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    • 2. 发明授权
    • Sonic logging recording apparatus
    • 声波测井记录仪
    • US3930217A
    • 1975-12-30
    • US42226873
    • 1973-12-06
    • PHILLIPS PETROLEUM CO
    • WILEY BRUCE F
    • G01V1/52G01V1/40G04F10/04
    • G01V1/52
    • Apparatus is disclosed for recording the difference in travel times of acoustical signals from first and second spaced generators to a receiver. An up-down counter is first actuated to count up for a period of time corresponding to the travel time of the signal from the more distant generator to the receiver and is then actuated to count down for a period of time corresponding to the travel time of a signal from the closer generator to the receiver. The output signal from the counter is displayed digitally and/or converted to an analog signal and recorded.
    • 公开了用于记录从第一和第二间隔发生器到接收器的声音信号的行进时间差异的装置。 首先启动升降计数器以对应于从较远的发生器到接收器的信号的行进时间的一段时间进行计数,然后被启动以对应于对应于行进时间的时间段 从靠近发生器到接收器的信号。 来自计数器的输出信号以数字方式显示和/或转换为模拟信号并进行记录。
    • 3. 发明授权
    • Recovery of a propane-ethane product and recycle of propane in HF alkylation
    • 在HF烷基化中回收丙烷 - 乙烷产物和回收丙烷
    • US3929925A
    • 1975-12-30
    • US47717974
    • 1974-06-07
    • PHILLIPS PETROLEUM CO
    • CHAPMAN CHARLES C
    • C07C2/62C07C7/00C07C3/54
    • C07C2/62C07C7/005C07C2527/1206C07C9/00
    • An isoparaffin-olefin alkylation reaction product obtained using HF as a catalyst is fractionated to produce an overhead containing propane, ethane and HF, the overhead is partially condensed to produce liquid HF, liquid hydrocarbon, essentially propane lean in ethane, and a vapor stream rich in ethane, the propane lean in ethane is used to reflux the fractionation producing the overhead, the vapors are condensed forming phases and, upon separation of acid phase, the hydrocarbon phase formed is passed by pump to an HF stripper, overhead from the HF stripper is condensed forming phases, and acid phase is removed and hydrocarbon phase is returned to the stripper as reflux. Bottoms from the HF stripper are propane and ethane and after heating are fractionated to produce ethane-propane yield as product and a propane lean in ethane and lean in corrosive HF suitable for use as pump flush, and for increasing the ethane removal ability of the stripper by return thereto.
    • 将使用HF作为催化剂得到的异链烷烃烯烃烷基化反应产物进行分馏以产生含有丙烷,乙烷和HF的塔顶馏分,塔顶部分冷凝以产生液体HF,液体烃,基本上为丙烷贫乙烷,富含蒸气流 在乙烷中,用乙烷稀的丙烷用于回流产生塔顶馏出物的分馏,蒸气是冷凝的形成阶段,并且在酸相分离后,所形成的烃相通过泵通过HF汽提塔,从HF汽提塔 是缩合形成相,除去酸相,并将烃相作为回流返回到汽提塔。 来自HF汽提器的底部是丙烷和乙烷,并且在加热之后分馏以产生乙烷 - 丙烷产率,并且在乙烷中稀释丙烷并且倾向于腐蚀性HF中的贫,适合用作泵冲洗,并且用于提高汽提器的乙烷去除能力 返回。
    • 4. 发明授权
    • Process for making synthetic fuel gas from crude oil
    • 从原油制造合成燃料气的工艺
    • US3929430A
    • 1975-12-30
    • US35979173
    • 1973-05-14
    • PHILLIPS PETROLEUM CO
    • DIXON ROLLAND E
    • C10G69/00C10G37/10C10G11/28
    • C10G11/00C10G11/10C10G69/00
    • A synthetic fuel gas is produced from crude oil by a combination of inter-related steps which separate the oil into several fractions, a first ethane and lighter gaseous fraction, a further gas fraction containing propane and butane, a gasoline containing fraction boiling up to, about 400* F, and a heavy oil or residual fraction, the first two fractions are treated with caustic to remove sulfur and sulfur compounds therefrom, the third fraction is hydrodesulfurized and the fourth fraction is catalytically cracked to extinction to produce gaseous products and an additional gasoline fraction which is hydrodesulfurized whereupon all except the first fraction are combined and then converted by known operation to produce a synthetic natural gas or fuel. This gas or fuel can be combined with the first gas fraction either before or after hydrogen has been removed from it.
    • 合成燃料气体通过相互联系的步骤的组合从原油生产,其将油分离成几个馏分,第一乙烷和轻质气体馏分,另外的含有丙烷和丁烷的气体馏分,含汽油的馏分, 约400°F和重油或残余馏分,前两个馏分用苛性碱处理以从其中除去硫和硫化合物,第三馏分被加氢脱硫,第四馏分被催化裂化灭火以产生气态产物 加氢脱硫的汽油馏分,然后除了第一馏分之外的所有馏分合并,然后通过已知的操作转化以产生合成天然气或燃料。 在将氢气从其中除去之前或之后,该气体或燃料可与第一气体馏分组合。
    • 7. 发明授权
    • Processes for dehydrogenation of hydrocarbons
    • 烃脱氢方法
    • US3927138A
    • 1975-12-16
    • US49729074
    • 1974-08-14
    • PHILLIPS PETROLEUM CO
    • WALKER DARRELL W
    • C07C5/48
    • C07C5/48
    • Organic compounds are dehydrogenated to compounds having a higher degree of unsaturation by contacting the feedstock in the vapor phase in the presence of an oxygen-containing gas with a catalyst formed by combining at least one of nickel, cobalt or iron in association with tin, phosphorus and an alkali metal. Representative of such conversions is the oxidative dehydrogenation of, e.g., butane to butenes and butadiene. The conversion products are valuable compounds particularly useful as intermediates for the preparation of polymeric materials such as synthetic rubbers and the like.
    • 有机化合物通过在含氧气体存在下使气相中的原料与催化剂形成的催化剂脱氢成为具有较高不饱和度的化合物,所述催化剂通过将至少一种镍,钴或铁与锡,磷 和碱金属。 这种转化的代表是例如丁烷到丁烯和丁二烯的氧化脱氢。 转化产物是有价值的化合物,特别可用作制备聚合材料如合成橡胶等的中间体。
    • 10. 发明授权
    • Aminodicyano alkene compounds
    • 氨基二烯基烯烃化合物
    • US3925374A
    • 1975-12-09
    • US46004474
    • 1974-04-11
    • PHILLIPS PETROLEUM CO
    • VIVES VAN C
    • C07C255/30C07D295/145C07C121/45C07D211/34C07D295/14
    • C07D295/145C07C255/00
    • WHEREIN EACH Rii is an alkyl radical and Riii is selected from the group consisting of alkylene and oxydialkylene radicals. Also described are (1) a process for preparing the novel compounds of this invention which comprises reacting a secondary amine and a dicyano-substituted conjugated diene, and (2) a process for preparing the trans isomer of the novel compounds of this invention which comprises reacting a secondary amine and a dicyano-substituted conjugated diene in the presence of an aliphatic monocarboxylic acid. The compounds of this invention are useful as bactericides.

      HAVING FROM 8 TO 26 CARBON ATOMS PER MOLECULE, WHEREIN EACH R is individually selected from the group consisting of hydrogen, alkyl and cycloalkyl; each Ri is individually selected from the group consisting of R and aryl and Q is selected from the group consisting of

      Described herein are novel aminodicyano alkenes of the formula
    • 本文描述的是新型氨基二氰基烯烃,其分子式为RCNCNR |||| Q-C-C = C-C-H || RiRi,每个分子具有8至26个碳原子,每个R各自独立地选自氢,烷基和环烷基; 每个R 1独立地选自R和芳基组成的组,Q选自Rii -N ANGLE和-NRIIi RII,其中Rii是烷基,Riii选自亚烷基和氧基二烯基 。 还描述了(1)制备本发明新型化合物的方法,其包括使仲胺和二氰取代的共轭二烯反应,和(2)制备本发明新型化合物的反式异构体的方法,其包括 在脂族一元羧酸存在下使仲胺和二氰取代的共轭二烯反应。 本发明的化合物可用作杀菌剂。