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1. 发明授权

US08470289B2 Manganese oxides and their use in the oxidation of alkanes 有权
公开(公告)号：US08470289B2
公开(公告)日：2013-06-25
申请号：US12163393
申请日：2008-06-27
申请人： Helge Jaensch , Wilfried J. Mortier
发明人： Helge Jaensch , Wilfried J. Mortier
IPC分类号： G01G5/00
CPC分类号： C07C5/48 , B01J23/34 , B01J23/688 , B01J35/002 , B01J37/03 , B01J37/30 , C01G45/00 , C01G45/02 , C01P2002/08 , C01P2002/72 , C01P2002/85 , C07B33/00 , C07C45/33 , C07C51/215 , C07C51/252 , C07C2523/34 , Y02P20/582 , C07C11/02 , C07C57/04
摘要： Catalytic structures are provided comprising octahedral tunnel lattice manganese oxides ion-exchanged with metal cations or mixtures thereof. The structures are useful as catalysts for the oxidation of alkanes and may be prepared by treating layered manganese oxide under highly acidic conditions, optionally drying the treated product, and subjecting it to ion exchange.

2. 发明申请

US20090030214A1 Oxidation Process 失效
标题翻译：氧化工艺
公开(公告)号：US20090030214A1
公开(公告)日：2009-01-29
申请号：US11829346
申请日：2007-07-27
申请人： Helge Jaensch , Gary David Mohr
发明人： Helge Jaensch , Gary David Mohr
IPC分类号： C07D307/78 , C07C33/00 , C07C51/00 , C07F13/00 , C07F7/28 , C07F9/00 , C07F15/00 , C07C69/96 , C07D301/00
CPC分类号： C01B15/10 , C01B15/103 , Y02P20/582
摘要： Peroxo-carbonates derived from molten alkali and/or Group II metal salts, particularly carbonate salts are used as catalysts in oxidation and epoxidation reactions, transition metal compounds may be included to improve the selectivity of the reactions.
摘要翻译：衍生自熔融碱和/或II族金属盐，特别是碳酸盐的过氧碳酸酯用作氧化和环氧化反应中的催化剂，可以包括过渡金属化合物以改善反应的选择性。

3. 发明申请

US20060217580A1 Olefin oligomerization to produce hydrocarbon compositions useful as fuels 有权
标题翻译：烯烃低聚产生用作燃料的烃组合物
公开(公告)号：US20060217580A1
公开(公告)日：2006-09-28
申请号：US11342385
申请日：2006-01-27
申请人： Keith Kuechler , Stephen Brown , Helge Jaensch , Georges Mathys , Shifang Luo , Jane Cheng
发明人： Keith Kuechler , Stephen Brown , Helge Jaensch , Georges Mathys , Shifang Luo , Jane Cheng
IPC分类号： C07C2/02
CPC分类号： C10G50/00 , C09K8/32
摘要： In a process for producing a hydrocarbon composition, a feed comprising at least one C3 to C8 olefin and an olefinic recycle stream rich in C9− hydrocarbons is contacted with a crystalline molecular sieve catalyst having an average crystal size no greater than 0.05 micron and an alpha value between about 100 and about 600 in at least one reaction zone under olefin oligomerization conditions including an inlet temperature between about 150° C. and about 350° C., a pressure of at least 2,860 kPa and a recycle to feed weight ratio of about 0.1 to about 3.0. The contacting produces an oligomerization effluent stream, which is separated into at least a hydrocarbon product stream rich in C9+ hydrocarbons and the olefinic recycle stream.
摘要翻译：在制备烃组合物的方法中，包含至少一种C 3至C 8 O烯烃的进料和富含C 9 N的烯烃循环料流烃类与结晶分子筛催化剂接触，其结晶尺寸不大于0.05微米，在至少一个反应区域的α值为约100至约600之间，在烯烃低聚条件下，包括入口温度约为150℃ 约350℃，压力至少为2860kPa，循环至饲料重量比为约0.1至约3.0。接触产生低聚流出物流，其被分离成至少一种富含C 9+烃的烃产物流和烯烃再循环流。

4. 发明申请

US20230044129A1 Polyoxometalates Comprising Noble Metals and Metal Cluster Units Thereof 有权
公开(公告)号：US20230044129A1
公开(公告)日：2023-02-09
申请号：US17778404
申请日：2020-11-06
申请人： Ali S. Mougharbel , Helge Jaensch , Ananthu Rajan , Saurav Bhattacharya , Ulrich Kortz
发明人： Ali S. Mougharbel , Helge Jaensch , Ananthu Rajan , Saurav Bhattacharya , Ulrich Kortz
IPC分类号： C07F17/02 , C01G55/00 , C01G5/00 , C01G41/00
摘要： The invention relates to polyoxometalates represented by the formula (An)m+[(MR′t)sOyHqRz(X8W48+rO184+4r)]m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal cluster units, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in conversion of organic substrate.

5. 发明申请

US20140221716A1 Olefin Oligomerization Process 有权
标题翻译：烯烃低聚过程
公开(公告)号：US20140221716A1
公开(公告)日：2014-08-07
申请号：US14233199
申请日：2012-06-14
申请人： Geraldine Tosin , An Verberckmoes , Helge Jaensch , George M. K. Mathys , Machteld M. W. Mertens , Sourav Saha , Hailian Li , Robert J. Saxton
发明人： Geraldine Tosin , An Verberckmoes , Helge Jaensch , George M. K. Mathys , Machteld M. W. Mertens , Sourav Saha , Hailian Li , Robert J. Saxton
IPC分类号： C07C2/10 , C07C2/18
CPC分类号： C07C2/10 , B01D15/00 , B01J20/06 , B01J20/08 , C07C2/12 , C07C2/18 , C07C7/12 , C07C2521/04 , C07C2523/755 , C07C2529/06 , C07C2529/70 , Y02P20/52 , C07C11/06 , C07C11/08 , C07C11/10 , C07C11/02
摘要： The present invention provides an olefin oligomerization process comprising the steps of: i) reducing the level of acetonitrile in an olefin feed by contacting the feed with a non-zeolitic metal oxide; and ii) contacting the olefin feed with reduced level of acetonitrile with an olefin oligomerization catalyst under conditions suitable to oligomerize the olefin.
摘要翻译：本发明提供烯烃低聚方法，其包括以下步骤：i）通过使进料与非沸石金属氧化物接触来降低烯烃进料中乙腈的含量; 和ii）在适于使烯烃低聚的条件下，使烯烃进料与烯烃低聚催化剂在降低的乙腈水平下接触。

6. 发明申请

US20110319635A1 Process For Preparing N-Substituted Cyclic Imides 失效
标题翻译： N-取代的环状酰亚胺的制备方法
公开(公告)号：US20110319635A1
公开(公告)日：2011-12-29
申请号：US13202128
申请日：2010-02-01
申请人： Helge Jaensch
发明人： Helge Jaensch
IPC分类号： C07D209/48
CPC分类号： C07D209/48
摘要： In a process for making an N-substituted phthalimide compound, an amine is contacted with a carboxylic acid anhydride and allowed to react in an aqueous solution at a pH of about 2 to about 6. Optionally, the reactants are combined with an acid to lower the pH of the reaction solution wherein the lowering of the pH optimizes the yield of the desired N-substituted phthalimide product. The N-substituted phthalimide may be, for example, N-hydroxyphthalimide, and the reactants may be phthalic anhydride and hydroxylamine or a salt thereof. The N-substituted phthalimide compound is useful for, among other things, the oxidation of various hydrocarbons.
摘要翻译：在制备N-取代的邻苯二甲酰亚胺化合物的方法中，胺与羧酸酐接触，并使其在约2至约6的pH下在水溶液中反应。任选地，将反应物与酸组合以降低其中降低pH的反应溶液的pH优化所需N-取代的邻苯二甲酰亚胺产物的产率。 N-取代邻苯二甲酰亚胺可以是例如N-羟基邻苯二甲酰亚胺，反应物可以是邻苯二甲酸酐和羟胺或其盐。 N-取代的邻苯二甲酰亚胺化合物尤其可用于各种烃的氧化。

7. 发明申请

US20090023972A1 Manganese oxides and their use in the oxidation of alkanes 有权
标题翻译：锰氧化物及其在烷烃氧化中的应用
公开(公告)号：US20090023972A1
公开(公告)日：2009-01-22
申请号：US12163393
申请日：2008-06-27
申请人： Helge Jaensch , Wilfried J. Mortier
发明人： Helge Jaensch , Wilfried J. Mortier
IPC分类号： C01G45/12 , C01F17/00 , C07C5/333
CPC分类号： C07C5/48 , B01J23/34 , B01J23/688 , B01J35/002 , B01J37/03 , B01J37/30 , C01G45/00 , C01G45/02 , C01P2002/08 , C01P2002/72 , C01P2002/85 , C07B33/00 , C07C45/33 , C07C51/215 , C07C51/252 , C07C2523/34 , Y02P20/582 , C07C11/02 , C07C57/04
摘要： Catalytic structures are provided comprising octahedral tunnel lattice manganese oxides ion-exchanged with metal cations or mixtures thereof. The structures are useful as catalysts for the oxidation of alkanes and may be prepared by treating layered manganese oxide under highly acidic conditions, optionally drying the treated product, and subjecting it to ion exchange.
摘要翻译：提供催化结构，其包括与金属阳离子或其混合物离子交换的八面体隧道晶格锰氧化物。该结构可用作烷烃氧化的催化剂，并且可以通过在高度酸性条件下处理层状氧化锰，任选地干燥处理过的产品并进行离子交换来制备。

8. 发明申请

US20190030517A1 Polyoxometalates Comprising Noble Metals and Corresponding Metal Clusters 审中-公开
公开(公告)号：US20190030517A1
公开(公告)日：2019-01-31
申请号：US16071049
申请日：2017-01-19
申请人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
发明人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
IPC分类号： B01J27/185 , C01B25/45 , B01J21/08 , B01J35/02 , B01J37/03 , B01J37/02 , C07C5/10
摘要： The invention relates to poly oxometalates represented by the formula (An)m+{M′s[M″M15X10OyRzHq]}m− or solvates thereof, corresponding supported poly-oxometalates, and processes for their preparation, as well as corresponding metal-clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.

9. 发明授权

US08741255B2 Oxidation process 失效
标题翻译：氧化工艺
公开(公告)号：US08741255B2
公开(公告)日：2014-06-03
申请号：US11829346
申请日：2007-07-27
申请人： Helge Jaensch , Gary David Mohr
发明人： Helge Jaensch , Gary David Mohr
IPC分类号： C07D307/78 , C07C33/00 , C07C51/00 , C07F13/00 , C07F7/28 , C07F9/00 , C07F15/00 , C07C69/96 , C07D301/00
CPC分类号： C01B15/10 , C01B15/103 , Y02P20/582
摘要： Peroxo-carbonates derived from molten alkali and/or Group II metal salts, particularly carbonate salts are used as catalysts in oxidation and epoxidation reactions. Transition metal compounds may be included to improve the selectivity of the reactions.
摘要翻译：衍生自熔融碱和/或II族金属盐，特别是碳酸盐的过氧碳酸酯用作氧化和环氧化反应中的催化剂。可以包括过渡金属化合物以改善反应的选择性。

10. 发明授权

US10857527B2 Polyoxometalates comprising noble metals and corresponding metal clusters 有权
公开(公告)号：US10857527B2
公开(公告)日：2020-12-08
申请号：US16071049
申请日：2017-01-19
申请人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
发明人： Ulrich Kortz , Yixian Xiang , Zhengguo Lin , Peng Yang , Helge Jaensch , Wassim W. Ayass
IPC分类号： B01J27/185 , B01J35/10 , C07C5/10 , B01J23/00 , B01J29/03 , C01G55/00 , B01J37/03 , B01J21/08 , B01J35/02 , B01J37/02 , C01B25/45 , B01J35/00
摘要： The invention relates to poly oxometalates represented by the formula (An)m+{M′s[M″M15X10OyRzHq]}m− or solvates thereof, corresponding supported polyoxometalates, and processes for their preparation, as well as corresponding metal-clusters, optionally in the form of a dispersion in a liquid carrier medium or immobilized on a solid support, and processes for their preparation, as well as their use in reductive conversion of organic substrate.

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