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1. 发明授权

US5543547A Method of producing aromatic carbonate 失效
标题翻译：芳香族碳酸酯的制造方法
公开(公告)号：US5543547A
公开(公告)日：1996-08-06
申请号：US384258
申请日：1995-02-03
申请人： Hiroshi Iwane , Hidekazu Miyagi , Satoshi Imada , Shoichi Seo , Takahiro Yoneyama
发明人： Hiroshi Iwane , Hidekazu Miyagi , Satoshi Imada , Shoichi Seo , Takahiro Yoneyama
IPC分类号： C07C68/00 , C07C69/96
CPC分类号： C07C68/005
摘要： The present invention relates to a method of producing an aromatic carbonate by reacting an aromatic hydroxy compound, carbon monoxide and oxygen using as a catalyst a specified catalyst system containing palladium and cerium compounds. Specifically, the present invention relates to a method of producing an aromatic carbonate by reacting an aromatic hydroxy compound, carbon monoxide and oxygen in the presence of a catalyst containing the following compounds:(A) at least one selected from palladium and palladium compounds;(B) at least one of trivalent or tetravalent cerium compounds;(C) at least one selected from quaternary ammonium salts and quaternary phosphonium salts;(D) at least one selected from quinones and reduction products thereof, i.e., aromatic diols; or(A) and (B) components of the above; and(E) at least one inorganic halide selected from alkali metal halides and alkali earth metal halides.
摘要翻译：本发明涉及通过使用含有钯和铈化合物的规定催化剂体系的催化剂使芳香族羟基化合物，一氧化碳和氧气反应来制造芳香族碳酸酯的方法。具体地说，本发明涉及在含有以下化合物的催化剂存在下使芳族羟基化合物，一氧化碳和氧气反应制备芳香族碳酸酯的方法：（A）选自钯和钯化合物中的至少一种; （B）三价或四价铈化合物中的至少一种; （C）选自季铵盐和季鏻盐中的至少一种; （D）选自醌及其还原产物中的至少一种，即芳族二醇; 或（A）和（B）组分; 和（E）至少一种选自碱金属卤化物和碱土金属卤化物的无机卤化物。

2. 发明申请

US20190252672A1 LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 审中-公开
公开(公告)号：US20190252672A1
公开(公告)日：2019-08-15
申请号：US16394100
申请日：2019-04-25
申请人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
发明人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
IPC分类号： H01M4/131 , B60L50/64 , H01M4/587 , H01M10/0567 , H01M10/0569 , H01M10/052 , H01M4/583 , H01M4/505 , H01M2/16 , H01M2/08 , H01M2/02 , H01M10/625 , H01M10/0525 , H01M10/0568 , H01M4/133 , H01M4/1391 , H01M4/1393 , H01M4/485 , H01M4/525 , H01M4/04 , H01M10/613
CPC分类号： H01M4/131 , B60L50/64 , H01M2/0262 , H01M2/0287 , H01M2/08 , H01M2/1673 , H01M4/0428 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/1391 , H01M4/1393 , H01M4/364 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/583 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0587 , H01M10/613 , H01M10/625 , H01M2004/021 , H01M2004/027 , H01M2220/20 , H01M2300/0025 , H01M2300/004 , Y02E60/122 , Y02T10/7011
摘要： Provided is a lithium secondary battery having a nonaqueous electrolyte which contains at least one compound selected from the group consisting of monofluorophosphoric acid salts, and difluorophosphoric acid salts, in an amount of 10 ppm or more of the whole nonaqueous electrolyte, and a negative electrode selected from [1], [2], [3] and [6]: [1]: a negative electrode containing two or more carbonaceous substances differing in crystallinity; [2]: a negative electrode containing an amorphous carbonaceous substance which, when examined by wide-angle X-ray diffractometry, has an interplanar spacing (d002) for the (002) planes of 0.337 nm or larger and a crystallite size (Lc) of 80 nm or smaller and which, in an examination by argon ion laser Raman spectroscopy, has a Raman. R value of 0.2 or higher defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1; [3]: a negative-electrode active material a titanium-containing metal oxide capable of occluding and releasing lithium; [6]: as a negative-electrode active material, graphitic carbon particles which have a roundness of 0.85 or higher and an interplanar spacing (d002) for the (002) planes of smaller than 0.337 nm as determined by wide-angle X-ray diffractometry and which, in an examination by argon ion laser Raman spectroscopy, have a Raman R value of from 0.12 to 0.8 defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1.

3. 发明授权

US09029022B2 Lithium secondary batteries and nonaqueous electrolyte for use in the same 有权
标题翻译：锂二次电池和非水电解质用于其中
公开(公告)号：US09029022B2
公开(公告)日：2015-05-12
申请号：US13614215
申请日：2012-09-13
申请人： Hidekazu Miyagi , Ryoichi Kato , Masakazu Yokomizo , Hiroyuki Uono , Hitoshi Matsumoto , Tomohiro Satou , Minoru Kotato , Takayuki Nakajima , Hitoshi Suzuki , Hiroyuki Oshima
发明人： Hidekazu Miyagi , Ryoichi Kato , Masakazu Yokomizo , Hiroyuki Uono , Hitoshi Matsumoto , Tomohiro Satou , Minoru Kotato , Takayuki Nakajima , Hitoshi Suzuki , Hiroyuki Oshima
IPC分类号： H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/0569 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/36 , H01M10/0568 , H01M4/02
CPC分类号： H01M4/131 , B60L11/1879 , H01M2/0262 , H01M2/0287 , H01M2/08 , H01M2/1673 , H01M4/0428 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/1391 , H01M4/1393 , H01M4/364 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/583 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0587 , H01M10/613 , H01M10/625 , H01M2004/021 , H01M2004/027 , H01M2220/20 , H01M2300/0025 , H01M2300/004 , Y02E60/122 , Y02T10/7011
摘要： A lithium secondary battery is provided. The battery comprises: a positive electrode and a negative electrode which each has a specific composition and specific properties; and a nonaqueous electrolyte which contains a cyclic siloxane compound of formula (1), a fluorosilane compound of formula (2), a compound of formula (3), compound having an S—F bond in the molecule, nitric acid salt, nitrous acid salt, monofluorophosphoric acid salt, difluorophosphoric acid salt, acetic acid salt, or propionic acid salt in an amount of 10 ppm or more of the whole nonaqueous electrolyte.
摘要翻译：提供锂二次电池。电池包括：正电极和负电极，其各自具有特定的组成和特定性质; 和含有式（1）的环状硅氧烷化合物，式（2）的氟硅烷化合物，式（3）化合物，分子中具有S-F键的化合物，硝酸盐，亚硝酸盐，单氟磷酸盐，二氟磷酸盐，乙酸盐或丙酸盐，其量为全部非水电解质的10ppm以上。

4. 发明申请

US20130022861A1 LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 有权
标题翻译：锂二次电池和非电解电解质用于同一电池
公开(公告)号：US20130022861A1
公开(公告)日：2013-01-24
申请号：US13614215
申请日：2012-09-13
申请人： Hidekazu Miyagi , Ryoichi Kato , Masakazu Yokomizo , Hiroyuki Uono , Hitoshi Matsumoto , Tomohiro Satou , Minoru Kotato , Takayuki Nakajima , Hitoshi Suzuki , Hiroyuki Oshima
发明人： Hidekazu Miyagi , Ryoichi Kato , Masakazu Yokomizo , Hiroyuki Uono , Hitoshi Matsumoto , Tomohiro Satou , Minoru Kotato , Takayuki Nakajima , Hitoshi Suzuki , Hiroyuki Oshima
IPC分类号： H01M10/056 , H01M2/02
CPC分类号： H01M4/131 , B60L11/1879 , H01M2/0262 , H01M2/0287 , H01M2/08 , H01M2/1673 , H01M4/0428 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/1391 , H01M4/1393 , H01M4/364 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/583 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0587 , H01M10/613 , H01M10/625 , H01M2004/021 , H01M2004/027 , H01M2220/20 , H01M2300/0025 , H01M2300/004 , Y02E60/122 , Y02T10/7011
摘要： A lithium secondary battery is provided. The battery comprises: a positive electrode and a negative electrode which each has a specific composition and specific properties; and a nonaqueous electrolyte which contains a cyclic siloxane compound of formula (1), a fluorosilane compound of formula (2), a compound of formula (3), compound having an S—F bond in the molecule, nitric acid salt, nitrous acid salt, monofluorophosphoric acid salt, difluorophosphoric acid salt, acetic acid salt, or propionic acid salt in an amount of 10 ppm or more of the whole nonaqueous electrolyte.
摘要翻译：提供锂二次电池。电池包括：正电极和负电极，其各自具有特定的组成和特定性质; 和含有式（1）的环状硅氧烷化合物，式（2）的氟硅烷化合物，式（3）化合物，分子中具有S-F键的化合物，硝酸盐，亚硝酸盐，单氟磷酸盐，二氟磷酸盐，乙酸盐或丙酸盐，其量为全部非水电解质的10ppm以上。

5. 发明申请

US20100015514A1 LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 有权
标题翻译：锂二次电池和非电解电解质用于同一电池
公开(公告)号：US20100015514A1
公开(公告)日：2010-01-21
申请号：US12090655
申请日：2006-10-19
申请人： Hidekazu Miyagi , Ryoichi Kato , Masakazu Yokomizo , Hiroyuki Uono , Hitoshi Matsumoto , Tomohiro Satou , Minoru Kotato , Takayuki Nakajima , Hitoshi Suzuki , Hiroyuki Oshima
发明人： Hidekazu Miyagi , Ryoichi Kato , Masakazu Yokomizo , Hiroyuki Uono , Hitoshi Matsumoto , Tomohiro Satou , Minoru Kotato , Takayuki Nakajima , Hitoshi Suzuki , Hiroyuki Oshima
IPC分类号： H01M10/40
CPC分类号： H01M4/131 , B60L11/1879 , H01M2/0262 , H01M2/0287 , H01M2/08 , H01M2/1673 , H01M4/0428 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/1391 , H01M4/1393 , H01M4/364 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/583 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0587 , H01M10/613 , H01M10/625 , H01M2004/021 , H01M2004/027 , H01M2220/20 , H01M2300/0025 , H01M2300/004 , Y02E60/122 , Y02T10/7011
摘要： A lithium secondary battery comprising: a positive electrode and a negative electrode which each has a specific composition and specific properties; and a nonaqueous electrolyte which contains a cyclic siloxane compound represented by general formula (1), fluorosilane compound represented by general formula (2), compound represented by general formula (3), compound having an S—F bond in the molecule, nitric acid salt, nitrous acid salt, monofluorophosphoric acid salt, difluorophosphoric acid salt, acetic acid salt, or propionic acid salt in an amount of 10 ppm or more of the whole nonaqueous electrolyte. This lithium secondary battery has a high capacity, long life, and high output. [In general formula (1), R1 and R2 are an organic group having 1-12 carbon atoms and n is an integer of 3-10. In general formula (2), R3 to R5 are an organic group having 1-12 carbon atoms; x is an integer of 1-3; and p, q, and r each are an integer of 0-3, provided that 1≦p+q+r≦3. In general formula (3), R6 to R8 are an organic group having 1-12 carbon atoms and symbol A is a group constituted of H, C, N, O, F, S, Si, and/or P.]
摘要翻译：一种锂二次电池，包括：正极和负极，它们各自具有特定的组成和特定性能; 和含有通式（1）表示的环状硅氧烷化合物，通式（2）表示的氟硅烷化合物，通式（3）表示的化合物，分子中具有SF键的化合物，硝酸盐，亚硝酸盐，单氟磷酸盐，二氟磷酸盐，乙酸盐或丙酸盐，其量为全部非水电解质的10ppm以上。该锂二次电池具有容量大，寿命长，输出高的特点。 [通式（1）中，R 1，R 2为碳原子数1〜12的有机基团，n为3-10的整数。在通式（2）中，R 3至R 5为具有1-12个碳原子的有机基团; x是1-3的整数; 并且p，q和r各自为0-3的整数，条件是1 <= p + q + r <= 3。在通式（3）中，R 6至R 8为具有1-12个碳原子的有机基团，符号A为由H，C，N，O，F，S，Si和/或P构成的基团。

6. 发明授权

US6147265A Process for producing alkylene glycol 失效
标题翻译：亚烷基二醇的制备方法
公开(公告)号：US6147265A
公开(公告)日：2000-11-14
申请号：US66773
申请日：1998-04-27
申请人： Tomoatsu Iwakura , Hidekazu Miyagi
发明人： Tomoatsu Iwakura , Hidekazu Miyagi
IPC分类号： C07C29/10 , C07C27/00
CPC分类号： C07C29/106 , Y02P20/52
摘要： A process for producing an alkylene glycol which comprises a step of reacting an alkylene oxide with water in the presence of a catalyst, wherein the catalyst comprises an anion-exchange resin comprising: a polymer of a vinylaromatic compound as a substrate; and quaternary ammoniums group each bonded to the respective aromatic groups of the polymer substrate via a connecting group having a chain length of three or more atoms.
摘要翻译：一种制备亚烷基二醇的方法，其包括在催化剂存在下使烯化氧与水反应的步骤，其中所述催化剂包含阴离子交换树脂，其包含：作为底物的乙烯基芳族化合物的聚合物; 和各自通过链长为3个以上原子的连接基团与高分子基材的各芳香族基团键合的季铵基。

7. 发明申请

US20170040593A1 LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 审中-公开
标题翻译：锂二次电池和非电解电解质用于同一电池
公开(公告)号：US20170040593A1
公开(公告)日：2017-02-09
申请号：US15291314
申请日：2016-10-12
申请人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
发明人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
IPC分类号： H01M4/131 , H01M10/0568 , H01M4/133 , H01M4/04 , H01M4/1393 , H01M4/525 , H01M4/485 , H01M4/587 , H01M10/0525 , H01M4/1391
摘要： Provided is a lithium secondary battery having a nonaqueous electrolyte which contains at least one compound selected from the group consisting of monofluorophosphoric acid salts; and difluorophosphoric acid salts, in an amount of 10 ppm or more of the whole nonaqueous electrolyte, and a negative electrode selected from [1], [2], [3] and [6]: [1]: a negative electrode containing two or more carbonaceous substances differing in crystallinity; [2]: a negative electrode containing an amorphous carbonaceous substance which, when examined by wide-angle X-ray diffractometry, has an interplanar spacing (d002) for the (002) planes of 0.337 nm or larger and a crystallite size (Lc) of 80 nm or smaller and which, in an examination by argon ion laser Raman spectroscopy, has a Raman. R value of 0.2 or higher defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1; [3]: a negative-electrode active material a titanium-containing metal oxide capable of occluding and releasing lithium; [6]: as a negative-electrode active material, graphitic carbon particles which have a roundness of 0.85 or higher and an interplanar spacing (d002) for the (002) planes of smaller than 0.337 nm as determined by wide-angle X-ray diffractometry and which, in an examination by argon ion laser Raman spectroscopy, have a Raman R value of from 0.12 to 0.8 defined as the ratio of the peak intensity at 1,360 cm−1 to the peak intensity at 1,580 cm−1.
摘要翻译：一种锂二次电池，包括：正极和负极，它们各自具有特定的组成和特定性能; 和含有通式（1）表示的环状硅氧烷化合物，通式（2）表示的氟硅烷化合物，通式（3）表示的化合物，分子中具有SF键的化合物，硝酸盐，亚硝酸盐，单氟磷酸盐，二氟磷酸盐，乙酸盐或丙酸盐，其量为全部非水电解质的10ppm以上。该锂二次电池具有容量大，寿命长，输出高的特点。 [通式（1）中，R 1和R 2为碳原子数1〜12的有机基团，n为3-10的整数。通式（2）中，R 3〜R 5为具有1-12个碳原子的有机基团， x是1-3的整数; 并且p，q和r各自为0-3的整数，条件是1‰p + q + r‰3.在通式（3）中，R 6至R 8为具有1-12个碳原子的有机基团符号A是由H，C，N，O，F，S，Si和/或P构成的基团。

8. 发明申请

US20150243936A1 LITHIUM SECONDARY BATTERIES AND NONAQUEOUS ELECTROLYTE FOR USE IN THE SAME 审中-公开
标题翻译：锂二次电池和非电解电解质用于同一电池
公开(公告)号：US20150243936A1
公开(公告)日：2015-08-27
申请号：US14660517
申请日：2015-03-17
申请人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
发明人： Hidekazu MIYAGI , Ryoichi KATO , Masakazu YOKOMIZO , Hiroyuki UONO , Hitoshi MATSUMOTO , Tomohiro SATOU , Minoru KOTATO , Takayuki NAKAJIMA , Hitoshi SUZUKI , Hiroyuki OSHIMA
IPC分类号： H01M2/02 , H01M10/0567 , H01M2/08 , B60L11/18 , H01M10/0587 , H01M4/583 , H01M4/505 , H01M10/0525 , H01M2/16
摘要： A lithium secondary battery comprising a battery case and an electrode group is provided. The electrode group comprises a positive electrode, a negative electrode, a microporous film separator and a nonaqueous electrolyte comprising a lithium salt. The electrode group and the nonaqueous electrolyte are held in the battery case and the electrodes each comprise a current collector and an active-material layer containing an active material capable of occluding/releasing a lithium ion. The nonaqueous electrolyte comprises a difluorophosphoric acid salt in an amount of 10 ppm or more of the whole nonaqueous electrolyte. The battery case comprises a casing material in which at least part of the battery inner side comprises a sheet formed from a thermoplastic resin and with which the electrode group can be enclosed by placing the electrode group in the casing material and heat sealing layers of the thermoplastic resin to each other.
摘要翻译：提供了包括电池壳体和电极组的锂二次电池。电极组包括正极，负极，微孔膜分离器和包含锂盐的非水电解质。电极组和非水电解质保持在电池壳体中，电极各自包含集流体和含有能够吸留/释放锂离子的活性物质的活性物质层。非水电解质包含全部非水电解质的10ppm以上的二氟磷酸盐。电池壳体包括壳体材料，其中电池内侧的至少一部分包括由热塑性树脂形成的片材，并且可以通过将电极组放置在外壳材料中并且可以封闭电极组，并且热塑性塑料的热封层树脂彼此。

9. 发明授权

US09112236B2 Lithium secondary batteries and nonaqueous electrolyte for use in the same 有权
标题翻译：锂二次电池和非水电解质用于其中
公开(公告)号：US09112236B2
公开(公告)日：2015-08-18
申请号：US12090655
申请日：2006-10-19
申请人： Hidekazu Miyagi , Ryoichi Kato , Takayuki Nakajima , Hitoshi Suzuki , Hiroyuki Oshima
发明人： Hidekazu Miyagi , Ryoichi Kato , Takayuki Nakajima , Hitoshi Suzuki , Hiroyuki Oshima
IPC分类号： H01M10/05 , H01M10/052 , H01M10/0567 , H01M10/0569 , H01M4/131 , H01M4/133 , H01M4/134 , H01M4/36 , H01M10/0568 , H01M4/02
CPC分类号： H01M4/131 , B60L11/1879 , H01M2/0262 , H01M2/0287 , H01M2/08 , H01M2/1673 , H01M4/0428 , H01M4/0471 , H01M4/133 , H01M4/134 , H01M4/1391 , H01M4/1393 , H01M4/364 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/583 , H01M4/587 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/0587 , H01M10/613 , H01M10/625 , H01M2004/021 , H01M2004/027 , H01M2220/20 , H01M2300/0025 , H01M2300/004 , Y02E60/122 , Y02T10/7011
摘要： A lithium secondary battery comprising: a positive electrode and a negative electrode which each has a specific composition and specific properties; and a nonaqueous electrolyte which contains a cyclic siloxane compound represented by general formula (1), fluorosilane compound represented by general formula (2), compound represented by general formula (3), compound having an S—F bond in the molecule, nitric acid salt, nitrous acid salt, monofluorophosphoric acid salt, difluorophosphoric acid salt, acetic acid salt, or propionic acid salt in an amount of 10 ppm or more of the whole nonaqueous electrolyte. This lithium secondary battery has a high capacity, long life, and high output. [In general formula (1), R1 and R2 are an organic group having 1-12 carbon atoms and n is an integer of 3-10. In general formula (2), R3 to R5 are an organic group having 1-12 carbon atoms; x is an integer of 1-3; and p, q, and r each are an integer of 0-3, provided that 1≦p+q+r≦3. In general formula (3), R6 to R8 are an organic group having 1-12 carbon atoms and symbol A is a group constituted of H, C, N, O, F, S, Si, and/or P.]
摘要翻译：一种锂二次电池，包括：正极和负极，它们各自具有特定的组成和特定性能; 和含有通式（1）表示的环状硅氧烷化合物，通式（2）表示的氟硅烷化合物，通式（3）表示的化合物，分子中具有S-F键的化合物，硝酸盐，亚硝酸盐，单氟磷酸盐，二氟磷酸盐，乙酸盐或丙酸盐，其总量为全部非水电解质的10ppm以上。该锂二次电池具有容量大，寿命长，输出高的特点。 [通式（1）中，R 1，R 2为碳原子数1〜12的有机基团，n为3-10的整数。在通式（2）中，R 3至R 5为具有1-12个碳原子的有机基团; x是1-3的整数; 并且p，q和r各自为0-3的整数，条件是1＆nlE; p + q + r＆nlE; 3。在通式（3）中，R 6至R 8为具有1-12个碳原子的有机基团，符号A为由H，C，N，O，F，S，Si和/或P构成的基团。

10. 发明授权

US5498789A Method of producing aromatic carbonate 失效
标题翻译：芳香族碳酸酯的制造方法
公开(公告)号：US5498789A
公开(公告)日：1996-03-12
申请号：US348116
申请日：1994-11-28
申请人： Masatoshi Takagi , Hidekazu Miyagi , Yuji Ohgomori , Hiroshi Iwane
发明人： Masatoshi Takagi , Hidekazu Miyagi , Yuji Ohgomori , Hiroshi Iwane
IPC分类号： C07C68/00 , C07C69/96
CPC分类号： C07C68/005
摘要： The present invention relates to a method of producing an aromatic carbonate by reacting an aromatic hydroxy compound, carbon monoxide and oxygen using a catalyst system for suppressing the production of aryl aromatic o-hydroxycarboxylate as a by-product. The catalyst system consists of the following compounds:(A) at least one selected from palladium and palladium compounds;(B) at least one selected from lead compounds; and(C) at least one halide selected from quaternary ammonium halides and quaternary phosphonium halides; and if required,(D) at least one selected from copper and copper compounds.The method of the present invention can increase the yield of an aromatic carbonate per palladium (the turnover number of palladium).
摘要翻译：本发明涉及通过芳香族羟基化合物，一氧化碳和氧气的反应来制造芳香族碳酸酯的方法，该催化剂体系用于抑制作为副产物的芳基芳族邻羟基羧酸酯的生产。催化剂体系由以下化合物组成：（A）选自钯和钯化合物中的至少一种; （B）选自铅化合物中的至少一种; 和（C）选自季铵卤化物和季鏻卤化物的至少一种卤化物; 如果需要，（D）选自铜和铜化合物中的至少一种。本发明的方法可以提高每钯的芳族碳酸酯的收率（钯的转换数）。

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