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1. 发明授权

US07335295B2 Coated zeolite catalysts and use for hydrocarbon conversion 有权
标题翻译：涂层沸石催化剂和用于烃转化
公开(公告)号：US07335295B2
公开(公告)日：2008-02-26
申请号：US10862849
申请日：2004-06-07
申请人： Jannetje Maatje van den Berge , Gary David Mohr , Kenneth Ray Clem , Wilfried Jozef Mortier , Machteld Maria Mertens , Michael C. Bradford
发明人： Jannetje Maatje van den Berge , Gary David Mohr , Kenneth Ray Clem , Wilfried Jozef Mortier , Machteld Maria Mertens , Michael C. Bradford
IPC分类号： C10G35/04
CPC分类号： B01J35/023 , B01J29/40 , B01J29/70 , B01J29/80 , B01J37/0246 , B01J2229/12 , B01J2229/26 , B01J2229/42 , B01J2229/62 , C07C2/864 , C07C5/2708 , C07C6/123 , C07C2529/40 , C07C2529/70 , C07C2529/87 , C10G3/45 , C10G3/47 , C10G3/49 , C10G11/05 , C10G35/065 , C10G35/095 , C10G45/64 , C10G2300/1044 , C10G2300/4018 , C10G2300/708 , C10G2400/20 , Y02P20/52 , Y02P30/20 , C07C15/08
摘要： There is provided a coated zeolite catalyst in which the accessibility of the acid sites on the external surfaces of the zeolite is controlled and a process for converting hydrocarbons utilizing the coated zeolite catalyst. The zeolite catalyst comprises core crystals of a first zeolite and a discontinuous layer of smaller size second crystals of a second zeolite which cover at least a portion of the external surface of the first crystals The coated zeolite catalyst finds particular application in hydrocarbon conversion processes where catalyst activity in combination with zeolite structure are important for reaction selectivity, e.g., catalytic cracking, alkylation, disproportional of toluene, isomerization, and transalkylation reactions.
摘要翻译：提供了一种涂层沸石催化剂，其中控制沸石外表面上的酸性位点的可及性以及利用涂覆的沸石催化剂转化烃的方法。沸石催化剂包括第一沸石的核心晶体和覆盖第一晶体的至少部分外表面的第二沸石的较小尺寸的第二晶体的不连续层。涂覆的沸石催化剂在烃转化过程中特别适用于其中催化剂结合沸石结构的活性对于反应选择性是重要的，例如催化裂化，烷基化，甲苯不成比例，异构化和烷基转移反应。

2. 发明授权

US06645370B2 Preparation of high silica zeolites bound by zeolite and use thereof 有权
公开(公告)号：US06645370B2
公开(公告)日：2003-11-11
申请号：US10315353
申请日：2002-12-10
申请人： Johannes P. Verduijn , Gary David Mohr
发明人： Johannes P. Verduijn , Gary David Mohr
IPC分类号： C10G1105
CPC分类号： C01B39/026 , B01J29/40 , B01J37/0009 , B01J2229/42 , Y10S423/22
摘要： This invention relates to a process for producing zeolite-bound high silica zeolites and the use of the zeolite-bound high silica zeolite produced by the process for hydrocarbon conversion. The process is carried out by forming an extrudable paste comprising a mixture of high silica zeolite in the hydrogen form, water, silica, and optionally an extrusion aid, extruding the extrudable paste to form silica-bound high silica zeolite extrudates, and then converting the silica of the binder to a zeolite binder. The zeolite-bound high silica zeolite produced by the process comprises high silica zeolite crystals that are bound together by zeolite binder crystals. The zeolite-bound high silica zeolite finds particular application in hydrocarbon conversion processes, e.g., catalytic cracking, alkylation, disproportionation of toluene, isomerization, and transalkylation reactions.

3. 发明授权

US06627577B2 Hydrocarbon conversion catalyst and its use 失效
标题翻译：烃转化催化剂及其用途
公开(公告)号：US06627577B2
公开(公告)日：2003-09-30
申请号：US10161121
申请日：2002-05-31
申请人： Robert Scott Smith , Gary David Mohr , Jannetje Maatje van den Berge
发明人： Robert Scott Smith , Gary David Mohr , Jannetje Maatje van den Berge
IPC分类号： B01J2718
CPC分类号： C10G49/08 , B01J29/005 , B01J29/84 , B01J29/85 , B01J2229/26 , B01J2229/42 , C10G3/48 , C10G3/49 , C10G3/50 , C10G11/05 , C10G35/095 , C10G2300/1037 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P30/20
摘要： There is provided catalysts and conversion processes for converting hydrocarbons using the catalysts. The catalysts comprises a first alumino-phosphospho-molecular sieves and a binder comprising a second alumino-phopho-molecular sieves. Exemplary conversion processes include the conversion of oxygenates to olefins, dewaxing, reforming, dealkylation, dehydrogenation, transalkylation, alkylation, and isomerization.
摘要翻译：提供了使用催化剂转化烃的催化剂和转化方法。催化剂包括第一铝磷磷分子筛和包含第二铝 - 磷光分子筛的粘合剂。示例性的转化方法包括将含氧化合物转化为烯烃，脱蜡，重整，脱烷基化，脱氢，烷基转移，烷基化和异构化。

4. 发明申请

US20100282641A1 Process for Reducing Bromine Index of Hydrocarbon Feedstocks 有权
标题翻译：降低碳氢化合物原料溴指数的方法
公开(公告)号：US20100282641A1
公开(公告)日：2010-11-11
申请号：US12766372
申请日：2010-04-23
申请人： Stephen Harold Brown , Gary David Mohr , Michael Christopher Clark , Selma Lawrence
发明人： Stephen Harold Brown , Gary David Mohr , Michael Christopher Clark , Selma Lawrence
IPC分类号： C10G17/00
CPC分类号： C10G29/16 , C10G25/003 , C10G25/03 , C10G53/02 , C10G53/08 , C10G67/06 , C10G67/14 , C10G69/12 , C10G2300/4018 , C10G2300/4056 , C10G2300/701
摘要： A process for reducing the Bromine Index of a hydrocarbon feedstock, the process comprising the step of contacting the hydrocarbon feedstock with a catalyst at conversion conditions, wherein the catalyst includes at least one molecular sieve and at least one clay, and wherein said catalyst is sufficient to reduce more than 50% of the Bromine Index of a hydrocarbon feedstock.
摘要翻译：一种用于降低烃原料的溴指数的方法，该方法包括在转化条件下使烃原料与催化剂接触的步骤，其中催化剂包括至少一种分子筛和至少一种粘土，并且其中所述催化剂是足够的以减少烃原料的溴指数的50％以上。

5. 发明申请

US20090030214A1 Oxidation Process 失效
标题翻译：氧化工艺
公开(公告)号：US20090030214A1
公开(公告)日：2009-01-29
申请号：US11829346
申请日：2007-07-27
申请人： Helge Jaensch , Gary David Mohr
发明人： Helge Jaensch , Gary David Mohr
IPC分类号： C07D307/78 , C07C33/00 , C07C51/00 , C07F13/00 , C07F7/28 , C07F9/00 , C07F15/00 , C07C69/96 , C07D301/00
CPC分类号： C01B15/10 , C01B15/103 , Y02P20/582
摘要： Peroxo-carbonates derived from molten alkali and/or Group II metal salts, particularly carbonate salts are used as catalysts in oxidation and epoxidation reactions, transition metal compounds may be included to improve the selectivity of the reactions.
摘要翻译：衍生自熔融碱和/或II族金属盐，特别是碳酸盐的过氧碳酸酯用作氧化和环氧化反应中的催化剂，可以包括过渡金属化合物以改善反应的选择性。

6. 发明授权

US06924405B2 Xylene isomerization 失效
标题翻译：二甲苯异构化
公开(公告)号：US06924405B2
公开(公告)日：2005-08-02
申请号：US10870512
申请日：2004-06-17
申请人： Gary David Mohr
发明人： Gary David Mohr
IPC分类号： C07C5/27 , C07C15/08
CPC分类号： C07C15/08 , C07C5/2708 , C07C2521/04 , C07C2521/16 , C07C2523/42 , C07C2529/22 , C07C2529/40 , C07C2529/62 , C07C2529/65 , C07C2529/70 , C07C2529/74 , C07C2529/85 , C07C15/067
摘要： A xylene isomerization process is disclosed in which any ethylbenzene in the feed is removed, either by dealkylation or isomerization, in a separate reactor upstream of the xylene isomerization reactor and the xylene isomerization catalyst is contained in the same reactor, typically a clay treater, as that used to accommodate the olefin removal catalyst. In certain cases, a single catalyst may be used to effect both xylene isomerization and olefin removal.
摘要翻译：公开了二甲苯异构化方法，其中在二甲苯异构化反应器上游的单独的反应器中，通过脱烷基化或异构化除去进料中的任何乙苯，并且二甲苯异构化催化剂包含在相同的反应器（通常为粘土处理器）中，作为其用于容纳烯烃除去催化剂。在某些情况下，可以使用单一催化剂来实现二甲苯异构化和烯烃除去。

7. 发明授权

US06811684B2 Hydrocarbon conversion process and catalyst useful therein 有权
标题翻译：烃转化方法和催化剂在其中有用
公开(公告)号：US06811684B2
公开(公告)日：2004-11-02
申请号：US10132755
申请日：2002-04-25
申请人： Gary David Mohr , Wilfried Jozef Mortier , Xiaobing Feng , Per Johan Sterte , Lubomira Borislavova Tosheva
发明人： Gary David Mohr , Wilfried Jozef Mortier , Xiaobing Feng , Per Johan Sterte , Lubomira Borislavova Tosheva
IPC分类号： C10G2500
CPC分类号： B01J37/0018 , B01J29/06 , B01J29/40 , C07C5/2737 , Y02P20/52 , C07C15/08
摘要： There is provided a process for converting hydrocarbons using a catalyst comprising macrostructures having a three-dimensional network of particles comprised of porous inorganic material. The particles of the macrostructures occupy less than 75% of the total volume of the macrostructures and are joined together to form a three-dimensional interconnected network comprised of pores having diameters greater than about 20 Å. The macrostructures can be made by forming an admixture containing a porous organic ion exchanger and a synthesis mixture capable of forming the porous inorganic material; converting the synthesis mixture to the porous inorganic material; and removing the porous organic ion exchanger from the inorganic material.
摘要翻译：提供了一种使用包含具有由多孔无机材料构成的三维网状网络的宏观结构的催化剂转化烃的方法。宏观结构的颗粒占宏观结构的总体积的小于75％并且连接在一起以形成包括直径大于约的孔的三维互连网络。宏观结构可以通过形成含有多孔有机离子交换剂和能够形成多孔无机材料的合成混合物的混合物来制备; 将合成混合物转化为多孔无机材料; 并从无机材料中除去多孔有机离子交换剂。

8. 发明授权

US08048294B2 Process for reducing bromine index of hydrocarbon feedstocks 有权
标题翻译：降低烃原料溴指数的方法
公开(公告)号：US08048294B2
公开(公告)日：2011-11-01
申请号：US12766372
申请日：2010-04-23
申请人： Stephen Harold Brown , Gary David Mohr , Michael Christopher Clark , Selma Lawrence
发明人： Stephen Harold Brown , Gary David Mohr , Michael Christopher Clark , Selma Lawrence
IPC分类号： C07C2/02
CPC分类号： C10G29/16 , C10G25/003 , C10G25/03 , C10G53/02 , C10G53/08 , C10G67/06 , C10G67/14 , C10G69/12 , C10G2300/4018 , C10G2300/4056 , C10G2300/701
摘要： A process for reducing the Bromine Index of a hydrocarbon feedstock, the process comprising the step of contacting the hydrocarbon feedstock with a catalyst at conversion conditions, wherein the catalyst includes at least one molecular sieve and at least one clay, and wherein said catalyst is sufficient to reduce more than 50% of the Bromine Index of a hydrocarbon feedstock.
摘要翻译：一种用于降低烃原料的溴指数的方法，该方法包括在转化条件下使烃原料与催化剂接触的步骤，其中催化剂包括至少一种分子筛和至少一种粘土，并且其中所述催化剂是足够的以减少烃原料的溴指数的50％以上。

9. 发明申请

US20100288617A1 Pyrolysis Reactor Materials and Methods 有权
标题翻译：热解反应堆材料与方法
公开(公告)号：US20100288617A1
公开(公告)日：2010-11-18
申请号：US12576002
申请日：2009-10-08
申请人： Frank Hershkowitz , ChangMin Chun , Paul F. Keusenkothen , Shiun Ling , Gary David Mohr
发明人： Frank Hershkowitz , ChangMin Chun , Paul F. Keusenkothen , Shiun Ling , Gary David Mohr
IPC分类号： C10B57/16 , C04B35/01 , B01J8/00 , B01J19/00 , C10B23/00 , C10G9/00 , C10B47/00 , C10B1/00 , C07C4/04 , C07C4/06
CPC分类号： C04B35/488 , B01J4/002 , B01J8/0438 , B01J8/0442 , B01J8/0492 , B01J19/02 , B01J19/2485 , B01J2208/00115 , B01J2208/00309 , B01J2208/00504 , B01J2208/0084 , B01J2208/00849 , B01J2219/00081 , B01J2219/00117 , B01J2219/00157 , B01J2219/00159 , B01J2219/0263 , C04B35/486 , C04B35/505 , C04B2235/3206 , C04B2235/3208 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3244 , C04B2235/3246 , C04B2235/3251 , C04B2235/3256 , C04B2235/3258 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3418 , C04B2235/528 , C04B2235/5296 , C04B2235/5436 , C04B2235/5445 , C04B2235/5472 , C04B2235/5481 , C04B2235/6021 , C04B2235/658 , C04B2235/6584 , C04B2235/72 , C04B2235/762 , C04B2235/77 , C04B2235/96 , C04B2235/9607 , C04B2235/9669 , C04B2235/9684 , C10G1/02 , C10G9/00 , C10G9/005 , C10G9/18 , C10G9/26 , C10G75/00 , Y02P20/582
摘要： In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and that remains in oxide form when exposed to a gas having a carbon partial pressure of 10−22 bar, an oxygen partial pressure of 10−10 bar, at a temperature of 1200° C.
摘要翻译：在一个方面，本发明包括用于热解烃原料的反应器装置，该装置包括：反应器组件，其包含氧化物形式的耐火材料，耐火材料的熔点至少为2060℃，并保留在氧化物当暴露于碳分压为10-22巴，氧气分压为10-10巴的气体时，在1200℃的温度下形成。在一些实施方案中，反应器包括再生热解反应器装置，在其它实施方案中它包括逆流再生反应器装置。在其他方面，本发明包括使用热解反应器系统热解烃原料的方法，该方法包括在加热区域中提供用于热解烃原料的热解反应器系统，包括氧化物形式的耐火材料的装置，耐火材料材料具有至少2060℃的熔点，并且当暴露于碳分压为10-22巴，氧分压为10-10巴的气体时，在1200℃的温度下保持为氧化物形式 C。

10. 发明授权

US06787023B1 Metal-containing macrostructures of porous inorganic oxide, preparation thereof, and use 有权
标题翻译：多孔无机氧化物的含金属宏观结构及其制备及用途
公开(公告)号：US06787023B1
公开(公告)日：2004-09-07
申请号：US09574432
申请日：2000-05-20
申请人： Gary David Mohr , Wilfried Jozef Mortier , Xiaobing Feng , Per Johan Sterte , Lubomira Borislavova Tosheva
发明人： Gary David Mohr , Wilfried Jozef Mortier , Xiaobing Feng , Per Johan Sterte , Lubomira Borislavova Tosheva
IPC分类号： B01J2906
CPC分类号： B01J29/06 , B01J29/44 , B01J29/48 , B01J29/7415 , B01J29/7615 , B01J37/0009 , B01J37/0018 , B01J2229/60 , C10G3/49 , C10G11/05 , C10G29/205 , C10G35/065 , C10G45/64 , Y02P30/20
摘要： There is provided a catalyst containing porous macrostructures comprised of: (a) a three-dimensional network of particles of porous inorganic material (e.g., zeolites); and, (b) at least one metal (e.g., a catalytically active metal). The particles of the at least one macrostructure occupy less than 75% of the total volume of the at least one macrostructure and are jointed together to form a three-dimensional interconnected network. The three-dimensional interconnected network will usually be comprised of pores having diameters greater than about 20 Å. The macrostructures can be made by forming an admixture containing a porous organic ion exchanger (e.g., a polymer-based ion exchange resin) and a synthesis mixture (e.g., for zeolite formation) capable of forming the porous inorganic material and the at least one metal; converting the synthesis mixture to the porous inorganic material; and removing the porous organic ion exchanger from the inorganic material. The metal-containing macrostructures find application in hydrocarbon conversion (e.g., hydrogenation, dehydrogenation, dehydrocyclization, isomerization, hydrocracking, dewaxing, reforming, conversion of alkyl aromatics, etc.) and in the reduction of emissions of hydrocarbons, carbon monoxide, and/or oxides of nitrogen from an internal combustion engine.
摘要翻译：提供了含有多孔宏观结构的催化剂，其包括：（a）多孔无机材料（例如沸石）颗粒的三维网络; 和（b）至少一种金属（例如催化活性金属）。所述至少一个宏观结构的颗粒占据所述至少一个宏观结构的总体积的小于75％并且连接在一起以形成三维互连网络。三维互连网络通常由直径大于约的孔组成。宏观结构可以通过形成含有多孔有机离子交换剂（例如，基于聚合物的离子交换树脂）和能够形成多孔无机材料的合成混合物（例如，用于沸石形成）和至少一种金属 ; 将合成混合物转化为多孔无机材料; 并从无机材料中除去多孔有机离子交换剂。含金属的宏观结构可用于烃转化（例如氢化，脱氢，脱氢环化，异构化，加氢裂化，脱蜡，重整，烷基芳族化合物的转化等）和减少烃，一氧化碳和/或来自内燃机的氮氧化物。

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