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1. 发明授权

US08394460B2 Method for mask-free localized organic grafting on conductive or semiconductive portions of composite surfaces 有权
标题翻译：在复合表面的导电或半导体部分上进行无掩模的局部有机接枝的方法
公开(公告)号：US08394460B2
公开(公告)日：2013-03-12
申请号：US10614516
申请日：2003-07-08
申请人： Christophe Bureau , Serge Palacin , Jean-Philippe Bourgoin , Sami Ameur , Julienne Charlier
发明人： Christophe Bureau , Serge Palacin , Jean-Philippe Bourgoin , Sami Ameur , Julienne Charlier
IPC分类号： B05D1/04 , B05D3/02
CPC分类号： C09D5/4476 , B05D1/007 , B05D1/18
摘要： A process for mask-free localized grafting of organic molecules capable of being electrically activated, onto a composite surface comprising conductive and/or semiconductive portions, by placing said organic molecules in contact with said composite surface, in which said grafting is performed electrochemically in a single step on chosen, defined areas of said conductive and/or semiconductive portions, said areas being brought to a potential higher than or equal to a threshold electrical potential determined relative to a reference electrode, said threshold electrical potential being the potential above which grafting of said organic molecules takes place.
摘要翻译：通过将所述有机分子与所述复合表面接触而将能够电激活的有机分子的无掩模局部接枝到包含导电和/或半导体部分的复合表面上的方法，其中所述接枝在电化学在所述导电和/或半导体部分的选定的限定区域上的单步骤，所述区域被置于高于或等于相对于参考电极确定的阈值电位的电位，所述阈值电势是其上表示有机分子发生。

2. 发明申请

US20120015138A1 MODIFIED SURFACE MATERIAL, METHOD FOR PREPARING SAME AND USES THEREOF 有权
标题翻译：改性表面材料，其制备方法及其用途
公开(公告)号：US20120015138A1
公开(公告)日：2012-01-19
申请号：US13243430
申请日：2011-09-23
申请人： Mohamed Mehdi CHEHIMI , Jean Pinson , Bernadette Charleux , Christophe Bureau , Christopher Tronche , Tarik Matrab , Christian Perruchot , Eva Cabet-Deliry , Maud Save
发明人： Mohamed Mehdi CHEHIMI , Jean Pinson , Bernadette Charleux , Christophe Bureau , Christopher Tronche , Tarik Matrab , Christian Perruchot , Eva Cabet-Deliry , Maud Save
IPC分类号： B32B27/16 , C25D11/00 , C25D7/12 , B32B7/02 , B05D5/00
CPC分类号： C08F2/50 , C08F4/40 , C08F292/00 , Y10T428/23979 , Y10T428/24975 , Y10T428/31504 , Y10T428/31612 , Y10T428/31678
摘要： The use of at least one diazonium salt bearing an initiator function, for forming an undercoat obtained by grafting a graft derived from the diazonium salt and bearing an initiator function at the surface of a conductive or semiconductive material on the undercoat, and for forming on the undercoat a polymeric layer obtained by polymerization, in particular free radical polymerization, in situ of at least one monomer, initiated from the initiator function.
摘要翻译：使用至少一种具有引发剂功能的重氮盐，用于形成底涂层，所述底涂层通过在底涂层上的导电或半导电材料的表面上接枝衍生自重氮盐并具有引发剂官能团的接枝，并在底涂层是通过由引发剂官能团引发的由至少一种单体原位聚合，特别是自由基聚合得到的聚合物层。

3. 发明授权

US07591937B2 Method of fixing macro-objects to an electricity conducting- or semi-conducting surface by means of electrografting, surfaces thus obtained and applications thereof 有权
标题翻译：通过电动移动将大型物体固定到导电或半导电表面的方法，如此获得的表面及其应用
公开(公告)号：US07591937B2
公开(公告)日：2009-09-22
申请号：US10508665
申请日：2003-03-19
申请人： Christophe Bureau , Guy Deniau , José Gonzalez , Serge Palacin
发明人： Christophe Bureau , Guy Deniau , José Gonzalez , Serge Palacin
IPC分类号： C25D11/32 , C25D11/34
CPC分类号： C09D5/4476 , Y10T29/49126 , Y10T29/49128 , Y10T29/49165 , Y10T428/12493
摘要： The invention relates to a method of fixing macro-objects to an electricity conducting- or semi-conducting surface by means of electrografting. The invention also relates to the electricity conducting- or semi-conducting-surfaces obtained using the aforementioned method and to the applications of same.
摘要翻译：本发明涉及一种通过电动移动将大型物体固定到导电或半导电表面的方法。本发明还涉及使用上述方法获得的导电或半导体表面及其应用。

4. 发明申请

US20060141156A1 Surface-coating method 有权
标题翻译：表面涂布法
公开(公告)号：US20060141156A1
公开(公告)日：2006-06-29
申请号：US10545400
申请日：2004-02-13
申请人： Pascal Viel , Sami Ameur , Christophe Bureau
发明人： Pascal Viel , Sami Ameur , Christophe Bureau
IPC分类号： B05D5/00
CPC分类号： C25D15/00 , C09D5/4407 , C23C26/00 , C25D3/38 , C25D5/34 , C25D5/54 , Y10T428/12493
摘要： The invention relates to the deposition or attachment of materials to surfaces. It relates to a process for coating a surface with a first material and a second material, comprising the following steps: placing the first material on the said surface, inserting into the first material placed on the said surface precursor molecules of the second material, converting the said precursor molecules of the second material inserted into the first material into the said second material such that this second material becomes formed on the said surface to be coated and within the said first material placed on the said surface. The object of the process of the invention is to allow the deposition of materials of any type onto surfaces of any type.
摘要翻译：本发明涉及材料沉积或附着到表面上。它涉及一种用第一材料和第二材料涂覆表面的方法，包括以下步骤：将第一材料放置在所述表面上，将第一材料插入放置在所述表面上的第一材料中，将第二材料的前体分子转化将所述第二材料的所述前体分子插入到所述第二材料中，使得所述第二材料变得形成在所述待涂覆的所述表面上并且位于所述表面上的所述第一材料内。本发明方法的目的是允许将任何类型的材料沉积在任何类型的表面上。

5. 发明申请

US20050272143A1 Solid support comprising a functionalized electricity conductor or semiconductor surface, method for preparing same and uses thereof 审中-公开
标题翻译：固体支持体，其包含功能化电导体或半导体表面，其制备方法及其应用
公开(公告)号：US20050272143A1
公开(公告)日：2005-12-08
申请号：US10518923
申请日：2003-06-16
申请人： Christophe Bureau , Brigitte Mouanda , Sami Ameur , Julienne Charlier , Serge Palacin
发明人： Christophe Bureau , Brigitte Mouanda , Sami Ameur , Julienne Charlier , Serge Palacin
IPC分类号： C08F2/00 , C08F2/58 , C08F8/00 , C08G85/00 , C09D5/44 , C12M1/34
CPC分类号： C09D5/4476
摘要： The invention concerns a solid support comprising a functionalized electricity conductor or semiconductor surface coated with a functionalized electrografted organic layer wherein at least 90% of the number of functional groups of interest is accessible. The invention also concerns the method for preparing such a support and uses thereof, in particular as adhesive primer for fixing molecules of interest or objects bearing a complementary function (molecular adhesive).
摘要翻译：本发明涉及一种固体支持物，其包含官能化的电导体或涂覆有官能化的电接枝有机层的半导体表面，其中感兴趣的官能团数量的至少90％是可接近的。本发明还涉及制备这种载体及其用途的方法，特别是作为用于固定感兴趣的分子或具有互补功能的物质（分子粘合剂）的粘合剂底漆。

6. 发明授权

US5194822A Automatic gain control method and device for a variable gain amplifier and application thereof to controlling the gain of a tuner, in particular for a videocommunication network 失效
标题翻译：用于可变增益放大器的自动增益控制方法和装置及其应用来控制调谐器的增益，特别是用于视频通信网络
公开(公告)号：US5194822A
公开(公告)日：1993-03-16
申请号：US744721
申请日：1991-08-14
申请人： Christophe Bureau , Stephane Ruggeri
发明人： Christophe Bureau , Stephane Ruggeri
IPC分类号： H03G3/00 , H03G3/20 , H03G3/30 , H04N7/10
CPC分类号： H03G3/3052 , H03G3/001
摘要： The automatic gain control method adapted to maintain the output level equal of the variable gain amplifier to a required value, includes a preliminary calibration phase for establishing a relationship representing the variations in the amplifier gain control signal as a function of variations in the input signal level with a constant output level equal to the required value or as a function of variations in the output signal level for a constant input signal level. The method further includes an operative phase for applying to the amplifier of a particular value of the gain control signal, measuring the corresponding output level, detecting any offset between the result of the measurement and the required value, and if such an offset is detected, determining a corresponding control signal value conditioned by the relationship previously established, and depending on the mode utilized to establish the relationship, either an input level whose offset relative to the corresponding input level given by the relationship at the particular value of the control signal is opposite to said detected offset, or an output level whose offset relative to the required value is opposite to the detected value, and finally, selectively updating the particular value when an offset is detected to so that the particular value becomes equal to the value obtained by the determination.
摘要翻译：适于将可变增益放大器的输出电平维持在所需值的自动增益控制方法包括用于建立表示放大器增益控制信号中的变化的关系的初步校准阶段，作为输入信号电平的变化的函数具有等于所需值的恒定输出电平或作为恒定输入信号电平的输出信号电平变化的函数。该方法还包括用于向放大器施加增益控制信号的特定值的操作阶段，测量对应的输出电平，检测测量结果与所需值之间的任何偏差，并且如果检测到这样的偏移，确定由先前建立的关系调节的对应的控制信号值，并且根据用于建立该关系的模式，输入电平的相对于由控制信号的特定值处的关系给出的相应输入电平的偏移量相反或者相对于所需值的偏移与检测值相反的输出电平，最后，当检测到偏移量时，选择性地更新特定值，使得特定值变得等于由决心。

7. 发明授权

US08784635B2 Formation of organic electro-grafted films on the surface of electrically conductive or semi-conductive surfaces 有权
标题翻译：在导电或半导体表面的表面上形成有机电接枝膜
公开(公告)号：US08784635B2
公开(公告)日：2014-07-22
申请号：US11711849
申请日：2007-02-28
申请人： Christophe Bureau
发明人： Christophe Bureau
IPC分类号： C25D9/02 , C25D13/18 , C09D5/44
CPC分类号： C25D7/12 , A61F2/82 , A61F2210/0076 , A61L31/10 , A61L31/14 , A61L2420/04 , A61L2420/08 , C09D5/24 , C09D5/4407 , C09D5/4419 , C09D5/4423 , C09D5/4476 , C09D5/448 , C25D9/02 , C25D13/18
摘要： The invention relates to a method for grafting an organic film onto an electrically conductive or semiconductive surface by electro-reduction of a solution, wherein the solution comprises one diazonium salt and one monomer bearing at least one chain polymerizable functional group. During the electrolyzing process, at least one protocol consisting of an electrical polarization of the surface by applying a variable potential over at least a range of values which are more cathodic that the reduction or peak potential of all diazonium salts in said solution is applied.The invention also relates to an electrically conducting or semiconducting surface obtained by implementing this method.The invention further relates to electrolytic compositions.
摘要翻译：本发明涉及通过电解还原溶液将有机膜接枝到导电或半导体表面上的方法，其中溶液包含一个重氮盐和一个带有至少一个可链聚合官能团的单体。在电解过程期间，至少一个方案由表面的电极化构成，在至少一个范围内的值更大的阴极处施加可变电位，使得所述溶液中的所有重氮盐的还原或峰值电位被施加。本发明还涉及通过实施该方法获得的导电或半导体表面。本发明还涉及电解组合物。

8. 发明授权

US07736484B2 Method for grafting and growing a conductive organic film on a surface 有权
标题翻译：在表面上接枝和生长导电有机膜的方法
公开(公告)号：US07736484B2
公开(公告)日：2010-06-15
申请号：US10487731
申请日：2002-08-27
申请人： Christophe Bureau , Edouard Levy , Pascal Viel
发明人： Christophe Bureau , Edouard Levy , Pascal Viel
IPC分类号： C25D11/00
CPC分类号： H01B1/12 , B05D5/12 , C09D5/4476
摘要： The present invention relates to a process for grafting and growing a conductive organic film on(to) an electrically conductive or semiconductive surface in which the grafting and growing of the film are performed simultaneously by electro-reduction of a diazonium salt that is a precursor of the said film on(to) the said surface cathodically polarized at a potential greater than or equal, in absolute value, to the electro-reduction potential of the diazonium salt relative to a reference electrode.The invention finds an application especially in the protection of surfaces, the manufacture of localized conductive coatings, of chemical sensors in the fields of chemistry and molecular biology, the manufacture of biomedical equipment, etc.
摘要翻译：本发明涉及一种用于在导电或半导体表面上接枝和生长导电有机膜的方法，其中通过电还原作为前体的重氮盐同时进行膜的接枝和生长所述膜以（绝对值）大于或等于绝对值的电位被阴极极化地转换为重氮盐相对于参比电极的电还原电位。本发明尤其在化学和分子生物学领域的化学传感器的表面保护，局部导电涂层的制造，生物医学设备的制造等方面发现。

9. 发明申请

US20090301862A1 METHOD FOR MODIFYING INSULATING OR SEMI-CONDUCTIVE SURFACES, AND RESULTING PRODUCTS 有权
标题翻译：用于修改绝缘或半导体表面的方法和结果产品
公开(公告)号：US20090301862A1
公开(公告)日：2009-12-10
申请号：US12091894
申请日：2006-10-09
申请人： Christophe Bureau , Jean Pinson
发明人： Christophe Bureau , Jean Pinson
IPC分类号： B01J19/10 , B01J19/12
CPC分类号： H01L21/306 , C08J7/12 , C08J2323/10 , C08J2371/10
摘要： The present invention relates to the use of a R—N2+ diazonium salt carrying an aromatic group R, for grafting of the aromatic group onto insulating, semiconductor, binary or ternary compound or composite material surfaces, the diazonium salt being present at a concentration close to its solubility limit, notably at a concentration higher than 0.05 M, and preferably varying between approximately 0.5 M to approximately 4 M.
摘要翻译：本发明涉及携带芳族基团R的R-N2 +重氮盐用于将芳族基团接枝到绝缘，半导体，二元或三元化合物或复合材料表面上的用途，重氮盐以接近其溶解度极限，特别是在高于0.05M的浓度下，优选在约0.5M至约4M之间变化。

10. 发明授权

US07605050B2 Method of bonding a polymer surface to a conducting or semiconducting surface and application of the same 有权
标题翻译：将聚合物表面粘结到导电或半导体表面上的方法及其应用
公开(公告)号：US07605050B2
公开(公告)日：2009-10-20
申请号：US10525592
申请日：2003-08-25
申请人： Christophe Bureau , Julienne Charlier
发明人： Christophe Bureau , Julienne Charlier
IPC分类号： H01L21/30
CPC分类号： C09D5/4476 , C08J5/121 , C08J5/122
摘要： The invention relates to a method of bonding a polymer surface to an electrically conductive or semiconductive surface, which method is characterized in that it comprises: a) the electrografting of an organic film onto the conductive or semiconductive surface; and then b) an operation of bonding the polymer surface to the conductive or semiconductive surface thus grafted. It also relates to applications of this method and to structures obtained by its implementation.
摘要翻译：本发明涉及一种将聚合物表面粘合到导电或半导体表面上的方法，该方法的特征在于其包括：a）将有机膜电解到导电或半导体表面上; 然后b）将聚合物表面粘合到由此接枝的导电或半导体表面上的操作。它还涉及该方法的应用和通过其实现获得的结构。

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