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1. 发明授权

US08535564B2 Light emitting device employing luminescent substances with oxyorthosilicate luminophores 有权
标题翻译：使用发光物质的发光器件与氧硅酸发光体
公开(公告)号：US08535564B2
公开(公告)日：2013-09-17
申请号：US12767253
申请日：2010-04-26
申请人： Chung Hoon Lee , Walter Tews , Gundula Roth , Detlef Starick
发明人： Chung Hoon Lee , Walter Tews , Gundula Roth , Detlef Starick
IPC分类号： C09K11/08 , C09K11/59
CPC分类号： C09K11/7792 , H01L33/502 , H01L2224/48091 , H01L2224/73265 , H01L2224/8592 , H01L2924/181 , H01L2924/19107 , H05B33/14 , H01L2924/00014 , H01L2924/00012
摘要： A light emitting device having oxyorthosilicate luminophores is disclosed. The light emitting device includes a light emitting diode and luminescent substances disposed around the light emitting diode, to absorb at least a portion of light emitted from the light emitting diode and emitting light having different wavelength from that of the absorbed light. The luminescent substances have Eu2+-doped silicate luminophores in which solid solutions in the form of mixed phases between alkaline earth metal oxyorthosilicates and rare earth metal oxyorthosilicates are used as base lattices for the Eu2+activation leading to luminescence. The luminescent substances are used as radiation converters to convert a higher-energy primary radiation, for example, ultra violet (UV) radiation or blue light, into a longer-wave visible radiation and are therefore preferably employed in corresponding light-emitting devices.
摘要翻译：公开了一种具有氧硅酸发光体的发光器件。发光器件包括发光二极管和布置在发光二极管周围的发光物质，以吸收从发光二极管发出的光的至少一部分并发射具有与吸收光的波长不同的波长的光。发光物质具有Eu 2+掺杂的硅酸盐发光体，其中使用碱土金属氧化硅酸钙和稀土金属氧化硅酸盐之间的混合相形式的固溶体作为导致发光的Eu 2+激活的基质晶格。发光物质用作辐射转换器以将较高能量的一次辐射（例如紫外线（UV）辐射或蓝光）转换成更长波的可见光，因此优选地应用于相应的发光器件中。

2. 发明申请

US20120001205A1 LIGHT EMITTING DEVICE HAVING STRONTIUM OXYORTHOSILICATE TYPE PHOSPHORS 有权
标题翻译：具有氧化硅酸钠型磷光体的发光装置
公开(公告)号：US20120001205A1
公开(公告)日：2012-01-05
申请号：US12972996
申请日：2010-12-20
申请人： Chung Hoon LEE , Walter TEWS , Gundula ROTH , Detlef STARICK
发明人： Chung Hoon LEE , Walter TEWS , Gundula ROTH , Detlef STARICK
IPC分类号： H01L27/15 , H01L33/50
CPC分类号： C09K11/7734 , H01L33/50 , H01L33/647 , H01L2224/32257 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2924/181 , H01L2924/00014 , H01L2924/00012
摘要： Exemplary embodiments of the present invention relate to light emitting devices including strontium oxyorthosilicate-type phosphors. The light emitting device includes a light emitting diode, which emits light in the UV or visible range, and phosphors disposed around the light emitting diode to absorb light emitted from the light emitting diode and emit light having a different wavelength from the absorbed light. The phosphors include an oxyorthosilicate phosphor having a general formula of Sr3-x-y-zCaxMIIySiO5: Euz with a calcium molar fraction in the range of 0
摘要翻译：本发明的示例性实施例涉及包括氧化硅酸锶型磷光体的发光器件。发光装置包括发射紫外或可见光范围的光的发光二极管，以及设置在发光二极管周围的荧光体，以吸收从发光二极管发出的光并发射具有与吸收光不同的波长的光。磷光体包括具有通式Sr3-x-y-zCaxMIIySiO5：Euz的氧化正硅酸盐荧光体，钙摩尔分数在0

3. 发明授权

US07855393B2 Light emitting device with a non-activated luminescent material 有权
标题翻译：具有非活化发光材料的发光器件
公开(公告)号：US07855393B2
公开(公告)日：2010-12-21
申请号：US12278257
申请日：2007-01-08
申请人： Sven Rösler , Sylke Rösler , Wolfgang Kempfert , Detlef Starick , Peter Pachler , Stefan Tasch , Paul Hartmann , Hans Hoschopf
发明人： Sven Rösler , Sylke Rösler , Wolfgang Kempfert , Detlef Starick , Peter Pachler , Stefan Tasch , Paul Hartmann , Hans Hoschopf
IPC分类号： H01L33/00
CPC分类号： C09K11/7706 , C09K11/02 , C09K11/592 , H01L33/50 , H01L33/56 , H01L2933/0091
摘要： The invention relates to a light emitting device having a radiation emitting element, for example a light emitting diode, and a luminescent material which is able to absorb a part of the radiation sent out by the radiation emitting element and to send out light with a wavelength which is different from the wavelength of the absorbed radiation. The device further has diffusing particles which are able to scatter a part of the radiation sent out by the radiation emitting element, and/or to scatter a part of the light sent out by the luminescent material. The diffusing particles are of non-activated luminescent material, through which production is simplified.
摘要翻译：本发明涉及具有辐射发射元件（例如发光二极管）和能够吸收由辐射发射元件发出的辐射的一部分并发出波长的光的发光材料的发光器件其与吸收的辐射的波长不同。该装置还具有能够散射由辐射发射元件发出的辐射的一部分的散射颗粒和/或散射由发光材料发出的光的一部分。漫射颗粒是非活化的发光材料，通过该方法可以简化生产。

4. 发明授权

US07138660B2 Light emitting device 有权
标题翻译：发光装置
公开(公告)号：US07138660B2
公开(公告)日：2006-11-21
申请号：US11087579
申请日：2005-03-24
申请人： Koichi Ota , Atsuo Hirano , Akihito Ota , Stefan Tasch , Peter Pachler , Gundula Roth , Walter Tews , Wolfgang Kempfert , Detlef Starick
发明人： Koichi Ota , Atsuo Hirano , Akihito Ota , Stefan Tasch , Peter Pachler , Gundula Roth , Walter Tews , Wolfgang Kempfert , Detlef Starick
IPC分类号： H01L27/15
CPC分类号： C09K11/7795 , B82Y20/00 , C09K11/7721 , C09K11/7734 , C09K11/774 , F21Y2105/10 , F21Y2115/10 , G02B6/0036 , G02B6/0073 , H01L25/0753 , H01L33/06 , H01L33/32 , H01L33/502 , H01L33/507 , H01L2224/16145 , H01L2224/32245 , H01L2224/32257 , H01L2224/45139 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2224/48257 , H01L2224/49107 , H01L2224/73265 , H01L2924/00011 , H01L2924/181 , H01L2933/0091 , Y02B20/181 , H01L2924/00014 , H01L2924/00 , H01L2924/01049 , H01L2924/00012
摘要： The light emitting device has a light emitting diode which is made of a nitride semiconductor and a phosphor which absorbs a part of lights emitted from the light emitting diode and emits different lights with wavelengths other than those of the absorbed lights. The phosphor is made of alkaline earth metal silicate fluorescent material activated with europium.
摘要翻译：发光装置具有由氮化物半导体构成的发光二极管和吸收从发光二极管发出的一部分光并发出不同于吸收光的波长的不同光的荧光体。磷光体由铕活化的碱土金属硅酸盐荧光材料制成。

5. 发明授权

US07067071B1 Zinc sulfide electroluminophores and method for production thereof 有权
标题翻译：硫化锌电致发光体及其制造方法
公开(公告)号：US07067071B1
公开(公告)日：2006-06-27
申请号：US09869956
申请日：2000-11-09
申请人： Frank Kappe , Benedikt Ahlers , Arnim Franz-Burgholz , Hans-Jürgen Limburg , Detlef Starick , Monika Voh
发明人： Frank Kappe , Benedikt Ahlers , Arnim Franz-Burgholz , Hans-Jürgen Limburg , Detlef Starick , Monika Voh
IPC分类号： C09K11/56 , C09K11/58
CPC分类号： C09K11/025 , C09K11/565 , C09K11/584 , Y10T428/2993
摘要： Zinc sulfide electroluminophores are prepared from solutions of zinc salts with hydrogen sulfide. The zinc sulfide compounds are mixed with activator and coactivator compounds to produce luminophores, and the mixtures are fired in the presence of fixing agents. These fired materials are then treated in an acid bath, washed, neutralized, and optionally filtered and dried.
摘要翻译：硫化锌电解液由锌盐与硫化氢的溶液制成。将硫化锌化合物与活化剂和辅助剂化合物混合以产生发光体，并且在固定剂存在下烧结混合物。然后将这些烧制的材料在酸浴中处理，洗涤，中和，任选地过滤并干燥。

6. 发明授权

US08945421B2 Surface-modified silicate luminophores 有权
标题翻译：表面改性硅酸盐发光体
公开(公告)号：US08945421B2
公开(公告)日：2015-02-03
申请号：US13184271
申请日：2011-07-15
申请人： Chung Hoon Lee , Walter Tews , Gundula Roth , Detlef Starick
发明人： Chung Hoon Lee , Walter Tews , Gundula Roth , Detlef Starick
IPC分类号： H01L33/50 , C09K11/80 , C09K11/79 , C09K11/59 , C09K11/77
CPC分类号： C09K11/7734 , C09K11/025 , H01L33/501 , H01L33/502 , H01L2224/48091 , H01L2224/48247 , H01L2224/73265 , H01L2224/8592 , H01L2924/181 , H01L2924/19107 , Y02B20/181 , Y10T428/2991 , Y10T428/2993 , Y10T428/2998 , H01L2924/00014 , H01L2924/00012
摘要： A surface-modified silicate luminophore includes a silicate luminophore and a coating includes at least one of (a) a fluorinated coating including a fluorinated inorganic agent, a fluorinated organic agent, or a combination of fluorinated inorganic and organic agents, the fluorinated coating generating hydrophobic surface sites and (b) a combination of the fluorinated coating and at least one moisture barrier layer. The moisture barrier layer includes MgO, Al2O3, Y2O3, La2O3, Gd2O3, Lu2O3, and SiO2 or the corresponding precursors, and the coating is disposed on the surface of the silicate luminophore.
摘要翻译：表面改性硅酸盐发光体包括硅酸盐发光体，涂层包括（a）包含氟化无机物，氟化有机物或氟化无机和有机物的组合的氟化涂层中的至少一种，氟化涂层产生疏水性表面部位和（b）氟化涂层和至少一个防潮层的组合。防潮层包括MgO，Al 2 O 3，Y 2 O 3，La 2 O 3，Gd 2 O 3，Lu 2 O 3和SiO 2或相应的前体，并且涂层设置在硅酸盐发光体的表面上。

7. 发明申请

US20120181481A1 STRONTIUM OXYORTHOSILICATE PHOSPHORS HAVING IMPROVED STABILITY UNDER A RADIATION LOAD AND RESISTANCE TO ATMOSPHERIC HUMIDITY 有权
标题翻译：具有辐射负载和抵抗大气湿度的改进稳定性的锑氧化硅酸盐磷酸盐
公开(公告)号：US20120181481A1
公开(公告)日：2012-07-19
申请号：US13434529
申请日：2012-03-29
申请人： Chung Hoon LEE , Walter TEWS , Gundula ROTH , Detlef STARICK
发明人： Chung Hoon LEE , Walter TEWS , Gundula ROTH , Detlef STARICK
IPC分类号： C09K11/79
CPC分类号： C09K11/7734 , H05B33/14
摘要： Exemplary embodiments of the present invention relate to inorganic phosphors based on silicate compounds having improved stability under a resulting radiation load and resistance to atmospheric humidity, which are capable of converting higher-energy excitation radiation, i.e. ultraviolet (UV) or blue light, with high efficiency into a longer-wavelength radiation which may be in the visible spectral range. A calcium molar fraction x having a value between 0 and 0.05 is added to a silicate phosphor having the general formula Sr3-x-y-zCaxMIIySiO5:Euz.
摘要翻译：本发明的示例性实施方案涉及基于硅酸盐化合物的无机磷光体，其在所得到的辐射负载和耐大气湿度下具有改进的稳定性，其能够将高能激发辐射即紫外（UV）或蓝光转化为高效率变成可能在可见光谱范围内的较长波长辐射。向具有通式Sr3-x-y-zCaxMIIySiO5：Euz的硅酸盐荧光体中加入0至0.05的值的钙摩尔分数x。

8. 发明申请

US20110147662A1 STRONTIUM OXYORTHOSILICATE PHOSPHORS HAVING IMPROVED STABILITY UNDER A RADIATION LOAD AND RESISTANCE TO ATMOSPHERIC HUMIDITY 有权
标题翻译：具有辐射负载和抵抗大气湿度的改进稳定性的锑氧化硅酸盐磷酸盐
公开(公告)号：US20110147662A1
公开(公告)日：2011-06-23
申请号：US12879361
申请日：2010-09-10
申请人： Chung Hoon LEE , Walter TEWS , Gundula ROTH , Detlef STARICK
发明人： Chung Hoon LEE , Walter TEWS , Gundula ROTH , Detlef STARICK
IPC分类号： C09K11/79 , C09K11/54 , C09K11/81
CPC分类号： C09K11/7734 , H05B33/14
摘要： Exemplary embodiments of the present invention relate to inorganic phosphors based on silicate compounds having improved stability under a resulting radiation load and resistance to atmospheric humidity, which are capable of converting higher-energy excitation radiation, i.e. ultraviolet (UV) or blue light, with high efficiency into a longer-wavelength radiation which may be in the visible spectral range. A calcium molar fraction x having a value between 0 and 0.05 is added to a silicate phosphor having the general formula Sr3-x-y-zCaxMIIySiO5:Euz.
摘要翻译：本发明的示例性实施方案涉及基于硅酸盐化合物的无机磷光体，其在所得到的辐射负载和耐大气湿度下具有改进的稳定性，其能够将高能激发辐射即紫外（UV）或蓝光转化为高效率变成可能在可见光谱范围内的较长波长辐射。向具有通式Sr3-x-y-zCaxMIIySiO5：Euz的硅酸盐荧光体中加入0至0.05的值的钙摩尔分数x。

9. 发明申请

US20100288972A1 RARE-EARTH DOPED ALKALINE-EARTH SILICON NITRIDE PHOSPHOR, METHOD FOR PRODUCING AND RADIATION CONVERTING DEVICE COMPRISING SUCH A PHOSPHOR 有权
标题翻译：稀土碱性碱土金属氮化硅磷酸盐，包含这种磷酸盐的生产和辐射转换装置的方法
公开(公告)号：US20100288972A1
公开(公告)日：2010-11-18
申请号：US12738213
申请日：2008-10-14
申请人： Sven Roesler , Sylke Rösler , Detlef STARICK , Sven Rösler , Anne Charlotte Antoinette Delsing , Cheng-Jun Duan
发明人： Sven Roesler , Sylke Rösler , Detlef STARICK , Sven Rösler , Anne Charlotte Antoinette Delsing , Cheng-Jun Duan
IPC分类号： C09K11/59
CPC分类号： C09K11/0883 , C09K11/773 , C09K11/7734
摘要： The invention relates to a method of manufacturing a rare-earth doped alkaline-earth silicon nitride phosphor of a stoichiometric composition. Said method comprising the step of selecting one or more compounds each comprising at least one element of the group comprising the rare-earth elements (RE), the alkaline-earth elements (AE), silicon (Si) and nitrogen (N) and together comprising the necessary elements to form the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE). The method further comprises the step of bringing the compounds at an elevated temperature in reaction for forming the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE). In such a method normally a small amount of oxygen, whether intentionally or not-intentionally added, will be incorporated in the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE). According to the invention the creation of defects by formation of a non-stoichiometric oxygen containing phosphor is at least partly prevented by partly substituting for the ions (AE, Si, N) of the alkaline-earth silicon nitride phosphor (AE2Si5N8:RE) suitable further elements of the periodic system by which vacancies are created, filled or annihilated resulting in the formation of a modified alkaline-earth silicon nitride phosphor (AE2Si5N8:RE) having a stoichiometric composition. In this way a modified phosphor is obtained having excellent and stable optical properties. The invention further relates to a modified phosphor obtainable by the above-mentioned method and a radiation converting device comprising such a phosphor.
摘要翻译：本发明涉及一种制备化学计量组成的稀土掺杂碱土金属氮化硅荧光体的方法。所述方法包括选择一种或多种化合物的步骤，每种化合物包含稀土元素（RE），碱土元素（AE），硅（Si）和氮（N）的组中的至少一种元素并在一起包括形成稀土掺杂的碱土金属氮化硅荧光体（AE2Si5N8：RE）所必需的元素。该方法还包括使化合物在升高的温度下反应以形成稀土掺杂的碱土金属氮化硅荧光体（AE2Si5N8：RE）的步骤。在这种方法中，通常将少量的氧，无论有意或没有有意添加，都将被掺入稀土掺杂的碱土金属氮化硅荧光体（AE2Si5N8：RE）中。根据本发明，通过部分代替碱土金属氮化硅荧光体（AE2Si5N8：RE）中的离子（AE2Si5N8：RE），至少部分地替代了通过形成非化学计量的含氧荧光体来产生缺陷，产生空位的周期性系统的另外的元素，填充或消除，导致形成具有化学计量组成的改性碱土金属氮化硅荧光体（AE2Si5N8：RE）。以这种方式获得具有优异且稳定的光学性质的改性荧光体。本发明还涉及通过上述方法获得的改性荧光体和包含这种荧光体的辐射转换装置。

10. 发明申请

US20080251764A1 Carbidonitridosilicate Luminescent Substance 有权
标题翻译：碳二碳酸硅酸盐发光物质
公开(公告)号：US20080251764A1
公开(公告)日：2008-10-16
申请号：US12065480
申请日：2006-08-29
申请人： Detlef Starick , Sven Rosler , Sylke Rosler , Hubertus Theresia Hintzen , Yuan Qiang Li
发明人： Detlef Starick , Sven Rosler , Sylke Rosler , Hubertus Theresia Hintzen , Yuan Qiang Li
IPC分类号： C09K11/79 , C09K11/08
CPC分类号： C04B35/584 , C04B35/597 , C04B2235/3224 , C04B2235/3225 , C04B2235/3229 , C04B2235/3856 , C04B2235/40 , C09K11/0883 , C09K11/7721 , C09K11/7749 , C09K11/7774 , C09K11/7792 , H05B33/14 , Y02B20/181
摘要： The invention relates to a luminescent substance consisting of a doped host lattice which absorbs at least one part of exciting radiation when it is excited by a high-energy radiation, thereby releasing an energy-poor emission radiation. The host lattice is embodied in the form of a carbidonitridosilicate-based compound. An illuminant which is used for producing white light and comprises a light emitting element and said luminescent substance are also disclosed.
摘要翻译：本发明涉及一种由掺杂的主晶格组成的发光物质，其在被高能辐射激发时吸收至少一部分激发辐射，从而释放出能量不足的发射辐射。主晶格体现为基于碳矽基硅酸盐的化合物的形式。还公开了用于产生白光并包括发光元件和所述发光物质的光源。

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