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    • 2. 发明授权
    • Preparation and provision of high assay decabromodiphenylethane
    • 高分析十溴二苯乙烷的制备和提供
    • US08217207B2
    • 2012-07-10
    • US13204146
    • 2011-08-05
    • Saadat HussainArthur G. Mack
    • Saadat HussainArthur G. Mack
    • C07C25/00
    • C07C1/26C07C17/10C07C2529/40C08K5/03C07C9/00C07C19/075
    • High assay, reaction-derived decabromodiphenylethane product is prepared by feeding (i) diphenylethane or (ii) partially brominated diphenylethane having an average bromine number less than about two, or (iii) both of (i) and (ii), into the liquid confines of a reaction mixture. Such reaction mixture is (a) formed from components comprised of excess liquid bromine and aluminum-based Lewis acid bromination catalyst, and (b) maintained at one or more elevated reaction temperatures of from about 45°-90° C., and at least when elevated pressure is needed to keep a liquid state in the reaction mixture at the temperature(s) used, the reaction mixture is at such an elevated pressure, whereby ar-bromination occurs. The feeding is conducted at a rate slow enough to form high assay reaction-derived decabromodiphenylethane product, which is an effective flame retardant.
    • 通过将(i)平均溴数小于约2的(ii)二苯基乙烷或(ii)部分溴化的二苯基乙烷,或(iii)(i)和(ii)两者加入到液体中来制备高分离反应衍生的十溴二苯乙烷产物 反应混合物的限制。 这种反应混合物是(a)由过量的液态溴和铝基路易斯酸溴化催化剂组成的组分形成的,和(b)保持在一个或多个升高的​​反应温度为约45-90℃,至少 当需要提高压力以在反应混合物中使用的温度保持液体状态时,反应混合物处于这样一个升高的压力下,从而发生溴化。 饲料以足够慢的速度进行,以形成高分析反应衍生的十溴二苯乙烷产物,其是有效的阻燃剂。
    • 3. 发明授权
    • Processing of solid brominated aromatic organic compounds containing occluded bromine
    • 含有阻塞溴的固体溴化芳族有机化合物的加工
    • US08034986B2
    • 2011-10-11
    • US11840302
    • 2007-08-17
    • Saadat HussainArthur G. Mack
    • Saadat HussainArthur G. Mack
    • C07C17/38C07C25/00C07C17/00
    • C07C17/38C07C25/18C07C41/34C07C43/29C09K21/08
    • Solid-state highly brominated compounds such as solid brominated flame retardants with bromine contents of at least about 60 wt % often contain occluded bromine. Because of their high bromine contents, such compounds have relatively low solubility in common organic solvents. Despite this low solubility, the content of occluded bromine in such solid brominated compounds is effectively reduced by agitating a concentrated agitated slurry of the compound in an inert solvent at a suitable temperature for at least about 1 hour. Thereafter, solids with reduced content of occluded bromine are isolated or recovered from the slurry. Novel products having substantially reduced or eliminated occluded bromine contents and other very desirable characteristics are also provided.
    • 固态高度溴化的化合物,例如溴含量至少约60wt%的固体溴化阻燃剂通常含有阻塞的溴。 由于溴含量高,所以这些化合物在常见的有机溶剂中的溶解度相对较低。 尽管这种低溶解度,但是通过在惰性溶剂中在合适的温度下搅拌化合物的浓缩的搅拌浆料至少约1小时,可以有效地降低这些固体溴化化合物中封闭的溴的含量。 此后,从浆液中分离或回收含有减少的阻塞溴含量的固体。 还提供了具有显着降低或消除了阻塞的溴含量和其它非常理想特性的新产品。