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1. 发明授权

US08053567B2 Modified surface material, method for preparing same and uses thereof 有权
标题翻译：改性表面材料及其制备方法及其应用
公开(公告)号：US08053567B2
公开(公告)日：2011-11-08
申请号：US11628205
申请日：2005-06-02
申请人： Mohamed Mehdi Chehimi , Jean Pinson , Bernadette Charleux , Christophe Bureau , Christopher Tronche , Tarik Matrab , Christian Perruchot , Eva Cabet-Deliry , Maud Save
发明人： Mohamed Mehdi Chehimi , Jean Pinson , Bernadette Charleux , Christophe Bureau , Christopher Tronche , Tarik Matrab , Christian Perruchot , Eva Cabet-Deliry , Maud Save
IPC分类号： C08F2/50 , C07C245/06 , C07C245/00
CPC分类号： C08F2/50 , C08F4/40 , C08F292/00 , Y10T428/23979 , Y10T428/24975 , Y10T428/31504 , Y10T428/31612 , Y10T428/31678
摘要： The use of at least one diazonium salt bearing an initiator function, for forming an undercoat obtained by grafting a graft derived from the diazonium salt and bearing an initiator function at the surface of a conductive or semiconductive material on the undercoat, and for forming on the undercoat a polymeric layer obtained by polymerization, in particular free radical polymerization, in situ of at least one monomer, initiated from the initiator function.
摘要翻译：使用至少一种具有引发剂功能的重氮盐，用于形成底涂层，所述底涂层通过在底涂层上的导电或半导电材料的表面上接枝衍生自重氮盐并具有引发剂官能团的接枝，并在底涂层是通过由引发剂官能团引发的由至少一种单体原位聚合，特别是自由基聚合得到的聚合物层。

2. 发明申请

US20080249272A1 Modification Process For Polymer Surfaces, Notably For Hydroxylation Of Polymer Surfaces And Products So Obtained 有权
标题翻译：聚合物表面的改性方法，显着地用于获得的聚合物表面和产物的羟基化
公开(公告)号：US20080249272A1
公开(公告)日：2008-10-09
申请号：US12089960
申请日：2006-10-10
申请人： Christophe Bureau , Jean Pinson
发明人： Christophe Bureau , Jean Pinson
IPC分类号： C08F20/06
CPC分类号： C08F8/00 , A61L29/04 , C08F8/18 , C08J7/12 , C08J2323/06 , C08J2323/12 , C08J2355/02 , C08F110/06 , C08F110/02 , C08F257/02
摘要： The present invention concerns the use of RO. radicals, R being a hydrogen, an alkyl group having 2 to 15 carbons, an acyl group —COR′ in which R′ represents an alkyl group having 2 to 15 carbons, or an aroyl group —COAr in which Ar represents an aromatic group having 6 to 15 carbons, for the hydroxylation, alkoxylation or oxycarbonylation of polymer surfaces, the said polymers being different from polymers chosen from: polymethylmethacrylate (PMMA) and fluorocarbon polymers when R represents a hydrogen, or of polymer mixture surfaces, notably hydrophobic ones, the said polymers consisting in monomeric units of which at least 50% among these are aliphatic units, and the said RO. radicals being generated by electrochemical or photochemical means.
摘要翻译：本发明涉及RO的用途。基团，R为氢，碳原子数2〜15的烷基，酰基-COR'，其中R'表示碳原子数2〜15的烷基，或芳基-COAr，Ar表示芳基，对于聚合物表面的羟基化，烷氧基化或氧羰基化，所述聚合物不同于聚合甲基丙烯酸甲酯（PMMA）和氟碳聚合物，当R表示氢时，或聚合物混合物表面，特别是疏水性聚合物，所述聚合物由其中至少50％为脂族单元的单体单元和所述RO组成。自由基是通过电化学或光化学方法产生的。

3. 发明授权

US07182822B2 Metal material with modified surface, preparation method and use of same 有权
标题翻译：具有改性表面的金属材料，其制备方法和用途
公开(公告)号：US07182822B2
公开(公告)日：2007-02-27
申请号：US10203376
申请日：2001-02-09
申请人： Jean Pinson , Olivier Fagebaume , Fetah Podvorica
发明人： Jean Pinson , Olivier Fagebaume , Fetah Podvorica
IPC分类号： C23C22/48 , C23C8/06 , B32B7/04 , B32B15/07
CPC分类号： C23C22/48 , C09D5/4476 , C23C22/02 , C25D9/02 , C25D11/00 , Y10T428/31536 , Y10T428/31678
摘要： A metal material whose surface is modified by bonding of aromatic groups, optionally substituted by functional groups.
摘要翻译：一种金属材料，其表面通过任选被官能团取代的芳基键合而被改性。

4. 发明授权

US08361908B2 Modified surface material, method for preparing same and uses thereof 有权
标题翻译：改性表面材料及其制备方法及其应用
公开(公告)号：US08361908B2
公开(公告)日：2013-01-29
申请号：US13243430
申请日：2011-09-23
申请人： Mohamed Mehdi Chehimi , Jean Pinson , Bernadette Charleux , Christophe Bureau , Christopher Tronche , Tarik Matrab , Christian Perruchot , Eva Cabet-Deliry , Maud Save
发明人： Mohamed Mehdi Chehimi , Jean Pinson , Bernadette Charleux , Christophe Bureau , Christopher Tronche , Tarik Matrab , Christian Perruchot , Eva Cabet-Deliry , Maud Save
IPC分类号： H01L21/469 , C23C2/02 , C23C2/26
CPC分类号： C08F2/50 , C08F4/40 , C08F292/00 , Y10T428/23979 , Y10T428/24975 , Y10T428/31504 , Y10T428/31612 , Y10T428/31678
摘要： The use of at least one diazonium salt bearing an initiator function, for forming an undercoat obtained by grafting a graft derived from the diazonium salt and bearing an initiator function at the surface of a conductive or semiconductive material on the undercoat, and for forming on the undercoat a polymeric layer obtained by polymerization, in particular free radical polymerization, in situ of at least one monomer, initiated from the initiator function.
摘要翻译：使用至少一种具有引发剂功能的重氮盐，用于形成底涂层，所述底涂层通过在底涂层上的导电或半导电材料的表面上接枝衍生自重氮盐并具有引发剂官能团的接枝，并在底涂层是通过由引发剂官能团引发的由至少一种单体原位聚合，特别是自由基聚合得到的聚合物层。

5. 发明授权

US08133549B2 Method for modifying insulating or semi-conductive surfaces, and resulting products 有权
标题翻译：用于改变绝缘或半导体表面的方法以及所得产品
公开(公告)号：US08133549B2
公开(公告)日：2012-03-13
申请号：US12091894
申请日：2006-10-09
申请人： Christophe Bureau , Jean Pinson
发明人： Christophe Bureau , Jean Pinson
IPC分类号： C08F2/00 , C08J7/00 , H01L21/31
CPC分类号： H01L21/306 , C08J7/12 , C08J2323/10 , C08J2371/10
摘要： The present invention relates to the use of a R—N2+ diazonium salt carrying an aromatic group R, for grafting of the aromatic group onto insulating, semiconductor, binary or ternary compound or composite material surfaces, the diazonium salt being present at a concentration close to its solubility limit, notably at a concentration higher than 0.05 M, and preferably varying between approximately 0.5 M to approximately 4 M.
摘要翻译：本发明涉及携带芳族基团R的R-N2 +重氮盐用于将芳族基团接枝到绝缘，半导体，二元或三元化合物或复合材料表面上的用途，重氮盐以接近其溶解度极限，特别是在高于0.05M的浓度下，优选在约0.5M至约4M之间变化。

6. 发明授权

US07364648B2 Electromechanical reduction of a diazonium salt to modify the surface of a metallic material 有权
标题翻译：机械还原重氮盐以改变金属材料的表面
公开(公告)号：US07364648B2
公开(公告)日：2008-04-29
申请号：US11119754
申请日：2005-05-03
申请人： Jean Pinson , Olivier Fagebaume , Fetah Podvorica
发明人： Jean Pinson , Olivier Fagebaume , Fetah Podvorica
IPC分类号： C23C22/02 , C23C22/48 , C25D11/00
CPC分类号： C23C22/48 , C09D5/4476 , C23C22/02 , C25D9/02 , C25D11/00 , Y10T428/31536 , Y10T428/31678
摘要： The invention concerns a metal material with a surface which is modified by bonding an aromatic group, optionally substituted by a functional group, on the surface. In one embodiment, an aromatic group is attached to the surface by electrochemical reduction of a diazonium salt containing the aromatic group. The metal material is brought into contact with a solution of the diazonium salt in a solvent and negatively polarized relative to an anode that is also in contact with the solution. A carbon-metal bond of the covalent type is formed.
摘要翻译：本发明涉及一种具有表面的金属材料，该表面通过在表面上键合任选被官能团取代的芳族基团进行改性。在一个实施方案中，芳族基团通过电化学还原含有芳族基团的重氮盐而附着在表面上。使金属材料与重氮盐在溶剂中的溶液接触，并且相对于也与溶液接触的阳极负极化。形成共价型的碳 - 金属键。

7. 发明授权

US09290856B2 Selective nanoparticle deposition 有权
标题翻译：选择性纳米颗粒沉积
公开(公告)号：US09290856B2
公开(公告)日：2016-03-22
申请号：US13508669
申请日：2010-11-03
申请人： Jean Dijon , Xavier Joyeux , Jean Pinson
发明人： Jean Dijon , Xavier Joyeux , Jean Pinson
IPC分类号： C25B3/00 , C07C1/26 , C07C29/58 , C07C51/15 , C07C67/08 , C25D13/04 , B82Y30/00 , B82Y40/00 , H01L21/285 , H01L21/768
CPC分类号： C25D13/04 , B82Y30/00 , B82Y40/00 , H01L21/28556 , H01L21/76814 , H01L21/76876 , H01L21/76879 , H01L2221/1094
摘要： The invention relates to a method for deposition of nanoparticles made of an insulating, semi-conductive, or conductive material onto predetermined areas, made of a conductive or semi-conductive material, located on a substrate. The invention also relates to a method for manufacturing electrodes. The method of the invention includes the steps of a) creating insulating material areas I around areas Z when said areas I are not already present; b) deposition, by means of electrografting, of a polymer P prepared from a diazonium salt or vinyl monomer salt, or a mixture of the above, onto the conductive or semi-conductive material that forms the areas Z; c) coating the nanoparticles with a coating material that includes a bifunctional molecule capable of creating a bond with the nanoparticles and a bond with the polymer P; d) suspending the coated nanoparticles obtained in Step c) in a solvent, preferably a coating material solution used in Step c); e) immersing the substrate S obtained in Step b) into the suspension obtained in Step d); and f) removing the polymer P. The invention is in particular useful for manufacturing electrodes.
摘要翻译：本发明涉及一种用于将由绝缘，半导体或导电材料制成的纳米颗粒沉积到由位于基底上的导电或半导体材料制成的预定区域上的方法。本发明还涉及一种用于制造电极的方法。本发明的方法包括以下步骤：a）当所述区域I不存在时，在区域Z周围产生绝缘材料区域I; b）通过电移植将由重氮盐或乙烯基单体盐或其混合物制备的聚合物P沉积在形成区域Z的导电或半导体材料上; c）用包括能够与纳米颗粒形成键和与聚合物P的键的双官能分子的涂层材料涂覆纳米颗粒; d）将步骤c）中得到的涂覆的纳米颗粒悬浮在溶剂，优选步骤c）中使用的涂料溶液中; e）将步骤b）中获得的基材S浸入步骤d）中获得的悬浮液中; 和f）除去聚合物P.本发明特别适用于制造电极。

8. 发明申请

US20120015138A1 MODIFIED SURFACE MATERIAL, METHOD FOR PREPARING SAME AND USES THEREOF 有权
标题翻译：改性表面材料，其制备方法及其用途
公开(公告)号：US20120015138A1
公开(公告)日：2012-01-19
申请号：US13243430
申请日：2011-09-23
申请人： Mohamed Mehdi CHEHIMI , Jean Pinson , Bernadette Charleux , Christophe Bureau , Christopher Tronche , Tarik Matrab , Christian Perruchot , Eva Cabet-Deliry , Maud Save
发明人： Mohamed Mehdi CHEHIMI , Jean Pinson , Bernadette Charleux , Christophe Bureau , Christopher Tronche , Tarik Matrab , Christian Perruchot , Eva Cabet-Deliry , Maud Save
IPC分类号： B32B27/16 , C25D11/00 , C25D7/12 , B32B7/02 , B05D5/00
CPC分类号： C08F2/50 , C08F4/40 , C08F292/00 , Y10T428/23979 , Y10T428/24975 , Y10T428/31504 , Y10T428/31612 , Y10T428/31678
摘要： The use of at least one diazonium salt bearing an initiator function, for forming an undercoat obtained by grafting a graft derived from the diazonium salt and bearing an initiator function at the surface of a conductive or semiconductive material on the undercoat, and for forming on the undercoat a polymeric layer obtained by polymerization, in particular free radical polymerization, in situ of at least one monomer, initiated from the initiator function.
摘要翻译：使用至少一种具有引发剂功能的重氮盐，用于形成底涂层，所述底涂层通过在底涂层上的导电或半导电材料的表面上接枝衍生自重氮盐并具有引发剂官能团的接枝，并在底涂层是通过由引发剂官能团引发的由至少一种单体原位聚合，特别是自由基聚合得到的聚合物层。

9. 发明授权

US06217740B1 Process for electrochemically producing a carbonaceous material with a surface modified by functionalized groups, novel surface-modified carbonaceous material and application of this material 有权
标题翻译：通过官能化基团改性的表面电化学生产碳质材料的方法，新型表面改性含碳材料及其应用
公开(公告)号：US06217740B1
公开(公告)日：2001-04-17
申请号：US09398944
申请日：1999-09-03
申请人： Claude Andrieux , Felipe Gonzalez , Jean Pinson , Jean-Michel Saveant
发明人： Claude Andrieux , Felipe Gonzalez , Jean Pinson , Jean-Michel Saveant
IPC分类号： C25B300
CPC分类号： C09D5/4476 , C25D11/02 , D01F11/16
摘要： The invention concerns a process for electrochemically producing a carbonaceous material with its surface modified by organic groups, in particular functionalized organic groups. The process comprises providing a solution, in a protic or aprotic solvent, comprising a salt of a carboxylate of an organic residue capable of undergoing a Kolbe reaction. The solution is then put in contact with a carbonaceous material, wherein the carbonaceous material is positively polarized with respect to a cathode that is also in contact with the solution. The solution may optionally contain an electrolyte. The invention also concerns carbonaceous materials modified at the surface with arylmethyl groups and the use of these modified materials, for example, in the production of composite materials.
摘要翻译：本发明涉及一种电化学生产含碳材料的方法，其表面被有机基团特别是官能化的有机基团改性。该方法包括在质子或非质子溶剂中提供包含能够经历Kolbe反应的有机残基的羧酸盐的溶液。然后将溶液与碳质材料接触，其中碳质材料相对于也与溶液接触的阴极是正极化的。溶液可以任选地含有电解质。本发明还涉及在芳基甲基的表面改性的碳质材料，以及这些改性材料的用途，例如在复合材料的生产中。

10. 发明申请

US20090301862A1 METHOD FOR MODIFYING INSULATING OR SEMI-CONDUCTIVE SURFACES, AND RESULTING PRODUCTS 有权
标题翻译：用于修改绝缘或半导体表面的方法和结果产品
公开(公告)号：US20090301862A1
公开(公告)日：2009-12-10
申请号：US12091894
申请日：2006-10-09
申请人： Christophe Bureau , Jean Pinson
发明人： Christophe Bureau , Jean Pinson
IPC分类号： B01J19/10 , B01J19/12
CPC分类号： H01L21/306 , C08J7/12 , C08J2323/10 , C08J2371/10
摘要： The present invention relates to the use of a R—N2+ diazonium salt carrying an aromatic group R, for grafting of the aromatic group onto insulating, semiconductor, binary or ternary compound or composite material surfaces, the diazonium salt being present at a concentration close to its solubility limit, notably at a concentration higher than 0.05 M, and preferably varying between approximately 0.5 M to approximately 4 M.
摘要翻译：本发明涉及携带芳族基团R的R-N2 +重氮盐用于将芳族基团接枝到绝缘，半导体，二元或三元化合物或复合材料表面上的用途，重氮盐以接近其溶解度极限，特别是在高于0.05M的浓度下，优选在约0.5M至约4M之间变化。

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