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1. 发明申请

US20110237799A1 Process for Producing Phosphonium Borate Compound, Novel Phosphonium Borate Compound, and Method of Using the Same 有权
标题翻译：制备硼酸鏻化合物，新型硼酸鏻化合物的方法及其使用方法
公开(公告)号：US20110237799A1
公开(公告)日：2011-09-29
申请号：US13078118
申请日：2011-04-01
申请人： Shin MASAOKA , Hideyuki IWAZAKI
发明人： Shin MASAOKA , Hideyuki IWAZAKI
IPC分类号： C07D213/16 , C07C253/30 , C07C227/10 , C07C67/343 , C07F7/08 , C07C213/08 , C07C29/58
CPC分类号： B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
摘要： The invention relates to methods for carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and/or carbon-oxygen bond forming reactions using phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3, and Ar4 are as defined herein in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex.
摘要翻译：本发明涉及使用由式（R1）（R2）（R3）PH.BAr4表示的硼酸硼酸盐化合物进行碳 - 碳键形成反应，碳 - 氮键形成反应和/或碳 - 氧键形成反应的方法，其中R 1，R 2，R 3和Ar 4如本文所定义，与过渡金属，过渡金属盐，过渡金属氧化物或过渡金属络合物组合。

2. 发明申请

US20050070730A1 Production processes for triorganomonoalkoxysilanes and triorganomonochlorosilanes 有权
标题翻译：三有机基烷氧基硅烷和三有机氯氯硅烷的生产方法
公开(公告)号：US20050070730A1
公开(公告)日：2005-03-31
申请号：US10495075
申请日：2002-11-08
申请人： Tadashi Bannou , Shin Masaoka , Yoshiki Hayakawa
发明人： Tadashi Bannou , Shin Masaoka , Yoshiki Hayakawa
IPC分类号： C07F7/12 , C07F7/18 , C07F7/08
CPC分类号： C07F7/123 , C07F7/1876 , C07F7/188
摘要： A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3-(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2) ySiCl3-(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3-(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4-(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.
摘要翻译：含有大体积烃基或其中R基并且具有式（III）的硅烷可以通过使式（III）R3-（x + y）（R 1）x（R 2）y Si（OR 3）式（I）的硅烷（R 1）x（R 2）y SiCl 3 - （x + y）（OR 3）与式（II）的格利雅试剂反应。另外，式（XIIa）（R 1）（R 2）（R 3））SiCl的有机氯氯硅烷可以通过使式（XIa）（R 1））（R 2）（R 3）SiZ 1与盐酸反应。此外，当式（ⅩⅢ）的三烷基氧基硅烷R 3 - （x + y）（R 1）x（R 2）y Si（OR 3）（ⅩⅪ）（R 1）x（R 2）y SiCl 4 - （x + y）与式（ⅩⅫ）的格利雅试剂RMgX反应，加入并与醇或环氧化合物反应反应。

3. 发明授权

US08163950B2 Processes for the production of tri-organo-monoalkoxysilanes and process for the production of tri-organo-monochlorosilanes 有权
标题翻译：生产三有机 - 单烷氧基硅烷的方法和生产三有机 - 一氯硅烷的方法
公开(公告)号：US08163950B2
公开(公告)日：2012-04-24
申请号：US13186031
申请日：2011-07-19
申请人： Tadashi Bannou , Shin Masaoka , Yoshiki Hayakawa
发明人： Tadashi Bannou , Shin Masaoka , Yoshiki Hayakawa
IPC分类号： C07F7/04
CPC分类号： C07F7/123 , C07F7/1876 , C07F7/188
摘要： A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2)ySiCl3−(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4−(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.
摘要翻译：具有式（III）的式（III）的R3-（x + y）（R1）x（R2）ySi（OR3）的含有大体积烃基或基团R的硅烷可以通过使式（I）的硅烷 R 1）x（R 2）y SiCl 3 - （x + y）（OR 3）与式（II）的格利雅试剂RMgX另外，式（XIIa）（R1）（R2）（R3）的三有机氯氯硅烷可以通过使式（XIa）（R1）（R2）（R3）SiZ1的三有机硅烷与盐酸反应来制备SiCl。另外，式（XXI）（R1）x（R2）的硅烷可以生成式（ⅩⅩⅢ）R3-（x + y）（R1）x（R2）ySi（OR3）的三有机单烷氧基硅烷）ySiCl 4 - （x + y）与式（XXII）RMgX的格氏试剂反应，在反应期间加入并与醇或环氧化合物反应。

4. 发明授权

US08124809B2 Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same 有权
标题翻译：硼酸鏻化合物的制造方法，新型硼酸鏻化合物及其使用方法
公开(公告)号：US08124809B2
公开(公告)日：2012-02-28
申请号：US13078118
申请日：2011-04-01
申请人： Shin Masaoka , Hideyuki Iwazaki
发明人： Shin Masaoka , Hideyuki Iwazaki
IPC分类号： C07F9/54 , C07F5/02 , C07F15/00 , C07B37/02
CPC分类号： B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
摘要： The invention relates to methods for carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and/or carbon-oxygen bond forming reactions using phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3, and Ar4 are as defined herein in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex.
摘要翻译：本发明涉及使用由式（R1）（R2）（R3）PH.BAr4表示的硼酸硼酸盐化合物进行碳 - 碳键形成反应，碳 - 氮键形成反应和/或碳 - 氧键形成反应的方法，其中R 1，R 2，R 3和Ar 4如本文所定义，与过渡金属，过渡金属盐，过渡金属氧化物或过渡金属络合物组合。

5. 发明申请

US20110275849A1 PROCESSES FOR THE PRODUCTION OF TRI-ORGANO-MONOALKOXYSILANES AND PROCESS FOR THE PRODUCTION OF TRI-ORGANO-MONOCHLOROSILANES 有权
标题翻译：三羟甲基纤维素生产工艺及生产三氯单氰酸酯的方法
公开(公告)号：US20110275849A1
公开(公告)日：2011-11-10
申请号：US13186031
申请日：2011-07-19
申请人： Tadashi BANNOU , Shin MASAOKA , Yoshiki HAYAKAWA
发明人： Tadashi BANNOU , Shin MASAOKA , Yoshiki HAYAKAWA
IPC分类号： C07F7/18
CPC分类号： C07F7/123 , C07F7/1876 , C07F7/188
摘要： A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2)ySiCl3−(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid.Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4−(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.
摘要翻译：具有式（III）的式（III）的R3-（x + y）（R1）x（R2）ySi（OR3）的含有大体积烃基或基团R的硅烷可以通过使式（I）的硅烷 R 1）x（R 2）y SiCl 3 - （x + y）（OR 3）与式（II）的格利雅试剂RMgX另外，式（XIIa）（R1）（R2）（R3）的三有机氯氯硅烷可以通过使式（XIa）（R1）（R2）（R3）SiZ1的三有机硅烷与盐酸反应来制备SiCl。另外，式（XXI）（R1）x（R2）的硅烷可以生成式（ⅩⅩⅢ）R3-（x + y）（R1）x（R2）ySi（OR3）的三有机单烷氧基硅烷）ySiCl 4 - （x + y）与式（XXII）RMgX的格氏试剂反应，在反应期间加入并与醇或环氧化合物反应。

6. 发明授权

US07459577B2 Production processes for triorganomonoalkoxysilanes and triorganomonochlorosilanes 有权
公开(公告)号：US07459577B2
公开(公告)日：2008-12-02
申请号：US10495075
申请日：2002-11-08
申请人： Tadashi Bannou , Shin Masaoka , Yoshiki Hayakawa
发明人： Tadashi Bannou , Shin Masaoka , Yoshiki Hayakawa
IPC分类号： C07F7/04
CPC分类号： C07F7/123 , C07F7/1876 , C07F7/188
摘要： A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3-(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2)ySiCl3-(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3-(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4-(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.

7. 发明授权

US08604249B2 Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same 有权
标题翻译：硼酸鏻化合物的制造方法，新型硼酸鏻化合物及其使用方法
公开(公告)号：US08604249B2
公开(公告)日：2013-12-10
申请号：US12947311
申请日：2010-11-16
申请人： Shin Masaoka , Hideyuki Iwazaki
发明人： Shin Masaoka , Hideyuki Iwazaki
IPC分类号： C07F9/28 , C07F9/54
CPC分类号： B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
摘要： The invention relates to novel phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3 and Ar4 are as defined herein, and compositions including such phosphonium borate compounds in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex for use in carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and carbon-oxygen bond forming reactions.
摘要翻译：本发明涉及由式（R1）（R2）（R3）PH.BAr4表示的新的硼酸鏻化合物，其中R1，R2，R3和Ar4如本文所定义，组合物包括这种硼酸鏻化合物与过渡金属，过渡金属盐，用于碳 - 碳键形成反应的过渡金属氧化物或过渡金属络合物，碳 - 氮键形成反应和碳 - 氧键形成反应。

8. 发明授权

US08008521B2 Processes for the production of tri-organo-monoalkoxysilanes and process for the production of tri-organo-monochlorosilanes 有权
标题翻译：生产三有机 - 单烷氧基硅烷的方法和生产三有机 - 一氯硅烷的方法
公开(公告)号：US08008521B2
公开(公告)日：2011-08-30
申请号：US12324286
申请日：2008-11-26
申请人： Tadashi Bannou , Shin Masaoka , Yoshiki Hayakawa
发明人： Tadashi Bannou , Shin Masaoka , Yoshiki Hayakawa
IPC分类号： C07F7/08
CPC分类号： C07F7/123 , C07F7/1876 , C07F7/188
摘要： A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2)ySiCl3−(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4−(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.
摘要翻译：具有式（III）的式（III）的R3-（x + y）（R1）x（R2）ySi（OR3）的含有大体积烃基或基团R的硅烷可以通过使式（I）的硅烷 R 1）x（R 2）y SiCl 3 - （x + y）（OR 3）与式（II）的格利雅试剂RMgX另外，式（XIIa）（R1）（R2）（R3）的三有机氯氯硅烷可以通过使式（XIa）（R1）（R2）（R3）SiZ1的三有机硅烷与盐酸反应来制备SiCl。另外，式（XXI）（R1）x（R2）的硅烷可以生成式（ⅩⅩⅢ）R3-（x + y）（R1）x（R2）ySi（OR3）的三有机单烷氧基硅烷）ySiCl 4 - （x + y）与式（XXII）RMgX的格氏试剂反应，在反应期间加入并与醇或环氧化合物反应。

9. 发明申请

US20110166389A1 Process for Producing Phosphonium Borate Compound, Novel Phosphonium Borate Compound, and Method of Using the Same 有权
标题翻译：制备硼酸鏻化合物，新型硼酸鏻化合物的方法及其使用方法
公开(公告)号：US20110166389A1
公开(公告)日：2011-07-07
申请号：US12947311
申请日：2010-11-16
申请人： Shin MASAOKA , Hideyuki IWAZAKI
发明人： Shin MASAOKA , Hideyuki IWAZAKI
IPC分类号： C07F5/02
CPC分类号： B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
摘要： The invention relates to novel phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3 and Ar4 are as defined herein, and compositions including such phosphonium borate compounds in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex for use in carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and carbon-oxygen bond forming reactions.
摘要翻译：本发明涉及由式（R1）（R2）（R3）PH.BAr4表示的新的硼酸鏻化合物，其中R1，R2，R3和Ar4如本文所定义，组合物包括这种硼酸鏻化合物与过渡金属，过渡金属盐，用于碳 - 碳键形成反应的过渡金属氧化物或过渡金属络合物，碳 - 氮键形成反应和碳 - 氧键形成反应。

10. 发明授权

US07728176B2 Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same 有权
标题翻译：硼酸鏻化合物的制造方法，新型硼酸鏻化合物及其使用方法
公开(公告)号：US07728176B2
公开(公告)日：2010-06-01
申请号：US10580699
申请日：2004-11-26
申请人： Shin Masaoka , Hideyuki Iwazaki
发明人： Shin Masaoka , Hideyuki Iwazaki
IPC分类号： C07F9/02
CPC分类号： B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
摘要： The invention relates to a phosphonium borate compound represented by Formula (I) (hereinafter, the compound (I)). The invention has objects of providing (A) a novel process whereby the compound is produced safely on an industrial scale, by simple reaction operations and in a high yield; (B) a novel compound that is easily handled; and (C) novel use as catalyst. Formula (I): (R1)(R2)(R3)PH.BAr4 (I) wherein R1, R2, R3 and Ar are as defined in the specification. The process (A) includes reacting a phosphine with a) HCl or b) H2SO4 to produce a) a hydrochloride or b) a sulfate; and reacting the salt with a tetraarylborate compound. The compound (B) has for example a secondary or tertiary alkyl group as R1 and is easily handled in air without special attention. The use (C) is characterized in that the compound (I) is used instead of an unstable phosphine compound of a transition metal complex catalyst for catalyzing C—C bond, C—N bond and C—O bond forming reactions and the compound produces an effect that is equal to that achieved by the transition metal complex catalyst.
摘要翻译：本发明涉及由式（I）表示的硼酸鏻化合物（以下称为化合物（I））。本发明的目的是提供（A）通过简单的反应操作和高产率使化合物在工业规模上安全生产的新方法; （二）易于处理的新型化合物; 和（C）新型用作催化剂。式（I）：（R1）（R2）（R3）PH.BAr4（I）其中R1，R2，R3和Ar如说明书中所定义。方法（A）包括使膦与a）HCl或b）H 2 SO 4反应以产生a）盐酸盐或b）硫酸盐; 并使该盐与四芳基硼酸盐化合物反应。化合物（B）具有例如作为R 1的仲或叔烷基，并且容易在空气中处理而没有特别注意。使用（C）的特征在于，使用化合物（I）来代替用于催化C-C键，C-N键和C-O键形成反应的过渡金属络合物催化剂的不稳定膦化合物，并且化合物产生其效果等于过渡金属络合物催化剂所达到的效果。

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