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1. 发明授权

US08293945B2 Method for producing an amine 有权
标题翻译：胺的制备方法
公开(公告)号：US08293945B2
公开(公告)日：2012-10-23
申请号：US12809649
申请日：2008-12-10
申请人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
发明人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C209/16 , C07D265/30 , C07D295/03 , C07D241/04 , B01J31/00 , B01J23/76 , B01J23/835 , B01J23/843 , B01J23/883
CPC分类号： B01J23/883 , B01J23/002 , B01J23/76 , B01J23/835 , B01J23/8435 , B01J23/8437 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C213/02 , C07D295/023 , Y02P20/582 , B01J2523/44 , B01J2523/48 , B01J2523/842 , B01J2523/847 , B01J2523/68 , B01J2523/51 , B01J2523/43 , B01J2523/53 , B01J2523/54
摘要： Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, nickel, and iron, and 0.2 to 5.5% by weight of at least one oxygen compound of tin, lead, bismuth, molybdenum, antimony or phosphorus, calculated as SnO, PbO, Bi2O3, MoO3, Sb2O3 and H3PO4 respectively; and wherein the catalytically active composition of the catalyst does not comprise any copper.
摘要翻译：用于制备胺的方法，该方法包括：将选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺，仲胺及其混合物，在二氧化锆和含镍催化剂的存在下; 其中所述催化剂包含催化活性组合物，其在用氢还原之前包括锆，镍和铁的氧化合物和0.2至5.5重量％的至少一种氧化合物的锡，铅，铋，钼，锑或磷，分别计算为SnO，PbO，Bi2O3，MoO3，Sb2O3和H3PO4; 并且其中催化剂的催化活性组合物不包含任何铜。

2. 发明授权

US07550632B2 Methods of treating triethanolamine with acid components and basic components, and triethanolamine compositions containing the same 失效
标题翻译：用酸组分和碱性组分处理三乙醇胺的方法和含有它们的三乙醇胺组合物
公开(公告)号：US07550632B2
公开(公告)日：2009-06-23
申请号：US11661544
申请日：2005-08-04
申请人： Frank Haese , Johann-Peter Melder , Roman Dostalek , Manfred Julius
发明人： Frank Haese , Johann-Peter Melder , Roman Dostalek , Manfred Julius
IPC分类号： C07C209/84
CPC分类号： C07C213/10 , C07C215/08
摘要： Methods for improving color properties of triethanolamine, and triethanolamine compositions treated thereby, are disclosed, wherein the methods comprise: (a) providing a composition comprising triethanolamine; and (b) contacting the composition with an acid component and a basic component; wherein the acid component comprises an acid selected from the group consisting of phosphorous acid, hypophosphorous acid and mixtures thereof; and wherein the basic component comprises a compound selected from the group consisting of alkali metal hydroxides, alkaline earth metal hydroxides, ammonium hydroxides according to general formula (I), and mixtures thereof: [R1R2R3(2-hydroxyethyl)ammonium] hydroxide (I) wherein R1, R2 and R3 each independently represents a C1-30 alkyl or a C2-10 hydroxyalkyl; with the proviso that where the basic component comprises an alkali metal hydroxide, the molar ratio of acid component: basic component is 1:0.1 to 1:1, and where the basic component comprises an alkaline earth metal hydroxide, the molar ratio of acid component: basic component is 1:0.05 to 1:0.5.
摘要翻译：公开了用于改善三乙醇胺的颜色特性和由此处理的三乙醇胺组合物的方法，其中所述方法包括：（a）提供包含三乙醇胺的组合物; 和（b）使组合物与酸组分和碱性组分接触; 其中所述酸组分包含选自亚磷酸，次磷酸及其混合物的酸; 并且其中所述碱性组分包括选自碱金属氢氧化物，碱土金属氢氧化物，根据通式（I）的氢氧化铵的化合物及其混合物：<？在线公式描述=“在线公式“end =”lead“→> [R1R2R3（2-羟乙基）铵]氢氧化物（I）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中R1，R2和R3 各自独立地表示C1-30烷基或C2-10羟基烷基; 条件是碱性成分含有碱金属氢氧化物时，酸成分：碱成分的摩尔比为1:0.1〜1:1，碱性成分为碱土金属氢氧化物时，酸成分基本成分为1:0.05〜1:0.5。

3. 发明申请

US20090076306A1 PROCESS FOR CONTINUOUS PREPARATION OF A PRIMARY AROMATIC AMINE 审中-公开
标题翻译：连续制备主要芳香胺的方法
公开(公告)号：US20090076306A1
公开(公告)日：2009-03-19
申请号：US12159099
申请日：2006-12-21
申请人： Frank Haese , Joachim Wulff-Doring , Ulrich Kohler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
发明人： Frank Haese , Joachim Wulff-Doring , Ulrich Kohler , Peter Gaa , Frank-Friedrich Pape , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C209/00 , C07C211/46
CPC分类号： C07C209/18 , C07C211/45
摘要： A process for continuously preparing a primary aromatic amine by reacting a corresponding cycloaliphatic alcohol with ammonia in the presence of hydrogen at a temperature in the range from 80 to 350° C. in the presence of a heterogeneous catalyst, wherein the catalytically active composition of the catalyst, before its reduction with hydrogen, comprises from 90 to 99.8% by weight of zirconium dioxide (ZrO2), from 0.1 to 5.0% by weight of oxygen compounds of palladium and from 0.1 to 5.0% by weight of oxygen compounds of platinum.
摘要翻译：一种在多异性催化剂存在下，在80-350℃的温度下，在氢气存在下使相应的脂环族醇与氨反应连续制备伯芳香胺的方法，其中催化活性组合物催化剂在用氢还原之前包含90-99.8重量％的二氧化锆（ZrO 2），0.1-5.0重量％的氧化合物钯和0.1-5.0重量％的氧化合物铂。

4. 发明申请

US20080255390A1 Shaped Body Comprising an Aluminosilicate and Aluminium Oxide and Process for the Continuous Preparation of Methylamines 有权
标题翻译：包含硅铝酸盐和氧化铝的成形体和用于连续制备甲胺的方法
公开(公告)号：US20080255390A1
公开(公告)日：2008-10-16
申请号：US12088743
申请日：2006-09-21
申请人： Marco Bosch , Roderich Rottger , Jan Eberhardt , Thomas Krug , Manfred Julius , Karl-Heinz Ross , Theodor Weber
发明人： Marco Bosch , Roderich Rottger , Jan Eberhardt , Thomas Krug , Manfred Julius , Karl-Heinz Ross , Theodor Weber
IPC分类号： B01J21/12 , B01J21/04 , B01J35/10 , C07C209/16
CPC分类号： C07C209/16 , B01J21/12 , B01J21/16 , B01J35/002 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/109 , B01J35/1095 , B01J37/0009 , B01J37/0018 , C07C211/04
摘要： Shaped body comprising an aluminosilicate and aluminum oxide, wherein the shaped body has a molar Al/Si ratio in the range from 10 to 30 and an at least bimodal pore distribution for pores having a diameter of greater than 1 nm, with the volume of the pores of the shaped body having a diameter of greater than 10 nm corresponding to at least 40% of the total pore volume of the shaped body, process for producing it and process for the continuous preparation of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the abovementioned shaped bodies are used as catalyst.
摘要翻译：包括铝硅酸盐和氧化铝的成形体，其中成形体的Al / Si摩尔比在10至30的范围内，并且对于具有大于1nm直径的孔的至少双峰孔分布，其体积成形体的孔径大于10nm，对应于成形体的总孔体积的至少40％，其生产方法和通过甲醇和/或二甲醚的反应连续制备甲胺的方法在存在非均相催化剂的情况下使用氨，其中上述成形体用作催化剂。

5. 发明授权

US07256313B2 Method for the production of isophorondiamine (ipda, 3-aminomethyl-3,5,5-trimethyl- cyclohexylamine) having a high cis/tran-isomer ratio 有权
标题翻译：用于制备具有高顺/异构体比例的异佛尔酮二胺（ipda，3-氨基甲基-3,5,5-三甲基 - 环己胺）的方法
公开(公告)号：US07256313B2
公开(公告)日：2007-08-14
申请号：US10522994
申请日：2003-08-06
申请人： Frank Funke , Thomas Hill , Jobst Rüdiger Von Watzdorf , Wolfgang Mattmann , Wolfgang Harder , Erhard Henkes , Gerd Littmann , Manfred Julius
发明人： Frank Funke , Thomas Hill , Jobst Rüdiger Von Watzdorf , Wolfgang Mattmann , Wolfgang Harder , Erhard Henkes , Gerd Littmann , Manfred Julius
IPC分类号： C07C209/84 , C07C209/86 , C07C209/88
CPC分类号： C07C209/84 , C07C209/86 , C07C2601/14 , C07C211/36
摘要： The invention relates to processes for preparing 3-aminomethyl-3,5,5-trimethylcyclo-hexylamine (isophoronediamine, IPDA) having a high cis/trans isomer ratio. IPDA having a cis/trans isomer ratio in the range from 63/37 to 66/34 can be obtained in any desired cis/trans isomer ratio, irrespective of temperature, by reacting IPDA with H2 and NH3 in the presence of a hydrogenation catalyst. IPDA having a cis/trans isomer ratio of at least 73/27 which is an important starting material for the synthesis of polyurethanes and polyamides can be obtained by combining this isomerization process with distillative processes.
摘要翻译：本发明涉及具有高顺/反异构体比的3-氨基甲基-3,5,5-三甲基环己胺（异佛尔酮二胺，IPDA）的方法。具有63/37至66/34范围内的顺式/反式异构体比例的IPDA可通过使IPDA与H 2 N和NH反应，以任何所需顺式/反式异构体比例与温度无关地获得在氢化催化剂的存在下进行。具有至少73/27的顺/反异构体比例的IPDA可以通过将该异构化方法与蒸馏过程组合来获得，其是用于合成聚氨酯和聚酰胺的重要原料。

6. 发明授权

US08608824B2 Integrated method for producing carbonyl iron powder and hydrocarbons 失效
标题翻译：生产羰基铁粉和碳氢化合物的综合方法
公开(公告)号：US08608824B2
公开(公告)日：2013-12-17
申请号：US13063321
申请日：2009-09-02
申请人： Jochen Steiner , Ekkehard Schwab , Andreas Keller , Otto Watzenberger , Ulrich Gräβle , Manfred Julius
发明人： Jochen Steiner , Ekkehard Schwab , Andreas Keller , Otto Watzenberger , Ulrich Gräβle , Manfred Julius
IPC分类号： B22F9/30 , C07C1/00
CPC分类号： B01J23/745 , B01J23/78 , B01J37/086 , C07C1/044 , C07C2523/745 , C10G2/332 , C10G2400/20 , C10J3/00 , C10J2300/0916 , C10J2300/093 , C10J2300/1659 , C10K1/00 , Y02P20/125 , Y02P20/145 , Y02P20/52 , C07C11/02
摘要： Integrated process, in which pure carbonyl iron powder (CIP) is prepared by decomposition of pure iron pentacarbonyl (IPC) in a plant A, carbon monoxide (CO) liberated in the decomposition of the IPC is used in plant A for the preparation of further CIP from iron or is fed to an associated plant B for the preparation of synthesis gas or is fed to an associated plant C for the preparation of hydrocarbons from synthesis gas, and the CIP prepared in plant A is used as catalyst or catalyst component in an associated plant C for the preparation of hydrocarbons from synthesis gas from plant B.
摘要翻译：通过在植物A中分解纯铁五羰基（IPC）制备纯羰基铁粉（CIP）的综合方法，在植物A中使用在IPC分解中释放出的一氧化碳（CO）用于制备进一步的将CIP从铁中加入到相关联的工厂B中用于制备合成气，或者将其进料到合成工厂C用于从合成气制备烃，并将在工厂A中制备的CIP用作催化剂或催化剂组分联合植物C用于从植物B的合成气制备烃。

7. 发明授权

US08278489B2 Method for producing an amine 有权
标题翻译：胺的制备方法
公开(公告)号：US08278489B2
公开(公告)日：2012-10-02
申请号：US12809653
申请日：2008-12-10
申请人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
发明人： Petr Kubanek , Wolfgang Mägerlein , Ekkehard Schwab , Johann-Peter Melder , Manfred Julius
IPC分类号： C07C209/16 , C07D265/30 , C07D295/03 , C07D241/04 , B01J23/835 , B01J37/03 , B01J37/18
CPC分类号： B01J23/835 , B01J23/002 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C213/02 , C07D295/02 , C07D295/06 , C07C217/08
摘要： Processes for preparing an amine, which processes comprise: reacting a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones, and mixtures thereof, with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a zirconium dioxide-, copper- and nickel-containing catalyst; wherein the catalyst comprises a catalytically active composition which comprises, before reduction with hydrogen, oxygen compounds of zirconium, copper, nickel and tin, and 0.5 to 8.0% by weight of an oxygen compound of cobalt, calculated as CoO, and wherein the catalytically active composition does not comprise any ruthenium.
摘要翻译：用于制备胺的方法，该方法包括：将选自伯醇，仲醇，醛，酮及其混合物的反应物与氢和选自以下的氮化合物反应：氨，伯胺，仲胺及其混合物，在二氧化锆，含铜和镍的催化剂存在下; 其中所述催化剂包含催化活性组合物，所述催化活性组合物在用氢还原之前包括锆，铜，镍和锡的氧化合物和0.5至8.0重量％的作为CoO计算的钴的氧化合物，并且其中催化活性组合物不包含任何钌。

8. 发明授权

US08246793B2 Method for the continuous separation of mixtures comprising morpholine (MO), monoaminodiglycol (ADG), ammonia and water by means of distillation 有权
标题翻译：通过蒸馏法连续分离包含吗啉（MO），单氨基二甘醇（ADG），氨和水的混合物的方法
公开(公告)号：US08246793B2
公开(公告)日：2012-08-21
申请号：US12443563
申请日：2007-09-12
申请人： Helmut Schmidtke , Oliver Buβmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
发明人： Helmut Schmidtke , Oliver Buβmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
IPC分类号： B01D3/14 , C07D295/02
CPC分类号： C07D295/027
摘要： Processes for the continuous fractional distillation of a mixture comprising morpholine (MO), monoaminodiglycol (ADG), ammonia and water from a reaction of diethylene glycol (DEG) with ammonia, the process comprising: (i) separating off ammonia from the mixture at a top of a first distillation column K10; (ii) feeding a bottom fraction from the first distillation column to a second distillation column K20, wherein water and an organic product are separated off at a top of the second distillation column at a top temperature of 45 to 198° C. and a pressure in the range from 0.1 to 15 bar; (iii) feeding a bottom fraction from the second distillation column to a third distillation column K30, wherein morpholine and an organic product having a boiling point of 190° C. (1.013 bar) are separated off at a bottom of the third distillation column, and (iv) feeding the morpholine-comprising stream from the third distillation column to a fourth column K40, wherein morpholine is separated off at a side offtake of the fourth column, an organic product having a boiling point of ≦128° C. (1.013 bar) is separated off at a top of the fourth distillation column and an organic product having a boiling point of ≧128° C. (1.013 bar) is separated off at a bottom of the fourth distillation column.
摘要翻译：用于从二甘醇（DEG）与氨的反应连续分馏含有吗啉（MO），单氨基二甘醇（ADG），氨和水的混合物的方法，该方法包括：（i）在第一蒸馏塔K10顶部; （ii）将底部馏分从第一蒸馏塔进料到第二蒸馏塔K20，其中在顶部温度为45至198℃的温度下，在第二蒸馏塔的顶部分离出水和有机产物，并将压力在0.1至15巴的范围内; （iii）将第二蒸馏塔的塔底馏分进料到第三蒸馏塔K30，其中将吗啉和沸点<140℃（1.013巴）的有机产物在选自顶部和在第三蒸馏塔的底部分离出第三蒸馏塔的侧馏分和单胺二醇和沸点> 190℃（1.013巴）的有机产物，和（iv）将含吗啉从第三蒸馏塔到第四塔K40的流，其中吗啉在第四塔的出口侧分离出，沸点为＆amp; NlE的有机产物为128℃（1.013巴）在顶部分离的第四蒸馏塔和沸点为≧128℃的有机产物（1.013巴）在第四蒸馏塔的底部分离。

9. 发明授权

US08197646B2 Processes for continuous fractional distillation of mixtures comprising morpholine, monoaminodiglycol, ammonia and water 有权
$Processes for continuous fractional distillation of mixtures comprising morpholine, monoaminodiglycol, ammonia and water$
标题翻译：用于连续分馏含有吗啉，单氨基二甘醇，氨和水的混合物的方法
公开(公告)号：US08197646B2
公开(公告)日：2012-06-12
申请号：US12443573
申请日：2007-09-12
申请人： Helmut Schmidtke , Oliver Buβmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
发明人： Helmut Schmidtke , Oliver Buβmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
IPC分类号： B01D3/14 , C07D295/02
CPC分类号： C07D295/027 , Y10S203/20
摘要： Process for the continuous fractional distillation of mixtures including morpholine (MO), monoaminodiglycol (ADG), ammonia and water obtained by reaction of diethylene glycol (DEG) with ammonia, which includes separating off ammonia at the top of a first distillation column K10, feeding the bottoms from K10 to a second distillation column K20 in which water and organic products are separated off at the top at a temperature at the top in the range from 45 to 198° C. and a pressure in the range from 0.1 to 15 bar, feeding the bottoms from K20 to a third distillation column K30 in which MO and organic products having a boiling point of 190° C. (1.013 bar) are separated off at the bottom, feeding the MO including stream which is separated off at the top or at a side offtake of the column K30 to a fourth column K40 in which organic products having a boiling point of ≦128° C. (1.013 bar) are separated off at the top and MO and organic products having a boiling point of ≧128° C. (1.013 bar) are separated off at the bottom and the bottoms from K40 are fed to a fifth distillation column K55 in which MO is separated off at the top and organic products having a boiling point of ≧128° C. (1.013 bar) are separated off at the bottom.
摘要翻译：用于连续分馏包括吗啉（MO），单氨基二甘醇（ADG），氨和二乙二醇（DEG）与氨反应得到的水的混合物的方法，其包括在第一蒸馏塔K10的顶部分离出氨，从K10到第二蒸馏塔K20的底部，其中水和有机产物在顶部的温度在45至198℃的范围内分离，压力在0.1至15巴的范围内，将塔底物从K20进料到第三蒸馏塔K30，其中MO和沸点<140℃（1.013巴）的有机产物在顶部或侧面被分离出来，ADG和具有沸点的有机产物在底部分离> 190℃（1.013巴）的点，将包含在柱K30的顶部或侧面分离出的MO的MO进料到第四塔K40，其中有机产物具有沸点从顶部分离出128℃（1.013巴），在底部分离出MO和沸点为128℃（1.013巴）的有机产物，将来自K40的底部进料至其中MO在顶部分离出的第五个蒸馏塔K55和沸点为≧128℃（1.013巴）的有机产物在底部分离。

10. 发明申请

US20120024689A1 METHOD FOR THE CONTINUOUS SEPARATION OF MIXTURES COMPRISING MORPHONLINE (MO), MONOAMINODIGLYCOL (ADG), AMMONIA AND WATER BY MEANS OF DISTILLATION 有权
标题翻译：通过蒸馏法连续分离含有摩尔（MO），单胺基（ADG），氨和水的混合物的方法
公开(公告)号：US20120024689A1
公开(公告)日：2012-02-02
申请号：US12443581
申请日：2007-09-12
申请人： Helmut Schmidtke , Oliver Bußmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
发明人： Helmut Schmidtke , Oliver Bußmann , Ralph Versch , Udo Rheude , Uwe Leyk , Manfred Julius , Martin Rudloff , Erhard Henkes
IPC分类号： B01D3/34 , B01D3/14
CPC分类号： C07C213/10 , C07D295/023 , C07C217/08
摘要： Processes for the continuous fractional distillation of a mixture comprising morpholine (MO), monoaminodiglycol (ADG), ammonia and water from a reaction of diethylene glycol (DEG) with ammonia, the process comprising: (i) separating off ammonia from the mixture at a top of a first distillation column K10; (ii) feeding a bottom fraction from the first distillation column to a second distillation column K20, wherein water and an organic product are separated off at a top of the second distillation column at a top temperature of 45 to 198° C. and a pressure in the range from 0.1 to 15 bar; (iii) feeding a bottom fraction from the second distillation column to a third distillation column K30, wherein morpholine and an organic product having a boiling point of 190° C. (1.013 bar) are separated off at a bottom of the third ditillation column, and (iv) feeding the morpholine-comprising stream from the third distillation column to a fourth column K40, wherein morpholine is separated off at a side offtake of the fourth column, an organic product having a boiling point of ≦128° C. (1.013 bar) is separated off at a top of the fourth distillation column and an organic product having a boiling point of ≧128° C. (1.013 bar) is separated off at a bottom of the fourth distillation column.
摘要翻译：用于从二甘醇（DEG）与氨的反应连续分馏含有吗啉（MO），单氨基二甘醇（ADG），氨和水的混合物的方法，该方法包括：（i）在第一蒸馏塔K10顶部; （ii）将底部馏分从第一蒸馏塔进料到第二蒸馏塔K20，其中在顶部温度为45至198℃的温度下，在第二蒸馏塔的顶部分离出水和有机产物，并将压力在0.1至15巴的范围内; （iii）将第二蒸馏塔的塔底馏分进料到第三蒸馏塔K30，其中将吗啉和沸点<140℃（1.013巴）的有机产物在选自顶部和在第三蒸馏塔的底部分离出第三蒸馏塔的侧馏分和单胺二醇和沸点> 190℃（1.013巴）的有机产物，（iv）将含吗啉从第三蒸馏塔到第四塔K40的流，其中吗啉在第四塔的出口侧分离出，沸点为＆amp; NlE的有机产物为128℃（1.013巴）在顶部分离的第四蒸馏塔和沸点为≧128℃的有机产物（1.013巴）在第四蒸馏塔的底部分离。

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