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    • 3. 发明申请
    • Method to make single-layer pet bottles with high barrier and improved clarity
    • 制造具有高屏障和改善清晰度的单层宠物瓶的方法
    • US20060246245A1
    • 2006-11-02
    • US10569614
    • 2004-08-05
    • Zhenguo LiuSanjay MehtaXiaoyan HuangDavid Schiraldi
    • Zhenguo LiuSanjay MehtaXiaoyan HuangDavid Schiraldi
    • B65D1/02
    • C08K3/24B29B2911/1402B29B2911/14026B29B2911/14033B29B2911/1404B29B2911/14106B29B2911/14133B29B2911/1416B29C49/0005B29C49/06B29K2067/00B65D1/0207C08G63/6886C08K5/098C08K5/42C08L67/02C08L77/06Y10T428/13Y10T428/1352Y10T428/139C08L2666/20
    • The present invention comprises a blend of polyester and a partially aromatic polyamide with an ionic compatibilizer and a cobalt salt. This blend can be processed into a container that has both active and passive oxygen barrier and carbon dioxide barrier properties at an improved color and clarity than containers known in the art. The partially aromatic polyamide is preferably meta-xylylene adipamide. The ionic compatibilizer is preferably 5-sodiumsulfoisophthalic acid or 5-zincsulfoisophthalic acid, or their dialkyl esters such as the dimethyl ester (SIM) and glycol ester (SIPEG). The cobalt salt is selected form the class of cobalt acetate, cobalt carbonate, cobalt chloride, cobalt hydroxide, cobalt naphthenate, cobalt oleate, cobalt linoleate, cobalt octoate, cobalt stearate, cobalt nitrate, cobalt phosphate, cobalt sulfate, cobalt (ethylene glycolate), or mixtures of two or more of these. The partially aromatic polyamide is present in a range from about 1 to about 10 wt. % of said composition. The ionic compatibilizer is present in a range from about 0.1 to about 2.0 mol-% of said composition. The cobalt salt is present in a range from about 20 to about 500 ppm of said composition.
    • 本发明包括聚酯和部分芳族聚酰胺与离子增容剂和钴盐的共混物。 与现有技术中已知的容器相比,该混合物可以加工成具有主动和被动氧气阻隔性和二氧化碳阻隔性能的容器,其颜色和透明度得到改善。 部分芳族聚酰胺优选为间二甲苯基己二酰胺。 离子增容剂优选为5-钠磺基间苯二甲酸或5-锌磺基间苯二甲酸,或其二烷基酯如二甲酯(SIM)和乙二醇酯(SIPEG)。 钴盐选自乙酸钴,碳酸钴,氯化钴,氢氧化钴,环烷酸钴,油酸钴,亚油酸钴,辛酸钴,硬脂酸钴,硝酸钴,磷酸钴,硫酸钴,钴(乙醇酸)等。 ,或这些中的两种或更多种的混合物。 部分芳族聚酰胺的存在量为约1至约10重量%。 %的所述组合物。 离子相容剂的存在量为所述组合物的约0.1至约2.0mol%。 钴盐以所述组合物的约20至约500ppm的范围存在。