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1. 发明授权

US08530544B2 Modification of the surface chemistry of macromolecular species in the presence of a conjugated guanidine 有权
标题翻译：在共轭胍存在下改性大分子物质的表面化学性质
公开(公告)号：US08530544B2
公开(公告)日：2013-09-10
申请号：US12736293
申请日：2009-03-27
申请人： Vincent Gaud , Fabien Rouge
发明人： Vincent Gaud , Fabien Rouge
IPC分类号： B01J8/02 , C01B21/06 , C08F283/00 , C08F283/04 , C08F290/14 , C08G18/00 , C08G18/08 , C08G18/18 , C08G63/48 , C08G63/91 , C08G65/32 , C08G73/02 , C08K9/00 , C08L67/00 , C08L71/00 , C08L71/02 , C08L75/00 , C08L83/00
CPC分类号： C08J7/16 , B01J31/0251
摘要： The present invention relates to a method for preparing macromolecular species with a modified surface, comprising a step (e) in which macromolecular species (M), initially carrying —OH and/or —SH functions, are brought into contact with: a catalyst (C) carrying at least one conjugated guanidine function; and reactive species (E), comprising reactive groups including: (i) at least one group including an a,b-unsaturated carbonyl group C═C—C═O and/or an a,b-unsaturated thiocarbonyl group C═C—C═S; and/or (ii) at least one heterocyclic group comprising from 3 to 5 ring members, said group being selected from cyclic ethers, cyclic thioethers and aziridine rings; and/or (iii) at least one group selected from isocyanate —N═C═O or thioisocyanate —N═C═S groups, and trivalent groups of formula >C═CZ—, where Z is an electron-withdrawing group. The invention also relates to the macromolecular species with a modified surface that are obtained in this context.
摘要翻译：本发明涉及一种制备具有改性表面的高分子物质的方法，其包括步骤（e），其中最初携带-OH和/或-SH官能团的高分子物质（M）与下列物质接触：催化剂 C）携带至少一种共轭胍功能; 和反应性物质（E），其包含反应性基团，包括：（i）至少一个包括a，b不饱和羰基C = C-C = O和/或a，b-不饱和硫代羰基C = C-C = S的基团; 和/或（ii）至少一个包含3至5个环成员的杂环基，所述基团选自环醚，环硫醚和氮丙啶环; 和/或（iii）选自异氰酸酯-N = C = O或硫代异氰酸酯-N = C = S基团中的至少一个基团和式C = CZ-的三价基团，其中Z为吸电子基团。本发明还涉及在本文中获得的具有改性表面的大分子物质。

2. 发明授权

US10283660B2 Photovoltaic devices comprising an anti-reflective layer containing dispersed objects having areas with different refractive indices 有权
$Photovoltaic devices comprising an anti-reflective layer containing dispersed objects having areas with different refractive indices$
公开(公告)号：US10283660B2
公开(公告)日：2019-05-07
申请号：US13636559
申请日：2011-03-23
申请人： Vincent Gaud , Mélanie Louarn , Fabien Rouge
发明人： Vincent Gaud , Mélanie Louarn , Fabien Rouge
IPC分类号： H01L31/048 , C09D5/00 , C23C18/12 , G02B1/11 , C09D7/62
摘要： The present invention relates to photovoltaic devices which comprise: a semiconducting material able to ensure a photovoltaic effect when it is subject to electromagnetic radiation; a anti-reflective layer, transparent towards said electromagnetic radiation ensuring the photovoltaic effect, this anti-reflective layer containing, in the dispersed state, objects with dimensions of less than 5 microns, preferably less than 2 microns, said objects comprising at least two areas consisting of two different substrates, transparent towards said electromagnetic radiation and having distinct refraction indices, i.e.: a core having a first refractive index nC; and a layer surrounding the core, a so-called crust, having a second refractive index nE, distinct from the refractive index nC of the core, the ratio of the dimensions of the core to the dimensions of the core/crust assembly being comprised 1:1.5 and 1:5.

3. 发明申请

US20120038989A1 ANTIREFLECTION COATINGS INCLUDING SCATTERED OBJECTS HAVING TWO SEPARATE RANGES WITH SEPARATE REFRACTION INDICES 审中-公开
标题翻译：抗反射涂层，包括具有单独折射率指示的两个单独范围的散射物体
公开(公告)号：US20120038989A1
公开(公告)日：2012-02-16
申请号：US13120246
申请日：2009-09-23
申请人： Melanie Louarn , Vincent Gaud , Fabien Rouge
发明人： Melanie Louarn , Vincent Gaud , Fabien Rouge
IPC分类号： G02B1/11 , B05D5/06
CPC分类号： G02B1/111
摘要： The present invention relates to a surface treatment method with which anti-reflection properties toward electromagnetic radiation may be imparted to the surface of a substrate. A transparent coating toward said electromagnetic radiation is deposited on said surface, which contains in the dispersed state within said layer, objects with dimensions of less than 5 microns comprising: a core with a first refractive index nC, and a layer, a so-called skin, surrounding the core, having a second refractive index nE distinct from the refractive index nC of the core wherein the ratio of the dimensions of the core to the dimensions of the core/skin assembly is comprised between 1:15 and 1:5. The invention also relates to the coated substrates obtained according to this method.
摘要翻译：本发明涉及一种表面处理方法，其可以赋予基板表面电磁辐射的抗反射性能。朝向所述电磁辐射的透明涂层沉积在所述表面上，所述表面在所述层内包含处于分散状态的物体，其尺寸小于5微米，包括：具有第一折射率nC的芯和所谓的皮肤，围绕芯部，具有与芯部的折射率nC不同的第二折射率nE，其中芯部的尺寸与芯/皮肤组件的尺寸的比率在1:15至1:5之间。本发明还涉及根据该方法获得的涂覆基材。

4. 发明申请

US20130061905A1 Photovoltaic Devices Comprising an Anti-Reflective Layer Containing Dispersed Objects Having Areas with Different Refractive Indices 审中-公开
$Photovoltaic Devices Comprising an Anti-Reflective Layer Containing Dispersed Objects Having Areas with Different Refractive Indices$
标题翻译：包含具有不同折射率指示区域的分散对象的防反射层的光伏器件
公开(公告)号：US20130061905A1
公开(公告)日：2013-03-14
申请号：US13636559
申请日：2011-03-23
申请人： Vincent Gaud , Mélanie Louarn , Fabien Rouge
发明人： Vincent Gaud , Mélanie Louarn , Fabien Rouge
IPC分类号： H01L31/0232 , H01L31/042
CPC分类号： G02B1/11 , C09D5/006 , C09D7/62 , C23C18/1254 , C23C18/127 , H01L31/048 , Y02E10/50
摘要： The present invention relates to photovoltaic devices which comprise: a semiconducting material able to ensure a photovoltaic effect when it is subject to electromagnetic radiation; a anti-reflective layer, transparent towards said electromagnetic radiation ensuring the photovoltaic effect, this anti-reflective layer containing, in the dispersed state, objects with dimensions of less than 5 microns, preferably less than 2 microns, said objects comprising at least two areas consisting of two different substrates, transparent towards said electromagnetic radiation and having distinct refraction indices, i.e.: a core having a first refractive index nC; and a layer surrounding the core, a so-called crust, having a second refractive index nE, distinct from the refractive index nC of the core, the ratio of the dimensions of the core to the dimensions of the core/crust assembly being comprised 1:1.5 and 1:5.
摘要翻译：本发明涉及光伏器件，其包括：半导体材料，当其经受电磁辐射时能够确保光伏效应; 所述抗反射层对于确保光伏效应的所述电磁辐射是透明的，该抗反射层在分散状态下包含尺寸小于5微米，优选小于2微米的物体，所述物体包括至少两个区域由两个不同的衬底组成，对所述电磁辐射透明并具有不同的折射指数，即具有第一折射率nC的芯; 以及围绕芯的层，所谓的外壳，具有与芯的折射率nC不同的第二折射率nE，芯/尺寸与芯/外壳组合的尺寸之比为1 ：1.5和1：5。

5. 发明申请

US20110015304A1 Modification of the Surface Chemistry of Macromolecular Species in the Presence of a Conjugated Guanidine 有权
标题翻译：在共轭胍存在下大分子物种的表面化学改性
公开(公告)号：US20110015304A1
公开(公告)日：2011-01-20
申请号：US12736293
申请日：2009-03-27
申请人： Vincent Gaud , Fabien Rouge
发明人： Vincent Gaud , Fabien Rouge
IPC分类号： C08G63/06 , C08F8/30 , C08G75/04 , C08L75/04 , C08L67/00
CPC分类号： C08J7/16 , B01J31/0251
摘要： The present invention relates to a method for preparing macromolecular species with a modified surface, comprising a step (e) in which macromolecular species (M), initially carrying —OH and/or —SH functions, are brought into contact with: a catalyst (C) carrying at least one conjugated guanidine function; and reactive species (E), comprising reactive groups including: (i) at least one group including an a,b-unsaturated carbonyl group C═C—C═O and/or an a,b-unsaturated thiocarbonyl group C═C—C═S; and/or (ii) at least one heterocyclic group comprising from 3 to 5 ring members, said group being selected from cyclic ethers, cyclic thioethers and aziridine rings; and/or (iii) at least one group selected from isocyanate —N═C═O or thioisocyanate —N═C═S groups, and trivalent groups of formula >C═CZ—, where Z is an electron-withdrawing group. The invention also relates to the macromolecular species with a modified surface that are obtained in this context.
摘要翻译：本发明涉及一种制备具有改性表面的高分子物质的方法，其包括步骤（e），其中最初携带-OH和/或-SH官能团的高分子物质（M）与下列物质接触：催化剂（ C）携带至少一种共轭胍功能; 和反应性物质（E），其包含反应性基团，包括：（i）至少一个包含a，b不饱和羰基C = C-C = O和/或a，b-不饱和硫代羰基C = C- C = S 和/或（ii）至少一个包含3至5个环成员的杂环基，所述基团选自环醚，环硫醚和氮丙啶环; 和/或（iii）选自异氰酸酯-N = C = O或硫代异氰酸酯-N = C = S基团中的至少一个基团，以及式为C = CZ-的三价基团，其中Z为吸电子基团。本发明还涉及在本文中获得的具有改性表面的大分子物质。

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