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    • 1. 发明授权
    • Nonaqueous electrolyte solution for secondary battery and nonaqueous electrolyte secondary battery
    • 二次电池和非水电解质二次电池用非水电解液
    • US08323839B2
    • 2012-12-04
    • US11234239
    • 2005-09-26
    • Noriyuki TamuraToshikazu YoshidaMaruo KaminoShin FujitaniMasahiro TakeharaMakoto Ue
    • Noriyuki TamuraToshikazu YoshidaMaruo KaminoShin FujitaniMasahiro TakeharaMakoto Ue
    • H01M6/04
    • H01M4/139H01M4/045H01M4/134H01M4/525H01M4/661H01M4/70H01M10/052H01M10/0567H01M10/0569H01M2300/0025
    • A nonaqueous electrolyte secondary battery in which the decomposition of an electrolyte solution is reduced exhibits high coulombic efficiency and excellent charge and discharge cycle performance, and has high energy density. This nonaqueous electrolyte secondary battery includes a negative electrode that is formed by depositing a thin film of active material on a collector by a CVD method, sputtering, evaporation, thermal spraying, or plating, wherein the thin film of the active material can lithiate and delithiate and is divided into columns by cracks formed in the thickness direction, and the bottom of each column is adhered to the collector; a positive electrode that can lithiate and delithiate; and a nonaqueous electrolyte solution containing a lithium salt in a nonaqueous solvent. The electrolyte solution contains a compound expressed by a general formula (I). Rn-M=0  (I) (wherein, Rs are alkyl groups optionally having a substituent, may be identical or different from one another, may be independent substituents, or may be bound together to form a ring; M is S or P; and n is 2 when M is S and is 3 when M is P).
    • 其中电解液的分解降低的非水电解质二次电池显示出高的库仑效率和优异的充放电循环性能,并且具有高的能量密度。 该非水电解质二次电池包括通过CVD法,溅射法,蒸镀法,热喷镀法或电镀法将活性物质薄膜沉积在集电体上形成的负极,其中活性物质的薄膜可以锂化和脱锂 并通过在厚度方向上形成的裂纹分成列,并且每列的底部粘附到集电体; 可以锂化和脱锂的正极; 以及在非水溶剂中含有锂盐的非水电解液。 电解质溶液含有由通式(I)表示的化合物。 Rn-M = 0(I)(其中,R 5是任选具有取代基的烷基可以相同或不同,可以是独立的取代基,或者可以结合在一起形成环; M是S或P; 当M为S时n为2,M为P时为3)。