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1. 发明授权

US08398087B2 Bonded piston seal 有权
标题翻译：接合活塞密封
公开(公告)号：US08398087B2
公开(公告)日：2013-03-19
申请号：US12310383
申请日：2007-08-08
申请人： Tomoaki Nishimura , Yoshiyuki Kanzaki , Kiyofumi Fukasawa , Katsumi Abe
发明人： Tomoaki Nishimura , Yoshiyuki Kanzaki , Kiyofumi Fukasawa , Katsumi Abe
IPC分类号： F16J9/20
CPC分类号： F16J15/3284 , C08K3/22 , C08L11/00 , C08L15/02 , F16D25/12 , F16D48/02 , F16D2048/0212 , F16J15/3252 , Y10T428/28 , Y10T428/31678
摘要： A bonded piston seal, which comprises a metal ring, and a rubbery elastomer seal as vulcanization-bonded thereto expect the sliding site along which a mating seal member slides, where the rubbery elastomer seal is partially bonded to the metal ring through an adhesive layer, wherein the adhesive layers comprises (a) an underlayer adhesive layer comprising a phenol resin and an epoxy resin, and (b) an overlayer adhesive layer comprising a phenol resin, a halogenated polymer, and a metal oxide. Not only the distinguished initial adhesiveness, but also the distinguished water-resistance can be obtained by providing (a) the underlayer adhesive layer of the afore-mentioned components and (b) the overlayer adhesive layer of the afore-mentioned components.
摘要翻译：包括金属环的粘合活塞密封件和硫化粘合的橡胶弹性体密封件期望配合密封件滑动的滑动位置，其中橡胶弹性体密封件通过粘合剂层部分地结合到金属环上，其中所述粘合剂层包括（a）包含酚醛树脂和环氧树脂的底层粘合剂层，和（b）包含酚醛树脂，卤化聚合物和金属氧化物的覆层粘合剂层。通过提供（a）前述组分的下层粘合剂层和（b）前述组分的覆盖层粘合剂层，不仅可以获得突出的初始粘合性，而且可以获得显着的耐水性。

2. 发明申请

US20090311543A1 Acrylic Rubber-Metal Composite 失效
标题翻译：丙烯酸橡胶 - 金属复合材料
公开(公告)号：US20090311543A1
公开(公告)日：2009-12-17
申请号：US12226042
申请日：2007-04-12
申请人： Katsumi Abe , Kiyofumi Fukasawa
发明人： Katsumi Abe , Kiyofumi Fukasawa
IPC分类号： B32B15/08
CPC分类号： B32B15/06 , B32B25/14 , C08F220/00 , C08G59/621 , C08J5/128 , C08J2333/06 , C08J2461/00 , C08J2463/00 , C08L33/00 , C08L61/06 , C08L71/00 , C08L2666/16 , C08L2666/22 , C09J163/00 , Y10T428/28 , Y10T428/2804 , Y10T428/2852 , Y10T428/31678
摘要： An acrylic rubber-metal composite, which comprises a metal, (a) an undercoat adhesive layer comprising phenol resin and epoxy resin, (b) an overcoat adhesive layer comprising phenol resin, halogenated polymer, and a metal oxide, and (c) an acrylic rubber layer, the layers (a), (b) and (c) being successively laid on the surface of the metal, having not only a distinguished initial adhesiveness, but also a good water resistance, where the acrylic rubber is bonded to the metal without surface treatment of the metal such as a chemical treatment, e.g. zinc phosphate treatment, etc., a blast treatment, or a primer treatment.
摘要翻译：一种丙烯酸橡胶 - 金属复合材料，其包含金属，（a）包含酚醛树脂和环氧树脂的底涂层粘合剂层，（b）包含酚醛树脂，卤化聚合物和金属氧化物的外涂层粘合剂层，和（c）丙烯酸橡胶层，层（a），（b）和（c）依次铺设在金属表面上，不仅具有突出的初始粘合性，而且具有良好的耐水性，其中丙烯酸橡胶与没有金属表面处理的金属例如化学处理，例如磷酸锌处理等，喷丸处理或底漆处理。

3. 发明申请

US20060041059A1 Water-based vulcanizable adhesive composition 审中-公开
标题翻译：水性硫化胶粘剂组合物
公开(公告)号：US20060041059A1
公开(公告)日：2006-02-23
申请号：US10541339
申请日：2004-01-22
申请人： Kiyofumi Fukasawa , Katsumi Abe
发明人： Kiyofumi Fukasawa , Katsumi Abe
IPC分类号： C08F16/06
CPC分类号： C09J161/04
摘要： An aqueous vulcanizable adhesive composition, which comprises a phenol resin emulsion prepared from a water-insoluble phenol resin solution in methyl ethyl ketone and an aqueous water-soluble polymeric substance solution, and a curing agent for phenol resin, uses a partially water-miscible methyl ethyl ketone in place of a completely water-miscible organic solvent, where an amount of methyl ethyl ketone is considerably reduced. PVA, preferably aceto-acetyl-modified PVA, is used as the water-soluble polymeric substance, and the aqueous vulcanizable adhesive composition is suitably used for vulcanization bonding of a metal to (hydrogenated) NBR or acrylic rubber.
摘要翻译：一种含水可硫化粘合剂组合物，其包含由甲基乙基酮中的水不溶性酚醛树脂溶液和水溶性聚合物溶液制备的酚醛树脂乳液和酚醛树脂的固化剂，使用部分水混溶性甲基乙基酮代替完全水混溶的有机溶剂，其中甲基乙基酮的量显着降低。 PVA，优选乙酰 - 乙酰基改性的PVA用作水溶性聚合物，并且该可水性硫化粘合剂组合物适用于金属与（氢化）NBR或丙烯酸橡胶的硫化粘合。

4. 发明申请

US20110111219A1 Vulcanizable Adhesive Composition 审中-公开
标题翻译：可硫化胶粘剂组合物
公开(公告)号：US20110111219A1
公开(公告)日：2011-05-12
申请号：US12226045
申请日：2007-04-12
申请人： Katsumi Abe , Shinichiro Sano , Kiyofumi Fukasawa
发明人： Katsumi Abe , Shinichiro Sano , Kiyofumi Fukasawa
IPC分类号： C08K3/22 , C09J111/00 , C09J115/02 , C09J147/00 , C09J161/10 , B32B7/12
CPC分类号： C08J5/125 , B32B15/06 , C08J2321/00 , C08J2333/06 , C08K3/22 , C08L15/02 , C08L27/00 , C08L2666/04 , C09J5/02 , C09J161/06 , C09J2205/306 , C09J2461/00 , Y10T428/2804
摘要： A vulcanizable adhesive composition, which comprises 45-75% by weight of phenol resin, preferably a mixture of novolak-type and resol-type phenol resins, 5-25% by weight of halogenated polymer, and 10-30% by weight of a metal oxide, can improve an interlayer adhesiveness between the acrylic rubber and metal without surface treatment of metal, such as a chemical treatment, e.g. zinc phosphate treatment, etc., blast treatment, or primer treatment, and thus can be effectively used in the production of a metal/adhesive layer/acrylic rubber composite.
摘要翻译：一种可硫化的粘合剂组合物，其包含45-75重量％的酚醛树脂，优选酚醛清漆型和甲阶酚醛型酚醛树脂的混合物，5-25重量％的卤化聚合物和10-30重量％的金属氧化物，可以改善丙烯酸橡胶和金属之间的层间粘合性而不进行金属的表面处理，例如化学处理，例如，磷酸锌处理等，喷砂处理或底漆处理，因此可以有效地用于生产金属/粘合剂层/丙烯酸橡胶复合材料。

5. 发明申请

US20100261019A1 Primer Composition and Metal-Rubber Laminate Using the Same 审中-公开
标题翻译：底漆组合物和使用其的金属 - 橡胶层压板
公开(公告)号：US20100261019A1
公开(公告)日：2010-10-14
申请号：US12083525
申请日：2006-10-02
申请人： Shinichiro Sano , Katsumi Abe , Kiyofumi Fukasawa
发明人： Shinichiro Sano , Katsumi Abe , Kiyofumi Fukasawa
IPC分类号： B32B15/08 , C08L27/12 , B32B27/32 , C08L29/08
CPC分类号： F16J15/0818 , B32B15/06 , B32B2255/06 , B32B2255/26 , B32B2255/28 , B32B2581/00 , C08K5/0091 , C08K5/057 , C08K5/098 , C09J125/18 , C09K3/10 , F16J15/0806 , F16J2015/0856 , H01M8/028 , Y02P70/56 , Y10T428/3154 , Y10T428/31692
摘要： A primer composition for use as a primer in the production of metal/primer/adhesive/rubber laminates, which comprises 100 parts by weight of polyparavinylphenol and 50-300 parts by weight of an organometallic compound can give distinguished water resistance and acid resistance, when used for vulcanization bonding of a plated steel sheet and unvulcanized rubber or for simple bonding of a plated steel sheet and vulcanized rubber, and metal-rubber laminates produced by using the primer composition can be effectively used as rubber-metal integrated type gaskets, particularly fuel cell gaskets, HDD cover gaskets (metallic separator-integrated type gaskets), etc.
摘要翻译：在金属/底漆/粘合剂/橡胶层压材料的制造中用作底漆的底漆组合物，其包含100重量份的聚亚丙酰基苯酚和50-300重量份的有机金属化合物，可以提供显着的耐水性和耐酸性，用于镀覆钢板和未硫化橡胶的硫化粘合或用于电镀钢板和硫化橡胶的简单粘合，以及通过使用底漆组合物制造的金属 - 橡胶层压材料可以有效地用作橡胶 - 金属一体型垫圈，特别是燃料电池垫片，HDD盖垫片（金属分离器一体型垫片）等

6. 发明授权

US07247388B2 Vulcanizable adhesive composition 有权
标题翻译：可硫化粘合剂组合物
公开(公告)号：US07247388B2
公开(公告)日：2007-07-24
申请号：US10506490
申请日：2003-08-27
申请人： Kiyofumi Fukasawa , Tomohiro Kaise
发明人： Kiyofumi Fukasawa , Tomohiro Kaise
IPC分类号： C09J161/10 , C09J109/02
CPC分类号： C09J109/02 , B32B15/06 , C08L9/02 , C08L23/286 , C08L27/04 , C08L61/06 , C08L65/04 , C08L2666/02 , C08L2666/06 , C08L2666/12 , C08L2666/16 , C08L2666/22 , C09J123/286 , C09J161/06 , C09J165/04 , Y10T428/31688 , Y10T428/31696
摘要： A vulcanizable adhesive composition, which comprises 100 parts by weight of phenolxylylene resin or phenolbiphenyl resin, 10 to 1,000 parts by weight of resol-type phenol resin, 0 to 1,000 parts by weight of novolak-type phenol resin, 10 to 1,000 parts by weight of unvulcanized nitrile rubber and 10 to 500 parts by weight of chlorinated polyethylene, is effectively applied to (hydrogenated) nitrile rubber with a nitrile content of 18 to 48%, and has a suppression effect on a decrease in the adhesiveness even if exposed to dip in various cryogenic liquids such as flon gas, polyalkylene glycol, water, etc. for a long time.
摘要翻译：一种可硫化粘合剂组合物，其包含100重量份的苯二酚树脂或苯酚联苯树脂，10至1,000重量份的甲阶酚醛树脂型酚醛树脂，0至1,000重量份的酚醛清漆型酚醛树脂，10至1,000重量份的未硫化丁腈橡胶和10〜500重量份氯化聚乙烯，有效地应用于腈含量为18〜48％的（氢化）丁腈橡胶，并且即使暴露于浸渍时也具有抑制粘合性降低的作用在各种低温液体如氟利昂气体，聚亚烷基二醇，水等中长时间使用。

7. 发明授权

US09925741B2 Acrylic rubber-metal composite 有权
公开(公告)号：US09925741B2
公开(公告)日：2018-03-27
申请号：US12663310
申请日：2008-05-13
申请人： Katsumi Abe , Kiyofumi Fukasawa
发明人： Katsumi Abe , Kiyofumi Fukasawa
IPC分类号： B32B15/08 , B32B3/10 , B32B15/06 , C23C22/08 , B32B5/14 , B32B7/12 , B32B15/18
CPC分类号： B32B15/06 , B32B5/147 , B32B7/12 , B32B15/18 , B32B2255/06 , B32B2255/20 , B32B2255/26 , B32B2307/306 , B32B2307/538 , B32B2307/554 , B32B2307/714 , C23C22/08 , Y10T428/24355 , Y10T428/31696
摘要： An acrylic rubber-metal composite, which comprises an iron phosphate treated iron-based metal, and an adhesive layer comprising a phenol resin and a metal oxide, and preferably further a halogenated polymer, and an acrylic rubber layer, successively provided on the iron-based metal surface, has not only distinguished initial adhesiveness and water resistance, when the acrylic rubber is bonded to the metal owing to application of the iron phosphate treatment to the metal surface, but also can reduce the abrasion of the mating materials when brought into contact with rubber-unbaked parts of the sheet, because the surface roughness Ra[according to JIS 0601(1994)] of the surface treated steel sheet is 0.6 or less.

8. 发明授权

US08455106B2 Acrylic rubber-metal composite 失效
标题翻译：丙烯酸橡胶 - 金属复合材料
公开(公告)号：US08455106B2
公开(公告)日：2013-06-04
申请号：US12226042
申请日：2007-04-12
申请人： Katsumi Abe , Kiyofumi Fukasawa
发明人： Katsumi Abe , Kiyofumi Fukasawa
IPC分类号： B32B15/08
CPC分类号： B32B15/06 , B32B25/14 , C08F220/00 , C08G59/621 , C08J5/128 , C08J2333/06 , C08J2461/00 , C08J2463/00 , C08L33/00 , C08L61/06 , C08L71/00 , C08L2666/16 , C08L2666/22 , C09J163/00 , Y10T428/28 , Y10T428/2804 , Y10T428/2852 , Y10T428/31678
摘要： An acrylic rubber-metal composite, which comprises a metal, (a) an undercoat adhesive layer comprising phenol resin and epoxy resin, (b) an overcoat adhesive layer comprising phenol resin, halogenated polymer, and a metal oxide, and (c) an acrylic rubber layer, the layers (a), (b) and (c) being successively laid on the surface of the metal, having not only a distinguished initial adhesiveness, but also a good water resistance, where the acrylic rubber is bonded to the metal without surface treatment of the metal such as a chemical treatment, e.g. zinc phosphate treatment, etc., a blast treatment, or a primer treatment.
摘要翻译：一种丙烯酸橡胶 - 金属复合材料，其包含金属，（a）包含酚醛树脂和环氧树脂的底涂层粘合剂层，（b）包含酚醛树脂，卤化聚合物和金属氧化物的外涂层粘合剂层，和（c）丙烯酸橡胶层，层（a），（b）和（c）依次铺设在金属表面上，不仅具有突出的初始粘合性，而且具有良好的耐水性，其中丙烯酸橡胶与没有金属表面处理的金属例如化学处理，例如磷酸锌处理等，喷丸处理或底漆处理。

9. 发明授权

US07311978B2 Primer for vulcanization bonding 有权
标题翻译：用于硫化粘合的底漆
公开(公告)号：US07311978B2
公开(公告)日：2007-12-25
申请号：US10545204
申请日：2003-08-27
申请人： Kiyofumi Fukasawa , Tomohiro Kaise
发明人： Kiyofumi Fukasawa , Tomohiro Kaise
IPC分类号： B32B9/04
CPC分类号： C09D183/08 , B60C1/00 , B60C2009/0021 , C09D5/002 , C09D183/14 , C09J5/02 , C09J2205/306 , C09J2400/163 , C09J2421/006 , C09J2483/003 , Y10T428/31663
摘要： A primer for vulcanization bonding, which comprises a copolymerization copolymer of amino group-containing alkoxysilane and vinyl group-containing alkoxysilane, and an organometallic compound, can give a metal-rubber composite having a water-resistant adhesiveness equivalent or superior to that of coating type chromate processing agent, without application of harmful coating type chromate processing to a metal, and thus can be effectively used in surface treatment of metals such as stainless steel, etc. for the production of seal products of rubber-bonded metal (e.g. oil seals, packings and gaskets), valves, vibration-controlled or vibration damped products (e.g. vibration-controlled steel sheets and vibration-damped rubber), industrial rubber products, etc.
摘要翻译：包含含氨基的烷氧基硅烷和含乙烯基的烷氧基硅烷的共聚合物和有机金属化合物的硫化粘合用底漆可以得到耐水粘合性等于或优于涂布型的金属 - 橡胶复合材料铬酸盐处理剂，不对金属施加有害涂层型铬酸盐处理，因此可有效地用于金属如不锈钢等的表面处理，用于生产橡胶粘合金属（例如油封，填料和垫片），阀门，振动控制或减振产品（例如振动控制钢板和减振橡胶），工业橡胶制品等。

10. 发明授权

US08641047B2 Fluororubber-metal laminate gasket material 有权
标题翻译：氟橡胶金属层压垫片材料
公开(公告)号：US08641047B2
公开(公告)日：2014-02-04
申请号：US12933731
申请日：2008-12-10
申请人： Yasuaki Kitajima , Kiyofumi Fukasawa
发明人： Yasuaki Kitajima , Kiyofumi Fukasawa
IPC分类号： F02F11/00 , F16J15/12
CPC分类号： F16J15/12
摘要： A fluororubber-metal laminate gasket material, which comprises a metallic steel sheet, a zirconium element-, phosphorus element-, and aluminum element-containing surface-treating agent layer, a silica-containing thermosetting phenol resin-based vulcanizing adhesive layer, and a fluororubber layer, as successively laid upon one another on the metallic steel sheet, where the silica-containing thermosetting phenol-based vulcanizing adhesive is a thermosetting phenol resin-based vulcanizing adhesive comprising silica and cresol novolak-type epoxy resin or phenol novolak-type epoxy resin, and further containing 11-80 parts by weight of an aliphatic amine-based compound or a mixture thereof with an imidazole-based compound as a curing accelerator on the basis of 100 parts by weight of the thermosetting phenol resin, where the aliphatic amine-based compound and the imidazol-based compound are in a proportion of the former to the latter of 100-10 wt. % to 0-90 wt. %.
摘要翻译：一种氟橡胶金属层压垫片材料，其包括金属钢板，含锆元素，磷元素和含铝元素的表面处理剂层，含二氧化硅的热固性酚醛树脂基硫化粘合剂层和氟橡胶层，其在金属钢板上相继铺设，其中含二氧化硅的热固性酚基硫化粘合剂是包含二氧化硅和甲酚酚醛清漆型环氧树脂或苯酚酚醛清漆型环氧树脂的热固性酚醛树脂基硫化粘合剂树脂，并且基于100重量份的热固性酚醛树脂，还包含11-80重量份的基于脂族胺的化合物或其与咪唑类化合物作为固化促进剂的混合物，其中脂族胺基的化合物和咪唑基化合物的比例为前者与后者的比例为100-10重量％。％至0-90wt。％。

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