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    • 1. 发明授权
    • Dual curing polymers and methods for their preparation and use
    • 双固化聚合物及其制备和使用方法
    • US08168737B2
    • 2012-05-01
    • US12517220
    • 2007-12-10
    • Khristopher Edward AlvarezNick Evan ShephardJames Tonge
    • Khristopher Edward AlvarezNick Evan ShephardJames Tonge
    • C08G77/08
    • C08G77/14C08G77/50C08J3/243C08J2383/06C08J2383/14C08L83/06C08L83/14C09D183/14C08L2666/28
    • A polymer cures by both radiation and moisture curing mechanisms. The polymer is prepared by hydrosilylation. The polymer is useful in adhesive compositions. The polymer includes units of formulae (I), (R22Si02/2)b, (R2Si03/2)c, (Si04/2)d, (R1)f, and (R23SiO1/2)g, where each R1 is independently an oxygen atom or a divalent hydrocarbon group; each R1 is independently divalent hydrocarbon group; each R2 is independently a monovalent organic group that is free of terminal aliphatic unsaturation each X is independently a monovalent hydrolyzable group; each J is independently a monovalent epoxy functional organic group; subscript a has a value of 1 or more; subscript b has a value of 0 or more; subscript c has a value of 0 or more; subscript d has a value of 0 or more; subscript e has a value of 1 or more; subscript f has a value of 0 or more; subscript g has a value of 0 or more; subscript s is 1, 2, or 3; and subscript t is 1, 2, or 3.
    • 聚合物通过辐射和湿气固化机制固化。 聚合物通过氢化硅烷化制备。 该聚合物可用于粘合剂组合物。 聚合物包括式(I),(R 22 SiO 2/2)b,(R 2 SiO 3/2)c,(SiO 4/2)d,(R 1)f和(R 23 SiO 1/2)g的单元,其中每个R 1独立地为 氧原子或二价烃基; 每个R 1独立地为二价烃基; 每个R 2独立地是不含末端脂族不饱和键的一价有机基团,每个X独立地是一价可水解基团; 每个J独立地是一价环氧官能的有机基团; 下标a的值为1以上; 下标b的值为0以上; 下标c的值为0以上; 下标d的值为0以上; 下标e的值为1以上; 下标f的值为0以上; 下标g的值为0以上; 下标s为1,2或3; 下标t为1,2或3。
    • 4. 发明申请
    • Dual Curing Polymers and Methods for Their Preparation and Use
    • 双固化聚合物及其制备和使用方法
    • US20100069523A1
    • 2010-03-18
    • US12517220
    • 2007-12-10
    • Khristopher Edward AlvarezNick Evan ShephardJames Tonge
    • Khristopher Edward AlvarezNick Evan ShephardJames Tonge
    • C08J3/28C08G77/04C08G77/12
    • C08G77/14C08G77/50C08J3/243C08J2383/06C08J2383/14C08L83/06C08L83/14C09D183/14C08L2666/28
    • A polymer cures by both radiation and moisture curing mechanisms. The polymer is prepared by hydrosilylation. The polymer is useful in adhesive compositions. The polymer includes units of formulae (I), (R22Si02/2)b, (R2Si03/2)c, (Si04/2)d, (R1)f, and (R23SiO1/2)g, where each R1 is independently an oxygen atom or a divalent hydrocarbon group; each R1 is independently divalent hydrocarbon group; each R2 is independently a monovalent organic group that is free of terminal aliphatic unsaturation each X is independently a monovalent hydrolyzable group; each J is independently a monovalent epoxy functional organic group; subscript a has a value of 1 or more; subscript b has a value of 0 or more; subscript c has a value of 0 or more; subscript d has a value of 0 or more; subscript e has a value of 1 or more; subscript f has a value of 0 or more; subscript g has a value of 0 or more; subscript s is 1, 2, or 3; and subscript t is 1, 2, or 3.
    • 聚合物通过辐射和湿气固化机制固化。 聚合物通过氢化硅烷化制备。 该聚合物可用于粘合剂组合物。 聚合物包括式(I),(R 22 SiO 2/2)b,(R 2 SiO 3/2)c,(SiO 4/2)d,(R 1)f和(R 23 SiO 1/2)g的单元,其中每个R 1独立地为 氧原子或二价烃基; 每个R 1独立地为二价烃基; 每个R 2独立地是不含末端脂族不饱和键的一价有机基团,每个X独立地是一价可水解基团; 每个J独立地是一价环氧官能的有机基团; 下标a的值为1以上; 下标b的值为0以上; 下标c的值为0以上; 下标d的值为0以上; 下标e的值为1以上; 下标f的值为0以上; 下标g的值为0以上; 下标s为1,2或3; 下标t为1,2或3。
    • 5. 发明授权
    • Fire resistant sealant composition
    • 耐火密封剂组合物
    • US06271299B1
    • 2001-08-07
    • US09244226
    • 1999-02-02
    • Khristopher Edward AlvarezKiersten Lynn Shephard
    • Khristopher Edward AlvarezKiersten Lynn Shephard
    • C08J334
    • C08K3/34C08G77/045C08G77/12C08G77/16C08G77/18C08G77/20C08G77/24C08G77/70C08G77/80C08L83/04C09D183/04C08L2666/44C08L2666/54C08L83/00
    • Curable liquid silicone rubber compositions that are curable to form silicone elastomers which are useable as fire resistant sealants. These compositions have low heat release and form hard chars on burning, and comprise: (A) a liquid polyorganosiloxane polymer described by the formula  where each R1 is independently selected from the group consisting of alkyl, alkenyl, aryl, and halogenated alkyl groups having from 1 to 18 carbon atoms, each R2 is independently selected from the group consisting of hydroxyl, alkoxy, alkenyl, and alkynyl groups, and x is an integer having a value of from about 10 to 1500, (B) a cross-linking organosilicon compound having at least 3 silicon-bonded reactive groups, (C) a catalyst capable of promoting the reaction between the silicon-bonded R2 groups of Component A and the silicon-bonded reactive group of Component B, (D) wollastonite, and (E) an optional reinforcing filler.
    • 可固化以形成可用作耐火密封剂的硅氧烷弹性体的可固化液体硅橡胶组合物。 这些组合物具有低的热释放并在燃烧时形成硬焦炭,并且包括:(A)由下式描述的液体聚有机硅氧烷聚合物,其中每个R 1独立地选自烷基,烯基,芳基和卤代烷基, 1至18个碳原子,每个R 2独立地选自羟基,烷氧基,烯基和炔基,x是值为约10至1500的整数,(B)交联有机硅化合物 具有至少3个硅键合的反应性基团,(C)能够促进组分A的硅键合的R 2基团与组分B的硅键合的反应性基团(D)硅灰石之间的反应的催化剂,和(E) 一种可选的增强填料。
    • 6. 发明授权
    • Silicone gel composition and silicone gel produced therefrom
    • 硅胶凝胶组合物和硅胶
    • US06169155A
    • 2001-01-02
    • US09231447
    • 1999-01-14
    • Khristopher Edward AlvarezPaul Anthony BerryMichael Allen StangaMichael Raymond Strong
    • Khristopher Edward AlvarezPaul Anthony BerryMichael Allen StangaMichael Raymond Strong
    • C08G7720
    • C08L83/04C08G77/045C08G77/20C08G77/24C08G77/70C08L83/00C08L2666/44
    • A silicone gel composition, (A) 100 parts by weight of a first polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule and having a viscosity of from 0.2 to 10 Pa·s at 25° C.; (B) at least about 0.5 part by weight of a second polydiorganosiloxane containing an average of at least two silicon-bonded alkenyl groups per molecule, wherein the second polydiorganosiloxane has a viscosity at 25° C. of at least four times the viscosity of the first polydiorganosiloxane at 25° C.; (C) an organohydrogensiloxane having the average formula R7Si(SiOR82H)3 wherein R7 is an alkyl group having 1 to 18 carbon atoms or aryl, R8 is an alkyl group having 1 to 4 carbon atoms, in an amount sufficient to provide from 0.1 to 1.5 silicon-bonded hydrogen atoms per alkenyl group in components (A) and (B) combined; and (D) a hydrosilylation catalyst in an amount sufficient to cure the composition. A silicone gel comprising a reaction product of the silicone gel composition. A kit for preparing a silicone gel composition.
    • 硅氧烷凝胶组合物,(A)100重量份的每分子平均具有至少两个硅键合的烯基的第一聚二有机硅氧烷,并且在25℃下的粘度为0.2-10Pa.s。 (B)至少约0.5重量份的每分子平均具有至少两个与硅键合的烯基的第二聚二有机硅氧烷,其中所述第二聚二有机硅氧烷在25℃下的粘度为所述粘度的至少四倍 第一聚二有机硅氧烷在25℃。 (C)具有平均式为R7Si(SiOR82H)3的有机氢硅氧烷,其中R7是具有1至18个碳原子的烷基或芳基,R8是具有1至4个碳原子的烷基,其量足以提供0.1至 组分(A)和组分(B)中每个烯基的硅键合氢原子为1.5; 和(D)足以固化组合物的量的氢化硅烷化催化剂。 一种硅凝胶,其包含硅凝胶组合物的反应产物。 一种用于制备硅胶组合物的试剂盒。