专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US09433924B2 Metaloxide—ZrO2 catalysts for the esterification and transesterification of free fatty acids and triglycerides to obtain bio-diesel 有权
标题翻译：用于酯化和酯交换游离脂肪酸和甘油三酯以获得生物柴油的金属氧化物 - ZrO2催化剂
公开(公告)号：US09433924B2
公开(公告)日：2016-09-06
申请号：US13508738
申请日：2010-11-08
申请人： Manhoe Kim , Steven O. Salley , K. Y. Simon Ng
发明人： Manhoe Kim , Steven O. Salley , K. Y. Simon Ng
IPC分类号： B01J21/06 , B01J21/08 , B01J23/00 , B01J23/06 , B01J23/10 , B01J23/80 , B01J37/03 , C11C3/00
CPC分类号： B01J21/066 , B01J21/063 , B01J23/002 , B01J23/06 , B01J23/10 , B01J23/80 , B01J37/031 , B01J37/036 , B01J2523/00 , C10G2300/1003 , C10G2300/1011 , C11C3/003 , Y02E50/13 , Y02P30/20 , B01J2523/27 , B01J2523/3725 , B01J2523/41 , B01J2523/47 , B01J2523/48 , B01J2523/3743 , B01J2523/847 , B01J2523/3787
摘要： Mixed metal oxide catalysts (ZnO, CeO, La2O3, NiO, Al203, Si02, TiO2, Nd2O3, Yb2O3, or any combination of these) supported on zirconia (ZrO2) or hydrous zirconia are provided. These mixed metal oxide catalysts can be prepared via coprecipitation, impregnation, or sol-gel methods from metal salt precursors with/without a Zirconium salt precursor. Metal oxides/ZrO2 catalyzes both esterification and transesterification of oil containing free fatty acids in one batch or in single stage. In particular, these mixed metal oxides supported or added on zirconium oxide exhibit good activity and selectivity for esterification and transesterification. The low acid strength of this catalyst can avoid undesirable side reaction such as alcohol dehydration or cracking of fatty acids. Metal oxides/ZrO2 catalysts are not sensitive to any water generated from esterification. Thus, esterification does not require a water free condition or the presence of excess methanol to occur when using the mixed metal oxide catalyst. The FAME yield obtained with metal oxides/ZrO2 is higher than that obtained with homogeneous sulfuric acid catalyst. Metal oxides/ZrO2 catalasts can be prepared as strong pellets and in various shapes for use directly in a flow reactor. Furthermore, the pellet has a strong resistance toward dissolution to aqueous or oil phases.
摘要翻译：提供负载在氧化锆（ZrO2）或含水氧化锆上的混合金属氧化物催化剂（ZnO，CeO，La2O3，NiO，Al2O3，SiO2，TiO2，Nd2O3，Yb2O3或它们的任意组合）。这些混合金属氧化物催化剂可以通过共沉淀，浸渍或溶胶 - 凝胶法从具有/不具有锆盐前体的金属盐前体制备。金属氧化物/ ZrO2催化一批或单一阶段含油游离脂肪酸的酯化和酯交换反应。特别地，负载或添加到氧化锆上的这些混合金属氧化物表现出良好的酯化和酯交换活性和选择性。该催化剂的低酸强度可以避免不希望的副反应，例如醇脱水或脂肪酸的裂解。金属氧化物/ ZrO2催化剂对由酯化产生的任何水不敏感。因此，当使用混合金属氧化物催化剂时，酯化不需要无水条件或过量甲醇的存在。用金属氧化物/ ZrO2获得的FAME产率高于用均相硫酸催化剂获得的FAME产率。金属氧化物/ ZrO 2催化剂可以制备成强颗粒，并且可以用于流动反应器中直接使用的各种形状。此外，颗粒对水相或油相具有很强的溶解性。

2. 发明授权

US08975426B2 ZnO nanoparticle catalysts for use in transesterification and esterification reactions and method of making 有权
标题翻译：用于酯交换和酯化反应的ZnO纳米颗粒催化剂及其制备方法
公开(公告)号：US08975426B2
公开(公告)日：2015-03-10
申请号：US13378931
申请日：2010-06-16
申请人： Shuli Yan , Steven O. Salley , K. Y. Simon Ng
发明人： Shuli Yan , Steven O. Salley , K. Y. Simon Ng
IPC分类号： C07C51/00 , C11C1/00 , C11C3/00 , B01J23/06 , B01J23/10 , B01J35/00 , B01J35/02 , B01J37/03 , B01J37/08 , C10L1/02 , C11C3/10
CPC分类号： B01J23/06 , B01J23/10 , B01J35/002 , B01J35/006 , B01J35/023 , B01J37/031 , B01J37/08 , C10L1/026 , C11C3/003 , C11C3/10 , Y02E50/13
摘要： A method of forming a product from an oil feedstock, such as a biodiesel product, and a heterogeneous catalyst system used to form said product is disclosed. This catalyst system, which has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock, may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system is comprised of a mixture of zinc oxide and a second metal oxide. The zinc oxide includes a mixture of amorphous zinc oxide and zinc oxide nanocrystals, the zinc nanocrystals having a mean grain size between about 20 and 80 nanometers with at least one of the nanocrystals including a mesopore having a diameter of about 5 to 15 nanometers. Preferably, the second metal oxide is a lanthanum oxide, the lanthanum oxide being selected as one from the group of La2CO5, LaOOH, and combinations or mixtures thereof.
摘要翻译：公开了一种从油原料形成产物的方法，例如生物柴油产品和用于形成所述产品的多相催化剂体系。对油原料中存在水和游离脂肪酸（FFA）具有高耐受性的该催化剂体系可以同时催化FAA的酯化和油原料中存在的甘油三酯的酯交换。催化剂体系由氧化锌和第二金属氧化物的混合物组成。氧化锌包括无定形氧化锌和氧化锌纳米晶体的混合物，锌纳米晶体的平均晶粒尺寸在约20至80纳米之间，其中至少一个纳米晶体包括直径约5至15纳米的中孔。优选地，第二金属氧化物是氧化镧，氧化镧选自La 2 CO 5，LaOOH中的一种，以及它们的组合或混合物。

3. 发明授权

US08895764B2 ZnO nanoparticle catalysts for use in biodiesel production and method of making 有权
标题翻译：用于生物柴油生产的ZnO纳米颗粒催化剂及其制备方法
公开(公告)号：US08895764B2
公开(公告)日：2014-11-25
申请号：US12485433
申请日：2009-06-16
申请人： Shuli Yan , Steven O. Salley , K. Y. Simon Ng
发明人： Shuli Yan , Steven O. Salley , K. Y. Simon Ng
IPC分类号： C07C51/00 , C11C1/00 , C11C3/00 , B01J23/00 , B01J23/10 , B01J23/02 , B01J23/44 , B01J37/08 , B01J23/06 , B01J35/00 , C10L1/02 , B01J37/03 , B01J35/02
CPC分类号： B01J23/06 , B01J23/10 , B01J35/002 , B01J35/006 , B01J35/023 , B01J37/031 , B01J37/08 , C10L1/026 , C11C3/003 , Y02E50/13
摘要： A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system is comprised of a mixture of zinc oxide and a second metal oxide. The zinc oxide includes a mixture of amorphous zinc oxide and zinc oxide nanocrystals, the zinc nanocrystals having a mean grain size between about 20 and 80 nanometers with at least one of the nanocrystals including a mesopore having a diameter of about 5 to 15 nanometers. Preferably, the second metal oxide is a lanthanum oxide, the lanthanum oxide being selected as one from the group of La2CO5, LaOOH, and combinations or mixtures thereof.
摘要翻译：公开了形成生物柴油产物的方法和用于形成对油原料中存在水和游离脂肪酸（FFA）的高耐受性的所述产物的多相催化剂体系。该催化剂体系可以同时催化FAA的酯化和油原料中存在的甘油三酯的酯交换。催化剂体系由氧化锌和第二金属氧化物的混合物组成。氧化锌包括无定形氧化锌和氧化锌纳米晶体的混合物，锌纳米晶体的平均晶粒尺寸在约20至80纳米之间，其中至少一个纳米晶体包括直径约5至15纳米的中孔。优选地，第二金属氧化物是氧化镧，氧化镧选自La 2 CO 5，LaOOH中的一种，以及它们的组合或混合物。

4. 发明授权

US08163946B2 Methods and catalysts for making biodiesel from the transesterification and esterification of unrefined oils 有权
标题翻译：从未精制油的酯交换和酯化制备生物柴油的方法和催化剂
公开(公告)号：US08163946B2
公开(公告)日：2012-04-24
申请号：US12468309
申请日：2009-05-19
申请人： Shuli Yan , Steven O. Salley , K. Y. Simon Ng
发明人： Shuli Yan , Steven O. Salley , K. Y. Simon Ng
IPC分类号： C11C3/10
CPC分类号： C11C3/003 , B01J23/002 , B01J23/10 , B01J37/03 , B01J2523/00 , C10L1/026 , Y02E50/13 , B01J2523/27 , B01J2523/3706
摘要： A method of forming a biodiesel product and a heterogeneous catalyst system used to form said product that has a high tolerance for the presence of water and free fatty acids (FFA) in the oil feedstock is disclosed. This catalyst system may simultaneously catalyze both the esterification of FAA and the transesterification of triglycerides present in the oil feedstock. The catalyst system according to one aspect of the present disclosure represents a class of zinc and lanthanum oxide heterogeneous catalysts that include different ratios of zinc oxide to lanthanum oxides (Zn:La ratio) ranging from about 10:0 to 0:10. The Zn:La ratio in the catalyst is believed to have an effect on the number and reactivity of Lewis acid and base sites, as well as the transesterification of glycerides, the esterification of fatty acids, and the hydrolysis of glycerides and biodiesel.
摘要翻译：公开了形成生物柴油产物的方法和用于形成对油原料中存在水和游离脂肪酸（FFA）的高耐受性的所述产物的多相催化剂体系。该催化剂体系可以同时催化FAA的酯化和油原料中存在的甘油三酯的酯交换。根据本公开一个方面的催化剂体系表示一类锌和镧异相催化剂，其包括氧化锌与氧化镧的不同比例（Zn：La比）为约10：0至0:10。据信催化剂中的Zn：La比对路易斯酸和碱基位点的数量和反应性以及甘油酯的酯交换，脂肪酸的酯化以及甘油酯和生物柴油的水解具有影响。

5. 发明授权

US09162212B2 Supported catalyst systems and method of making biodiesel products using such catalysts 有权
标题翻译：支持的催化剂体系和使用这种催化剂制备生物柴油产品的方法
公开(公告)号：US09162212B2
公开(公告)日：2015-10-20
申请号：US13255305
申请日：2010-03-09
申请人： Manhoe Kim , Shuli Yan , Steven O. Salley , K. Y. Simon Ng
发明人： Manhoe Kim , Shuli Yan , Steven O. Salley , K. Y. Simon Ng
IPC分类号： B01J23/00 , B01J23/10 , B01J21/06 , B01J23/02 , B01J29/40 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/08 , C10L1/02 , C11C3/10
CPC分类号： B01J23/002 , B01J21/06 , B01J23/02 , B01J23/10 , B01J29/405 , B01J37/0009 , B01J37/0201 , B01J37/031 , B01J37/08 , B01J2523/00 , C10L1/026 , C11C3/10 , Y02E50/13 , B01J2523/23 , B01J2523/3706 , B01J2523/3712 , B01J2523/47 , B01J2523/31 , B01J2523/48
摘要： A heterogeneous catalyst system, a method of preparing the catalyst system and a method of forming a biodiesel product via transesterification reactions using the catalyst system is disclosed. The catalyst system according to one aspect of the present disclosure represents a class of supported mixed metal oxides that include at least calcium oxide and another metal oxide deposited on a lanthanum oxide or cerium oxide support. Preferably, the catalysts include CaO—CeO2ZLa2O3 or CaO—La2O3/CeO2. Optionally, the catalyst may further include additional metal oxides, such as CaO—La2O3—GdOxZLa2O3.
摘要翻译：公开了一种非均相催化剂体系，制备催化剂体系的方法以及通过使用催化剂体系的酯交换反应形成生物柴油产物的方法。根据本公开一个方面的催化剂体系表示一类负载的混合金属氧化物，其至少包含沉积在氧化镧或氧化铈载体上的氧化钙和另一种金属氧化物。优选地，催化剂包括CaO-CeO 2·Zr 2 O 3或CaO-La 2 O 3 / CeO 2。任选地，催化剂还可以包括另外的金属氧化物，例如CaO-La 2 O 3 -GdO x ZrL 2 O 3。

6. 发明授权

US08070836B2 Combined homogeneous and heterogeneous catalytic transesterification process for biodiesel production 失效
标题翻译：用于生物柴油生产的组合均相和多相催化酯交换法
公开(公告)号：US08070836B2
公开(公告)日：2011-12-06
申请号：US12252875
申请日：2008-10-16
申请人： K. Y. Simon Ng , Manhoe Kim , Steven O. Salley
发明人： K. Y. Simon Ng , Manhoe Kim , Steven O. Salley
IPC分类号： C10L1/18 , C07C51/00
CPC分类号： C11C3/003 , C07C67/03 , C10G2300/1014 , C10L1/026 , Y02E50/13 , Y02P30/20 , C07C69/52 , C07C69/24
摘要： In one aspect, a process for producing a biofuel comprises reacting a feed material that comprises a glyceride with an alcohol in the presence of a catalytic composition such that at least some of the glyceride in the feed material is converted into a biofuel mixture that comprises glycerol and the corresponding alcoholic ester of the glyceride. The catalytic composition comprises a heterogeneous catalyst and a homogeneous catalyst. The heterogeneous catalyst and the homogeneous catalyst have a synergistic effect in catalyzing the reaction of the glyceride in the feed material with the alcohol.
摘要翻译：一方面，生产生物燃料的方法包括在催化组合物存在下使包含甘油酯的进料与醇反应，使得进料中的至少一些甘油酯转化为包含甘油的生物燃料混合物和甘油酯的相应醇酯。催化组合物包含非均相催化剂和均相催化剂。非均相催化剂和均相催化剂在催化进料中甘油酯与醇的反应方面具有协同效应。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式