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1. 发明授权

US5883277A Metallocene complexes with cationic bridges 失效
标题翻译：茂金属与阳离子桥络合
公开(公告)号：US5883277A
公开(公告)日：1999-03-16
申请号：US894238
申请日：1997-08-14
申请人： David Fischer , Franz Langhauser , Gunther Schweier , Hans-Herbert Brintzinger , Nadine Leyser
发明人： David Fischer , Franz Langhauser , Gunther Schweier , Hans-Herbert Brintzinger , Nadine Leyser
IPC分类号： B01J31/22 , C07F9/54 , C07F17/00 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F10/00 , C07F7/08 , C07F9/00
CPC分类号： C07F17/00 , C07F9/5435 , C08F10/00 , C08F4/61908 , C08F4/61912 , C08F4/61927
摘要： Metallocene complexes having a cationic bridge of the formula ##STR1## where the substituents have the following meanings: M is a metal of transition group III, IV, V or VI of the Periodic Table of the Elements or a metal of the lanthanide group,X is fluorine, chlorine, bromine, iodine, hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or --OR.sup.5,R.sup.1 to R.sup.12, Y, Z and n having the meanings set out in the specification, said complexes can be prepared via ligand systems of the formula II ##STR2## as intermediates.
摘要翻译： PCT No.PCT / EP96 / 00619 Sec。 371日期1997年8月14日 102（e）日期1997年8月14日PCT 1996年2月14日PCT PCT。公开号WO96 / 26211 PCT 日期1996年8月29日具有下式的阳离子桥的茂金属络合物其中取代基具有以下含义：M是元素周期表的过渡族III，IV，V或VI族的金属或金属的镧系元素，X是氟，氯，溴，碘，氢，C 1 -C 10 - 烷基，C 6 -C 15 - 芳基或-OR 5，R 1〜R 12，Y，Z和n具有说明书中列出的含义，所述络合物可以通过式II II的配体体系制备为中间体。

2. 发明授权

US5670683A Racemic metallocene complexes and their preparation 失效
标题翻译：外消旋茂金属络合物及其制备
公开(公告)号：US5670683A
公开(公告)日：1997-09-23
申请号：US620318
申请日：1996-03-22
申请人： Franz Langhauser , Jurgen Kerth , Gunther Schweier , Hans-Herbert Brintzinger , Stefan Mansel
发明人： Franz Langhauser , Jurgen Kerth , Gunther Schweier , Hans-Herbert Brintzinger , Stefan Mansel
IPC分类号： C07F7/08 , C07F17/00 , C08F4/6192 , C08F4/622 , C08F4/6392 , C08F4/642 , C08F4/646 , C08F4/68 , C08F10/00
CPC分类号： C08F10/00 , C07F17/00 , C07F7/0807 , C07F7/0818 , C08F4/61927 , C08F4/63927 , Y10S526/943
摘要： Cyclopentadineyl compounds of the formula II ##STR1## and formula III ##STR2## their preparation and their use as intermediates in the preparation of metallocene complexes of the formula I.
摘要翻译：式II的环戊二氢茚基化合物II和式III的化合物及其作为制备式I的茂金属络合物的中间体的用途。

3. 发明授权

US5639839A Oligomers and polymers of aminoalkenes 失效
标题翻译：氨基烯烃的低聚物和聚合物
公开(公告)号：US5639839A
公开(公告)日：1997-06-17
申请号：US529971
申请日：1995-09-19
申请人： David Fischer , Franz Langhauser , Jurgen Kerth , Gunther Schweier , Rolf Muelhaupt , Martin Schneider
发明人： David Fischer , Franz Langhauser , Jurgen Kerth , Gunther Schweier , Rolf Muelhaupt , Martin Schneider
IPC分类号： C07F7/12 , C08F4/642 , C08F4/68 , C08F8/00 , C08F30/08 , C08F210/00 , C08F230/08
CPC分类号： C08F30/08 , C08F210/00 , Y10S526/943
摘要： Oligomers and polymers, obtainable fromA) from 0.001 to 100 mol % of at least one aminoalkene of the general formula I ##STR1## where X is an integer from 0 to 25 andR.sup.1 to R.sup.6 are hydrogen, C.sub.1 - to C.sub.10 -alkyl, 5- to 7-membered cycloalkyl which, in turn, can carry C.sub.1 - to C.sub.6 -alkyl groups as substituents or C.sub.6 - to C.sub.15 -aryl andB) from 0 to 99.999 mol % of at least one alkene,for x=1 in formula I propene being excluded as component B).
摘要翻译：低聚物和聚合物，可由A）0.001至100摩尔％的至少一种通式I的氨基链烯，其中X为0至25的整数，R 1至R 6为氢，C 1至C 10 - 烷基 5至7元环烷基，其又可以携带C 1至C 6烷基作为取代基或C 6至C 15 - 芳基，B）为0至99.999摩尔％的至少一种烯烃，x = 1 在式I中，作为组分B）排除丙烯。

4. 发明授权

US5831106A Preparation of bridged metallocene complexes 失效
标题翻译：桥联茂金属络合物的制备
公开(公告)号：US5831106A
公开(公告)日：1998-11-03
申请号：US648704
申请日：1996-05-16
申请人： Franz Langhauser , David Fischer , Gunther Schweier , Hans-Herbert Brintzinger , Hans-Robert-Hellmuth Damrau
发明人： Franz Langhauser , David Fischer , Gunther Schweier , Hans-Herbert Brintzinger , Hans-Robert-Hellmuth Damrau
IPC分类号： C07F17/00 , C07F7/08 , C07F3/02 , C07F7/28 , C07F7/30
CPC分类号： C07F17/00
摘要： A process for preparing metallocene complexes of the general ##STR1## in which the substituents have the following meanings: M is titanium, zirconium, hafnium, vanadium, niobium or tantalum, X is fluorine, chlorine, bromine, iodine, hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or --OR.sup.5, where R.sup.5 is C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl, aryl-alkyl, fluoroalkyl or fluoroaryl with, in each case, 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical, R.sup.1 to R.sup.4 and R.sup.6 to R.sup.9 are hydrogen, C.sub.1 -C.sub.10 -alkyl, 5- to 7-membered cycloalkyl which can in turn carry C.sub.1 -C.sub.10 -alkyls as substituents, or C.sub.6 -C.sub.15 -aryl or aryl-alkyl, it also being possible where appropriate for two adjacent radicals together to be cyclic groups having 4 to 15 carbon atoms, or Si(R.sup.10).sub.3 with R.sup.10 being C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl or C.sub.3 -C.sub.10 -cyclo-alkyl, ##STR2## where Z is silicon, germanium, tin or carbon, and R.sup.11,R.sup.12, R.sup.13 and R.sup.14 are hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.6 -C.sub.15 -aryl, it also being possible where appropriate for two adjacent radicals together to be cyclic groups having 4 to 15 carbon atoms, which comprises reacting compounds of the general formula II ##STR3## where Q is beryllium, magnesium, calcium, strontium or barium, and L.sup.1 and L.sup.2 are Lewis bases with compounds of the general formula III ##STR4## where R.sup.15 and R.sup.16 are C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.10 -cycloalkyl or C.sub.6 -C.sub.15 -aryl.
摘要翻译：制备一般化合物的茂金属络合物的方法，其中取代基具有以下含义：M是钛，锆，铪，钒，铌或钽，X是氟，氯，溴，碘，氢，C1- C 1 -C 15 - 芳基或-OR 5，其中R 5是C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，烷基芳基，芳基 - 烷基，氟代烷基或氟代芳基，在每种情况下，在芳基中的烷基和6至20个碳原子，R 1至R 4和R 6至R 9为氢，C 1 -C 10 - 烷基，5-至7-元环烷基，其又可携带C1-C10-烷基作为取代基，或 C 6 -C 15 - 芳基或芳基 - 烷基时，两个相邻的基团一起可以是具有4至15个碳原子的环状基团，或者具有R 10的Si（R 10）3是C 1 -C 10烷基，C 6 -C 15 芳基或C 3 -C 10 - 环烷基，其中Z是硅，锗，锡或碳，R 11，R 12，R 13和R 14是氢，C 1 -C 10 - 烷基，C 3 -C 10 - 环烷基或C 6 -C 10 - C15-芳基，它也是可能的其中适当地将两个相邻的基团一起作为具有4至15个碳原子的环状基团，其包括使Q为铍，镁，钙，锶或钡的通式II II的化合物与L1和L2反应路易斯碱与通式III的化合物III，其中R 15和R 16是C 1 -C 10 - 烷基，C 3 -C 10 - 环烷基或C 6 -C 15 - 芳基。

5. 发明授权

US4113933A Manufacture of homopolymers and copolymers of .alpha.-monoolefins 失效
标题翻译： “ - 烯烃的共聚物和共聚物的制备”
公开(公告)号：US4113933A
公开(公告)日：1978-09-12
申请号：US762858
申请日：1977-01-27
申请人： Gunther Schweier , Erich Kolk , Heinz Mueller-Tamm , Hans Frielingsdorf , Robert Bachl , Wolfgang Gruber
发明人： Gunther Schweier , Erich Kolk , Heinz Mueller-Tamm , Hans Frielingsdorf , Robert Bachl , Wolfgang Gruber
IPC分类号： C08F10/00 , C08F4/02 , C08F10/02
CPC分类号： C08F10/00
摘要： A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins of 2 to 6 carbon atoms by polymerizing the monomer or monomers by means of a Ziegler catalyst system comprising (1) a catalyst component containing titanium and (2) a particular compound of aluminum, magnesium or zinc, the atomic ratio of titanium from catalyst component (1) to metal (Me) from catalyst component (2) being from 1 : 0.1 to 1 : 500, wherein the titanium-containing catalyst component (1) employed is the solid-phase product (VI) obtained by (1.1) first bringing into contact (1.1.1) a particular finely divided, porous, inorganic oxidic material (I) and (1.1.2) a particular aluminum compound (II) dissolved in an organic solvent, to form a solid-phase product (III) and (1.2) then bringing into contact (1.2.1) the solid-phase product (III) obtained from stage (1.1) and (1.2.2) a solution (IV) which is obtained on bringing together (IVa) 100 parts by weight of a particular alcohol, (IVb) from 0.01 to 6 parts by weight (calculated as titanium) of a titanium trihalide and (IVc) from 0.01 to 4 parts by weight (calculated as magnesium) of a magnesium compound which is soluble in the alcohol (IVa), to form a dispersion (V), and evaporating the dispersion (V) until it has a dry consistency, thus forming the solid-phase product (VI). The new process is particularly advantageous for the manufacture of homopolymers and copolymers having, for example, particularly advantageous morphological properties.

6. 发明申请

US20060172884A1 Supported, titanized chromium catalyst and its use for preparing homopolymers and copolymers of ethylene 有权
标题翻译：负载型，钛酸化铬催化剂及其制备乙烯均聚物和共聚物的用途
公开(公告)号：US20060172884A1
公开(公告)日：2006-08-03
申请号：US11330071
申请日：2006-01-12
申请人： Martin Schneider , Rainer Karer , Dieter Lilge , Volker Rauschenberger , Philipp Rosendorfer , Joachim Wulff-Doring , Gunther Schweier , Martin Lux , Peter Bauer
发明人： Martin Schneider , Rainer Karer , Dieter Lilge , Volker Rauschenberger , Philipp Rosendorfer , Joachim Wulff-Doring , Gunther Schweier , Martin Lux , Peter Bauer
IPC分类号： C08F4/02
CPC分类号： C08F210/16 , C08F2410/04 , C08F4/24 , C08F4/69 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/04 , C08F2500/26
摘要： Novel supported, titanized chromium catalysts for the homopolymerization of ethylene and the copolymerization of ethylene with α-olefins, a process for preparing them and to their use for the polymerization of olefins.
摘要翻译：用于乙烯均聚和乙烯与α-烯烃的共聚合的新型负载的钛化铬催化剂，其制备方法及其用于烯烃聚合的方法。

7. 发明授权

US6022935A Preparation of polymers of alk-1-enes in the presence of a supported metallocene catalyst system and of antistatic agent 失效
标题翻译：在负载型金属茂催化剂体系和抗静电剂的存在下制备烷-1-烯的聚合物
公开(公告)号：US6022935A
公开(公告)日：2000-02-08
申请号：US839811
申请日：1997-04-18
申请人： David Fischer , Helmut Frank , Martin Lux , Roland Hingmann , Gunther Schweier
发明人： David Fischer , Helmut Frank , Martin Lux , Roland Hingmann , Gunther Schweier
IPC分类号： C08F4/64 , C08F2/34 , C08F2/44 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F4/68 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/16 , C08J5/18 , D01F6/04 , D01F6/06 , D01F6/30
CPC分类号： C08J5/18 , C08F10/00 , C08F10/06 , D01F6/04 , D01F6/06 , D01F6/30 , B60K2015/03576 , C08F110/06 , C08F210/16 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F4/63927 , C08J2323/04 , C08J2323/10 , Y10S526/901 , Y10S526/902
摘要： Polymers of C.sub.2 -C.sub.12 -alk-1-enes are prepared at from -50 to 300.degree. C. and from 0.5 to 3000 bar in the presence of a catalyst system by a process in which the catalyst system used is one which containsA) an inorganic or organic carrier,B) a metallocene complex,C) a compound forming metallocenium ions andD) if required, a metal compound of the general formula IM.sup.1 (R.sup.1).sub.r (R.sup.2).sub.s (R.sup.3).sub.t I whereM.sup.1 is an alkali metal, an alkaline earth metal or a metal of main group III of the Periodic Table,R.sup.1 is hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl or arylalkyl, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,R.sup.2 and R.sup.3 are each hydrogen, halogen, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.15 -aryl, alkylaryl, arylalkyl or alkoxy, each having 1 to 10 carbon atoms in the alkyl radical and 6 to 20 carbon atoms in the aryl radical,r is an integer from 1 to 3 ands and t are integers from 0 to 2, the sum r+s+t corresponding to the valency of M.sup.1,and in which an antistatic agent is used.
摘要翻译：在催化剂体系的存在下，在-50至300℃和0.5至3000巴下制备C 2 -C 12烷-1-烯的聚合物，其中使用的催化剂体系是含有A）无机或有机载体，B）茂金属络合物，C）形成金属茂离子的化合物和D）如果需要，通式为IM1（R1）r（R2）s（R3）t1的金属化合物，其中M1为碱金属，碱土金属或元素周期表第Ⅲ族金属的金属，R1是氢，C1-C10烷基，C6-C15 - 芳基，烷基芳基或芳基烷基，它们在烷基中具有1-10个碳原子，芳基中的6至20个碳原子，R 2和R 3各自为氢，卤素，C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，烷基芳基，芳基烷基或烷氧基，每个在烷基中具有1-10个碳原子，6 至20个碳原子，r为1至3的整数，s和t为0至2的整数，r + s + t的总和对应于M1的化合价，其中抗静电剂用来。

8. 发明授权

US5483002A Propylene polymers having low-temperature impact strength 失效
标题翻译：具有低温冲击强度的丙烯聚合物
公开(公告)号：US5483002A
公开(公告)日：1996-01-09
申请号：US303717
申请日：1994-09-09
申请人： Stephan Seelert , Franz Langhauser , Jurgen Kerth , Patrik Muller , David Fischer , Gunther Schweier
发明人： Stephan Seelert , Franz Langhauser , Jurgen Kerth , Patrik Muller , David Fischer , Gunther Schweier
IPC分类号： C08F2/34 , C08F4/642 , C08F4/646 , C08F4/68 , C08F4/69 , C08L23/00 , C08L23/12
CPC分类号： C08L23/12 , C08L2205/02 , C08L2205/025 , C08L2314/02 , C08L2314/06
摘要： Propylene polymers containA) a semicrystalline propylene homopolymer having a melting point of 125 to 165.degree. C. and a glass transition temperature which is greater than -10.degree. C. andB) a semicrystalline propylene homopolymer having a melting point below 130.degree. C. and a glass transition temperature which is less than or equal to -10.degree. C. or a non-crystallizing propylene homopolymer having a glass transition temperature which is less than or equal to -10.degree. C.
摘要翻译：丙烯聚合物含有A）熔点为125〜165℃，玻璃化转变温度大于-10℃的半结晶丙烯均聚物，B）熔点低于130℃的半结晶丙烯均聚物。玻璃化转变温度小于或等于-10℃，或玻璃化转变温度低于-10℃的非结晶丙烯均聚物。

9. 发明申请

US20050085610A1 Random propylene copolymers 有权
公开(公告)号：US20050085610A1
公开(公告)日：2005-04-21
申请号：US10971080
申请日：2004-10-25
申请人： David Appleyard , Franz Langhauser , Murray Horton , Roland Hingmann , Gunther Schweier , Volker Rauschenberger , Ingolf Hennig , Dieter Lilge , Werner Schone , Meinolf Kersting
发明人： David Appleyard , Franz Langhauser , Murray Horton , Roland Hingmann , Gunther Schweier , Volker Rauschenberger , Ingolf Hennig , Dieter Lilge , Werner Schone , Meinolf Kersting
IPC分类号： C08F2/34 , C08F4/02 , C08F4/658 , C08F210/06 , C08F210/16 , D01F6/30 , C08F8/00
CPC分类号： D01F6/30 , C08F210/06 , C08F210/16 , Y10T428/31938 , C08F4/6546 , C08F210/08 , C08F2500/12
摘要： Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4-C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4-C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.

10. 发明申请

US20050085609A1 Random propylene copolymers 有权
标题翻译：无规丙烯共聚物
公开(公告)号：US20050085609A1
公开(公告)日：2005-04-21
申请号：US10971079
申请日：2004-10-25
申请人： David Appleyard , Franz Langhauser , Murray Horton , Roland Hingmann , Gunther Schweier , Volker Rauschenberger , Ingolf Hennig , Dieter Lilge , Werner Schone , Meinolf Kersting
发明人： David Appleyard , Franz Langhauser , Murray Horton , Roland Hingmann , Gunther Schweier , Volker Rauschenberger , Ingolf Hennig , Dieter Lilge , Werner Schone , Meinolf Kersting
IPC分类号： C08F2/34 , C08F4/02 , C08F4/658 , C08F210/06 , C08F210/16 , D01F6/30 , C08F110/00
CPC分类号： D01F6/30 , C08F210/06 , C08F210/16 , Y10T428/31938 , C08F4/6546 , C08F210/08 , C08F2500/12
摘要： Random copolymers of propylene with other 1-alkenes having up to carbon atoms, whose content of comonomers is in the range from 0.7 to 1.4% by weight if the only comonomer present in the propylene copolymers is ethylene, or whose content of comonomers is in the range from 0.7 to 3.0% by weight if at least one C4-C10-1-alkene is present as comonomer, and whose cold-xylene-soluble fraction is from 1.0 to 2.5% by weight if ethylene is present as a comonomer in the propylene copolymers, or whose cold-xylene-soluble fraction is from 0.75 to 2.0% by weight if the only comonomers present are C4-C10-1-alkenes, and a process for preparing the random copolymers of propylene is described, as is their use for producing films, fibers or moldings, and also the films, fibers and moldings themselves and biaxially stretched films made from random propylene copolymers of this type and processes for their production.
摘要翻译：丙烯与具有至多碳原子的其它1-烯烃的无规共聚物，如果丙烯共聚物中存在的共聚单体中唯一的共聚单体为共聚单体，其共聚单体的含量为0.7-1.4重量％，或其共聚单体的含量为如果至少一个C 4 -C 10 - 1-烯烃作为共聚单体存在，其冷二甲苯可溶成分为如果乙烯作为丙烯共聚物中的共聚单体存在，则其重量为1.0至2.5重量％，或者如果仅存在共聚单体为C 4 - 4，则冷二甲苯可溶成分为0.75-2.0重量％描述了用于制备膜，纤维或模制品的方法，以及薄膜，纤维和模制品本身以及双轴的方法制备丙烯的无规共聚物的方法。由这种类型的无规丙烯共聚物制成的拉伸薄膜及其生产方法。

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