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1. 发明申请

US20080149531A1 PROCESS FOR SLURRY PHASE HYDROCONVERSION OF HEAVY HYDROCARBON FEEDS AND/OR COAL USING A SUPPORTED CATALYST 有权
标题翻译：使用支持的催化剂的重油相进料和/或煤的浆液相变过程
公开(公告)号：US20080149531A1
公开(公告)日：2008-06-26
申请号：US11961132
申请日：2007-12-20
申请人： Magalie Roy-Auberger , Denis Guillaume
发明人： Magalie Roy-Auberger , Denis Guillaume
IPC分类号： C10G47/02
CPC分类号： B01J37/0063 , B01J21/04 , B01J23/24 , B01J23/40 , B01J23/74 , B01J23/85 , B01J23/883 , B01J27/19 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/108 , B01J37/0018 , B01J37/10 , C10G45/08 , C10G49/04 , C10G2300/301
摘要： The invention concerns a process for converting heavy feeds carried out in a slurry reactor in the presence of hydrogen and in the presence of a catalyst comprising at least one catalytic metal or a compound of a catalytic metal from group VIB and/or VIII supported on alumina, the pore structure of which is composed of a plurality of juxtaposed agglomerates each formed by a plurality of acicular platelets, the platelets of each agglomerate being generally radially oriented with respect to the others and with respect to the centre of the agglomerate, said catalyst having an irregular and non-spherical shape and being mainly in the form of fragments, obtained using a process including the following steps: a) granulation starting from an active alumina powder having a low crystallinity and/or amorphous structure, to obtain agglomerates in the form of beads; b) maturing in a moist atmosphere between 60° C. and 100° C. then drying said beads; c) sieving to recover a fraction of said beads; d) crushing said fraction; e) calcining at least a portion of said crushed fraction at a temperature in the range 250° C. to 900° C.; f) impregnating with acid and hydrothermal treatment at a temperature in the range 80° C. to 250° C.; g) drying then calcining at a temperature in the range 500° C. to 1100° C. h) depositing at least one catalytic metal or compound of a catalytic metal from group VIB and/or group VIII by impregnation. The process of the invention employs a catalyst with a specific pore texture, shape and granulometry, resulting in improved performances.
摘要翻译：本发明涉及一种在氢气存在下，在含有至少一种催化金属或催化金属化合物的催化剂存在下，在淤浆反应器中进行重质进料的方法，所述催化剂金属或载体在氧化铝上的VIB族和/或VIII族的催化剂金属化合物其孔结构由多个并列聚集体组成，每个团聚体由多个针状血小板形成，每个附聚物的血小板通常相对于其它凝聚块大致径向取向，并且相对于附聚物的中心，所述催化剂具有不规则的和非球形的并且主要以片段的形式，使用包括以下步骤的方法获得：a）从具有低结晶度和/或无定形结构的活性氧化铝粉末开始制粒，以获得形式的附聚物的珠子 b）在60℃至100℃之间的潮湿环境中熟化，然后干燥所述珠粒; c）筛分以回收所述珠粒的一部分; d）破碎所述级分; e）在250℃至900℃的温度范围内煅烧所述粉碎部分的至少一部分; f）在80℃至250℃的温度下用酸浸渍和水热处理; g）干燥，然后在500℃至1100℃的温度下煅烧。h）通过浸渍沉积至少一种催化金属或来自VIB族和/或VIII族的催化金属的化合物。本发明的方法采用具有特定孔结构，形状和粒度的催化剂，从而提高了性能。

2. 发明授权

US07270738B2 Catalyst and process for hydrocracking hydrocarbon-containing feedstocks 有权
标题翻译：用于加氢裂化含烃原料的催化剂和方法
公开(公告)号：US07270738B2
公开(公告)日：2007-09-18
申请号：US10696561
申请日：2003-10-30
申请人： Patrick Euzen , Carole Bobin , Magalie Roy-Auberger , Eric Benazzi , Patrick Bourges , Christophe Gueret
发明人： Patrick Euzen , Carole Bobin , Magalie Roy-Auberger , Eric Benazzi , Patrick Bourges , Christophe Gueret
IPC分类号： C01G47/00 , C01G45/00 , C01G17/00 , B01J23/00 , B01J21/00
CPC分类号： B01J35/10 , B01J21/12 , B01J23/24 , B01J23/42 , B01J23/74 , B01J23/85 , B01J23/888 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0009 , C10G47/12 , C10G47/14 , C10G47/16 , C10G47/20 , C10G65/12 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018 , C10G2300/70
摘要： This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 Å, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 160 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 200 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 500 Å, of less than 0.01 ml/g, an X diffraction diagram contains at least the main lines that are characteristic of at least one of the transition aluminas contained in the group that consists of the alpha, rho, chi, eta, gamma, kappa, theta and delta aluminas.
摘要翻译：本发明涉及硅铝基板，催化剂以及使用它们的加氢裂化和加氢处理方法。该催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和非沸石二氧化硅 - 氧化铝基底物的含氢量超过5的氢脱氢元件重量百分比和小于或等于95重量％的二氧化硅（SiO 2/2），并具有以下特征：通过水银孔率法测量的平均孔径包含在20和140之间，a 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间，通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间，包括在 100和550m 2 / g，通过水银孔率法测量的孔体积包含在直径大于140埃，小于0.1ml / g的孔中，孔体积由包含在直径大于160埃，小于0的孔中的水银孔率法。 1毫升/克，通过水银孔率测定法测量的孔体积，直径大于200埃，小于0.1毫升/克，通过水银孔率法测定的孔体积，包含在直径为大于500埃，小于0.01ml / g，X衍射图至少包含由α，rho，chi，eta等组成的组中包含的至少一种过渡氧化铝的特征的主线， γ，κ，θ和δ氧化铝。

3. 发明授权

US07241815B2 Process for synthesising hydrocarbons in a three-phase reactor in the presence of a catalyst comprising a group VIII metal supported on zirconia or on a zirconia-alumina mixed oxide 失效
标题翻译：在包含负载在氧化锆上的第Ⅷ族金属或氧化锆 - 氧化铝混合氧化物的催化剂存在下，在三相反应器中合成烃的方法
公开(公告)号：US07241815B2
公开(公告)日：2007-07-10
申请号：US11076033
申请日：2005-03-10
申请人： Magalie Roy-Auberger , Renaud Revel , Virginie Tissot , Dan Ion Enache , Roberto Zennaro , Giovanni Pederzani
发明人： Magalie Roy-Auberger , Renaud Revel , Virginie Tissot , Dan Ion Enache , Roberto Zennaro , Giovanni Pederzani
IPC分类号： C07C27/00
CPC分类号： C10G2/333 , C10G2/332
摘要： A process is described for synthesising hydrocarbons from a mixture comprising carbon monoxide and hydrogen and possibly carbon dioxide CO2, in the presence of a supported catalyst comprising at least one group VIII metal. The support comprises zirconia or a mixed zirconia-alumina oxide and the zirconia is present in the quadratic and/or amorphous form. Said catalyst is used in a liquid phase in a three-phase reactor.
摘要翻译：描述了在包含一氧化碳和氢气以及可能的二氧化碳CO 2的混合物中，在包含至少一种VIII族金属的负载型催化剂的存在下合成烃的方法。载体包括氧化锆或混合氧化锆 - 氧化铝氧化物，氧化锆以二次和/或无定形的形式存在。所述催化剂在三相反应器中以液相形式使用。

4. 发明授权

US06977273B2 Process for synthesising hydrocarbons in the presence of a catalyst comprising a group VIII metal supported on silica-alumina 有权
标题翻译：在包含负载在二氧化硅 - 氧化铝上的第Ⅷ族金属的催化剂存在下合成烃的方法
公开(公告)号：US06977273B2
公开(公告)日：2005-12-20
申请号：US10075235
申请日：2002-02-15
申请人： Magalie Roy-Auberger , Philippe Courty , Renaud Revel , Roberto Zennaro
发明人： Magalie Roy-Auberger , Philippe Courty , Renaud Revel , Roberto Zennaro
IPC分类号： B01J21/12 , B01J23/40 , B01J23/74 , B01J23/75 , B01J35/10 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/08 , C10G2/00 , C07C27/00 , B01J21/04 , B01J21/08 , B01J23/00
CPC分类号： C10G2/331 , B01J21/12 , B01J23/40 , B01J23/74 , B01J23/75 , B01J35/1019 , B01J37/0045 , B01J37/0201 , B01J37/03 , B01J37/08 , C10G2/332 , C10G2/333
摘要： A process is described for synthesizing hydrocarbons from a mixture comprising carbon monoxide and hydrogen in the presence of a catalyst comprising at least one group VIII metal supported on a silica-alumina prepared by co-precipitating and calcining at a temperature in the range from about 500° C. to about 1200° C. for at least 6 hours so that said silica-alumina has a specific surface area of less than 260 m2/g. Said catalyst is used in a fixed bed or in suspension in a liquid phase of a three-phase reactor.
摘要翻译：描述了一种方法，用于在包含一氧化碳和氢气的混合物的存在下，在包含至少一种负载在二氧化硅 - 氧化铝上的第Ⅷ族金属的存在下合成烃，所述Ⅷ族金属通过共沉淀和在约500℃的温度下煅烧约1200℃至少6小时，使得所述二氧化硅 - 氧化铝的比表面积小于260平方米/克。所述催化剂用于固定床或悬浮在三相反应器的液相中。

5. 发明授权

US07935244B2 Process for hydroconversion of heavy hydrocarbon feeds in a slurry reactor in the presence of a heteropolyanion-based catalyst 有权
标题翻译：在淤浆反应器中在杂多阴离子催化剂存在下加氢转化重质烃进料的方法
公开(公告)号：US07935244B2
公开(公告)日：2011-05-03
申请号：US12076237
申请日：2008-03-14
申请人： Magalie Roy-Auberger , Denis Guillaume , Karin Marchand
发明人： Magalie Roy-Auberger , Denis Guillaume , Karin Marchand
IPC分类号： C10G47/02
CPC分类号： B01J37/038 , B01J23/882 , B01J23/883 , B01J27/188 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/108 , B01J35/12 , B01J37/12 , B01J37/20 , C10G45/08 , C10G45/16 , C10G49/04 , C10G49/12
摘要： The invention concerns a process for slurry phase hydroconversion of liquid sulphur-containing heavy hydrocarbon feeds, in the presence of hydrogen and in the presence of a solid catalyst, said catalyst being obtained from an aqueous solution formed from at least one cobalt and/or nickel salt of at least one heteropolyanion combining molybdenum and cobalt or molybdenum and nickel in its structure. The aqueous solution is introduced into a hydrocarbon oil containing asphaltenes and/or resins to form an emulsion and said emulsion is then injected upstream or directly into the slurry reactor.
摘要翻译：本发明涉及一种用于在氢存在下和在固体催化剂存在下，液体含硫重烃进料的淤浆相加氢转化的方法，所述催化剂由至少一种钴和/或镍形成的水溶液获得至少一个结合钼和钴或钼和镍的杂多阴离子的盐。将水溶液引入含有沥青质和/或树脂的烃油中以形成乳液，然后将所述乳液上游或直接注入到浆料反应器中。

6. 发明授权

US07879224B2 Doped alumino-silicate catalyst and improved process for treatment of hydrocarbon feeds 有权
标题翻译：掺杂铝硅酸盐催化剂和改进的烃类进料处理方法
公开(公告)号：US07879224B2
公开(公告)日：2011-02-01
申请号：US11663497
申请日：2005-09-20
申请人： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Patrick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
发明人： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Patrick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
IPC分类号： C10G11/02 , B01J27/185
CPC分类号： B01J21/12 , B01J21/02 , B01J23/883 , B01J23/888 , B01J27/1853 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/0201 , B01J37/20 , B01J37/28 , C10G49/02 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
摘要： The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
摘要翻译：本发明涉及具有适用的大孔含量和加氢裂化/加氢转化和使用它们的加氢处理方法的铝硅酸盐载体上的掺杂催化剂。该催化剂包含至少一种选自元素周期表第VIB族和第VIII族的元素形成的氢化脱氢元素，受控量的磷（任选与硼和/或硅组合）作为掺杂元素， - 基于含有大于5重量％和95重量％或更少的二氧化硅（SiO 2）的量的氧化铝 - 二氧化硅的硅铝石载体。

7. 发明授权

US06733657B2 Hydrocracking catalyst having a unique silica-alumina substrate 有权
标题翻译：具有独特二氧化硅 - 氧化铝底物的加氢裂化催化剂
公开(公告)号：US06733657B2
公开(公告)日：2004-05-11
申请号：US10045678
申请日：2002-01-15
申请人： Eric Benazzi , Tivadar Cseri , Magalie Roy-Auberger , Patrick Euzen
发明人： Eric Benazzi , Tivadar Cseri , Magalie Roy-Auberger , Patrick Euzen
IPC分类号： C10G4704
CPC分类号： C10G47/12 , B01J21/12 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/20
摘要： A hydrocarbon conversion catalyst contains at least one silica-alumina having the following characteristics: A content by weight of silica SiO2 of between 10 and 60% by weight; an Na content less than 300 ppm by weight; a total pore volume of between 0.5 and 1.2 m/g measured by mercury porosimetry; a porosity of said silica-alumina wherein: the volume of mesopores whose diameter is between 40 Å and 150 Å, and whose mean diameter varies between 80 and 120 Å represents between 30 and 80% of the total pore volume, and (ii) the volume of macropores, whose diameter is greater than 500 Å and preferably between 1000 Å and 10,000 Å represents between 20 and 80% of the total pore volume; a specific surface area greater than 200 m2/g, and at least one hydro-dehydrogenating element selected metals of group VIB and group VIII, and optionally phosphorus, boron, silicon, or elements of group VIIA, VIIB or VB.
摘要翻译：烃转化催化剂含有至少一种具有以下特征的二氧化硅 - 氧化铝：二氧化硅SiO 2的重量含量为10至60重量％; Na含量小于300重量ppm; 通过水银孔率法测量的总孔体积为0.5-1.2m 2 / g; 所述二氧化硅 - 氧化铝的孔隙率，其中直径为介于40和150之间，其平均直径在80和120之间变化的介孔的体积占总孔体积的30至80％，和（ii）其直径大于500埃，优选在1000埃至10,000埃之间的大孔体积占总孔体积的20至80％; 比表面积大于200m 2 / g，以及至少一种加氢脱氢元素选择VIB族和VIII族的金属，以及任选的磷，硼，硅或VIIA，VIIB或VB族的元素。

8. 发明授权

US06465530B2 Process for synthetizing hydrocarbons in the presence of a catalyst comprising a group VIII metal supported on silica-alumina 有权
标题翻译：在包含负载在二氧化硅 - 氧化铝上的第Ⅷ族金属的催化剂存在下合成烃的方法
公开(公告)号：US06465530B2
公开(公告)日：2002-10-15
申请号：US09778842
申请日：2001-02-08
申请人： Magalie Roy-Auberger , Philippe Courty , Laurent Normand , Roberto Zennaro
发明人： Magalie Roy-Auberger , Philippe Courty , Laurent Normand , Roberto Zennaro
IPC分类号： C07C2700
CPC分类号： C10G2/332 , B01J21/12 , B01J23/75 , B01J37/03
摘要： A process is described for synthetizing hydrocarbons from a mixture comprising carbon monoxide and hydrogen in the presence of a catalyst comprising at least one group VIII metal supported on a silica-alumina prepared by co-precipitating and calcining at a temperature in the range from about 500° C. to about 1200° C. for at least 6 hours such that said silica-alumina has a specific surface area of less than 260 m2/g. Said catalyst is used in a fixed bed or in suspension in a liquid phase of a three-phase reactor.
摘要翻译：描述了一种方法，用于在包含一氧化碳和氢气的混合物的催化剂存在下合成烃，所述催化剂包含负载在二氧化硅 - 氧化铝上的至少一种第Ⅷ族金属，其通过共沉淀和在约500℃的温度下煅烧约1200℃至少6小时，使得所述二氧化硅 - 氧化铝具有小于260m 2 / g的比表面积。所述催化剂用于固定床或悬浮在三相反应器的液相中。

9. 发明申请

US20090176894A1 PROCESS OF FISCHER-TROPSCH SYNTHESIS BY CONTROL OF THE PARTIAL PRESSURE OF WATER IN THE REACTION ZONE 有权
标题翻译：通过控制反应区水中部分压力进行FISCHER-TROPSCH合成的方法
公开(公告)号：US20090176894A1
公开(公告)日：2009-07-09
申请号：US12348044
申请日：2009-01-02
申请人： Marie-Claire MARION , Francois Hugues , Magalie Roy-Auberger
发明人： Marie-Claire MARION , Francois Hugues , Magalie Roy-Auberger
IPC分类号： C07C1/00
CPC分类号： B01J23/75 , B01J35/1061 , C10G2/32
摘要： The subject of the invention is a process for the synthesis of hydrocarbons based on a synthesis gas type feedstock in which said synthesis gas is brought into contact with a catalyst in a reactor under Fischer-Tropsch synthesis conditions and in which the partial pressure of water is controlled in order to keep it below a critical value ppH2Olimit defined by the formula: ppH2Olimit=exp(−7751/dp·T)·Ps(T) where T is the reaction temperature in K, dp is the average diameter of the catalyst pores in nm, determined by nitrogen adsorption-desorption (BJH method), Ps(T) is the saturating water vapour pressure at temperature T, in bar.
摘要翻译：本发明的主题是基于合成气类型原料合成烃的方法，其中所述合成气在费 - 托合成条件下在反应器中与催化剂接触，并且其中水的分压为控制以保持其低于由以下公式定义的临界值ppH2Olimit：ppH2Olimit = exp（-7751 / dp.T）.Ps（T）其中T是K中的反应温度，dp是催化剂孔的平均直径以氮气吸附 - 解吸（BJH法）测定，Ps（T）为温度T下的饱和水蒸汽压，单位为bar。

10. 发明申请

US20050282917A1 Process for synthesising hydrocarbons in a three-phase reactor in the presence of a catalyst comprising a group VIII metal supported on zirconia or on a zirconia-alumina mixed oxide 失效
标题翻译：在包含负载在氧化锆上的第Ⅷ族金属或氧化锆 - 氧化铝混合氧化物的催化剂存在下，在三相反应器中合成烃的方法
公开(公告)号：US20050282917A1
公开(公告)日：2005-12-22
申请号：US11076033
申请日：2005-03-10
申请人： Magalie Roy-Auberger , Renaud Revel , Virginie Tissot , Dan Enache , Roberto Zennaro , Giovanni Pederzani
发明人： Magalie Roy-Auberger , Renaud Revel , Virginie Tissot , Dan Enache , Roberto Zennaro , Giovanni Pederzani
IPC分类号： C07C27/26 , C10G2/00
CPC分类号： C10G2/333 , C10G2/332
摘要： A process is described for synthesising hydrocarbons from a mixture comprising carbon monoxide and hydrogen and possibly carbon dioxide CO2, in the presence of a supported catalyst comprising at least one group VIII metal. The support comprises zirconia or a mixed zirconia-alumina oxide and the zirconia is present in the quadratic and/or amorphous form. Said catalyst is used in a liquid phase in a three-phase reactor.
摘要翻译：描述了在包含一氧化碳和氢气以及可能的二氧化碳CO 2的混合物中，在包含至少一种VIII族金属的负载型催化剂的存在下合成烃的方法。载体包括氧化锆或混合氧化锆 - 氧化铝氧化物，氧化锆以二次和/或无定形的形式存在。所述催化剂在三相反应器中以液相形式使用。

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