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    • 2. 发明授权
    • Non-aqueous pigmented inkjet inks
    • 非水性着色喷墨油墨
    • US08097663B2
    • 2012-01-17
    • US12441718
    • 2007-10-01
    • Katrien BernaertsIvan HoogmartensGeert Deroover
    • Katrien BernaertsIvan HoogmartensGeert Deroover
    • C08G63/60C08G67/02C08G69/26C08J3/00C08K5/34C08K5/48C08L67/00C08L73/00C08L77/00C08L79/00C09B67/00C09D5/00C09D11/00
    • C09D11/36C09D11/326
    • A non-aqueous inkjet ink containing a pigment includes C.I. Pigment Violet 19 and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; wherein the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % with WTPOAC representing the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide representing the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and wherein the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
    • 含有颜料的非水性喷墨油墨包括C.I. 颜料紫19和根据式(I)的聚合物分散剂:其中T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C(O)An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 其中所述聚合物分散剂满足以下条件:WTPOAC> 55和NAmide≥65mol%,其中WTPOAC表示TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量,NAmide代表酰胺键的摩尔%; 并且其中WTPOAC和NAmide的值根据通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF(14.5:0.5)与0.1N高氯酸盐的混合物中的电位滴定测定的胺含量来计算。 。
    • 5. 发明申请
    • NON-AQUEOUS PIGMENTED INKJET INKS
    • 不含水的墨水INKJET墨水
    • US20090312463A1
    • 2009-12-17
    • US12441718
    • 2007-10-01
    • Katrien BernaertsIvan HoogmartensGeert Deroover
    • Katrien BernaertsIvan HoogmartensGeert Deroover
    • C09D11/10
    • C09D11/36C09D11/326
    • A non-aqueous inkjet ink containing a pigment includes C.I. Pigment Violet 19 and a polymeric dispersant according to Formula (I): wherein, T represents hydrogen or a polymerization terminating group; Z represents the residue of polyethyleneimine having a number-average molecular weight of at least 100; A represents an oxyalkylene carbonyl group; T-C(O)An- represents a TPOAC-chain which is bound to Z through an amide bond; and n and m are integers wherein m is at least 2 and n is from 2 to 100; wherein characterized in that the polymeric dispersant fulfills the conditions of: WTPOAC>57 and NAmide≧65 mol % with WTPOAC representing the ratio of the weight percentage of TPOAC-chains over the weight percentage of amide bonds in the polymeric dispersant; NAmide representing the mol % of amide bonds based on the total nitrogen content of the polymeric dispersant; and wherein the values of WTPOAC and NAmide are calculated from the total nitrogen content determined by dry combustion of the polymeric dispersant and from the amine content determined through potentiometric titration in a mixture of CH3COOH:THF (14.5:0.5) with 0.1N aqueous perchloric acid.
    • 含有颜料的非水性喷墨油墨包括C.I. 颜料紫19和根据式(I)的聚合物分散剂:其中T表示氢或聚合终止基团; Z表示数均分子量为100以上的聚乙烯亚胺的残基; A表示氧化烯羰基; T-C(O)An-表示通过酰胺键与Z结合的TPOAC-链; 并且n和m是其中m为至少2且n为2至100的整数; 其特征在于,聚合物分散剂满足以下条件:WTPOAC> 55和NAmide> = 65mol%,WTPOAC代表TPOAC链的重量百分比与聚合物分散剂中酰胺键的重量百分比的比率; 基于聚合物分散剂的总氮含量,NAmide代表酰胺键的摩尔%; 并且其中WTPOAC和NAmide的值根据通过聚合物分散剂的干燃烧确定的总氮含量和通过在CH 3 COOH:THF(14.5:0.5)与0.1N高氯酸盐的混合物中的电位滴定测定的胺含量来计算。 。
    • 8. 发明授权
    • Pigment dispersions with polymeric dispersants having pending chromophore groups
    • 具有悬浮发色团的聚合物分散剂的颜料分散体
    • US07582150B2
    • 2009-09-01
    • US11995322
    • 2006-06-23
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • Wojciech JaunkyGeert DerooverJohan LoccufierLambertus Groenendaal
    • C09D11/02C08K5/23
    • C09B67/009C09B67/0046C09B67/0051C09B69/106C09D11/326C09D17/003
    • A pigment dispersion comprising a color pigment represented by formula (I) wherein, R1 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH, —COOCH3 and R2, R4 and R5 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH and —COOCH3; R3 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH, —COOCH3, —SO2NH—C6H5, —CONH—C6H5, —CONH—C6H5—CONH2 and —CONH2; R6 and R7 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, —CF3, —COOH and —COOCH3, or R6 and R7 represent the necessary atoms to form an imidazolone ring; and a polymeric dispersant having via a linking group covalently linked to its polymeric backbone at least one pending chromophore group which has a molecular weight smaller than 95% of the molecular weight of said color pigment. The pigment dispersion can be advantageously used in inkjet inks.
    • 一种颜料分散体,其包含由式(I)表示的着色颜料,其中R 1选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH ,-COOCH 3和R 2,R 4和R 5独立地选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH和-COOCH 3; R 3选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3,-COOH,-COOCH 3,-SO 2 NH-C 6 H 5,-CONH-C 6 H 5 - CONH-C6H5-CONH2和-CONH2; R6和R7独立地选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF3,-COOH和-COOCH3,或R6和R7表示必需的原子 形成咪唑啉酮环; 以及聚合物分散剂,其通过共价连接至其聚合物主链的至少一个分子量小于所述彩色颜料分子量的95%的待发色团。 颜料分散体可以有利地用于喷墨油墨中。