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    • 4. 发明授权
    • Process for adiabatic production of mononitrotoluene
    • 绝热生产单硝基甲苯的方法
    • US08907144B2
    • 2014-12-09
    • US13427688
    • 2012-03-22
    • Michael Gattrell
    • Michael Gattrell
    • C07C205/00C07B41/00C07C27/26
    • C07C201/08C07C205/06
    • A process for continuous adiabatic nitration of toluene to mononitrotoluene (MNT). The process yields a product quality of MNT that is comparable to that obtained by isothermal production. The process uses excess toluene, with the reaction rate being controlled to maintain a residual of 0.003-0.102 wt % nitric acid in the spent acid and an orange to red color of the spent acid. Further process conditions include re-concentrated sulfuric acid at 83 to 99 degrees C. with a concentration of sulfuric acid from 66 to 70.5 wt %. This is mixed with nitric acid to generate a mixed acid with 1.0 to 3.8 wt % nitric acid and toluene is added at a rate of 1.1 to 1.71 moles toluene/mole nitric acid. The reactants are mixed in a reactor with an overall average mixing intensity of 5.8 to 19 W/kg of contained solution.
    • 将甲苯连续绝热硝化成单硝基甲苯(MNT)的方法。 该方法产生与通过等温生产获得的MNT相当的MNT的产品质量。 该方法使用过量的甲苯,其反应速率被控制以维持废酸中的0.003-0.102重量%的硝酸残留量和废酸的橙色至红色。 进一步的工艺条件包括在83至99℃下的浓硫酸,浓度为66至70.5重量%的硫酸。 将其与硝酸混合以产生具有1.0至3.8重量%硝酸的混合酸,并以1.1至1.71摩尔甲苯/摩尔硝酸的速率加入甲苯。 反应物在反应器中混合,总体平均混合强度为5.8至19W / kg的所含溶液。