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1. 发明授权

US08192706B2 Method and device for purifying the flue gases of a sintering process of ores and/or other material-containing materials in metal production 有权
标题翻译：在金属生产中净化矿石和/或其他含材料的烧结过程的烟道气的方法和装置
公开(公告)号：US08192706B2
公开(公告)日：2012-06-05
申请号：US12518837
申请日：2007-12-14
申请人： Horst Grochowski
发明人： Horst Grochowski
IPC分类号： B01D53/46 , B01D53/74
CPC分类号： B01D53/08 , B01D53/60 , B01D53/685 , B01D53/83 , B01D2251/2062 , B01D2253/102 , B01D2257/2045 , B01D2258/025 , Y02A50/2344
摘要： A method for purifying waste gases of an at least partially burnt solid fuel to reduce pollutants such as SOx and/or HCl and NOx. The waste gas flows into a moving bed reactor from below through a lower and upper layer of an adsorption and/or absorption agent already polluted with NOx, SOx and/or HCl. SOx and/or HCl components are adsorbed from the waste gas into the NOx loaded adsorption and/or absorption agent. Thereafter, the waste gas is mixed with an ammonium-containing compound and flows through an upper horizontal gas inflow and bulk material removal tray of the moving bed reactor into the upper layer of the adsorption and/or absorption agent already polluted with NOx and small quantities of SOx and/or HCl. During the throughflow of the upper layer, NOx components are adsorbed from the waste gas onto the adsorption/absorption agent.
摘要翻译：一种用于净化至少部分燃烧的固体燃料的废气以减少诸如SOx和/或HCl和NOx的污染物的方法。废气通过已经用NO x，SO x和/或HCl污染的吸附剂和/或吸收剂的下层和上层从下方流入移动床反应器。 SO x和/或HCl组分从废气中吸附到负载NO x的吸附剂和/或吸收剂中。此后，将废气与含铵化合物混合，并通过移动床反应器的上部水平气体流入和散装材料移除托盘流入已被NO x和少量的污染的吸附剂和/或吸收剂的上层的SOx和/或HCl。在上层的通流期间，NOx成分从废气中吸附到吸附剂上。

2. 发明申请

US20100296991A1 METHOD AND DEVICE FOR PURIFYING THE FLUE GASES OF A SINTERING PROCESS OF ORES AND/OR OTHER MATERIAL-CONTAINING MATERIALS IN METAL PRODUCTION 有权
标题翻译：用于净化金属和/或金属生产中其他含材料的烧结过程的燃烧气体的方法和装置
公开(公告)号：US20100296991A1
公开(公告)日：2010-11-25
申请号：US12518837
申请日：2007-12-14
申请人： Horst Grochowski
发明人： Horst Grochowski
IPC分类号： B01D53/50 , B01D53/72 , B01D53/56 , B01D53/68 , B01D53/70
CPC分类号： B01D53/08 , B01D53/60 , B01D53/685 , B01D53/83 , B01D2251/2062 , B01D2253/102 , B01D2257/2045 , B01D2258/025 , Y02A50/2344
摘要： In a method for the purifying of the waste gases of a sintering process of ores in the production of metals, in which ore material is sintered with a solid fuel, with the combustion of the solids and passage through a smoldering process, at least the pollutants SOx and/or HCl and NOx are reduced or extensively eliminated. To this end, the sintering waste gas is guided into a moving bed reactor (50) from below through a lower and upper layer (54B; 54A) of an adsorption and/or absorption agent already polluted with NOx and SOx and/or HCl, wherein at least the main quantity of SOx and/or HCl components is adsorbed from the sintering waste gas into the pore system of the NOx-loaded adsorption and/or absorption agent. The sintering waste gas, purified of the main quantity of SOx and/or HCl components, is intimately mixed with an ammonium-containing compound, such as ammonia or urea, and flows in below through an upper horizontal gas inflow and bulk material removal tray (52A) of the moving bed reactor into the upper layer of the adsorption and/or absorption agent already polluted with NOx and small quantities of SOx and/or HCl. In the throughflow of the upper layer (54A), at least the main quantity of NOx components is adsorbed from the sintering waste gas onto the surface of the adsorption/absorption agent, loaded with NOx or N2 and small quantities of SOx and/or HCl.Fresh and/or regenerated adsorption/absorption agent is delivered, via a bulk material-distributing tray (50C), at the upper end of the moving bed reactor and subsequently migrates, without interruption, through the upper and lower layers of the entire moving bed reactor, wherein initially, NOx and N2 and water vapor is adsorbed onto its surface, and subsequently, with SOx, and/or HCl, in its pore system.
摘要翻译：在一种用于净化矿石在生产金属中的废气的方法中，其中矿石材料与固体燃料一起烧结，随着固体的燃烧和通过阴燃过程，至少污染物 SO x和/或HCl和NO x被还原或广泛消除。为此，烧结废气通过已经用NO x和SO x和/或HCl污染的吸附剂和/或吸收剂的下层和上层（54B; 54A）从下方引导到移动床反应器（50）中，其中SO x和/或HCl组分的至少主要量从烧结废气吸附到负载NO x的吸附剂和/或吸收剂的孔体系中。将主要量的SO x和/或HCl组分的纯化的烧结废气与含氨的化合物如氨或尿素紧密混合，并通过上部水平的气体流入和散装材料移除盘 52A）移动床已被NO x和少量SO x和/或HCl污染的吸附剂和/或吸收剂的上层。在上层（54A）的通流中，至少将主要量的NOx成分从烧结废气吸附到负载有NOx或N 2的吸附/吸收剂的表面上，并且少量的SO x和/或HCl 。新鲜和/或再生的吸附/吸收剂通过散装物料分配托盘（50C）在移动床反应器的上端输送，随后不间断地通过整个移动床的上层和下层反应器，其中最初，NOx和N 2以及水蒸汽在其表面上被吸附，随后在其孔系统中被吸附在SOx和/或HCl中。

3. 发明申请

US20080206120A1 Method For Purifying Waste Gases of a Glass Melting Process, Particularly For Glasses For Lcd Display 有权
公开(公告)号：US20080206120A1
公开(公告)日：2008-08-28
申请号：US11795106
申请日：2006-01-12
申请人： Horst Grochowski
发明人： Horst Grochowski
IPC分类号： B01D53/54
CPC分类号： B01D53/10 , B01D53/565 , B01D53/8625 , Y10S423/16
摘要： The invention relates to a method for purifying waste gases of a glass melting process during which SiO2-containing raw material for glass production having additives such as boron, arsenic and/or other, in particular, metal compounds is fed to the glass tank, and molten glass is withdrawn from the glass tank (1), this glass tank being heated by means of hot combustion waste gases. The waste gas of the glass melting process, which emanates from the combustion waste gas and/or from the glass melt, contains, in addition to gas constituents such as CO2, O2, H2O and/or N2 at least NOx as well as compounds resulting or escaping from the raw material as pollutant constituents and, optionally, SO2, HCl, heavy metals, in particular, Hg, dioxins, furans, dusts, condensable residues and/or sublimates of a portion of the inorganic pollutant constituents. In a moving bed reactor system (8) on at least one catalytically active adsorbent and/or absorbent, the waste gases of the glass melting process are, in essence, liberated in at least two stages from the pollutant components into one and the same moving bed. In the immediate inflow area and, optionally, in an adjacent lower layer of the moving bed (first separation stage, 8A) from the catalyst-damaging pollutant constituents consisting of catalyst-damaging compounds at least emanating from the composition of the raw material, these compounds being, e.g. boron and/or arsenic compositions, are bound in an absorptive manner, and the particle-shaped constituents are adhered, and the catalytic denitration is extensively carried out in the layer area (second separation stage, 8B) adjoining the direct inflow area and, optionally, the adjacent lower layer of the moving bed, and other optionally existing non-catalyst-damaging pollutant constituents such as dioxins and furans are absorptively removed in this second separation stage.

4. 发明授权

US5603907A Process and device for treating fluids by means of a pourable solid by the countercurrent method 失效
标题翻译：通过逆流法通过可倾倒固体处理流体的方法和装置
公开(公告)号：US5603907A
公开(公告)日：1997-02-18
申请号：US449286
申请日：1995-05-24
申请人： Horst Grochowski
发明人： Horst Grochowski
IPC分类号： B01D46/34 , B01D53/08 , B01D53/34 , B01D53/74 , B01D53/81 , B01D53/86 , B01D53/94 , B01J8/12 , B01D47/00
CPC分类号： B01D53/12 , B01D46/34 , B01D53/08 , B01D53/74 , B01D53/86 , B01J8/12 , B01D2253/102 , B01D2253/25 , B01D2257/2045 , B01D2257/206 , B01D2257/302 , B01D2257/404 , B01D2257/602 , B01D2258/0283 , B01D2259/40081
摘要： A process and device for the treatment of fluid, such as flue gas. A moving bed reactor has several reaction chambers. The reaction chambers are located in parallel flow locations. A solid bulk material is located in the reaction chambers. The fluid flows through the reaction chambers in parallel, from bottom to top of each reaction chamber. As the fluid flows through the reaction chambers, the fluid interacts with the bulk material to alter the fluid. Specifically, the bulk material absorbs and/or acts as a catalyst to remove impurities from the fluid. Flow through each of the reaction chambers can be interrupted without interruption of flow through the other reaction chambers. Some of the bulk material in each reaction chamber can be removed, as a layer, from the bottom and a replacement amount can be added, as a layer to the top.
摘要翻译：用于处理流体的方法和装置，例如废气。移动床反应器具有几个反应室。反应室位于平行的流动位置。固体散装材料位于反应室中。流体从每个反应室的底部到顶部平行地流过反应室。当流体流过反应室时，流体与散装材料相互作用以改变流体。具体地，散装材料吸收和/或用作催化剂以从流体中除去杂质。可以中断通过每个反应室的流动，而不会中断通过其它反应室的流动。每个反应室中的一些散装材料可以作为一层从底部去除，并且替代量可以作为层的顶部被去除。

5. 发明授权

US4149858A Method and apparatus for the separation of sulfur & nitrogen oxides from a waste gas 失效
标题翻译：用于从废气中分离硫和氮氧化物的方法和装置
公开(公告)号：US4149858A
公开(公告)日：1979-04-17
申请号：US803595
申请日：1977-06-06
申请人： Rolf Noack , Horst Lichtenberger , Stefan Gramelt , Harald Juntgen , Karl Knoblauch , Horst Grochowski , Jurgen Schwarte
发明人： Rolf Noack , Horst Lichtenberger , Stefan Gramelt , Harald Juntgen , Karl Knoblauch , Horst Grochowski , Jurgen Schwarte
IPC分类号： B01D53/06 , B01D53/08 , B01D19/00
CPC分类号： B01D53/08 , B01D2253/102 , B01D2257/302 , B01D2257/404 , B01D2258/0283 , B01D53/12
摘要： A method and apparatus for separating undesirable components from a waste gas by adsorption of the components onto a granular adsorbent. The gas is caused to flow serially through two distinct side-by-side layers of adsorbent both moving parallel to one another in a direction perpendicular to the direction of gas flow. The adsorbent material is so controlled that the particles of the second layer to be contacted by the gas are less loaded with impurities than the particles of the first layer. In one embodiment, this result is achieved by moving the second layer faster than the first layer.
摘要翻译：一种通过将组分吸附到颗粒状吸附剂上而从废气中分离不需要的组分的方法和装置。导致气体串联地流过沿着与气体流动方向垂直的方向彼此平行移动的两个不同并排的吸附剂层。吸附剂材料受到如此控制，使得与气体接触的第二层的颗粒的负载量比第一层的颗粒少。在一个实施例中，通过使第二层比第一层更快地实现该结果。

6. 发明申请

US20120216873A1 FLUID TREATMENT SYSTEM WITH BULK MATERIAL BEDS OPERATED IN PARALLEL AND METHOD FOR OPERATING SUCH A SYSTEM 有权
标题翻译：具有并行运行的大块材料床的流体处理系统和用于操作这种系统的方法
公开(公告)号：US20120216873A1
公开(公告)日：2012-08-30
申请号：US13464437
申请日：2012-05-04
申请人： Horst Grochowski
发明人： Horst Grochowski
IPC分类号： F17D1/00
CPC分类号： B01J8/002 , B01D53/08 , B01D53/8609 , B01D53/8631 , B01D2257/302 , B01D2257/404 , B01J8/003 , B01J8/0035 , B01J8/12 , B01J8/125 , B01J19/248 , B01J2208/00752 , B01J2208/00761 , B01J2208/00769 , Y10T137/0318 , Y10T137/87153
摘要： A fluid treatment system having bulk beds. The fluid to be treated essentially streams from the bottom up through a bulk bed, while the bulk material migrates through the bulk beds in countercurrent to the fluid essentially from the top down. This is accomplished by removing partial quantities of bulk material at the lower end of the bulk bed, and delivering partial quantities of the bulk material to the bulk bed at the top. At least one charging wagon provided with optionally sealable bulk material outlets is able to traverse a charging channel between a charging position and several partial bulk bed release positions above the bulk beds. Provided below the bulk material outlets and the bulk material valve of the charging wagon are bulk material through pipes, the bulk material outlet mouths of which end on bulk material cones of an underlying bulk bed.
摘要翻译：具有散装床的流体处理系统。待处理的流体基本上从底部向上流动通过散装床，而散装材料基本上从顶部向下流动通过散装床与流体逆流。这通过在散装床的下端去除部分量的散装材料并将部分量的散装材料输送到顶部的散装床来实现。设置有可选地可密封的散装材料出口的至少一个充电货车能够在充电位置和批量床之上的几个部分散装板释放位置之间穿过充电通道。在散装物料出口和装载货车的散装材料阀门下方设有通过管道的散装材料，其主体材料出口口在下面的散装床的散装材料锥体上。

7. 发明授权

US07666374B2 Method for cleaning exhaust gases produced by a sintering process for ores and/or other metal-containing materials in metal production 有权
标题翻译：用于在金属生产中清理用于矿石和/或其它含金属材料的烧结工艺产生的废气的方法
公开(公告)号：US07666374B2
公开(公告)日：2010-02-23
申请号：US11883862
申请日：2006-02-08
申请人： Horst Grochowski
发明人： Horst Grochowski
IPC分类号： B01D53/34 , B01D53/38 , B01D53/50 , B01D53/56 , B01D53/64 , B01D53/68 , B01D53/72
CPC分类号： B01D46/34 , B01D53/08 , B01D2251/404 , B01D2251/604 , B01D2253/102 , B01D2257/2045 , B01D2257/206 , B01D2257/302 , B01D2257/404 , B01D2257/602 , B01D2257/70 , B01D2257/704 , B01D2258/025 , B01D2259/40081 , B01D2259/4145 , Y10S423/16
摘要： The invention relates to a process for cleaning exhaust gases produced by a sintering process of metal-containing waste. The sintering exhaust gas includes one or more harmful substances which are eliminated in at least two steps by at least one adsorption and/or absorption agent in a single moving bed in a moving bed reactor system. The moving bed includes a particle layer (stage I) disposed above a flow input area and below an adsorption layer (stage II) of the moving bed. One or more harmful substances in the sintering exhaust gas are absorptively or adsorptively bound to potassium and/or sodium compounds and the harmful substances are trapped by adhesion in the flow input area or the Particle layer (stage I) of the moving bed. The substantial removal of NOx and the adsorptive or absorptive removal of dioxins and furans takes place in the adsorption layer (stage II) in the moving bed.
摘要翻译：本发明涉及一种清洗含金属废物的烧结工艺产生的废气的方法。烧结废气包括一种或多种在移动床反应器系统中的单个移动床中通过至少一种吸附剂和/或吸收剂在至少两个步骤中消除的有害物质。移动床包括设置在流动输入区域上方和移动床的吸附层（阶段II）之下的颗粒层（阶段I）。烧结废气中的一种或多种有害物质吸收或吸附结合于钾和/或钠化合物，并且有害物质通过流动输入区域或移动床的颗粒层（阶段I）的粘附而被捕获。在移动床中的吸附层（阶段II）中发生NOx的大量去除和二恶英和呋喃的吸附或吸收去除。

8. 发明授权

US4400363A Method for the removal of sulfur oxides and nitrogen oxides from exhaust gases 失效
标题翻译：从废气中去除硫氧化物和氮氧化物的方法
公开(公告)号：US4400363A
公开(公告)日：1983-08-23
申请号：US253652
申请日：1981-04-13
申请人： Horst Grochowski , Karl Knoblauch
发明人： Horst Grochowski , Karl Knoblauch
IPC分类号： B01D53/08 , B01D53/60 , B01D53/74 , B01D53/86 , B01D53/94 , B01J8/00 , C01B21/00 , C01B17/00
CPC分类号： B01D53/8637 , B01D53/60 , Y02C20/10
摘要： Sulfur oxides and nitrogen oxides are removed from exhaust gases containing additionally oxygen and steam, by the addition of gaseous ammonia at temperatures between about 110.degree. and 180.degree. C. The exhaust gases travel in the interior of a reactor across a travelling bed which goes from above to below, composed of granulated, carbon-containing adsorbent with or without catalysts. In the first travelling bed initially a large portion of the sulfur oxides is adsorptively removed. In the second travelling bed after dosed addition of gaseous ammonia the nitrogen oxides are catalytically reduced to nitrogen as well as further sulfur oxides being separated. The improvement involves extending the path of the exhaust gases between the first and the second travelling beds and introducing into the volume of the exhaust gas stream between the travelling beds a forced mixture of dosed added ammonia with the exhaust gas departing from the first travelling bed.
摘要翻译：通过在约110℃和180℃之间的温度下加入气态氨，将硫氧化物和氮氧化物从另外含氧和蒸汽的废气中除去。废气在反应器内部行进通过一个从由含有或不含催化剂的颗粒状含碳吸附剂组成。在第一个行进床中，最初大部分硫氧化物被吸附除去。在加入气态氨后的第二个移动床中，氮氧化物被催化还原为氮气，并进一步分离出硫氧化物。改进之处在于延长排气在第一和第二行进床之间的路径，并将进料床之间的排气流与从第一行进床排出的废气的强制混合物引入到排气流的体积中。

9. 发明授权

US5441704A Fluidized bed reactor arrangement 失效
标题翻译：流化床反应器装置
公开(公告)号：US5441704A
公开(公告)日：1995-08-15
申请号：US182667
申请日：1994-01-14
申请人： Horst Grochowski
发明人： Horst Grochowski
IPC分类号： B01D53/08 , B01D53/86 , B01J8/12 , B01J8/14 , B01J8/28
CPC分类号： B01J8/12 , B01D53/08 , B01D2253/102 , B01D2257/302 , B01D2257/404 , B01D2257/602 , B01D2258/0291 , B01D2259/40007 , B01D2259/40081 , B01D2259/402 , B01D53/12
摘要： A fluidized bed reactor arrangement (1) for the treatment of fluids by means of solid matter that is present in the form of bulk material (2), preferably in a countercurrent process, in which at least one bulk material moves from the top to the bottom and at least one fluid flows from the bottom to the top. The reactor is particularly intended to provide a better flexibility in the bulk material distribution into or in the bulk material discharge from at least two reaction chambers (5A, 5B) arranged on top of each other. Each reaction chamber is provided with a flow-past base (6A, 6B) for the distribution of the fluid over the cross section of the reaction chamber. Each reaction chamber is also provided with a bulk material distribution base (4A, 4B) for the distribution of bulk material over the cross section of the reaction chamber. Means (34,34B) are provided for distributing bulk material to the lower reaction chamber through the upper reaction chamber separately from the bulk material located in the upper reaction chamber, and means (9A) are provided for discharging bulk material from the upper reaction chamber through the lower reaction chamber separately from the bulk material in the lower reaction chamber.
摘要翻译： PCT No.PCT / EP90 / 00768 Sec。 371日期：1991年11月19日 102（e）1991年11月19日PCT PCT 1990年5月12日PCT公布。 WO90 / 14156 PCT公开号日期：1990年11月29日。一种流化床反应器装置（1），用于通过以块状材料（2）形式存在的固体物质处理流体，优选以逆流方式存在，其中至少一个体积材料从顶部移动到底部，并且至少一个流体从底部流向顶部。反应器特别旨在提供在从彼此顶部布置的至少两个反应室（5A，5B）排放到散装材料中或散装物质中的散装材料中的更好的柔性。每个反应室设置有流过基底（6A，6B），用于在反应室的横截面上分配流体。每个反应室还设置有用于在反应室的横截面上分配散装材料的散装材料分配基座（4A，4B）。提供装置（34,34B），用于通过与上反应室中的主体材料分离的上反应室将散装材料分配到下反应室，并且提供装置（9A）用于从上反应室通过下反应室与下反应室中的散装材料分开。

10. 发明授权

US4695444A Method of manufacturing sulphur from SO.sub.2 containing gases 失效
标题翻译：从含SO2的气体制造硫的方法
公开(公告)号：US4695444A
公开(公告)日：1987-09-22
申请号：US432398
申请日：1982-09-30
申请人： Horst Grochowski , Dieter Zurawsky , Karl Knoblauch , Klaus Goldschmidt , Jurgen Schwarte
发明人： Horst Grochowski , Dieter Zurawsky , Karl Knoblauch , Klaus Goldschmidt , Jurgen Schwarte
IPC分类号： C01B17/04 , C01B17/16 , C01B17/02
CPC分类号： C01B17/0482
摘要： Sulphur is manufactured out of sulphur dioxide containing gases by dividing the feed gas in two flows of gas having a volume ratio of 2 to 1 and reducing the greater flow of gas on a carbon containing substance like anthracite, thereby obtaining hydrogen sulfide which is mixed with the smaller flow of gas, the mixture being converted in a Claus process to sulphur.
摘要翻译：通过将体积比为2:1的两股气体中的进料气体除以减少含碳物质如无烟煤的气体流量，由含二氧化硫气体制造硫，从而得到与硫化氢混合的硫化氢较小的气体流，该混合物在克劳斯过程中转化成硫。

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