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    • 2. 发明授权
    • Reversible electrochemical mirror (REM) with improved electrolytic
solution
    • 具有改进电解液的可逆电化学镜(REM)
    • US6111685A
    • 2000-08-29
    • US356730
    • 1999-07-19
    • D. Morgan TenchLeslie F. Warren, Jr.Michael A. Cunningham
    • D. Morgan TenchLeslie F. Warren, Jr.Michael A. Cunningham
    • G02B5/08G02F1/15G02F1/155G02F1/153
    • G02F1/1506G02F1/155
    • A reversible electrochemical mirror (REM) includes a first electrode and a second electrode, one of which is substantially transparent to at least a portion of the spectrum of electromagnetic radiation. An electrolytic solution, disposed between the first and second electrodes, contains ions of a metal which can electrodeposit on the electrodes. The electrolytic solution also contains halide and/or pseudohalide anions having a total molar concentration ratio of at least 6:1 compared to that of the electrodepositable metal. A negative electrical potential applied to the first electrode causes deposited metal to be dissolved from the second electrode into the electrolytic solution and to be electrodeposited from the solution onto the first electrode to form a mirror deposit, thereby affecting the reflectivity of the REM device for electromagnetic radiation. A positive electrical potential applied to the first electrode causes deposited metal to be dissolved from the first electrode into the solution and electrodeposited from the solution onto the second electrode, thereby decreasing the reflectivity of the REM mirror. It is usually necessary to apply a surface modification layer to the first electrode to ensure uniform nucleation so that a mirror electrodeposit having high reflectivity is obtained. The high molar concentration ratio of halide and/or pseudohalide anions to electrodepositable metal ions in the electrolyte provides the inherent electrolyte stability, high deposit quality, good deposit erasure and long cycle life needed for practical applications.
    • 可逆电化学反射镜(REM)包括第一电极和第二电极,其中之一对于电磁辐射谱的至少一部分基本上是透明的。 设置在第一和第二电极之间的电解液含有能够电沉积在电极上的金属离子。 电解液还含有与可电沉积金属相比总摩尔浓度比至少为6:1的卤化物和/或拟卤化物阴离子。 施加到第一电极的负电位使沉积的金属从第二电极溶解到电解液中,并从溶液中电沉积到第一电极上以形成镜沉积物,从而影响REM装置的电磁反射率 辐射。 施加到第一电极的正电位使沉积的金属从第一电极溶解到溶液中并从溶液中电沉积到第二电极上,从而降低REM反射镜的反射率。 通常需要对第一电极施加表面改性层以确保均匀的成核,从而获得具有高反射率的镜电沉积。 卤化物和/或拟卤化物阴离子与电解金属离子在电解质中的高摩尔浓度比提供固有的电解质稳定性,高沉积质量,良好的沉积物擦除和实际应用所需的长循环寿命。
    • 3. 发明授权
    • Photoelectrochemical fabrication of electronic circuits
    • 电子电路的光电化学制造
    • US5595637A
    • 1997-01-21
    • US559952
    • 1995-11-17
    • D. Morgan TenchLeslie F. Warren, Jr.Young J. Chung
    • D. Morgan TenchLeslie F. Warren, Jr.Young J. Chung
    • H05K3/18C25D5/02C25D7/12H05K3/20C25D5/00B05D5/12
    • C25D7/123C25D5/024C25D7/0635H05K3/205
    • A photoelectrochemical method and apparatus are disclosed for fabricating electronic circuits. An electroplating solution is applied to the surface of a reverse biased p-type semiconductor material, such as NiO. The solution-covered NiO surface is illuminated with a light beam directed by computer aided design data to photoelectrochemically deposit a seed layer of metal in an electronic circuit pattern. The seed layer may be thickened by further deposition in a plating bath to form metallic circuit traces on the NiO. If desired, the metallic circuitry may be transferred from the NiO to an alternate substrate having a low dielectric constant. The porosity of the NiO surface can be adjusted to optimize the metallic circuit adhesion for image retention or ease of transfer. The metallic traces may also be treated to reduce adhesion of subsequently deposited metal that can be transferred readily. If sufficient residual metal remains on the NiO surface after circuit transfer, the trace can be rethickened to transfer multiple circuits of the same pattern without reimaging. An old metallic image can be electro-dissolved by changing the bias of the NiO with respect to the plating bath, thereby erasing the old image so that a new circuit pattern can be formed by photoelectrochemical deposition. The process can be performed on a rotating cylinder so that electronic circuits can be produced in a continuous process of photoelectrochemical deposition, seed metal thickening, adhesion reduction, circuit transfer, and image erasure that provides advantages in cost, circuit resolution, and environmental protection.
    • 公开了用于制造电子电路的光电化学方法和装置。 将电镀溶液施加到反向偏压p型半导体材料(例如NiO)的表面上。 溶液覆盖的NiO表面用计算机辅助设计数据指示的光束照射,以电子电化学方式沉积电子电路图案中的金属种子层。 种子层可以通过在镀浴中进一步沉积而增厚,以在NiO上形成金属电路迹线。 如果需要,金属电路可以从NiO转移到具有低介电常数的替代衬底。 可以调节NiO表面的孔隙率,以优化金属电路粘附,以保持图像或易于传输。 也可以处理金属痕迹以减少可以容易地转移的随后沉积的金属的粘附。 如果在电路传输后,NiO表面上剩余的残余金属残留,则可以重新设计迹线以传输相同图案的多个电路,而无需重新成像。 通过改变NiO相对于镀浴的偏压,可以使旧的金属图像电解,从而擦除旧图像,从而可以通过光电化学沉积形成新的电路图案。 该方法可以在旋转圆柱体上进行,使得可以在光电化学沉积,种子金属增厚,附着力降低,电路转移和图像擦除的连续过程中制造电子电路,从而提供成本,电路分辨率和环境保护方面的优点。
    • 5. 发明授权
    • Reversible electrodeposition device with ionic liquid electrolyte
    • 具有离子液体电解质的可逆电沉积装置
    • US06552843B1
    • 2003-04-22
    • US10066210
    • 2002-01-31
    • D. Morgan TenchLeslie F. Warren, Jr.
    • D. Morgan TenchLeslie F. Warren, Jr.
    • G02F100
    • G02F1/1506
    • The present invention is a reversible electrodeposition optical modulation device employing an ionic liquid electrolyte, which is comprised of a mixture of an ionic organic compound and the salt of an electrodepositable metal. The solventless ionic liquid can contain very high concentrations of electrodepositable metal ions and provides the high current carrying capability needed for fast device switching. Switching uniformity is also significantly improved since the electrolyte resistance is at least an order of magnitude higher than that of typical solvent-based electrolytes. Fast switching and good cycle life for high quality mirror electrodeposits in reversible electrochemical mirror (REM) devices was demonstrated. Best results were obtained for novel silver halide electrolytes employing pyrrolidinium and N-methylpyrrolidinium cations.
    • 本发明是一种使用离子液体电解质的可逆电沉积光调制装置,其由离子有机化合物和可电沉积金属的盐的混合物组成。 无溶剂离子液体可以含有非常高浓度的电沉积金属离子,并提供快速器件切换所需的高电流承载能力。 由于电解质电阻比典型的基于溶剂的电解质高至少一个数量级,开关均匀性也显着提高。 证明了可逆电化学镜(REM)器件中的高质量镜电沉积的快速切换和良好的循环寿命。 使用吡咯烷鎓和N-甲基吡咯烷鎓阳离子的新型卤化银电解质获得了最佳结果。
    • 6. 发明授权
    • Organic polymer O-plate compensator for improved gray scale performance in twisted nematic liquid crystal displays
    • 有机聚合物O板补偿器,用于改善扭曲向列型液晶显示器的灰度级性能
    • US06320634B1
    • 2001-11-20
    • US09388131
    • 1999-09-01
    • Bruce K. WinkerHong-Son RyangLeslie F. Warren, Jr.Charles RosenblattZili LiYoung J. Chung
    • Bruce K. WinkerHong-Son RyangLeslie F. Warren, Jr.Charles RosenblattZili LiYoung J. Chung
    • G02F11335
    • G02F1/133636G02B5/3016G02F1/133632G02F1/133634G02F2413/10G02F2413/105
    • An O-plate compensator comprising an organic liquid crystal polymer, and methods for fabricating the same, are disclosed. The compensator is a uniaxial birefringent thin film with its extraordinary axis oriented obliquely with respect to the surface of the film. (It is noted that the birefringent thin film could be weakly biaxial.) The oblique orientation of the liquid crystal director, which is parallel to the films extraordinary axis, is achieved by casting an organic thin film onto a surface specially prepared for a orienting liquid crystals, such as obliquely deposited SiO, mechanically rubbed alignment agents. The film can either be cast from a solution of the liquid crystal polymer or from a reactive liquid crystal monomer having a nematic phase. Any solvent that may be used during the fabrication process is evaporated off and the organic thin film is held at a temperature in its nematic phase. If a reactive monomer is used, the film is then photopolymerized. Alternative embodiments of an organic O-plate include the use of smectic-A and smectic-C materials. Fabrication techniques employing these materials are described.
    • 公开了一种包含有机液晶聚合物的O板补偿器及其制造方法。 补偿器是单轴双折射薄膜,其非常轴相对于膜的表面倾斜定向。 (注意,双折射薄膜可以是弱双轴的)。通过将有机薄膜浇注到特别为取向液体制备的表面上来实现与膜异常轴平行的液晶指向矢的倾斜取向 晶体,如倾斜沉积的SiO,机械摩擦对准剂。 该膜可以由液晶聚合物的溶液或具有向列相的反应性液晶单体浇铸。 在制造过程中可以使用的任何溶剂被蒸发掉,有机薄膜保持在其向列相的温度。 如果使用反应性单体,则将该膜光聚合。 有机O板的替代实施方案包括使用近晶A和近晶C材料。 描述了采用这些材料的制造技术。
    • 7. 发明授权
    • Method of forming a metallic oxide coating with a desired
crystallographic orientation
    • 形成具有所需晶体取向的金属氧化物涂层的方法
    • US5711804A
    • 1998-01-27
    • US642381
    • 1996-05-03
    • D. Morgan TenchLeslie F. Warren, Jr.Young J. Chung
    • D. Morgan TenchLeslie F. Warren, Jr.Young J. Chung
    • C30B5/00C30B1/10
    • C30B5/00C30B29/16
    • Oxide coatings are formed with a desired crystallographic texture over a large surface area. A metallic substrate is electrodeposited or vacuum deposited with a preferred crystallographic orientation, and a sol-gel/thermal process is used to form a "pseudo-epitaxial" oxide coating having crystallites that are influenced by the crystallographic orientation of the substrate. In one embodiment, p-type nickel oxide coatings with desirable electronic properties are produced by sol-gel/thermal processing on nickel substrates electrodeposited from a sulfamate nickel bath at a relatively high current density and low temperature. The electrodeposited nickel substrate has a strong Ni{100} preferred orientation. Epitaxial effects during sol-gel/thermal formation of NiO on the electrodeposited substrate enhance the extent to which the NiO{100} and NiO{111} crystal facets are aligned parallel to the coating surface, and minimize the NiO{110} orientation. This texture modification significantly improves the photoresponse of the nickel oxide coating. The method is anticipated to be useful in other metal oxide/metal substrate systems for the production of catalysts, cathodes for lithium ion and nickel-cadmium batteries, photoelectrochemical printed circuits, high-temperature electronic devices, flat panel displays, photoelectrochemical solar cells, and sensors. An advantage of the invention is that electrodeposition, vacuum deposition, and sol-gel/thermal processes are suitable for coating large surface areas.
    • 氧化物涂层在大的表面积上形成所需的晶体学结构。 以优选的结晶方向电沉积或真空沉积金属基底,并且使用溶胶 - 凝胶/热过程形成具有受基底结晶取向影响的微晶的“假外延”氧化物涂层。 在一个实施方案中,具有所需电子性能的p型氧化镍涂层通过溶胶 - 凝胶/热处理在以相当高的电流密度和低温度从氨基磺酸镍浴电沉积的镍基底上制备。 电沉积的镍基底具有很强的Ni {100}优选取向。 NiO在电沉积衬底上的溶胶凝胶/热形成过程中的外延效应增强了NiO {100}和NiO {111}晶面平行于涂层表面取向的程度,并使NiO {110}取向最小化。 这种纹理修饰显着改善了氧化镍涂层的光响应。 预期该方法可用于生产催化剂,锂离子和镍镉电池的阴极,光电化学印刷电路,高温电子器件,平板显示器,光电化学太阳能电池的其它金属氧化物/金属基底系统 传感器。 本发明的优点是电沉积,真空沉积和溶胶 - 凝胶/热处理适用于涂覆大的表面积。
    • 8. 发明授权
    • Semi-organic crystals for nonlinear optical devices
    • 用于非线性光学器件的半有机晶体
    • US5581010A
    • 1996-12-03
    • US278741
    • 1994-07-22
    • Patricia H. CunninghamLeslie F. Warren, Jr.Henry O. Marcy, 5thMark J. Rosker
    • Patricia H. CunninghamLeslie F. Warren, Jr.Henry O. Marcy, 5thMark J. Rosker
    • G02F1/35C07F5/04G02F1/355G02F1/361G02F1/03
    • G02F1/3619C07F5/04
    • A nonlinear optical material includes a noncentrosymmetric crystal of an anionic boron complex salt containing a cation and at least one organic ligand coordinated to a boron atom. The nonlinear optical crystal may consist of a compound having the formula A[BC.sub.2 ] where A is a monocation, B is boron, and C is the organic ligand, or a compound having the formula A[BC.sub.2 ].sub.2 where A is a dication, B is boron, and C is the organic ligand. The organic ligands may also be organic molecules having .alpha.-dihydroxy functionalities. Furthermore, the organic ligands may be selected from the group consisting of .alpha.-hydroxy carboxylic acids and 1,2-diols or from the group consisting of d-malic acid, d-lactic acid, d-tartaric acid, dimethyl-d-tartrate, diethyl-d-tartrate, l-malic acid, l-lactic acid, l-tartaric acid, dimethyl-l-tartrate, diethyl-l-tartrate, and ethylene glycol. The anionic boron complex may be selected from the group consisting of boro-di(l-malate), boro-di(l-tartrate), boro-di(l-lactate), boro-di(diethyl-l-tartrate), boro-di(methyl-1-tartrate), boro-di(d-tartrate), boro-di(d-lactate), boro-di(diethyl-d-tartrate), boro-di(dimethyl-d-tartrate) and boro-di(ethylene glycolate). The cation may be selected from the group consisting of alkali metals, alkaline earth metals, ammonium ions, and Group 2B dications. The cation may be further selected from the group consisting of lithium, sodium, potassium, the ammonium NH.sub.4.sup.+ ion, the guanidinium C(NH.sub.2).sub.3.sup.+ ion, calcium, and zinc.
    • 非线性光学材料包括含有阳离子和至少一个与硼原子配位的有机配体的阴离子硼配合盐的非中心对称晶体。 非线性光学晶体可以由具有式A [BC2]的化合物组成,其中A是单体化,B是硼,C是有机配体,或具有式A [BC2] 2的化合物,其中A是二价键, B是硼,C是有机配体。 有机配体也可以是具有α-二羟基官能团的有机分子。 此外,有机配体可以选自α-羟基羧酸和1,2-二醇,或者由D-苹果酸,d-乳酸,酒石酸,d-酒石酸二甲酯 ,酒石酸二乙酯,1-苹果酸,1-乳酸,1-酒石酸,l-酒石酸二甲酯,酒石酸二乙酯和乙二醇。 阴离子性硼络合物可以选自硼酸二(1-苹果酸酯),硼 - 二(1-酒石酸盐),硼 - 二(1-乳酸),硼 - 二(二乙基-1-酒石酸盐), 硼酸二(d-酒石酸盐),硼二(d-酒石酸盐),硼二(d-乳酸盐),硼 - 二(二乙基-d酒石酸盐) 和硼二(乙醇酸乙二醇酯)。 阳离子可以选自碱金属,碱土金属,铵离子和2B族二次元。 阳离子可以进一步选自锂,钠,钾,NH 4 +离子,C(NH 2)3离子,钙和锌。
    • 9. 发明授权
    • Capacitor having an electrolyte containing a mixture of dinitriles
    • 具有含有二腈混合物的电解质的电容器
    • US5418682A
    • 1995-05-23
    • US260581
    • 1994-06-16
    • Leslie F. Warren, Jr.Henry O. Marcy, 5.sup.th
    • Leslie F. Warren, Jr.Henry O. Marcy, 5.sup.th
    • H01G11/54H01G9/02H01G9/035H01G11/02H01G11/30H01G11/40H01G11/44H01G11/46H01G11/60H01G11/62H01G9/038
    • H01G9/038H01G11/64Y02E60/13
    • An electrical capacitor includes an organic electrolyte to provide high power, high energy density, and broad operating temperature range. The capacitor includes electrodes and an electrolyte system comprising a salt combined with a solvent containing a nitrile. The electrolyte system is selected to be relatively nonreactive and difficult to oxidize or reduce so as to produce a high electric potential range. As examples, the electrolyte may include a solvent selected from the group consisting of acetonitrile, succinonitrile, glutaronitrile, propylene carbonate, and ethylene carbonate; a salt cation selected from the group consisting of tetraalkylamonium (R.sub.4 N.sup.+) and alkali metals; and an anion selected from the group consisting of trifluoromethylsulfonate (CF.sub.3 SO.sub.3.sup.-), bistrifluoromethylsulfurylimide (N(CF.sub.3 SO.sub.2).sub.2.sup.-), tristrifluoromethylsulfurylcarbanion (C(CF.sub.3 SO.sub.2).sub.3.sup.-), tetrafluoroborate (BF.sub.4.sup.-), hexafluorophosphate (PF.sub.6.sup.-), hexafluoroarsenate (AsF.sub.6.sup.-), and perchlorate (ClO.sub.4.sup.-).
    • 电容器包括提供高功率,高能量密度和宽工作温度范围的有机电解质。 电容器包括电极和包含与含有腈的溶剂组合的盐的电解质体系。 选择电解质体系相对非反应性,难以氧化或还原,从而产生高电位范围。 作为实例,电解质可以包括选自乙腈,丁腈腈,戊二腈,碳酸亚丙酯和碳酸亚乙酯的溶剂; 选自四烷基锍(R 4 N +)和碱金属的盐阳离子; 选自三氟甲基磺酸盐(CF 3 SO 3 - ),双三氟甲基亚磺酰亚胺(N(CF 3 SO 2)2 - ),三(三氟甲基硫基碳)阴离子(C(CF 3 SO 2)3 - ),四氟硼酸盐(BF 4 - ),六氟磷酸盐(PF 6 - ),六氟砷酸盐 - )和高氯酸盐(ClO4-)。