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1. 发明授权

US08471019B2 Quinoid systems as organic semiconductors 有权
标题翻译：醌类系统作为有机半导体
公开(公告)号：US08471019B2
公开(公告)日：2013-06-25
申请号：US12226182
申请日：2007-04-04
申请人： Ulrich Berens , Arno Stassen , Beat Schmidhalter , Wolfgang Kalb , Frank Bienewald
发明人： Ulrich Berens , Arno Stassen , Beat Schmidhalter , Wolfgang Kalb , Frank Bienewald
IPC分类号： H01L51/00 , C07D409/14 , C07D211/18 , C07D319/00 , C07D413/14
CPC分类号： H01L51/0074 , C07D493/04 , C07D493/22 , C07D495/04 , H01L51/0055 , H01L51/0073 , H01L51/0529 , H01L51/0533 , H01L51/0545 , Y02E10/549
摘要： A semiconducting layer comprising a non-polymeric quinoid heteroacene compound of the formula (I) wherein X stands for O, S or NR, each of R, R1, R2, R3, R4, R5, R6, R7, R8 being independently selected from hydrogen and an organic residue, or 2 or more thereof together forming one or more annealed rings, which may be substituted or unsubstituted, carbocyclic or helerocyclic, aromatic, quinoid or aliphatic, may be used e.g. for the manufacture of a diode, an organic field effect transistor, an organic thin film transistor, or a device containing a diode and/or an organic field effect transistor and/or organic thin film transistor.
摘要翻译：一种半导体层，其包含式（I）的非聚合醌型杂炔化合物，其中X代表O，S或NR，R，R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8中的每一个独立地选自氢和有机残基，或其中2个或更多个一起形成可以是取代或未取代的碳环或环丙基，芳族，醌型或脂族的一个或多个退火环，例如用于制造二极管，有机场效应晶体管，有机薄膜晶体管或包含二极管和/或有机场效应晶体管和/或有机薄膜晶体管的器件。

2. 发明授权

US08044058B2 Merocyanine derivatives 有权
标题翻译：梅花菁衍生物
公开(公告)号：US08044058B2
公开(公告)日：2011-10-25
申请号：US12715839
申请日：2010-03-02
申请人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jürg Haase
发明人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jürg Haase
IPC分类号： A61K31/517 , A61K31/445 , A61K31/16
CPC分类号： A61K8/498 , A61K8/4913 , A61K8/494 , A61Q17/04
摘要： Disclosed is the use of merocyanine derivatives of formula Q is hydrogen; C1-C22alkyl; —OH; —OR7; —NR7R8; or —N═R9; R1 is hydrogen; C1-C22alkyl; —OR7, —SR7; —NR7R8; C1-C22alkyl; C2-C12 alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl, C2-C11heteroaralkyl; C6-C10aryl; or C1-C9heteroaryl; R4 is cyano; COR7, COOR7; CONR7R8; SO2(C6-C12)aryl; C2-C12alk-1-enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl; C3-C5heterocycloalkyl; C6-C10aryl; or C1-C9heteroaryl; R5 is —COR7; —COOR7; —OR7; —SR7, —NHR7, —NR7R8; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12alkylphenyl; C1-C12alkoxy-C6-C10aryl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C3-C12cycloheteroalkyl; C6-C10aryl; C1-C12alkoxy-C6-C10aryl; or C1-C9heteroaryl; R6 is hydrogen; C1-C22alkyl; C1-C22alkoxy; or COR7; R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; —(CH2)tCOOH; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; C1-C9heteroaryl; Si—R10R11R12; Si(OR10)(OR11)(OR12); SiR10(OR11)(OR12); SiR10R11(OR12); —(CH2)u—O—(CH2)v—SiR10R11R12; or a radical X-Sil; t, u and v, independently from each other are a number from 1 to 5; R9 is a (C1-C6)alkylidene radical; R10, R11, R12 independently form each other are C1-C22alkyl; X is a linker; for protecting of human hair and skin against the damaging effect of UV radiation.
摘要翻译：披露式Q的部花青衍生物的用途是氢; C 1 -C 22烷基; -哦; -OR7; -NR7R8; 或-N = R9; R1是氢; C 1 -C 22烷基; -OR7，-SR7; -NR7R8; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; C7-C12芳烷基; C 1 -C 12杂烷基，C 2 -C 11杂芳烷基; C6-C10芳基; 或C 1 -C 9杂芳基; R4是氰基; COR7，COOR7; CONR7R8; SO2（C6-C12）芳基; C2-C12烷-1-烯基; C 3 -C 12环烯-1-烯基; C2-C12alk-1-inyl; C 2 -C 12杂烷基; C3-C5杂环烷基; C6-C10芳基; 或C 1 -C 9杂芳基; R5为-COR7; -COOR7; -OR7; -SR 7，-NHR 7，-NR 7 R 8; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; C7-C12芳烷基; C 1 -C 12烷基苯基; C 1 -C 12烷氧基-C 6 -C 10芳基; C 1 -C 12杂烷基; C 2 -C 11杂芳烷基; C 3 -C 12环杂烷基; C6-C10芳基; C 1 -C 12烷氧基-C 6 -C 10芳基; 或C 1 -C 9杂芳基; R6是氢; C 1 -C 22烷基; C1-C22烷氧基; 或COR7; R 7和R 8彼此独立地是氢; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; - （CH 2）t COOH; C7-C12芳烷基; C 1 -C 12杂烷基; C 2 -C 11杂芳烷基; C6-C10芳基; C1-C9杂芳基; Si-R10R11R12; Si（OR10）（OR11）（OR12）; SiR10（OR11）（OR12）; SiR10R11（OR12）; - （CH 2）u -O-（CH 2）v -SiR 10 R 11 R 12; 或基团X-Sil; t，u和v彼此独立地为1至5的数; R9是（C1-C6）亚烷基; R 10，R 11，R 12彼此独立地为C 1 -C 22烷基; X是一个连接子; 用于保护人的头发和皮肤免受紫外线辐射的破坏作用。

3. 发明申请

US20100297405A1 KETOPYRROLES AS ORGANIC SEMICONDUCTORS 有权
标题翻译：作为有机半导体的KETOPYRROLOL
公开(公告)号：US20100297405A1
公开(公告)日：2010-11-25
申请号：US12680920
申请日：2008-10-16
申请人： Jean-Charles Flores , Ulrich Berens , Frank Bienewald , Hans Jurg Kirner , Mathieu G.R. Turbiez
发明人： Jean-Charles Flores , Ulrich Berens , Frank Bienewald , Hans Jurg Kirner , Mathieu G.R. Turbiez
IPC分类号： C07D403/04 , C08F226/06 , B32B3/10
CPC分类号： H01L51/0036 , C08G61/123 , C08G61/124 , H01L51/0043 , H01L51/0545 , Y02E10/549 , Y10T428/24802
摘要： Monomeric or polymeric compounds comprising at least one moiety of the formula (Ia) wherein X is CR, where R is H or a substituent as defined in claim 1, or is another ketopyrrole moiety e.g. of the formula (1b) or (1c) with this moiety and all other symbols are as defined in claim 1, show good solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：包含至少一个式（Ia）部分的单体或聚合化合物，其中X是CR，其中R是H或如权利要求1所定义的取代基，或者是另一个酮基吡咯部分。的式（1b）或（1c）与所有其它符号如权利要求1中所定义，在有机溶剂中表现出良好的溶解性和优异的成膜性能。此外，当根据本发明的聚合物用于半导体器件或有机光伏（PV）器件时，可以观察到高的能量转换效率，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性太阳能电池）。

4. 发明申请

US20080130474A1 Optical Recording Materials Having High Stroage Density 审中-公开
标题翻译：具有高剧烈密度的光学记录材料
公开(公告)号：US20080130474A1
公开(公告)日：2008-06-05
申请号：US10561392
申请日：2004-06-25
申请人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
发明人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
IPC分类号： G11B7/24 , B32B3/02
CPC分类号： G11B7/248 , C09B47/26
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I). For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 300 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density even at high speeds.
摘要翻译：本发明涉及一种光记录介质，其包括基底，记录层和任选的一个或多个反射层，其中记录层包含式（I）的化合物。关于进一步取代基的详细定义，参见说明书。特别是在300〜500nm的波长下进行记录和回放，例如使用蓝色激光。录音和播放质量极佳，即使在高速下也能保持较高的存储密度。

5. 发明授权

US07141697B2 Process for the preparation of phenethylamine derivatives 有权
标题翻译：苯乙胺衍生物的制备方法
公开(公告)号：US07141697B2
公开(公告)日：2006-11-28
申请号：US10130196
申请日：2001-12-12
申请人： Niranjan Paingankar , Vilas N. Mumbaikar , Vadiraj S. Ekkundi , Hans-Peter Jalett , Urs Siegrist , Paul Adriaan Van Der Schaaf , Frank Bienewald , Martin Studer , Stefan Burkhardt
发明人： Niranjan Paingankar , Vilas N. Mumbaikar , Vadiraj S. Ekkundi , Hans-Peter Jalett , Urs Siegrist , Paul Adriaan Van Der Schaaf , Frank Bienewald , Martin Studer , Stefan Burkhardt
IPC分类号： C07C211/00
CPC分类号： C07C213/02 , C07C217/74 , C07C2601/14
摘要： Disclosed is a process for the preparation of a compound of formula wherein R1 is hydrogen, hydroxyl, or unsubstituted or substituted alkyl or alkoxy, R2 is hydrogen or a substituent which can be converted to hydrogen, and n is 0, 1 or 2, comprising hydrogenating a compound of formula wherein R1, R2 and n are as defined above, in the presence of a nickel or cobalt catalyst.
摘要翻译：公开了一种制备下式化合物的方法，其中R 1是氢，羟基或未取代或取代的烷基或烷氧基，R 2是氢或取代基，可以转化为氢，并且n为0,1或2，包括将下式化合物其中R 1，R 2，N和n如上定义的氢化，存在镍或钴催化剂。

6. 发明授权

US08436208B2 Substituted oligo- or polythiophenes 有权
标题翻译：取代的寡聚或聚噻吩
公开(公告)号：US08436208B2
公开(公告)日：2013-05-07
申请号：US12921176
申请日：2009-03-06
申请人： Hans Jürg Kirner , Frank Bienewald , Jean-Charles Flores , Olivier Frédéric Aebischer
发明人： Hans Jürg Kirner , Frank Bienewald , Jean-Charles Flores , Olivier Frédéric Aebischer
IPC分类号： C07C233/00 , C07C235/00 , C07C237/00 , C07C239/00
CPC分类号： C07D333/28 , C07D495/04 , C07D495/14 , C07F7/0814 , C07F9/6578 , C08G61/12 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/141 , C08G2261/3223 , C08G2261/3244 , C08G2261/3247 , C08G2261/364 , C08G2261/92 , H01L51/0036 , H01L51/0043 , H01L51/0094 , Y02E10/549
摘要： A process for the preparation of a substituted 2,2′-dithiophene is described, which process comprises the steps (a), (c) and optional steps (b) and (d): a reaction of a compound of the formula: with a suitable lithium organic compound, preferably Li-alkyl or Li-alkylamide; b) optional exchange of lithium against another metal selected from Mg1 Zn and Cu; c) reaction of the metallated intermediate obtained in step (a) or (b) with a suitable electrophil, which is CO2 or an aldehyde (addition reaction), or a compound Y′—R17 or Y′—R18-Z (substitution reaction), where R17 and R18 are as defined in claim 1; and optionally d) modification of the product obtained in step (c), e.g. by introducing one or more conjugating moieties Y ring closure between suitable monovalent residues R17, exchange or extension of functional groups or substituents such as addition to carbonyl or substitution of carbonyl in R17 or R18. The products, including or corresponding polymers, are excellent conducting materials
摘要翻译：描述了制备取代的2,2'-二噻吩的方法，该方法包括步骤（a），（c）和任选步骤（b）和（d）：下式化合物与合适的锂有机化合物，优选为Li-烷基或Li-烷基酰胺; b）任选地将锂与另一种选自Mg1 Zn和Cu的金属交换; c）将步骤（a）或（b）中获得的金属化中间体与合适的亲电体（其为CO 2或醛（加成反应））或化合物Y'-R17或Y'-R18-Z（取代反应），其中R 17和R 18如权利要求1所定义; 和任选地d）修饰步骤（c）中获得的产物，例如，通过在合适的单价残基R17之间引入一个或多个缀合部分Y闭环，官能团或取代基的交换或延伸，例如加成羰基或在R17或R18中取代羰基。包括或相应的聚合物的产品是优良的导电材料

7. 发明申请

US20110062426A1 SUBSTITUTED OLIGO- OR POLYTHIOPHENES 有权
标题翻译：取代的寡糖或聚乙二醇
公开(公告)号：US20110062426A1
公开(公告)日：2011-03-17
申请号：US12921176
申请日：2009-03-06
申请人： Hans Jurg Kirner , Frank Bienewald , Jean Charles Flores , Oliver Frédéric Aebischer
发明人： Hans Jurg Kirner , Frank Bienewald , Jean Charles Flores , Oliver Frédéric Aebischer
IPC分类号： H01L51/30 , C07D409/04 , C07D495/04 , C07F7/10 , C07D495/14 , C07F7/12 , C08G75/06 , H01L51/40
CPC分类号： C07D333/28 , C07D495/04 , C07D495/14 , C07F7/0814 , C07F9/6578 , C08G61/12 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/141 , C08G2261/3223 , C08G2261/3244 , C08G2261/3247 , C08G2261/364 , C08G2261/92 , H01L51/0036 , H01L51/0043 , H01L51/0094 , Y02E10/549
摘要： A process for the preparation of a substituted 2,2′-dithiophene is described, which process comprises the steps (a), (c) and optional steps (b) and (d): a reaction of a compound of the formula: with a suitable lithium organic compound, preferably Li-alkyl or Li-alkylamide; b) optional exchange of lithium against another metal selected from Mg1 Zn and Cu; c) reaction of the metallated intermediate obtained in step (a) or (b) with a suitable electrophil, which is CO2 or an aldehyde (addition reaction), or a compound Y′—R17 or Y′—R18-Z (substitution reaction), where R17 and R18 are as defined in claim 1; and optionally d) modification of the product obtained in step (c), e.g. by introducing one or more conjugating moieties Y ring closure between suitable monovalent residues R17, exchange or extension of functional groups or substituents such as addition to carbonyl or substitution of carbonyl in R17 or R18. The products, including or corresponding polymers, are excellent conducting materials
摘要翻译：描述了制备取代的2,2'-二噻吩的方法，该方法包括步骤（a），（c）和任选步骤（b）和（d）：下式化合物与合适的锂有机化合物，优选为Li-烷基或Li-烷基酰胺; b）任选地将锂与另一种选自Mg1 Zn和Cu的金属交换; c）将步骤（a）或（b）中获得的金属化中间体与合适的亲电体（其为CO 2或醛（加成反应））或化合物Y'-R17或Y'-R18-Z（取代反应），其中R 17和R 18如权利要求1所定义; 和任选地d）修饰步骤（c）中获得的产物，例如，通过在合适的单价残基R17之间引入一个或多个缀合部分Y闭环，官能团或取代基的交换或延伸，例如加成羰基或在R17或R18中取代羰基。包括或相应的聚合物的产品是优良的导电材料

8. 发明申请

US20110017981A1 PROCESS FOR THE PREPARATION OF SEMICONDUCTING LAYERS 审中-公开
标题翻译：制备半导体层的方法
公开(公告)号：US20110017981A1
公开(公告)日：2011-01-27
申请号：US12745075
申请日：2008-12-05
申请人： Gordon Bradley , Lukas Burgi , Frank Bienewald
发明人： Gordon Bradley , Lukas Burgi , Frank Bienewald
IPC分类号： H01L51/05 , H01L51/40 , H01L51/42
CPC分类号： H01L51/0545 , B82Y20/00 , B82Y30/00 , H01L51/0004 , H01L51/0558 , H01L2251/5369 , Y02E10/549 , Y02P70/521
摘要： A convenient way for preparing thin layers of organic semiconducting materials comprises application or deposition of particles of a semiconducting material containing an organic semiconductor on a suitable surface, and converting these particles into a semiconducting layer on a substrate by application of pressure and optionally elevated temperatures.
摘要翻译：制备有机半导体材料薄层的方便方法包括在合适的表面上施加或沉积含有有机半导体的半导体材料的颗粒，并通过施加压力和任选升高的温度将这些颗粒转化成衬底上的半导体层。

9. 发明授权

US07772242B2 Merocyanine derivatives 有权
公开(公告)号：US07772242B2
公开(公告)日：2010-08-10
申请号：US11630489
申请日：2005-06-20
申请人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jürg Haase
发明人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jürg Haase
IPC分类号： A61K31/519 , A61K31/445 , A61K31/16 , A61K31/165
CPC分类号： A61K8/498 , A61K8/4913 , A61K8/494 , A61Q17/04
摘要： Disclosed is the use of the compounds of formula wherein Q is —OH; —OR7; —NH2; —NHR7; —NR7R8; or —N═R9; T is —COR5; —CN; or —SO2—(C6-C12)aryl; R1 is hydrogen; —OR7, —SR7; —NHR7; —NR7R8; C1-C22alkyl; C2-C12Alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl, C2-C11heteroaralkyl; C6-C10aryl; or C1-C9heteroaryl; R2 and R3 independently from each other are C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl, C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl; C3-C12cycloheteroalkyl; C2-C11heteroaralkyl, C6-C10aryl; or C1-C9heteroaryl; R4 is cyano; COR7, COOR7; CONH2; CONHR7; CONR7R8; SO2(C6-C12)aryl, C2-C12alk-1 -enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl, C3-C5heterocycloalkyl, C6-C10aryl; or C1-C9heteroaryl; R5 is —COR7; —COOR7; —OR7; —SR7, —NHR7, —NR7R8; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12alkylphenyl; C1-C12alkoxy-C6-C10aryl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C3-C12cycloheteroalkyl; C6-C10aryl; C1-C12alkoxy-C6-C10aryl or C1-C9heteroaryl; R6, R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; o-C6-C10aryl; or C1-C9heteroaryl; R9 is a (C1-C6)alkylidene radical; or R1 and R2, R1 and Q, R1 and R4, R1 and R6, R2 and R3, R3 and Q, R6 and Q, T and Q, each independently, are linked together, so that 1, 2, 3 or 4 carbocyclic or N, O and/or S-heterocyclic rings are formed, wherein each of them, independently from each other, may be condensed with an aromatic or heteroaromatic ring, and/or more N-, O- and/or S-heterocycic rings, and each N atom in a N-heterocyclic ring may be substituted by C1-C22alkyl; and n is a number from 1 to 4; for protecting of human hair and skin against the damaging effect of UV radiation.

10. 发明授权

US07723521B2 Azaperylenes as organic semiconductors 有权
标题翻译：亚萘基作为有机半导体
公开(公告)号：US07723521B2
公开(公告)日：2010-05-25
申请号：US11919605
申请日：2006-05-03
申请人： Frank Bienewald , Beat Schmidhalter , Ulrich Berens , Hans Jürg Kirner
发明人： Frank Bienewald , Beat Schmidhalter , Ulrich Berens , Hans Jürg Kirner
IPC分类号： C07D471/02 , H01L21/02
CPC分类号： C09B5/028 , C07D471/06 , H01L51/0067 , H01L51/0069 , H01L51/0071 , H01L51/0072 , H01L51/0512 , H01L51/0541 , H01L51/5012 , Y10S428/93
摘要： A novel semiconductor device comprises an azaperylene organic semiconductor of the formula I wherein the substitutents are defined herein.
摘要翻译：一种新颖的半导体器件包括式I的氮杂伯有机半导体，其中取代基在本文中定义。

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