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1. 发明授权

US08377996B2 Zeolite supported cobalt hybrid Fischer-Tropsch catalyst 有权
标题翻译：沸石负载的钴混合费 - 托催化剂
公开(公告)号：US08377996B2
公开(公告)日：2013-02-19
申请号：US13031341
申请日：2011-02-21
申请人： Charles L. Kibby , Kandaswamy Jothimurugesan
发明人： Charles L. Kibby , Kandaswamy Jothimurugesan
IPC分类号： C07C27/00
CPC分类号： B01J37/16 , B01J29/068 , B01J29/072 , B01J29/44 , B01J29/46 , B01J37/0009 , B01J37/0203 , B01J37/12 , B01J37/14 , B01J37/18 , B01J2229/20 , B01J2229/42 , C10G2/332 , C10G2/334 , C10G2300/703
摘要： A method for forming a catalyst for synthesis gas conversion comprises impregnating a zeolite extrudate using a solution, for example, a substantially non-aqueous solution, comprising a cobalt salt to provide an impregnated zeolite extrudate and activating the impregnated zeolite extrudate by a reduction-oxidation-reduction cycle.
摘要翻译：形成合成气转化催化剂的方法包括使用包含钴盐的溶液例如基本上非水溶液浸渍沸石挤出物，以提供浸渍的沸石挤出物，并通过还原氧化活化浸渍的沸石挤出物 - 减少周期。

2. 发明申请

US20110160316A1 CO2 INJECTION INTO SYNTHESIS FEED GAS TO REDUCE OR ELIMINATE NET CO2 PRODUCTION DURING ISOSYNTHESIS OVER ZnO-Cr2O3 PLUS ZSM-5 HYBRID CATALYST COMBINATIONS 有权
标题翻译：二氧化碳注入合成进料气体，以减少或消除在氧化锌 - 氧化锆 - 二氧化硅混合物ZSM-5混合催化剂组合中的同位素产生的二氧化碳
公开(公告)号：US20110160316A1
公开(公告)日：2011-06-30
申请号：US12981665
申请日：2010-12-30
申请人： Charles L. Kibby
发明人： Charles L. Kibby
IPC分类号： C07C27/00
CPC分类号： C10L1/08 , C10G2/334 , C10G2400/02 , C10L1/06 , Y02P20/582
摘要： A process of form hydrocarbons boiling to the gasoline range and reducing or eliminating net CO2 production during isosynthesis over a ZnO—Cr2O3 plus ZSM-5 catalyst by adding from about 5% to about 15% CO2 to the synthesis gas mixture prior to contact to with catalyst.
摘要翻译：一种将烃类沸腾至汽油范围的方法，通过在接触之前向合成气混合物中加入约5％至约15％的CO 2而在ZnO-Cr 2 O 3加ZSM-5催化剂上的同质合成期间减少或消除净二氧化碳产生的过程催化剂。

3. 发明申请

US20060074134A1 Control of CO2 emissions from a fischer-tropsch facility by use of dual functional syngas conversion 审中-公开
标题翻译：通过双功能合成气转化控制费托设施的二氧化碳排放
公开(公告)号：US20060074134A1
公开(公告)日：2006-04-06
申请号：US11261632
申请日：2005-10-31
申请人： Dennis J. O'Rear , Charles L. Kibby
发明人： Dennis J. O'Rear , Charles L. Kibby
IPC分类号： B01J8/04 , C07C27/26
CPC分类号： C10G2/32 , C10G2300/4043 , Y02P20/132 , Y02P20/582 , Y02P30/446
摘要： CO2 emissions from Fischer-Tropsch facilities are controlled by using multiple reactors. A process for the conversion of syngas using multiple Fischer-Tropsch reactors comprises reacting at least a portion of a first syngas in a first Fischer-Tropsch reactor to form a first hydrocarbonaceous product and a second syngas. The second syngas is mixed with a H2-containing stream to form an adjusted syngas. At least a portion of the adjusted syngas is reacted in a second Fischer-Tropsch reactor to form a second hydrocarbonaceous product and a third syngas. At least a portion of the first and second hydrocarbonaceous products are blended to obtain a blended hydrocarbonaceous product.
摘要翻译：通过使用多个反应器来控制费 - 托设施的CO 2排放。使用多个费 - 托反应器转化合成气的方法包括使第一合成气的至少一部分在第一费 - 托反应器中反应以形成第一烃类产物和第二合成气。将第二合成气与含H2S的流混合以形成调节的合成气。至少一部分经调节的合成气在第二费 - 托反应器中反应以形成第二烃产物和第三合成气。混合至少一部分第一和第二烃类产物以获得混合的含烃产品。

4. 发明授权

US06703429B2 Process for converting synthesis gas into hydrocarbonaceous products 失效
标题翻译：将合成气转化为含烃产品的方法
公开(公告)号：US06703429B2
公开(公告)日：2004-03-09
申请号：US09938069
申请日：2001-08-23
申请人： Dennis J. O'Rear , Charles L. Kibby
发明人： Dennis J. O'Rear , Charles L. Kibby
IPC分类号： C07C2700
CPC分类号： C10G2/32 , C10G2/33 , C10L1/06
摘要： The present invention discloses a process for converting synthesis gas into hydrocarbonaceous products including the steps of: (a) subjecting a first portion of synthesis gas to a dual functional syngas conversion process to form a first effluent comprising a first hydrocarbonaceous product including aromatics and iso-paraffins; (b) subjecting a second portion of synthesis gas to a Fischer-Tropsch synthesis process to form a second effluent comprising a second hydrocarbonaceous product including linear paraffins and linear olefins; and (c) alkylating the linear olefins with the iso-paraffins to produce high octane gasoline range alkylate.
摘要翻译：本发明公开了一种将合成气转化成烃类产物的方法，包括以下步骤：（a）使第一部分合成气进行双功能合成气转化过程，形成第一流出物，其中第一流出物包括第一含烃产物，石蜡（b）使第二部分合成气进行费 - 托合成方法以形成第二流出物，其包含第二含烃产物，包括直链烷烃和直链烯烃; 和（c）用异链烷烃烷基化直链烯烃以产生高辛烷值汽油范围的烷基化物。

5. 发明授权

US06455595B1 Methods for optimizing fischer-tropsch synthesis 失效
标题翻译：优化费 - 托合成的方法
公开(公告)号：US06455595B1
公开(公告)日：2002-09-24
申请号：US09621904
申请日：2000-07-24
申请人： Dennis J. O'Rear , Charles L. Kibby , Georgieanna L. Scheuerman
发明人： Dennis J. O'Rear , Charles L. Kibby , Georgieanna L. Scheuerman
IPC分类号： C07C2700
CPC分类号： G01N31/10 , B01J19/0033 , B01J19/0046 , B01J2219/00695 , B01J2219/00702 , B01J2219/00745 , B01J2219/00747 , C07C1/04 , C10G2/00 , C10G2/32 , C40B30/08 , C40B40/18
摘要： Methods for discovering optimum catalyst systems for the conversion of syngas to higher molecular weight products via Fischer-Tropsch synthesis are disclosed. A combinatorial approach is used to identify combinations of catalyst systems useful for performing the reactions. The combinations of catalyst systems include Fischer-Tropsch catalysts and olefin isomerization catalysts. The method can advantageously be used to generate a database of combinations of catalyst systems and/or reaction conditions that provide various product streams, such that as market conditions vary and/or product requirements change, conditions suitable for forming desired products can be identified with little or no downtime. The catalysts are combined in a logical manner, for example in the form of arrays. The combinations of catalysts can be evaluated using varied reaction conditions, which can provide a) a combinatorial library of product streams and a database including the combination of catalysts and reaction conditions to provide each product stream and/or b) the optimum combination of catalysts and reaction conditions for obtaining a desired product stream.
摘要翻译：公开了通过费 - 托合成发现合成气转化为较高分子量产物的最佳催化剂体系的方法。组合方法用于鉴定用于进行反应的催化剂体系的组合。催化剂体系的组合包括费 - 托催化剂和烯烃异构化催化剂。该方法可以有利地用于产生提供各种产物流的催化剂体系和/或反应条件的组合的数据库，使得随着市场条件变化和/或产品要求的变化，可以很少地识别适合于形成所需产品的条件或不停机。催化剂以逻辑方式组合，例如以阵列的形式组合。可以使用不同的反应条件来评估催化剂的组合，其可以提供a）产物流的组合文库和包括催化剂和反应条件的组合的数据库，以提供每种产物流和/或b）催化剂和用于获得所需产物流的反应条件。

6. 发明授权

US4670414A Activated cobalt catalyst and synthesis gas conversion using same 失效
标题翻译：活化钴催化剂和合成气转化使用相同
公开(公告)号：US4670414A
公开(公告)日：1987-06-02
申请号：US876730
申请日：1986-06-20
申请人： Thaddeus P. Kobylinski , Charles L. Kibby , Richard B. Pannell , Elizabeth L. Eddy
发明人： Thaddeus P. Kobylinski , Charles L. Kibby , Richard B. Pannell , Elizabeth L. Eddy
IPC分类号： B01J23/75 , B01J23/89 , B01J37/14 , B01J37/18 , C07C1/04 , B01J27/20
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/894 , B01J37/14 , B01J37/18 , C07C2521/04 , C07C2523/10 , C07C2523/12 , C07C2523/46 , C07C2523/75
摘要： Synthesis gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon by contacting the synthesis gas under conversion conditions with a catalyst prepared by subjecting a cobalt carbonyl-impregnated alumina or silica support to an activation procedure at a temperature not exceeding 500.degree. C. comprising, in sequence, (A) reduction in hydrogen, (B) oxidation in an oxygen-containing gas, and (C) reduction in hydrogen.
摘要翻译：包含一氧化碳和氢的合成气体通过使转化条件下的合成气与通过在不超过500℃的温度下使羰基浸渍的氧化铝或二氧化硅载体进行活化程序制备的催化剂而转化为液体烃，包括，（A）氢的还原，（B）含氧气体中的氧化，和（C）氢的还原。

7. 发明授权

US4605676A Synthesis gas conversion using ROR-activated catalyst 失效
标题翻译：使用ROR活化催化剂的合成气转化
公开(公告)号：US4605676A
公开(公告)日：1986-08-12
申请号：US734189
申请日：1985-05-15
申请人： Thaddeus P. Kobylinski , Charles L. Kibby , Richard B. Pannell , Elizabeth L. Eddy
发明人： Thaddeus P. Kobylinski , Charles L. Kibby , Richard B. Pannell , Elizabeth L. Eddy
IPC分类号： B01J23/75 , B01J23/83 , B01J23/89 , B01J37/14 , B01J37/18 , C07C1/04
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/83 , B01J23/894 , B01J37/14 , B01J37/18 , C07C2521/04 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/46 , C07C2523/75
摘要： Synthesis gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon by contacting the synthesis gas under conversion conditions with a catalyst prepared by subjecting cobalt or nickel on a refractory metal oxide support to an activation procedure at a temperature below 500.degree. C. comprising, in sequence, (A) reduction in hydrogen, (B) oxidation in an oxygen-containing gas, and (C) reduction in hydrogen.
摘要翻译：包含一氧化碳和氢的合成气体通过使转化条件下的合成气与在难熔金属氧化物载体上的钴或镍在低于500℃的温度下进行活化程序制备的催化剂而转化为液体烃，（A）氢的还原，（B）含氧气体中的氧化，和（C）氢的还原。

8. 发明授权

US4585798A Synthesis gas conversion using ruthenium-promoted cobalt catalyst 失效
标题翻译：使用钌促进钴催化剂的合成气转化
公开(公告)号：US4585798A
公开(公告)日：1986-04-29
申请号：US635911
申请日：1984-07-30
申请人： Harold Beuther , Thaddeus P. Kobylinski , Charles L. Kibby , Richard B. Pannell
发明人： Harold Beuther , Thaddeus P. Kobylinski , Charles L. Kibby , Richard B. Pannell
IPC分类号： B01J23/75 , B01J23/89 , B01J37/14 , B01J37/18 , C07C1/04 , B01J23/40
CPC分类号： C07C1/0445 , B01J23/75 , B01J23/894 , B01J37/14 , B01J37/18 , C07C2521/04 , C07C2523/10 , C07C2523/12 , C07C2523/46 , C07C2523/75
摘要： Synthesis gas comprising carbon monoxide and hydrogen is converted to a liquid hydrocarbon by contacting the synthesis gas under conversion conditions with a supported cobalt-ruthenium catalyst in which the cobalt to ruthenium molar ratio is greater than about 200:1. The catalyst is preferably prepared by using a non-aqueous impregnation solution and using an activation procedure involving reduction, oxidation and reduction.
摘要翻译：包含一氧化碳和氢的合成气体通过在转化条件下与合成气与其中钴与钌摩尔比大于约200:1的负载型钴 - 钌催化剂接触而转化为液态烃。催化剂优选通过使用非水性浸渍溶液并使用包括还原，氧化和还原的活化方法来制备。

9. 发明授权

US08216963B2 Preparation of cobalt-ruthenium fischer-tropsch catalysts 有权
标题翻译：钴 - 钌费 - 托催化剂的制备
公开(公告)号：US08216963B2
公开(公告)日：2012-07-10
申请号：US12649108
申请日：2009-12-29
申请人： Charles L. Kibby , Alfred Haas
发明人： Charles L. Kibby , Alfred Haas
IPC分类号： B01J21/00
CPC分类号： B01J23/75 , B01J23/755 , B01J23/78 , B01J23/83 , B01J23/864 , B01J23/8892 , B01J23/8896 , B01J23/8913 , B01J23/894 , B01J37/0045 , B01J37/0205 , B01J37/035 , B01J37/038 , B01J37/08 , B01J37/12 , B01J37/16 , B01J37/32 , C10G2/332 , C10G2300/705
摘要： A method for forming a cobalt-containing Fischer-Tropsch catalyst involves precipitating a cobalt oxy-hydroxycarbonate species by turbulent mixing, during which a basic solution collides with an acidic solution comprising cobalt. The method further involves depositing the cobalt oxy-hydroxycarbonate species onto a support material to provide a catalyst comprising cobalt and the support material. The support material comprises one or more of alumina, silica, magnesia, titania, zirconia, ceria-zirconia, and magnesium aluminate.
摘要翻译：形成含钴费 - 托催化剂的方法包括通过湍流混合沉淀钴 - 羟基碳酸酯物质，在此期间碱性溶液与包含钴的酸性溶液碰撞。该方法还包括将羟基 - 羟基碳酸钴物质沉积到载体材料上以提供包含钴和载体材料的催化剂。载体材料包括氧化铝，二氧化硅，氧化镁，二氧化钛，氧化锆，二氧化铈 - 氧化锆和铝酸镁中的一种或多种。

10. 发明授权

US08163808B2 Acetylene enhanced conversion of syngas to Fischer-Tropsch hydrocarbon products 失效
标题翻译：乙炔增强合成气转化为费 - 托烃产品
公开(公告)号：US08163808B2
公开(公告)日：2012-04-24
申请号：US12342978
申请日：2008-12-23
申请人： Charles L. Kibby , Minquan Cheng , Yun Lei , David Lawrence Trimm , William L. Schinski
发明人： Charles L. Kibby , Minquan Cheng , Yun Lei , David Lawrence Trimm , William L. Schinski
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , C10G2300/304
摘要： A method is disclosed for converting syngas to Fischer-Tropsch (F-T) hydrocarbon products. A synthesis gas including carbon monoxide and hydrogen gas is provided to a F-T reactor. Also, acetylene is supplied to the F-T reactor. The ratio of the volume of acetylene to the volume of synthesis gas is at least 0.01. The synthesis gas and acetylene are reacted under suitable reaction conditions and in the presence of a catalyst to produce F-T hydrocarbon products. The F-T hydrocarbon products are then recovered from the reactor. The synthesis gas and acetylene may be provided in a combined feed stream or introduced separately into the reactor. The acetylene enhanced syngas conversion in a F-T reactor results in the synthesis of F-T products which have a tighter distribution of intermediate length carbon products than do F-T products synthesized according to conventional methods.
摘要翻译：公开了将合成气转化为费 - 托（F-T）烃产物的方法。将包含一氧化碳和氢气的合成气体提供给F-T反应器。此外，将乙炔供给到F-T反应器。乙炔体积与合成气体积之比至少为0.01。合成气和乙炔在合适的反应条件下和催化剂存在下反应生成F-T烃产物。然后从反应器中回收F-T烃产物。合成气和乙炔可以以组合的进料流提供或分开引入反应器。在F-T反应器中乙炔增强的合成气转化导致F-T产物的合成，其具有与根据常规方法合成的F-T产物相比中等长度碳产物分布更严格的F-T产物。

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