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1. 发明授权

US09006481B2 Process and apparatus for preparing isocyanates 有权
标题翻译：制备异氰酸酯的方法和装置
公开(公告)号：US09006481B2
公开(公告)日：2015-04-14
申请号：US13256541
申请日：2010-03-18
申请人： Torsten Mattke , Carsten Knoesche , Bernd Rumpf , Eckhard Stroefer
发明人： Torsten Mattke , Carsten Knoesche , Bernd Rumpf , Eckhard Stroefer
IPC分类号： C07C263/00 , C07B43/10 , C07C263/10 , F28D7/00 , F28D13/00
CPC分类号： C07B43/10 , B01J2219/00873 , C07C263/10 , F28D7/00 , F28D13/00 , C07C265/14 , C07C265/00
摘要： The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase, optionally in the presence of an inert medium, in which phosgene and amine are first evaporated and then superheated further to reaction temperature, and the superheated phosgene and amine are mixed and fed to a reactor in which the phosgene and the amine are converted to the isocyanate, wherein the residence time of the phosgene at temperatures greater than 300° C. is not more than 5 s, and/or the temperature of heat transfer surfaces in contact with phosgene is not more than 20 K above the phosgene temperature to be established. The invention further relates to an apparatus for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase.
摘要翻译：本发明涉及通过使气相中相应的胺与光气反应制备异氰酸酯的方法，任选地在惰性介质存在下，首先将光气和胺蒸发，然后进一步过热至反应温度，过热的光气和胺混合并加入到光气和胺转化为异氰酸酯的反应器中，其中光气在大于300℃的温度下的停留时间不超过5秒，和/或与光气接触的传热表面不超过要建立的光气温度20K。本发明还涉及通过气相中相应的胺与光气反应制备异氰酸酯的装置。

2. 发明授权

US08809575B2 Process for preparing isocyanates 有权
标题翻译：异氰酸酯的制备方法
公开(公告)号：US08809575B2
公开(公告)日：2014-08-19
申请号：US13131123
申请日：2009-11-30
申请人： Carsten Knoesche , Torsten Mattke , Patric Mueller
发明人： Carsten Knoesche , Torsten Mattke , Patric Mueller
IPC分类号： C07C263/10
CPC分类号： C07C263/10 , C07C265/00
摘要： The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase, optionally in the presence of an inert medium, in which the amine and the phosgene are first mixed and converted to the isocyanate in a reactor, and in which a reaction gas (1) which comprises isocyanate and hydrogen chloride leaving the reactor is cooled in a quench (3) by adding a liquid quench medium (5) to form a mixture of reaction gas and quench medium as the product stream (7). The quench medium (5) used is a mixture which comprises at least one solvent and isocyanate and which is withdrawn from the preparation process, any solid particles present in the quench medium (5) being removed before addition to the quench (3).
摘要翻译：本发明涉及一种制备异氰酸酯的方法，任选在惰性介质存在下，在气相中使相应的胺与光气反应，其中胺和光气首先在反应器中混合并转化成异氰酸酯，以及其中通过加入液体骤冷介质（5）将通过离开反应器的包含异氰酸酯和氯化氢的反应气体（1）在淬火（3）中冷却，形成作为产物流（7）的反应气体和骤冷介质的混合物）。使用的骤冷介质（5）是包含至少一种溶剂和异氰酸酯并从制备过程中排出的混合物，在加入骤冷（3）之前，将骤冷介质（5）中存在的任何固体颗粒除去。

3. 发明授权

US08779181B2 Process for preparing isocyanates 有权
标题翻译：异氰酸酯的制备方法
公开(公告)号：US08779181B2
公开(公告)日：2014-07-15
申请号：US13123787
申请日：2009-10-08
申请人： Torsten Mattke , Carsten Knoesche
发明人： Torsten Mattke , Carsten Knoesche
IPC分类号： C07C263/10 , C07C265/14
CPC分类号： C07C263/10 , C07C265/14
摘要： The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase, if appropriate in the presence of an inert medium, in which the amine and the phosgene are first mixed and converted to the isocyanate in a reactor, and in which a reaction gas which comprises isocyanate and hydrogen chloride and leaves the reactor is cooled in a quench space of a quench by adding a quench medium. The quench medium on addition to the quench space has a temperature above the condensation temperature or the desublimation temperature of the reaction gas.
摘要翻译：本发明涉及通过在气相中使相应的胺与光气反应制备异氰酸酯的方法，如果合适的话，在惰性介质的存在下，首先将胺和光气混合并转化成反应器中的异氰酸酯，并且其中包含异氰酸酯和氯化氢并离开反应器的反应气体通过加入骤冷介质在骤冷骤冷空间中冷却。淬火介质除了淬火空间之外，还具有高于冷凝温度或反应气体的冷凝温度的温度。

4. 发明授权

US08765996B2 Process for preparing isocyanates 有权
标题翻译：异氰酸酯的制备方法
公开(公告)号：US08765996B2
公开(公告)日：2014-07-01
申请号：US13001681
申请日：2009-07-23
申请人： Carsten Knoesche , Torsten Mattke
发明人： Carsten Knoesche , Torsten Mattke
IPC分类号： C07C263/10 , C07C265/14
CPC分类号： C07C263/10 , C07C265/14
摘要： The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase, if appropriate in the presence of at least one inert medium, the phosgene being passed into a reactor (21) through a first inlet and the amine through a second inlet of an ejector (1). The first inlet and the second inlet open into a mixing zone (17) in which the phosgene and the amine are mixed to give a reaction mixture. The mixing zone (17) is followed downstream by a diffuser (19) in which pressure and temperature of the reaction mixture composed of phosgene and amine are increased.
摘要翻译：本发明涉及通过在气相中使相应的胺与光气反应来制备异氰酸酯的方法，如果合适的话，在至少一种惰性介质的存在下，光气通过第一入口进入反应器（21）通过喷射器（1）的第二入口。第一入口和第二入口进入混合区（17），其中将光气和胺混合以产生反应混合物。混合区（17）在下游被扩散器（19）跟随，其中由光气和胺组成的反应混合物的压力和温度增加。

5. 发明申请

US20120253063A1 PROCESS FOR PREPARING ISOCYANATES 有权
标题翻译：制备异氰酸酯的方法
公开(公告)号：US20120253063A1
公开(公告)日：2012-10-04
申请号：US13513595
申请日：2010-12-03
申请人： Torsten Mattke , Eckhard Stroefer , Julia Leschinski , Radwan Abdallah , Axel Franzke , Michael Bock
发明人： Torsten Mattke , Eckhard Stroefer , Julia Leschinski , Radwan Abdallah , Axel Franzke , Michael Bock
IPC分类号： C07C263/00
CPC分类号： C07C263/04 , C07C265/12 , C07C265/14
摘要： Process for preparing aromatic isocyanates by reacting the corresponding formamides with an oxygen-comprising gas over noble metal catalysts at temperatures of from 300 to 600° C. and a contact time of from 1 to 1000 ms, wherein: a. the formamide is vaporized before entering the reaction zone, b. the reaction mixture obtained is quenched with an alcohol-comprising quenching liquid and c. the urethane formed is dissociated into isocyanate and alcohol.
摘要翻译：通过使贵金属催化剂上的相应的甲酰胺与含氧气体在300-600℃的温度和1至1000ms的接触时间下反应来制备芳族异氰酸酯的方法，其中：a。甲酰胺在进入反应区之前蒸发，b。得到的反应混合物用含醇的淬火液骤冷，c。所形成的聚氨酯被分解成异氰酸酯和醇。

6. 发明申请

US20120251435A1 PROCESS FOR PREPARING ISOCYANATES 有权
标题翻译：制备异氰酸酯的方法
公开(公告)号：US20120251435A1
公开(公告)日：2012-10-04
申请号：US13434135
申请日：2012-03-29
申请人： Vanessa Simone LEHR , Torsten Mattke , Carsten Knösche , Heiner Schelling , Gerhard Olbert
发明人： Vanessa Simone LEHR , Torsten Mattke , Carsten Knösche , Heiner Schelling , Gerhard Olbert
IPC分类号： C07C263/10 , C01B7/04 , C07C17/15
CPC分类号： C07C263/10 , C01B7/04 , Y02P20/22 , C07C265/00
摘要： A process is proposed for preparing isocyanates by phosgenating the corresponding amines in the gas phase, which comprises dividing a phosgene-containing reaction mixture from the gas phase synthesis of carbon monoxide and chlorine to phosgene, which is run with a stoichiometric carbon monoxide excess over chlorine, by means of a thermal separating process and/or of a membrane separating process into two streams, specifically into a first, low-carbon monoxide stream comprising not more than 1% by weight of carbon monoxide, based on the total weight of the first, low-carbon monoxide stream, and into a second, carbon monoxide-rich stream comprising more than 10% by weight of carbon monoxide, based on the total weight of the second, carbon monoxide-rich stream, and using the first, low-carbon monoxide stream as a reactant stream in the phosgenation of amines to isocyanates in the gas phase.
摘要翻译：提出了一种通过在气相中对相应的胺进行光气化来制备异氰酸酯的方法，其中包括从气相合成一氧化碳和氯中将含有光气的反应混合物分离成碳酰氯，其以化学计量的一氧化碳超过氯，通过热分离方法和/或膜分离方法转化为两股物流，特别是以包含不超过1重量％的一氧化碳的第一个低一氧化碳流，基于第一个，低碳一氧化碳流，以及基于第二种一氧化碳流的总重量，并进入包含大于10重量％的一氧化碳的第二，一氧化碳浓缩物流中，一氧化碳流作为气相中异氰酸酯在胺气相中的反应物流。

7. 发明申请

US20110213177A1 PROCESS FOR PREPARING ISOCYANATES IN THE GAS PHASE 有权
标题翻译：在气相中制备异氰酸酯的方法
公开(公告)号：US20110213177A1
公开(公告)日：2011-09-01
申请号：US13035166
申请日：2011-02-25
申请人： Torsten Mattke , Ralf Böhling , Carsten Knösche , Vanessa Simone Lehr
发明人： Torsten Mattke , Ralf Böhling , Carsten Knösche , Vanessa Simone Lehr
IPC分类号： C07C263/10
CPC分类号： C07C263/10 , C07C265/14
摘要： The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the gas phase, in the presence or absence of an inert medium, which comprises the following steps: (a) vaporization of the amine in a vaporizer, (b) superheating of the amine, (c) mixing of the gaseous amine with the phosgene and introduction into a reaction zone, (d) reaction of amine and phosgene to give isocyanate in the reaction zone, with a reaction mixture comprising isocyanate and hydrogen chloride being formed, (e) cooling of the reaction mixture comprising isocyanate and hydrogen chloride, wherein the vaporizer comprises a vessel in which tubes through which a heating medium flows are comprised, where number and diameter of the tubes are designed so that the tubes have a specific heat transfer area based on the volume through which the amine flows of at least 300 m2/m3.
摘要翻译：本发明涉及通过在惰性介质存在或不存在的情况下使气相中相应的胺与光气反应来制备异氰酸酯的方法，其包括以下步骤：（a）蒸发器中胺的蒸发，（b ）胺的过热，（c）将气态胺与光气混合并引入反应区，（d）胺和光气在反应区中反应得到异氰酸酯，反应混合物包含异氰酸酯和氯化氢形成（e）包含异氰酸酯和氯化氢的反应混合物的冷却，其中蒸发器包括容器，其中包含加热介质流过的管，其中管的数量和直径被设计成使得管具有特定的基于胺流动的体积至少为300m 2 / m 3的传热面积。

8. 发明申请

US20100305356A1 METHOD FOR PRODUCING ISOCYANATES 审中-公开
标题翻译：生产异氰酸酯的方法
公开(公告)号：US20100305356A1
公开(公告)日：2010-12-02
申请号：US12675137
申请日：2008-08-13
申请人： Gerhard Olbert , Torsten Mattke , Carsten Knoesche , Andreas Daiss , Jens Denecke
发明人： Gerhard Olbert , Torsten Mattke , Carsten Knoesche , Andreas Daiss , Jens Denecke
IPC分类号： C07C263/10 , B01F15/02 , B01J19/24
CPC分类号： C07C263/10 , B01F2005/0621 , B01F2005/0634 , B01F2005/0636 , C07C209/78 , C07C211/50 , C07C265/14
摘要： The present invention relates to a process for preparing isocyanates.
摘要翻译：本发明涉及一种制备异氰酸酯的方法。

9. 发明授权

US07799373B2 In situ recoating of catalyst beds 失效
标题翻译：催化剂床的原位重涂
公开(公告)号：US07799373B2
公开(公告)日：2010-09-21
申请号：US10551858
申请日：2004-04-02
申请人： Bernd Sachweh , Günther Huber , Mark Duda , Torsten Mattke , Gerhard Olbert
发明人： Bernd Sachweh , Günther Huber , Mark Duda , Torsten Mattke , Gerhard Olbert
IPC分类号： B05D7/22
CPC分类号： B01J37/0232 , B01J37/0215 , B01J37/0221
摘要： A process for coating internals in a reactor, except for the coating of electrically heatable, at least partly open-cell foams, with a catalytically active material or a precursor thereof, in which an aerosol which contains the catalytically active material or the precursor thereof as a disperse phase is provided and the aerosol is passed through the reactor at a rate in the range from 0.1 to 4 m/s, which is established so that the disperse phase of the aerosol is deposited on the internals in the reactor.
摘要翻译：除了用催化活性材料或其前体涂覆电可加热的，至少部分开放泡沫的泡沫以外，在反应器中涂覆内部件的方法，其中将含有催化活性材料或其前体的气溶胶作为提供分散相，气雾剂以0.1至4m / s的速率通过反应器，其速率被确定为使得气溶胶的分散相沉积在反应器内部。

10. 发明申请

US20100041915A1 METHOD FOR PRODUCING ISOCYANATES 审中-公开
标题翻译：生产异氰酸酯的方法
公开(公告)号：US20100041915A1
公开(公告)日：2010-02-18
申请号：US12521878
申请日：2007-12-12
申请人： Andreas Woelfert , Carsten Knoesche , Torsten Mattke , Eckhard Stroefer
发明人： Andreas Woelfert , Carsten Knoesche , Torsten Mattke , Eckhard Stroefer
IPC分类号： C07C263/10
CPC分类号： C07C263/10 , C07C265/14
摘要： The present invention relates to a process for preparing diisocyanates from diamines and phosgene in the gas phase.
摘要翻译：本发明涉及一种在气相中由二胺和光气制备二异氰酸酯的方法。

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