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    • 4. 发明授权
    • Simple tool for positional diamond mechanosynthesis, and its method of manufacture
    • 位置钻石机械合成的简单工具及其制造方法
    • US07687146B1
    • 2010-03-30
    • US11056567
    • 2005-02-11
    • Robert A. Freitas, Jr.
    • Robert A. Freitas, Jr.
    • B32B9/00
    • C01B32/25Y10T428/30
    • A method is described for building a mechanosynthesis tool intended to be used for the molecularly precise fabrication of physical structures—as for example, diamond structures. An exemplar tool consists of a bulk-synthesized dimer-capped triadamantane tooltip molecule which is initially attached to a deposition surface in tip-down orientation, whereupon CVD or equivalent bulk diamond deposition processes are used to grow a large crystalline handle structure around the tooltip molecule. The large handle with its attached tooltip can then be mechanically separated from the deposition surface, yielding an integral finished tool that can subsequently be used to perform diamond mechanosynthesis in vacuo. The present disclosure is the first description of a complete tool for positional diamond mechanosynthesis, along with its method of manufacture. The same toolbuilding process may be extended to other classes of tooltip molecules, other handle materials, and to mechanosynthetic processes and structures other than those involving diamond.
    • 描述了一种用于构建旨在用于物理结构的分子精确制造的机械合成工具的方法 - 例如金刚石结构。 示例性工具由大量合成的二聚体封端的三金刚塔工具提示分子组成,其最初以向下倾斜的方式附着到沉积表面,于是使用CVD或等效的块状金刚石沉积工艺在工具尖分子周围生长大的晶体手柄结构 。 具有附接的工具提示的大手柄然后可以与沉积表面机械分离,产生一个完整的成品工具,随后可用于在真空中进行金刚石机械合成。 本公开是用于位置金刚石机械合成的完整工具的第一描述及其制造方法。 相同的工具制造过程可以扩展到其他类别的工具提示分子,其他手柄材料,以及除涉及金刚石之外的机械合成过程和结构。
    • 5. 发明申请
    • Positional Diamondoid Mechanosynthesis
    • 位置金刚石机械合成
    • US20090093659A1
    • 2009-04-09
    • US12204642
    • 2008-09-04
    • Robert A. Freitas, JR.Ralph C. Merkle
    • Robert A. Freitas, JR.Ralph C. Merkle
    • C07C13/615B01J19/00
    • C07C2/00Y10S977/859Y10S977/877C07C13/615
    • The invention provides methods of using positionally controlled molecular tools in an inert environment (such as ultra high vacuum) to fabricate complex atomically precise structures, including diamond, graphite, nanotubes, fullerenes, additional sets of the selfsame molecular tools, and others. Molecular tools have atomically precise tooltips which interact directly with a workpiece to add, remove, and modify specific atoms and groups of atoms, and have handles by which they can be held and positioned; tools can be recharged after use. Specific tooltips are brought into contact with and bond to specific feedstock molecules distributed on a presentation surface, and then transfer said feedstock molecules to specific atomic sites on a workpiece using mechanosynthetic chemical reactions. Specific sites on a workpiece can be made chemically reactive, facilitating the transfer of specific groups to them. Repeated applications of molecular tools at different locations on a workpiece can build a desired atomically precise structure.
    • 本发明提供了在惰性环境(例如超高真空)中使用位置控制的分子工具来制造复杂的原子精确结构的方法,包括金刚石,石墨,纳米管,富勒烯,附加的一系列相同的分子工具等。 分子工具具有原子精确的工具提示,其与工件直接相互作用以添加,移除和修饰特定的原子和原子团,并具有可被保持和定位的手柄; 使用后可以对工具进行充电。 特定工具提示与分布在呈现表面上的特定原料分子接触并结合,然后使用机械合成化学反应将所述原料分子转移到工件上的特定原子位点。 工件上的特定位置可以化学反应,便于将特定组转移到它们。 分子工具在工件上不同位置的重复应用可以建立所需的原子精确结构。