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1. 发明申请

US20180053865A1 PV CELLS AND BACKSHEET POLYESTER FILMS 审中-公开
公开(公告)号：US20180053865A1
公开(公告)日：2018-02-22
申请号：US15557519
申请日：2016-03-11
申请人： Robert EVESON , Robert HUTCHINGS , Julian Neal ROBINSON , Moira TAYLER , DUPONT TEIJIN FILMS U.S. LIMITED PARTNERSHIP
发明人： Robert EVESON , Robert HUTCHINGS , Julian Neal ROBINSON , Moira TAYLER
IPC分类号： H01L31/049 , B32B27/08 , B32B27/30 , B32B27/36 , B32B7/12
CPC分类号： H01L31/049 , B32B7/12 , B32B27/08 , B32B27/26 , B32B27/306 , B32B27/36 , B32B2255/10 , B32B2255/26 , B32B2307/41 , B32B2307/412 , B32B2307/516 , B32B2307/518 , B32B2457/12 , C08K5/0025 , C08K5/353 , C09J7/22 , C09J7/35 , C09J2203/322 , C09J2205/102 , C09J2205/114 , C09J2423/04 , C09J2431/00 , C09J2467/006 , H01L31/048 , Y02E10/50
摘要： Photovoltaic cells which comprise a back plane comprising a polyester film and an adhesive coating derived from an ethylene vinyl acetate copolymer and an oxazoline crosslinking agent and methods for forming the same are described.

2. 发明授权

US08501300B2 Coated polymeric substrates having improved surface smoothness suitable for use in flexible electronic and opto-electronic devices 有权
标题翻译：涂覆的聚合物基材具有改善的表面光滑度，适用于柔性电子和光电子器件
公开(公告)号：US08501300B2
公开(公告)日：2013-08-06
申请号：US12640835
申请日：2009-12-17
申请人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
发明人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
IPC分类号： B32B3/00 , B32B27/06 , B32B27/08 , B32B27/20 , B32B27/36
CPC分类号： H01L51/0097 , C08J7/047 , C08J2367/02 , C08J2483/00 , C09D183/04 , H01L51/0002 , H01L51/52 , H05B33/14 , Y02E10/549 , Y02P70/521 , Y10S428/91 , Y10T428/1045 , Y10T428/1086 , Y10T428/1379 , Y10T428/24355 , Y10T428/24372 , Y10T428/24421 , Y10T428/25 , Y10T428/259 , Y10T428/26 , Y10T428/269 , Y10T428/31663 , Y10T428/31786 , C08L2666/54
摘要： A method of manufacture of a coated polymeric film which comprises performing in sequence the steps of: (i) forming a substrate layer comprising poly(ethylene naphthalate) having a thickness in a range from 50 μm to 250 μm; (ii) stretching the substrate layer in at least one direction; (iii) heat-setting the substrate layer under dimensional restraint at a tension in the range of about 19 to about 75 kg/m of film width, at a temperature above the glass transition temperature of the poly(ethylene naphthalate) but below the melting temperature thereof; (iv) heat-stabilizing the substrate layer under a tension of less than 5 kg/m of film width, and at a temperature above the glass transition temperature of the poly(ethylene naphthalate) but below the melting temperature thereof; and (v) disposing a coating layer on a surface of the substrate layer by a process comprising applying a planarizing coating composition thereto such that a surface of said coating layer exhibits an Ra value of less than 0.6 nm, and/or an Rq value of less than 0.8 nm; and wherein the coating layer has a dry thickness in a range from 1 μm to 20 μm and the number of surface peaks in the range 300 to 600 nm per 5 cm2 area (N(300-600)) of the film after coating is less than 50.
摘要翻译：一种制造涂覆的聚合物膜的方法，其包括以下步骤：（i）形成包含厚度在50μm至250μm之间的聚萘二甲酸乙二醇酯的基材层; （ii）在至少一个方向上拉伸基底层; （iii）在高于聚萘二甲酸乙二醇酯的玻璃化转变温度但低于熔融的玻璃化转变温度的温度下，以约19至约75kg / m 2的膜宽度的张力在尺寸限制下热定型基材层温度; （iv）在低于5kg / m 2膜宽的张力和高于聚萘二甲酸乙二醇酯的玻璃化转变温度但低于其熔融温度的温度下对基材层进行热稳定化; 和（v）通过包括在其上施加平坦化涂料组合物使得所述涂层的表面呈现小于0.6nm的Ra值和/或Rq值的方法在基材层的表面上设置涂层小于0.8nm; 并且其中所述涂层的干燥厚度为1μm至20μm，并且涂布后的膜的每5cm2面积（N（300-600））在300-600nm范围内的表面峰数量（N（300-600））较小超过50。

3. 发明授权

US07641957B2 Coated polymeric substrates having improved surface smoothness suitable for use in flexible electronic and opto-electronic devices 有权
标题翻译：涂覆的聚合物基材具有改善的表面光滑度，适用于柔性电子和光电子器件
公开(公告)号：US07641957B2
公开(公告)日：2010-01-05
申请号：US10510084
申请日：2003-03-19
申请人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
发明人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
IPC分类号： B32B27/08 , B32B27/20 , B32B27/36 , B05D7/04 , B05D7/24
CPC分类号： H01L51/0097 , C08J7/047 , C08J2367/02 , C08J2483/00 , C09D183/04 , H01L51/0002 , H01L51/52 , H05B33/14 , Y02E10/549 , Y02P70/521 , Y10S428/91 , Y10T428/1045 , Y10T428/1086 , Y10T428/1379 , Y10T428/24355 , Y10T428/24372 , Y10T428/24421 , Y10T428/25 , Y10T428/259 , Y10T428/26 , Y10T428/269 , Y10T428/31663 , Y10T428/31786 , C08L2666/54
摘要： The use of a coating composition comprising: (a) from about 5 to about 50 weight percent solids, the solids comprising from about 10 to about 70 weight percent silica and from about 90 to about 30 weight percent of a partially polymerized organic silanol of the general formula RSi(OH)3, wherein R is selected from methyl and up to about 40% of a group selected from the group consisting of vinyl, phenyl, gamma-glycidoxypropyl, and gamma-methacryloxypropyl, and (b) from about 95 to about 50 weight percent solvent, the solvent comprising from about 10 to about 90 weight percent water and from about 90 to about 10 weight percent lower aliphatic alcohol, wherein the coating composition has a pH of from about 3.0 to about 8.0, for the purpose of improving the surface smoothness of a polymeric substrate, particularly a heat-stabilised, heat-set, oriented polyester substrate, and use of said coated substrate in the manufacture of an electronic or optoelectronic device containing a conjugated conductive polymer.
摘要翻译：涂料组合物的用途包括：（a）约5至约50重量％的固体，固体包含约10至约70重量％的二氧化硅和约90至约30重量％的部分聚合的有机硅烷醇通式RSi（OH）3，其中R选自甲基和至多约40％的选自乙烯基，苯基，γ-缩水甘油氧基丙基和γ-甲基丙烯酰氧基丙基的基团，和（b）约95至约50重量％的溶剂，溶剂包含约10至约90重量％的水和约90至约10重量％的低级脂族醇，其中涂料组合物的pH为约3.0至约8.0，用于提高聚合物基材，特别是热稳定的热定型聚酯基材的表面光滑度，以及使用所述涂覆的基材制造含有共轭共聚物的电子或光电装置导电聚合物。

4. 发明授权

US5690994A Polymetric film 失效
标题翻译：聚光膜
公开(公告)号：US5690994A
公开(公告)日：1997-11-25
申请号：US465096
申请日：1995-06-05
申请人： Julian Neal Robinson
发明人： Julian Neal Robinson
IPC分类号： G03C1/91 , G03C1/93 , B32B27/06
CPC分类号： G03C1/93 , G03C1/91 , Y10T428/31504 , Y10T428/31794 , Y10T428/31797 , Y10T428/31913 , Y10T428/31928
摘要： A coated film having a polymeric film substrate with a subbing layer containing an organic acid and a polymer which has a repeating unit(s) containing a pendant nitrogen atom(s). The ratio of organic acid to polymer in the subbing layer is in the range from 1:0.1 to 20 by weight. The coated film exhibits excellent adhesion to photographic emulsion layers, even when applied prior to completion of any film stretching operation.
摘要翻译：一种具有聚合物膜基材的涂膜，其具有含有有机酸的底层和具有含有侧挂氮原子的重复单元的聚合物。底层中的有机酸与聚合物的比率为1:0.1〜20重量％。即使在完成任何膜拉伸操作之前，涂布膜对照相乳剂层表现出优异的粘附性。

5. 发明授权

US08318289B2 Coated polymeric substrates having improved surface smoothness suitable for use in flexible electronic and opto-electronic devices 有权
标题翻译：涂覆的聚合物基材具有改善的表面光滑度，适用于柔性电子和光电子器件
公开(公告)号：US08318289B2
公开(公告)日：2012-11-27
申请号：US12640826
申请日：2009-12-17
申请人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
发明人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
IPC分类号： B32B27/06 , B32B27/18 , B32B27/28 , B32B27/36
CPC分类号： H01L51/0097 , C08J7/047 , C08J2367/02 , C08J2483/00 , C09D183/04 , H01L51/0002 , H01L51/52 , H05B33/14 , Y02E10/549 , Y02P70/521 , Y10S428/91 , Y10T428/1045 , Y10T428/1086 , Y10T428/1379 , Y10T428/24355 , Y10T428/24372 , Y10T428/24421 , Y10T428/25 , Y10T428/259 , Y10T428/26 , Y10T428/269 , Y10T428/31663 , Y10T428/31786 , C08L2666/54
摘要： A composite film comprising a heat-stabilised, heat-set, oriented poly(ethylene naphthalate) substrate, and a coating layer having a surface; wherein said substrate exhibits one or more of: (i) a shrinkage at 30 mins at 230° C. of less than 1%; and/or (ii) a residual dimensional change ΔLr measured at 25° C. before and after heating the substrate from 8° C. to 200° C. and then cooling to 8° C., of less than 0.75% of the original dimension; and/or (iii) a coefficient of linear thermal expansion (CLTE) within the temperature range from −40° C. to +100° C. of less than 40×10−6/° C.; and wherein the surface of said coating layer exhibits an Ra value of less than 0.6 nm, and/or an Rq value of less than 0.8 nm, the thickness of the substrate is between 50 and 250 μm and wherein the number of surface peaks in the range 300 to 600 nm per 5 cm2 area (N(300-600)) of the film is less than 50.
摘要翻译：一种复合膜，包括热稳定的，热定型的聚萘二甲酸乙二醇酯基材和具有表面的涂层; 其中所述基材表现出以下一种或多种：（i）在230℃下30分钟的收缩率小于1％; 和/或（ii）在将基材从8℃加热至200℃之前和之后在25℃下测量的残余尺寸变化＆Dgr; Lr，然后冷却至8℃，小于0.75％原始尺寸; 和/或（iii）在-40℃至+ 100℃的温度范围内的线性热膨胀系数（CLTE）小于40×10-6 /℃; 并且其中所述涂层的表面呈现小于0.6nm的Ra值和/或小于0.8nm的Rq值，所述基材的厚度为50-250μm，并且其中所述表面峰的数目为范围为300〜600nm / 5cm 2面积（N（300-600））的膜小于50。

6. 发明申请

US20110244390A1 DONOR ELEMENT WITH MALEIC ANHYDRIDE BASED POLYMERS FOR THERMAL TRANSFER 审中-公开
标题翻译：用于热转印的基于无水基聚合物的助剂元素
公开(公告)号：US20110244390A1
公开(公告)日：2011-10-06
申请号：US12279591
申请日：2007-04-19
申请人： Thomas C. Felder , Christopher Ferguson , Richard Paul Pankratz , Julian Neal Robinson , Debra S. Strickland
发明人： Thomas C. Felder , Christopher Ferguson , Richard Paul Pankratz , Julian Neal Robinson , Debra S. Strickland
IPC分类号： G03C8/00 , B05D5/06 , B05D1/36
CPC分类号： B41M5/44 , B41M5/46
摘要： This invention pertains to a donor element for use with a receiver element in an imagable assemblage for light-induced transfer of material from the donor element to the receiver element. Specifically, this invention relates to such a donor element comprising a copolymer based on styrene and maleic anhydride.
摘要翻译：本发明涉及一种用于与用于光源从施主元件传递到接收器元件的材料的可成像组合中的接收器元件的施主元件。具体而言，本发明涉及包含基于苯乙烯和马来酸酐的共聚物的施主元素。

7. 发明授权

US5698329A Polymeric film 失效
标题翻译：聚合膜
公开(公告)号：US5698329A
公开(公告)日：1997-12-16
申请号：US465109
申请日：1995-06-05
申请人： Julian Neal Robinson
发明人： Julian Neal Robinson
IPC分类号： G03C1/91 , G03C1/93 , B32B27/06
CPC分类号： G03C1/93 , G03C1/91 , Y10T428/31504 , Y10T428/31794 , Y10T428/31797 , Y10T428/31913 , Y10T428/31928
摘要： A coated film having a polymeric film substrate with a subbing layer containing an organic acid and a polymer which has a repeating unit(s) containing a pendant nitrogen atom(s). The ratio of organic acid to polymer in the subbing layer is in the range from 1:0.1 to 20 by weight. The coated film exhibits excellent adhesion to photographic emulsion layers, even when applied prior to completion of any film stretching operation.
摘要翻译：一种具有聚合物膜基材的涂膜，其具有含有有机酸的底层和具有含有侧挂氮原子的重复单元的聚合物。底层中的有机酸与聚合物的比率为1:0.1〜20重量％。即使在完成任何膜拉伸操作之前，涂布膜对照相乳剂层表现出优异的粘附性。

8. 发明申请

US20110081530A1 Anti-Microbial Polymeric Film and Method of Manufacture of Said Film 审中-公开
标题翻译：抗微生物聚合物薄膜和所述薄膜的制造方法
公开(公告)号：US20110081530A1
公开(公告)日：2011-04-07
申请号：US12997496
申请日：2009-06-10
申请人： Julian Neal Robinson , Robert W. Eveson , Karl Rakos , David Brown , Jackie Symonds , Debbie A. Stephenson
发明人： Julian Neal Robinson , Robert W. Eveson , Karl Rakos , David Brown , Jackie Symonds , Debbie A. Stephenson
IPC分类号： B32B7/02 , B29C55/04 , B05D3/02 , B29C55/14
CPC分类号： B29C55/026 , B29C55/023 , B29C71/0009 , Y10T428/24942
摘要： A method of manufacture of an anti-microbial polymeric film comprising coextruding a polymeric substrate layer comprising a first layer of a first polymeric material and a second layer of a second polymeric material wherein the crystalline melting temperature (TM2) of said second polymeric material is lower than the crystalline melting temperature (TM1) of the first polymeric material; stretching the coextruded substrate in a first direction; optionally stretching the substrate layer in a second, orthogonal direction; disposing on the surface of the polymeric second layer a composition comprising a particulate antimicrobial compound and a liquid vehicle, and preferably also a surfactant; and heat-setting the stretched film at a temperature above the crystalline melting temperature (TM2) of the second polymeric material but below the crystalline melting temperature (TM1) of the first polymeric material; wherein the composition is applied to the polymeric second layer after the coextrusion step but before the heat-setting step; such that in the final film said second layer comprises said anti-microbial compound in an amount of from about 1 to about 80% by weight of said polymeric material of the second layer is described. Anti-microbial films are also described.
摘要翻译：一种制造抗微生物聚合物膜的方法，包括将包含第一聚合物材料的第一层和第二聚合物材料的第二层的聚合物基底层共挤出，其中所述第二聚合物材料的结晶熔融温度（TM2）较低比第一聚合物材料的结晶熔融温度（TM1）高; 在第一方向上拉伸所述共挤出的基材; 任选地在第二正交方向上拉伸基底层; 在聚合物第二层的表面上设置包含颗粒状抗微生物化合物和液体载体的组合物，优选还包括表面活性剂; 以及在高于第二聚合物材料的结晶熔化温度（TM2）但低于第一聚合物材料的结晶熔融温度（TM1）的温度下热定型拉伸膜; 其中所述组合物在共挤出步骤之后但在热定形步骤之前施加到聚合物第二层; 使得在最终膜中所述第二层包含所述抗微生物化合物的量为所述第二层聚合物材料的约1至约80重量％。还描述了抗微生物膜。

9. 发明申请

US20100159198A1 COATED POLYMERIC SUBSTRATES HAVING IMPROVED SURFACE SMOOTHNESS SUITABLE FOR USE IN FLEXIBLE ELECTRONIC AND OPTO-ELECTRONIC DEVICES 有权
标题翻译：具有适用于柔性电子和光电设备的改进表面光滑性的涂层聚合物基材
公开(公告)号：US20100159198A1
公开(公告)日：2010-06-24
申请号：US12640826
申请日：2009-12-17
申请人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
发明人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
IPC分类号： B32B3/00
CPC分类号： H01L51/0097 , C08J7/047 , C08J2367/02 , C08J2483/00 , C09D183/04 , H01L51/0002 , H01L51/52 , H05B33/14 , Y02E10/549 , Y02P70/521 , Y10S428/91 , Y10T428/1045 , Y10T428/1086 , Y10T428/1379 , Y10T428/24355 , Y10T428/24372 , Y10T428/24421 , Y10T428/25 , Y10T428/259 , Y10T428/26 , Y10T428/269 , Y10T428/31663 , Y10T428/31786 , C08L2666/54
摘要： The use of a coating composition comprising:(a) from about 5 to about 50 weight percent solids, the solids comprising from about 10 to about 70 weight percent silica and from about 90 to about 30 weight percent of a partially polymerized organic silanol of the general formula RSi(OH)3, wherein R is selected from methyl and up to about 40% of a group selected from the group consisting of vinyl, phenyl, gamma-glycidoxypropyl, and gamma-methacryloxypropyl, and (b) from about 95 to about 50 weight percent solvent, the solvent comprising from about to about 90 weight percent water and from about 90 to about 10 weight percent lower aliphatic alcohol, wherein the coating composition has a pH of from about 3.0 to about 8.0, for the purpose of improving the surface smoothness of a polymeric substrate, particularly a heat-stabilised, heat-set, oriented polyester substrate, and use of said coated substrate in the manufacture of an electronic or opto-electronic device containing a conjugated conductive polymer.
摘要翻译：涂料组合物的用途包括：（a）约5至约50重量％的固体，固体包含约10至约70重量％的二氧化硅和约90至约30重量％的部分聚合的有机硅烷醇通式RSi（OH）3，其中R选自甲基和至多约40％的选自乙烯基，苯基，γ-缩水甘油氧基丙基和γ-甲基丙烯酰氧基丙基的基团，和（b）约95至约50重量％的溶剂，溶剂包含约90重量％的水和约90至约10重量％的低级脂族醇，其中涂料组合物的pH为约3.0至约8.0，为了改善聚合物基材的表面光滑度，特别是热稳定的热定型聚酯基材的表面光滑度，以及所述涂覆的基材在制造包含共轭凝胶的电子或光电装置中的用途高分子聚合物

10. 发明申请

US20100154886A1 COATED POLYMERIC SUBSTRATES HAVING IMPROVED SURFACE SMOOTHNESS SUITABLE FOR USE IN FLEXIBLE ELECTRONIC AND OPTO-ELECTRONIC DEVICES 有权
标题翻译：具有适用于柔性电子和光电设备的改进表面光滑性的涂层聚合物基材
公开(公告)号：US20100154886A1
公开(公告)日：2010-06-24
申请号：US12640835
申请日：2009-12-17
申请人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
发明人： Julian Neal Robinson , Robert William Eveson , Karl Rakos
IPC分类号： H01L31/0216 , B05D3/12 , B05D5/12 , C08G63/13
CPC分类号： H01L51/0097 , C08J7/047 , C08J2367/02 , C08J2483/00 , C09D183/04 , H01L51/0002 , H01L51/52 , H05B33/14 , Y02E10/549 , Y02P70/521 , Y10S428/91 , Y10T428/1045 , Y10T428/1086 , Y10T428/1379 , Y10T428/24355 , Y10T428/24372 , Y10T428/24421 , Y10T428/25 , Y10T428/259 , Y10T428/26 , Y10T428/269 , Y10T428/31663 , Y10T428/31786 , C08L2666/54
摘要： The use of a coating composition comprising: (a) from about 5 to about 50 weight percent solids, the solids comprising from about 10 to about 70 weight percent silica and from about 90 to about 30 weight percent of a partially polymerized organic silanol of the general formula RSi(OH)3, wherein R is selected from methyl and up to about 40% of a group selected from the group consisting of vinyl, phenyl, gamma-glycidoxypropyl, and gamma-methacryloxypropyl, and (b) from about 95 to about 50 weight percent solvent, the solvent comprising from about 10 to about 90 weight percent water and from about 90 to about 10 weight percent lower aliphatic alcohol, wherein the coating composition has a pH of from about 3.0 to about 8.0, for the purpose of improving the surface smoothness of a polymeric substrate, particularly a heat-stabilised, heat-set, oriented polyester substrate, and use of said coated substrate in the manufacture of an electronic or opto-electronic device containing a conjugated conductive polymer.
摘要翻译：涂料组合物的用途包括：（a）约5至约50重量％的固体，固体包含约10至约70重量％的二氧化硅和约90至约30重量％的部分聚合的有机硅烷醇通式RSi（OH）3，其中R选自甲基和至多约40％的选自乙烯基，苯基，γ-缩水甘油氧基丙基和γ-甲基丙烯酰氧基丙基的基团，和（b）约95至约50重量％的溶剂，溶剂包含约10至约90重量％的水和约90至约10重量％的低级脂族醇，其中涂料组合物的pH为约3.0至约8.0，用于提高聚合物基材，特别是热稳定的热定型聚酯基材的表面光滑度，以及使用所述涂覆的基材在制造含有共轭C的电子或光电装置导电聚合物。

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