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1. 发明授权

US09074066B2 Nanotubular toughening inclusions 有权
标题翻译：纳米管增韧夹杂物
公开(公告)号：US09074066B2
公开(公告)日：2015-07-07
申请号：US13032045
申请日：2011-02-22
申请人： Cheol Park , Dennis C. Working , Emilie J. Siochi , Joycelyn S. Harrison
发明人： Cheol Park , Dennis C. Working , Emilie J. Siochi , Joycelyn S. Harrison
IPC分类号： C08L89/00 , C08L79/08 , C08G73/10 , C08K3/04 , B82Y30/00 , C08K7/24
CPC分类号： C08K7/24 , B82Y30/00 , C08K2201/011
摘要： Conventional toughening agents are typically rubbery materials or small molecular weight molecules, which mostly sacrifice the intrinsic properties of a matrix such as modulus, strength, and thermal stability as side effects. On the other hand, high modulus inclusions tend to reinforce elastic modulus very efficiently, but not the strength very well. For example, mechanical reinforcement with inorganic inclusions often degrades the composite toughness, encountering a frequent catastrophic brittle failure triggered by minute chips and cracks. Thus, toughening generally conflicts with mechanical reinforcement. Carbon nanotubes have been used as efficient reinforcing agents in various applications due to their combination of extraordinary mechanical, electrical, and thermal properties. Moreover, nanotubes can elongate more than 20% without yielding or breaking, and absorb significant amounts of energy during deformation, which enables them to also be an efficient toughening agent, as well as excellent reinforcing inclusion. Accordingly, an improved toughening method is provided by incorporating nanotubular inclusions into a host matrix, such as thermoset and thermoplastic polymers or ceramics without detrimental effects on the matrix's intrinsic physical properties.
摘要翻译：常规增韧剂通常是橡胶状材料或小分子量分子，其主要牺牲基质的固有性质，例如作为副作用的模量，强度和热稳定性。另一方面，高模量夹杂物倾向于非常有效地增强弹性模量，但是强度非常好。例如，具有无机夹杂物的机械增强剂常常降低复合材料的韧性，遇到由碎片和裂纹引起的频繁的灾难性脆性破坏。因此，增韧通常与机械加强冲突。碳纳米管由于其非凡的机械，电气和热性能的组合，已经在各种应用中用作有效的增强剂。此外，纳米管可以延伸超过20％而不产生或破裂，并且在变形期间吸收大量的能量，这使得它们也可以是有效的增韧剂，以及优异的增强夹杂物。因此，通过将纳米管状夹杂物结合到主体基质如热固性和热塑性聚合物或陶瓷中而不会对基体的固有物理性质产生不利影响，提供了改进的增韧方法。

2. 发明申请

US20110001398A1 Carbon Nanotube Film Electrode and an Electroactive Device Fabricated with the Carbon Nanotube Film Electrode and a Method for Making Same 审中-公开
标题翻译：碳纳米管薄膜电极和用碳纳米管薄膜电极制造的电活性装置及其制造方法
公开(公告)号：US20110001398A1
公开(公告)日：2011-01-06
申请号：US11937155
申请日：2007-11-08
申请人： Jin Ho Kang , Cheol Park , Joycelyn S. Harrison
发明人： Jin Ho Kang , Cheol Park , Joycelyn S. Harrison
IPC分类号： H01L41/047 , B05D5/12 , B32B37/02
CPC分类号： B32B43/006 , B32B5/16 , B32B37/06 , B32B37/10 , B32B37/14 , B32B2250/02 , B32B2264/108 , B32B2309/12 , B32B2313/02 , B32B2313/04 , B32B2315/02 , B32B2457/00 , B82Y30/00 , C08K7/24 , H01B1/04 , H01L41/0478 , H01L41/29 , H01L41/45 , Y10S977/75 , Y10S977/751 , Y10S977/752 , Y10S977/762 , Y10T156/10 , Y10T428/249921
摘要： A single wall carbon nanotube (SWCNT) film electrode (FE), all-organic electroactive device systems fabricated with the SWNT-FE, and methods for making same. The SWCNT can be replaced by multi-wall carbon nanotubes or few wall carbon nanotubes. The SWCNT film can be obtained by filtering SWCNT solution onto the surface of an anodized alumina membrane. A freestanding flexible SWCNT film can be collected by breaking up this brittle membrane. The conductivity of this SWCNT film can advantageously be higher than 280 S/cm. The EAP actuator layered with the SWNT-FE shows a higher electric field-induced strain than an EAP layered with metal electrodes because the flexible SWNT-FE relieves the restraint of the displacement of the polymeric active layer as compared to the metal electrode. In addition, if thin enough, the SWNT-FE is transparent in the visible light range, thus making it suitable for use in actuators used in optical devices.
摘要翻译：单壁碳纳米管（SWCNT）膜电极（FE），用SWNT-FE制造的全有机电活性器件系统及其制造方法。 SWCNT可以由多壁碳纳米管或几个壁碳纳米管代替。可以通过将SWCNT溶液过滤到阳极化氧化铝膜的表面上来获得SWCNT膜。可以通过破碎这个脆性膜来收集独立的柔性SWCNT膜。该SWCNT膜的电导率可有利地高于280S / cm。与SWNT-FE分层的EAP致动器表现出比用金属电极分层的EAP更高的电场诱导应变，因为与金属电极相比，柔性SWNT-FE减轻了聚合物有源层的位移的限制。另外，如果足够薄，SWNT-FE在可见光范围内是透明的，因此使其适用于光学器件中使用的致动器。

3. 发明申请

US20100078600A1 Electrically Conductive, Optically Transparent Polymer/Carbon Nanotube Composites And Process For Preparation Thereof 有权
标题翻译：导电，光学透明聚合物/碳纳米管复合材料及其制备方法
公开(公告)号：US20100078600A1
公开(公告)日：2010-04-01
申请号：US12550431
申请日：2009-08-31
申请人： John W. Connell , Joseph G. Smith , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
发明人： John W. Connell , Joseph G. Smith , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
IPC分类号： H01B1/24
CPC分类号： B82Y10/00 , B82Y30/00 , C08F2/44 , C08G73/10 , C08G73/1039 , C08G73/1071 , C08K5/00 , C08K7/24 , C08K2201/011 , C08L71/123 , C09J11/04 , H01B1/24 , Y10T428/25 , Y10T428/29 , Y10T428/2904 , Y10T428/2913 , Y10T428/2918 , Y10T428/2975 , C08L71/12
摘要： The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
摘要翻译：本发明涉及碳纳米管（CNT）在聚合物基质中的有效分散。使用聚合物基质制备纳米复合材料，并且表现出独特的性质组合，最显着的是在可见光范围（即400-800nm）中高保留光学透明度，导电性和高热稳定性。通过适当选择基体树脂，可以获得诸如真空紫外线辐射电阻，原子氧电阻，高玻璃化转变温度（Tg）等优异的韧性等附加特性。所得的纳米复合材料可用于制造或配制各种制品，例如各种基材，薄膜，泡沫，纤维，线，粘合剂和纤维涂层预浸料上的涂层。可以通过选择聚合物基质和CNT来调节具有高光学透明度和抗静电性能的制品来调节纳米复合材料的性能。

4. 发明授权

US07015624B1 Non-uniform thickness electroactive device 失效
标题翻译：不均匀厚度的电活性器件
公开(公告)号：US07015624B1
公开(公告)日：2006-03-21
申请号：US09696526
申请日：2000-10-23
申请人： Ji Su , Joycelyn S. Harrison
发明人： Ji Su , Joycelyn S. Harrison
IPC分类号： H01L41/08
CPC分类号： H01Q15/147 , C08F255/10 , C08F259/00 , C08F259/08 , C08F265/08 , C08F273/00 , C08F283/006 , C08F283/12 , H01L41/094 , H01L41/0973 , H01L41/193
摘要： An electroactive device comprises at least two layers of material, wherein at least one layer is an electroactive material and wherein at least one layer is of non-uniform thickness. The device can be produced in various sizes, ranging from large structural actuators to microscale or nanoscale devices. The applied voltage to the device in combination with the non-uniform thickness of at least one of the layers (electroactive and/or non-electroactive) controls the contour of the actuated device. The effective electric field is a mathematical function of the local layer thickness. Therefore, the local strain and the local bending/torsion curvature are also a mathematical function of the local thickness. Hence the thinnest portion of the actuator offers the largest bending and/or torsion response. Tailoring of the layer thicknesses can enable complex motions to be achieved.
摘要翻译：电活性器件包括至少两层材料，其中至少一层是电活性材料，并且其中至少一层具有不均匀的厚度。该装置可以生产各种尺寸，从大型结构致动器到微尺寸或纳米级装置。结合至少一个层（电活性和/或非电活性）的非均匀厚度的装置施加的电压控制致动装置的轮廓。有效电场是局部层厚度的数学函数。因此，局部应变和局部弯曲/扭曲曲率也是局部厚度的数学函数。因此，致动器的最薄部分提供最大的弯曲和/或扭转响应。层厚度的裁剪可以实现复杂的运动。

5. 发明申请

US20130119316A1 Boron nitride and boron nitride nanotube materials for radiation shielding 审中-公开
标题翻译：氮化硼和氮化硼纳米管材料用于辐射屏蔽
公开(公告)号：US20130119316A1
公开(公告)日：2013-05-16
申请号：US13068329
申请日：2011-05-09
申请人： Godfrey Sauti , Cheol Park , Jin Ho Kang , Jae-Woo Kim , Joycelyn S. Harrison , Michael W. Smith , Kevin Jordan , Sharon E. Lowther , Peter T. Lillehei , Sheila A. Thibeault
发明人： Godfrey Sauti , Cheol Park , Jin Ho Kang , Jae-Woo Kim , Joycelyn S. Harrison , Michael W. Smith , Kevin Jordan , Sharon E. Lowther , Peter T. Lillehei , Sheila A. Thibeault
IPC分类号： G21F1/10
CPC分类号： G21F1/103 , G21F1/00
摘要： Effective radiation shielding is required to protect crew and equipment in various fields including aerospace, defense, medicine and power generation. Light elements and in particular hydrogen are most effective at shielding against high-energy particles including galactic cosmic rays, solar energetic particles and fast neutrons. However, pure hydrogen is highly flammable, has a low neutron absorption cross-section, and cannot be made into structural components. Nanocomposites containing the light elements Boron, Nitrogen, Carbon and Hydrogen as well dispersed boron nano-particles, boron nitride nanotubes (BNNTs) and boron nitride nano-platelets, in a matrix, provide effective radiation shielding materials in various functional forms. Boron and nitrogen have large neutron absorption cross-sections and wide absorption spectra. The incorporation of boron and nitrogen containing nanomaterials into hydrogen containing matrices provides composites that can effectively shield against neutrons and a wide range of radiation species of all energies without fragmentation and the generation of harmful secondary particles.
摘要翻译：需要有效的辐射屏蔽来保护航空航天，国防，医药和发电等各个领域的船员和设备。轻元素，特别是氢是最有效的屏蔽高能粒子，包括星系宇宙射线，太阳能能粒子和快中子。然而，纯氢是高度易燃的，具有低的中子吸收横截面，并且不能制成结构部件。含有轻质元素的纳米复合材料可以提供各种功能形式的有效的辐射屏蔽材料，硼，氮，碳和氢以及分散的硼纳米颗粒，氮化硼纳米管（BNNTs）和氮化硼纳米血小板。硼和氮具有大的中子吸收截面和宽的吸收光谱。将含硼和氮的纳米材料掺入含氢基质提供了复合材料，可以有效地屏蔽所有能量的中子和宽范围的辐射种类，而不会产生碎片和产生有害的二次粒子。

6. 发明申请

US20120107594A1 Nanotube Film Electrode and an Electroactive Device Fabricated with the Nanotube Film Electrode and Methods for Making Same 审中-公开
标题翻译：纳米管薄膜电极和使用纳米管薄膜电极制造的电极及其制作方法
公开(公告)号：US20120107594A1
公开(公告)日：2012-05-03
申请号：US13284061
申请日：2011-10-28
申请人： Jin Ho Kang , Cheol Park , Joycelyn S. Harrison
发明人： Jin Ho Kang , Cheol Park , Joycelyn S. Harrison
IPC分类号： D01F9/12 , C01B21/082 , C01B21/064 , B32B37/06 , B32B38/10 , B32B5/16 , C01B35/02 , B32B37/10 , B82Y30/00
CPC分类号： B32B43/006 , B32B5/16 , B32B37/06 , B32B37/10 , B32B37/14 , B32B2250/02 , B32B2264/108 , B32B2309/12 , B32B2313/02 , B32B2313/04 , B32B2315/02 , B32B2457/00 , B82Y30/00 , C08K7/24 , H01B1/04 , H01L41/0478 , H01L41/29 , H01L41/45 , Y10S977/75 , Y10S977/751 , Y10S977/752 , Y10S977/762 , Y10T156/10 , Y10T428/249921
摘要： Disclosed is a single wall carbon nanotube (SWCNT) film electrode (FE), all-organic electroactive device systems fabricated with the SWNT-FE, and methods for making same. The SWCNT can be replaced by other types of nanotubes. The SWCNT film can be obtained by filtering SWCNT solution onto the surface of an anodized alumina membrane. A freestanding flexible SWCNT film can be collected by breaking up this brittle membrane. The conductivity of this SWCNT film can advantageously be higher than 280 S/cm. An electroactive polymer (EAP) actuator layered with the SWNT-FE shows a higher electric field-induced strain than an EAP layered with metal electrodes because the flexible SWNT-FE relieves the restraint of the displacement of the polymeric active layer as compared to the metal electrode. In addition, if thin enough, the SWNT-FE is transparent in the visible light range, thus making it suitable for use in actuators used in optical devices.
摘要翻译：公开了单壁碳纳米管（SWCNT）膜电极（FE），用SWNT-FE制造的全有机电活性器件系统及其制造方法。 SWCNT可以被其他类型的纳米管替代。可以通过将SWCNT溶液过滤到阳极化氧化铝膜的表面上来获得SWCNT膜。可以通过破碎这个脆性膜来收集独立的柔性SWCNT膜。该SWCNT膜的电导率可有利地高于280S / cm。与SWNT-FE分层的电活性聚合物（EAP）致动器显示出比用金属电极层叠的EAP更高的电场诱导应变，因为与金属相比，柔性SWNT-FE减轻了聚合物活性层位移的限制电极。另外，如果足够薄，SWNT-FE在可见光范围内是透明的，因此使其适用于光学器件中使用的致动器。

7. 发明申请

US20110105293A1 Negative Dielectric Constant Material Based on Ion Conducting Materials 有权
标题翻译：基于离子导电材料的负介电常数材料
公开(公告)号：US20110105293A1
公开(公告)日：2011-05-05
申请号：US12893289
申请日：2010-09-29
申请人： Keith L. Gordon , Jin Ho Kang , Cheol Park , Peter T. Lillehei , Joycelyn S. Harrison
发明人： Keith L. Gordon , Jin Ho Kang , Cheol Park , Peter T. Lillehei , Joycelyn S. Harrison
IPC分类号： C04B35/00 , C08L33/06 , C08K3/32 , C08K3/16 , C08K3/08 , C08K3/28
CPC分类号： H01B3/38 , C08G73/18 , C08L79/04 , G02F1/0009 , G02F2202/30 , G02F2202/42 , H01B1/12 , H01B3/12
摘要： Metamaterials or artificial negative index materials (NIMs) have generated great attention due to their unique and exotic electromagnetic properties. One exemplary negative dielectric constant material, which is an essential key for creating the NIMs, was developed by doping ions into a polymer, a protonated poly(benzimidazole) (PBI). The doped PBI showed a negative dielectric constant at megahertz (MHz) frequencies due to its reduced plasma frequency and an induction effect. The magnitude of the negative dielectric constant and the resonance frequency were tunable by doping concentration. The highly doped FBI showed larger absolute magnitude of negative dielectric constant at just above its resonance frequency than the less doped PBI.
摘要翻译：由于其特有的和异乎寻常的电磁特性，超材料或人造负指数材料（NIM）引起了极大的关注。通过将离子掺杂到聚合物质子化的聚（苯并咪唑）（PBI）中，开发了一种示例性的负介电常数材料，其是产生NIM的关键。掺杂的PBI由于其降低的等离子体频率和诱导效应而以兆赫（MHz）频率显示出负的介电常数。负介电常数和谐振频率的大小可以通过掺杂浓度来调节。高掺杂的FBI在较高的谐振频率下显示出更大的负介电常数绝对值，而不是较少掺杂的PBI。

8. 发明授权

US07906043B2 Electrically conductive, optically transparent polymer/carbon nanotube composites and process for preparation thereof 有权
标题翻译：导电，光学透明的聚合物/碳纳米管复合材料及其制备方法
公开(公告)号：US07906043B2
公开(公告)日：2011-03-15
申请号：US12550431
申请日：2009-08-31
申请人： John W. Connell , Joseph G. Smith , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
发明人： John W. Connell , Joseph G. Smith , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
IPC分类号： H01B1/04 , H01B1/24 , C08K3/04 , B32B9/00
CPC分类号： B82Y10/00 , B82Y30/00 , C08F2/44 , C08G73/10 , C08G73/1039 , C08G73/1071 , C08K5/00 , C08K7/24 , C08K2201/011 , C08L71/123 , C09J11/04 , H01B1/24 , Y10T428/25 , Y10T428/29 , Y10T428/2904 , Y10T428/2913 , Y10T428/2918 , Y10T428/2975 , C08L71/12
摘要： The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
摘要翻译：本发明涉及碳纳米管（CNT）在聚合物基质中的有效分散。使用聚合物基质制备纳米复合材料，并且表现出独特的性能组合，最显着的是在可见光范围（即400-800nm）中的高保留光学透明度，导电性和高热稳定性。通过适当选择基体树脂，可以获得诸如真空紫外线辐射电阻，原子氧电阻，高玻璃化转变温度（Tg）等优异的韧性等附加特性。所得的纳米复合材料可用于制造或配制各种制品，例如各种基材，薄膜，泡沫，纤维，线，粘合剂和纤维涂层预浸料上的涂层。可以通过选择聚合物基质和CNT来调节具有高光学透明度和抗静电性能的制品来调节纳米复合材料的性能。

9. 发明申请

US20100084618A1 Electrically Conductive, Optically Transparent Polymer/Carbon Nanotube Composites 有权
标题翻译：导电，光学透明聚合物/碳纳米管复合材料
公开(公告)号：US20100084618A1
公开(公告)日：2010-04-08
申请号：US12546724
申请日：2009-08-25
申请人： John W. Connell , Joseph G. Smith, JR. , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
发明人： John W. Connell , Joseph G. Smith, JR. , Joycelyn S. Harrison , Cheol Park , Kent A. Watson , Zoubeida Ounaies
IPC分类号： H01B1/24
CPC分类号： B82Y10/00 , B82Y30/00 , C08F2/44 , C08G73/10 , C08G73/1039 , C08G73/1071 , C08K5/00 , C08K7/24 , C08K2201/011 , C08L71/123 , C09J11/04 , H01B1/24 , Y10T428/25 , Y10T428/29 , Y10T428/2904 , Y10T428/2913 , Y10T428/2918 , Y10T428/2975 , C08L71/12
摘要： The present invention is directed to the effective dispersion of carbon nanotubes (CNTs) into polymer matrices. The nanocomposites are prepared using polymer matrices and exhibit a unique combination of properties, most notably, high retention of optical transparency in the visible range (i.e., 400-800 nm), electrical conductivity, and high thermal stability. By appropriate selection of the matrix resin, additional properties such as vacuum ultraviolet radiation resistance, atomic oxygen resistance, high glass transition (Tg) temperatures, and excellent toughness can be attained. The resulting nanocomposites can be used to fabricate or formulate a variety of articles such as coatings on a variety of substrates, films, foams, fibers, threads, adhesives and fiber coated prepreg. The properties of the nanocomposites can be adjusted by selection of the polymer matrix and CNT to fabricate articles that possess high optical transparency and antistatic behavior.
摘要翻译：本发明涉及碳纳米管（CNT）在聚合物基质中的有效分散。使用聚合物基质制备纳米复合材料，并且表现出独特的性能组合，最显着的是在可见光范围（即400-800nm）中的高保留光学透明度，导电性和高热稳定性。通过适当选择基体树脂，可以获得诸如真空紫外线辐射电阻，原子氧电阻，高玻璃化转变温度（Tg）等优异的韧性等附加特性。所得的纳米复合材料可用于制造或配制各种制品，例如各种基材，薄膜，泡沫，纤维，线，粘合剂和纤维涂层预浸料上的涂层。可以通过选择聚合物基质和CNT来调节具有高光学透明度和抗静电性能的制品来调节纳米复合材料的性能。

10. 发明申请

US20080287589A1 Sensing/Actuating Materials Made From Carbon Nanotube Polymer Composites and Methods for Making Same 有权
标题翻译：由碳纳米管聚合物复合材料制成的感应/致动材料及其制造方法
公开(公告)号：US20080287589A1
公开(公告)日：2008-11-20
申请号：US12109490
申请日：2008-04-25
申请人： Zoubeida Ounaies , Cheol Park , Joycelyn S. Harrison , Nancy M. Holloway , Gregory K. Draughon
发明人： Zoubeida Ounaies , Cheol Park , Joycelyn S. Harrison , Nancy M. Holloway , Gregory K. Draughon
IPC分类号： C08K3/04
CPC分类号： B82Y30/00 , C01B32/158 , H01L41/183 , Y10S977/783 , Y10S977/832 , Y10T428/25 , Y10T428/252 , Y10T428/256 , Y10T428/258
摘要： An electroactive sensing or actuating material comprises a composite made from a polymer with polarizable moieties and an effective amount of carbon nanotubes incorporated in the polymer for a predetermined electromechanical operation of the composite when such composite is affected by an external stimulus. In another embodiment, the composite comprises a third component of micro-sized to nano-sized particles of an electroactive ceramic that is also incorporated in the polymer matrix. The method for making the three-phase composite comprises either incorporating the carbon nanotubes in the polymer matrix before incorporation of the particles of ceramic or mixing the carbon nanotubes and particles of ceramic together in a solution before incorporation in the polymer matrix.
摘要翻译：电活性感测或致动材料包括由具有可极化部分的聚合物制成的复合材料，并且当这种复合材料受外部刺激影响时，有效量的纳入聚合物中的碳纳米管用于组合物的预定机电操作。在另一个实施方案中，所述复合材料包括还掺入聚合物基质中的电活性陶瓷的微尺寸至纳米尺寸颗粒的第三组分。制备三相复合材料的方法包括在引入陶瓷颗粒之前将碳纳米管掺入聚合物基质中，或者在引入到聚合物基质中之前将碳纳米管和陶瓷颗粒一起混合在溶液中。

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