyl compound (B) being 0.55 to 10 (mol) times the content of repeating units derived from the norbornene monomer (A); and a molded article obtained by molding the norbornene addition copolymer. According to the present invention, a norbornene addition copolymer exhibiting excellent transparency, a high refractive index, and a small intrinsic birefringence value, and a molded article obtained by molding the norbornene addition copolymer are provided.
摘要翻译：通过将降冰片烯单体（A），芳族乙烯基化合物（B）和具有2-20个碳原子（C）的α-烯烃进行加成共聚而得到的降冰片烯加成共聚物，来自降冰片烯单体（A）的含量和衍生自芳香族乙烯基化合物（B）的重复单元的含量相对于全部重复单元为25〜90摩尔％，芳香族乙烯基化合物（B）的重复单元的含量为从降冰片烯单体（A）衍生的重复单元的含量为0.55〜10（摩尔）倍; 以及通过将降冰片烯类加成共聚物成型得到的成型品。根据本发明，提供了显示出优异的透明性，高折射率和小的固有双折射值的降冰片烯加成共聚物和通过模塑降冰片烯加成共聚物而获得的模制品。

7. 发明授权

US07132477B2 Powder coating compositions 失效
标题翻译：粉末涂料组合物
公开(公告)号：US07132477B2
公开(公告)日：2006-11-07
申请号：US10928902
申请日：2004-08-27
申请人： Kurt A. Humbert , Karen S. Rechenberg , Edward R. Coleridge , Charles M. Kania , Paul H. Lamers
发明人： Kurt A. Humbert , Karen S. Rechenberg , Edward R. Coleridge , Charles M. Kania , Paul H. Lamers
IPC分类号： C08F8/00
CPC分类号： C09D5/033 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , B05D7/57 , C08F8/00 , C08F210/10 , C08F220/06 , C08F220/10 , C08F220/32 , C08F290/046 , C08G18/6229 , C08G18/6254 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G59/4261 , C08G2150/20 , C08L33/02 , C08L33/04 , C08L33/068 , C08L2312/00 , C09D123/22 , C09D133/062 , C09D133/068 , C09D133/08 , C09D163/00 , Y10T428/31855 , C08L2666/04 , C08F220/00 , C08F2500/26 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F212/00 , C08F222/00 , C08F214/18 , C08F2500/03 , C08F2500/02
摘要： A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material, and a monocarboxylic acid. Multi-component composite coatings, coated substrates, and related methods are also provided.
摘要翻译：一种热固性组合物，其包含可共反应的固体，具有官能团的成膜材料的颗粒混合物，具有至少两个与成膜材料中的官能团反应的官能团的交联剂和一元羧酸。还提供了多组分复合涂层，涂覆的基材和相关方法。

8. 发明申请

US20060241277A1 Method for preparing imide substituted copolymer resin 审中-公开
标题翻译：制备酰亚胺取代共聚物树脂的方法
公开(公告)号：US20060241277A1
公开(公告)日：2006-10-26
申请号：US11324953
申请日：2006-01-04
申请人： Moon-kyoon Chun , Tae-hoon Kim , Chan-hong Lee , Jae-il Roh
发明人： Moon-kyoon Chun , Tae-hoon Kim , Chan-hong Lee , Jae-il Roh
IPC分类号： C08G73/00
CPC分类号： C08F8/32 , C08F212/00
摘要： The present invention relates to a method for preparing an imide substituted copolymer resin comprising the steps of: copolymerization by feeding a mixture of an aromatic vinyl monomer and a vinyl cyanide monomer, a mixture of an unsaturated dicarboxylic anhydride monomer and a solvent, an initiator and a chain transfer agent at once to a copolymerization reactor; and imide substitution by continuously feeding the resultant polymerization solution to an imide substitution reactor while continuously feeding a primary amine. The preparation method according to the present invention is capable of continuously preparing an imide substituted copolymer resin having superior heat resistance and excellent fluidity and improving mechanical property and compatibility with ABS resin by inhibiting formation of aromatic vinyl homopolymer.
摘要翻译：本发明涉及一种制备酰亚胺取代共聚树脂的方法，包括以下步骤：通过将芳族乙烯基单体和乙烯基氰单体的混合物，不饱和二羧酸酐单体和溶剂的混合物，引发剂和一个链转移剂一次到共聚反应器; 并通过将所得聚合溶液连续供给到酰亚胺取代反应器中而连续进料伯胺进行酰亚胺取代。根据本发明的制备方法能够通过抑制芳族乙烯基均聚物的形成，连续地制备具有优异的耐热性和优异的流动性并提高机械性能和与ABS树脂的相容性的酰亚胺取代的共聚物树脂。

9. 发明授权

US07022794B2 Process for producing olefin/aromatic vinyl copolymer 失效
标题翻译：烯烃/芳族乙烯基共聚物的制备方法
公开(公告)号：US07022794B2
公开(公告)日：2006-04-04
申请号：US10477548
申请日：2002-05-15
申请人： Toru Arai , Toshiaki Otsu , Masataka Nakajima
发明人： Toru Arai , Toshiaki Otsu , Masataka Nakajima
IPC分类号： C08F212/02
CPC分类号： C08F212/04 , C08F4/65912 , C08F210/00 , C08F210/02 , C08K5/0091 , C08F4/65927 , C08F212/00 , C08F212/08 , C08F2500/20 , C08F2500/12 , C08F2500/26
摘要： An olefin/aromatic vinyl compound copolymer which is excellent in transparency and which satisfies flexibility and heat resistance simultaneously can be produced by carrying out polymerization in such a manner that at least one of conditions: (a) the polymerization is carried out to an aromatic vinyl compound monomer conversion ratio of at least 50 mol % when the polymerization is completed, and (b) the polymer concentration is at least 10 mass % relative to the polymerization solution when the polymerization is completed, is satisfied, and the olefin partial pressure is changed so that the olefin partial pressure when the polymerization is completed is from 1.3 to 20 times the olefin partial pressure at the initiation of the polymerization.
摘要翻译：透明性优异并且同时满足柔软性和耐热性的烯烃/芳香族乙烯基化合物共聚物可以通过以下方式进行聚合来制造：使以下条件中的至少一个条件：（a）聚合进行芳族乙烯基当聚合完成时，化合物单体转化率至少为50摩尔％，（b）当聚合完成时聚合物浓度相对于聚合溶液为至少10质量％，并且烯烃分压变化使得当聚合完成时的烯烃分压是聚合开始时烯烃分压的1.3至20倍。

10. 发明授权

US07005469B2 Modified rubber, process for producing the same, and composition 有权
公开(公告)号：US07005469B2
公开(公告)日：2006-02-28
申请号：US10257569
申请日：2002-02-14
申请人： Hiroshi Fusamae , Keiichi Toda
发明人： Hiroshi Fusamae , Keiichi Toda
IPC分类号： C08K3/34
CPC分类号： C08F8/00 , C08C19/22 , C08F8/08 , C08F297/00 , C08F212/00
摘要： The invention relates to: a modified rubber having a specific structure modified with a compound having two or more epoxy groups in the molecule; and a process for producing a modified rubber which includes copolymerizing a vinylaromatic hydrocarbon and a conjugated diene by the solution polymerization method using an organolithium as an initiator and modifying the resultant copolymer with a compound having two or more epoxy groups in the molecule. The invention further relates to a modified-rubber composition obtained by compounding a raw rubber containing the modified rubber with silica, and to rubber vibration isolators and a footwear article each obtained from the modified-rubber composition.

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