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    • 2. 发明申请
    • Production processes for triorganomonoalkoxysilanes and triorganomonochlorosilanes
    • 三有机基烷氧基硅烷和三有机氯氯硅烷的生产方法
    • US20050070730A1
    • 2005-03-31
    • US10495075
    • 2002-11-08
    • Tadashi BannouShin MasaokaYoshiki Hayakawa
    • Tadashi BannouShin MasaokaYoshiki Hayakawa
    • C07F7/12C07F7/18C07F7/08
    • C07F7/123C07F7/1876C07F7/188
    • A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3-(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2) ySiCl3-(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3-(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4-(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.
    • 含有大体积烃基或其中R基并且具有式(III)的硅烷可以通过使式(III)R3-(x + y)(R 1)x(R 2)y Si(OR 3) 式(I)的硅烷(R 1)x(R 2)y SiCl 3 - (x + y)(OR 3)与式(II)的格利雅试剂反应。另外, 式(XIIa)(R 1)(R 2)(R 3))SiCl的有机氯氯硅烷可以通过使式(XIa)(R 1) )(R 2)(R 3)SiZ 1与盐酸反应。 此外,当式(ⅩⅢ)的三烷基氧基硅烷R 3 - (x + y)(R 1)x(R 2)y Si(OR 3) (ⅩⅪ)(R 1)x(R 2)y SiCl 4 - (x + y)与式(ⅩⅫ)的格利雅试剂RMgX反应,加入并与醇或环氧化合物反应 反应。
    • 3. 发明授权
    • Processes for the production of tri-organo-monoalkoxysilanes and process for the production of tri-organo-monochlorosilanes
    • 生产三有机 - 单烷氧基硅烷的方法和生产三有机 - 一氯硅烷的方法
    • US08008521B2
    • 2011-08-30
    • US12324286
    • 2008-11-26
    • Tadashi BannouShin MasaokaYoshiki Hayakawa
    • Tadashi BannouShin MasaokaYoshiki Hayakawa
    • C07F7/08
    • C07F7/123C07F7/1876C07F7/188
    • A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2)ySiCl3−(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4−(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.
    • 具有式(III)的式(III)的R3-(x + y)(R1)x(R2)ySi(OR3)的含有大体积烃基或基团R的硅烷可以通过使式(I)的硅烷 R 1)x(R 2)y SiCl 3 - (x + y)(OR 3)与式(II)的格利雅试剂RMgX另外,式(XIIa)(R1)(R2)(R3)的三有机氯氯硅烷 可以通过使式(XIa)(R1)(R2)(R3)SiZ1的三有机硅烷与盐酸反应来制备SiCl。 另外,式(XXI)(R1)x(R2)的硅烷可以生成式(ⅩⅩⅢ)R3-(x + y)(R1)x(R2)ySi(OR3)的三有机单烷氧基硅烷 )ySiCl 4 - (x + y)与式(XXII)RMgX的格氏试剂反应,在反应期间加入并与醇或环氧化合物反应。
    • 4. 发明授权
    • Processes for the production of tri-organo-monoalkoxysilanes and process for the production of tri-organo-monochlorosilanes
    • 生产三有机 - 单烷氧基硅烷的方法和生产三有机 - 一氯硅烷的方法
    • US08163950B2
    • 2012-04-24
    • US13186031
    • 2011-07-19
    • Tadashi BannouShin MasaokaYoshiki Hayakawa
    • Tadashi BannouShin MasaokaYoshiki Hayakawa
    • C07F7/04
    • C07F7/123C07F7/1876C07F7/188
    • A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2)ySiCl3−(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4−(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.
    • 具有式(III)的式(III)的R3-(x + y)(R1)x(R2)ySi(OR3)的含有大体积烃基或基团R的硅烷可以通过使式(I)的硅烷 R 1)x(R 2)y SiCl 3 - (x + y)(OR 3)与式(II)的格利雅试剂RMgX另外,式(XIIa)(R1)(R2)(R3)的三有机氯氯硅烷 可以通过使式(XIa)(R1)(R2)(R3)SiZ1的三有机硅烷与盐酸反应来制备SiCl。 另外,式(XXI)(R1)x(R2)的硅烷可以生成式(ⅩⅩⅢ)R3-(x + y)(R1)x(R2)ySi(OR3)的三有机单烷氧基硅烷 )ySiCl 4 - (x + y)与式(XXII)RMgX的格氏试剂反应,在反应期间加入并与醇或环氧化合物反应。
    • 7. 发明申请
    • Fuel injection control system ensuring steady balance in pressure in accumulator
    • 燃油喷射控制系统确保蓄能器压力稳定平衡
    • US20070125343A1
    • 2007-06-07
    • US11633632
    • 2006-12-05
    • Yoshiki Hayakawa
    • Yoshiki Hayakawa
    • F02M57/02F02M51/00F02M63/00
    • F02M63/0225F02D41/221F02D41/3845F02M59/462
    • An accumulator fuel injection system working to energize fuel injectors to inject fuel at a sequence of injection timings into an internal combustion engine and also to control a fuel pump to feed the fuel to an accumulator at a sequence of controlled times for compensating for the amount of the fuel flowing out of the accumulator under feedback control. When having found a failure in operation of at least one of the fuel injectors, the system alters a mode of the feedback control to decrease the amount of fuel fed to the accumulator at one of the sequence of the controlled times which is at a selected interval away from one of the sequence of the injection timings at which the at least one of the fuel injectors is to be energized, thereby ensuring a steady balance between the amounts of fuel flowing into and out of the accumulator.
    • 一种蓄能器燃料喷射系统,其工作以激励燃料喷射器以将喷射定时的一系列喷射燃料喷射到内燃机中,并且还控制燃料泵以一系列控制时间将燃料供给蓄能器,以补偿燃料的量 在反馈控制下燃料从蓄能器流出。 当发现燃料喷射器中的至少一个操作失败时,系统改变反馈控制的模式,以以选定间隔的受控时间序列中的一个减小供给到累加器的燃料量 远离燃料喷射器中的至少一个燃料喷射器的喷射正时序列之一,从而确保流入和流出蓄压器的燃料量之间的稳定平衡。
    • 9. 发明授权
    • Fuel injection controller
    • 燃油喷射控制器
    • US07392793B2
    • 2008-07-01
    • US11727074
    • 2007-03-23
    • Yoshiki Hayakawa
    • Yoshiki Hayakawa
    • F02M59/02F02M59/36
    • F02D41/3845F02B3/06F02D2041/1409F02D2250/31
    • A fuel injection controller calculates a fuel pressure-feeding start angle of a fuel pump as a valve opening start angle of a metering valve, which regulates a discharge amount, by adding a base angle and a feedback correction value. The base angle is calculated in accordance with a command injection amount and target fuel pressure based on a basic map. The feedback correction value is calculated based on differential pressure between sensed fuel pressure and the target fuel pressure. If an abnormality is caused in either one of two metering valves, the base angle is calculated based on an abnormal period map instead of the basic map. Thus, controllability of the fuel pressure is maintained high even when the abnormality is caused in a part of multiple pressure-feeding systems including multiple plungers of the fuel pump.
    • 燃料喷射控制器通过添加基准角和反馈校正值来计算作为调节排出量的计量阀的开阀起始角度的燃料泵的燃料供给开始角度。 基于基准图,根据指令喷射量和目标燃料压力来计算底角。 基于检测到的燃料压力和目标燃料压力之间的压差来计算反馈校正值。 如果在两个计量阀中的任何一个中引起异常,则基于异常周期图而不是基本图来计算基准角。 因此,即使在包括燃料泵的多个柱塞的多个压力给送系统的一部分中引起异常,燃料压力的可控性也保持较高。