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    • 5. 发明申请
    • PRODUCTION METHOD FOR CHLORINATED VINYL CHLORIDE RESIN
    • 氯化氯乙烯树脂的生产方法
    • US20170008981A1
    • 2017-01-12
    • US15119438
    • 2015-03-31
    • SEKISUI CHEMICAL CO., LTD.TOKUYAMA SEKISUI CO., LTD.
    • Kenichi MATSUMURANorikazu MASHINO
    • C08F8/22
    • C08F8/22C08F14/06C08F214/06C08J5/18C08J2327/24C08K5/098C08K5/10C08L27/06C08L27/24C08L33/12C08L51/04C08F2/16C08F114/06
    • The present invention provides a method for producing a chlorinated polyvinyl chloride which is excellent in thermal stability (initial discoloration resistance, heat-resistant stability) and is capable of providing a transparent article. The present invention relates to a method for producing a chlorinated polyvinyl chloride through thermal chlorination of a reaction solution including a vinyl chloride aqueous suspension that contains a vinyl chloride resin in a hermetically sealable reaction vessel, the method including: step 1 of initiating thermal chlorination by heating the reaction solution to 55° C. to 70° C. and then introducing chlorine into the reaction vessel; step 2 of raising the temperature of the reaction solution while maintaining the temperature inside the reaction vessel not higher than the glass transition temperature of a partially chlorinated polyvinyl chloride; and step 3 of carrying out the thermal chlorination at a predetermined temperature of 85° C. or higher but lower than 115° C. after the chlorine content of the partially chlorinated polyvinyl chloride reaches 58% by weight or more, the steps 1 to 3 being performed under stirring at a net stirring power (Pv) inside the reaction vessel of 0.2 to 2.5 kw/m3 per 1 m3 of the reaction solution.
    • 本发明提供热稳定性(初始耐变色性,耐热稳定性)优异的能够提供透明制品的氯化聚氯乙烯的制造方法。 本发明涉及一种氯化聚氯乙烯的制备方法,该方法包括:在密封的反应容器中含有氯乙烯树脂的氯乙烯水悬浮体的反应溶液的热氯化,该方法包括:步骤1,通过 将反应溶液加热至55℃至70℃,然后将氯引入反应容器中; 在保持反应容器内的温度不高于部分氯化聚氯乙烯的玻璃化转变温度的同时提高反应溶液的温度的步骤2; 以及在部分氯化聚氯乙烯的氯含量达到58重量%以上之后,在85℃以上且低于115℃的规定温度下进行热氯化的步骤3,步骤1〜3 在反应容器内的净搅拌功率(Pv)下搅拌进行0.2至2.5kw / m3 / 1m 3反应溶液。