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    • 1. 发明授权
    • Method of treating nitrogen oxide-containing gas
    • 处理含氮氧化物气体的方法
    • US07972581B1
    • 2011-07-05
    • US12158166
    • 2007-04-13
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • B01D53/56
    • B01D53/8625B01D53/8696F23C13/06F23C13/08F23J2219/10F23N1/022F23N5/006F23N2035/06F23N2035/10F23N2035/12F23N2037/12F23N2041/04
    • First, the emission amount of nitrogen oxides can be decreased close to zero as much as possible, and the emission amount of carbon monoxide is decreased to a permissible range. Second, energy saving by combustion at a low air ratio close to 1.0 is realized. Third, air ratio control is performed stably in a combustion region at a low air ratio.The present invention includes: a combustion step of burning hydrocarbon-containing fuel in the burner, thereby generating gas free of hydrocarbons but containing oxygen, nitrogen oxides, and carbon monoxide; a hazardous-substance decreasing step of bringing the gas into contact with an oxidation catalyst, thereby oxidizing carbon monoxide contained in the gas by oxygen and reducing nitrogen oxides by carbon monoxide; and a concentration ratio adjusting step of adjusting a concentration ratio of oxygen, nitrogen oxides, and carbon monoxide in gas on a primary side of the oxidation catalyst to a predetermined concentration ratio in which a concentration of nitrogen oxides on a secondary side of the oxidation catalyst is decreased to substantially zero or a value equal to or lower than a predetermined value and a concentration of carbon monoxide on the secondary side of the oxidation catalyst is also decreased to substantially zero or a value equal to or lower than a predetermined value.
    • 首先,尽可能地将氮氧化物的排放量降低到接近零,一氧化碳的排放量降低到容许范围。 其次,实现了以低空气比燃烧的接近1.0的节能。 第三,在燃烧区域以低空气比稳定地进行空气比控制。 本发明包括:在燃烧器中燃烧含烃燃料的燃烧步骤,从而产生不含烃但含有氧,氮氧化物和一氧化碳的气体; 使气体与氧化催化剂接触的有害物质减少步骤,从而通过氧气氧化气体中包含的一氧化碳并用一氧化碳还原氮氧化物; 以及浓度比调节步骤,将氧化催化剂的一次侧的气体中的氧,氮氧化物和一氧化碳的浓度比调节至规定的浓度比,其中氧化催化剂的二次侧的氮氧化物的浓度 降低至基本为零或等于或低于预定值的值,并且氧化催化剂的二次侧的一氧化碳浓度也降低至基本为零或等于或低于预定值的值。
    • 2. 发明申请
    • COMBUSTION METHOD AND COMBUSTION APPARATUS
    • 燃烧方法和燃烧装置
    • US20100227283A1
    • 2010-09-09
    • US12162383
    • 2008-02-18
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • F23N5/26F23J15/02
    • F23J15/02B01D53/8646B01D2257/404B01D2257/502F22B21/04F22B37/008F23J2215/101F23J2215/40F23J2219/10
    • A combustion method applied to a water-tube boiler and a regenerator of an absorption-type refrigerator includes a concentration ratio adjusting step of adjusting a concentration ratio of nitrogen oxides, carbon monoxide, and oxygen in a gas from a gas generation source to a predetermined reference concentration ratio, and a hazardous-substance decreasing step of decreasing nitrogen oxides, using an oxidation catalyst having characteristics of decreasing the concentrations of nitrogen oxides and carbon monoxide on a secondary side to substantially zero when the concentration ratio on a primary side is set to be a reference concentration ratio, in which the concentration ratio adjusting step detects the concentration of oxygen on the secondary side of the oxidation catalyst to control the concentration ratio so that a detected oxygen concentration becomes a set oxygen concentration substantially close to zero. According to the combustion method, the emission amount of nitrogen oxides can be decreased to close to zero as much as possible, and the emission amount of carbon monoxide can be decreased to a permissible range. Further, the control of a concentration ratio can be performed stably by detecting the concentration of oxygen.
    • 应用于水管式锅炉和吸收式制冷机的再生器的燃烧方法包括浓度比调节步骤,其将来自气体发生源的气体中的氮氧化物,一氧化碳和氧气的浓度比调节至预定 使用具有将二次侧的氮氧化物和一氧化碳的浓度降低的特性的氧化催化剂在初级侧的浓度比设定为基本为零时的氧化物的降低的危险物质减少步骤 作为参考浓度比,其中浓度比调节步骤检测氧化催化剂的二次侧的氧浓度以控制浓度比,使得检测的氧浓度变为基本接近零的设定氧浓度。 根据该燃烧方法,氮氧化物的排出量尽可能地减少到接近零,一氧化碳的排放量可以降低到容许范围。 此外,可以通过检测氧浓度来稳定地进行浓度比的控制。
    • 5. 发明申请
    • METHOD OF TREATING NITROGEN OXIDE-CONTAINING GAS
    • 处理含氮氧化物的方法
    • US20110165048A1
    • 2011-07-07
    • US12158166
    • 2007-04-13
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • B01D53/56
    • B01D53/8625B01D53/8696F23C13/06F23C13/08F23J2219/10F23N1/022F23N5/006F23N2035/06F23N2035/10F23N2035/12F23N2037/12F23N2041/04
    • First, the emission amount of nitrogen oxides can be decreased close to zero as much as possible, and the emission amount of carbon monoxide is decreased to a permissible range. Second, energy saving by combustion at a low air ratio close to 1.0 is realized. Third, air ratio control is performed stably in a combustion region at a low air ratio.The present invention includes: a combustion step of burning hydrocarbon-containing fuel in the burner, thereby generating gas free of hydrocarbons but containing oxygen, nitrogen oxides, and carbon monoxide; a hazardous-substance decreasing step of bringing the gas into contact with an oxidation catalyst, thereby oxidizing carbon monoxide contained in the gas by oxygen and reducing nitrogen oxides by carbon monoxide; and a concentration ratio adjusting step of adjusting a concentration ratio of oxygen, nitrogen oxides, and carbon monoxide in gas on a primary side of the oxidation catalyst to a predetermined concentration ratio in which a concentration of nitrogen oxides on a secondary side of the oxidation catalyst is decreased to substantially zero or a value equal to or lower than a predetermined value and a concentration of carbon monoxide on the secondary side of the oxidation catalyst is also decreased to substantially zero or a value equal to or lower than a predetermined value.
    • 首先,尽可能地将氮氧化物的排放量降低到接近零,一氧化碳的排放量降低到容许范围。 其次,实现了以低空气比燃烧的接近1.0的节能。 第三,在燃烧区域以低空气比稳定地进行空气比控制。 本发明包括:在燃烧器中燃烧含烃燃料的燃烧步骤,从而产生不含烃但含有氧,氮氧化物和一氧化碳的气体; 使气体与氧化催化剂接触的有害物质减少步骤,从而通过氧气氧化气体中包含的一氧化碳并用一氧化碳还原氮氧化物; 以及浓度比调节步骤,将氧化催化剂的一次侧的气体中的氧,氮氧化物和一氧化碳的浓度比调节至规定的浓度比,其中氧化催化剂的二次侧的氮氧化物的浓度 降低至基本为零或等于或低于预定值的值,并且氧化催化剂的二次侧的一氧化碳浓度也降低至基本为零或等于或低于预定值的值。
    • 6. 发明申请
    • BOILER
    • 锅炉
    • US20090025655A1
    • 2009-01-29
    • US12282478
    • 2007-04-13
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • F24H9/20
    • B01D53/8625B01D53/8696F23N1/022F23N5/006F23N5/242F23N2035/06F23N2035/10F23N2035/12F23N2041/04
    • First, an emission amount of nitrogen oxide can be decreased to zero as much as possible and, an emission amount of carbon monoxide is decreased to a permissible range. Second, energy saving by combustion at a low air ratio close to 1.0 is realized. Third, air ratio control is performed stably in a combustion region at a low air ratio. Provided is a boiler, including: a premixed burner; a water pipe group for, by heat exchanging with a gas produced by the premixed burner, suppressing a temperature of the gas to thereby suppress a concentration of nitrogen oxide to a predetermined value or less; an oxidation catalyst for oxidizing carbon monoxide contained in the gas after the passage through the water pipe group by oxygen and for reducing nitrogen oxide contained therein by carbon monoxide; and an air-ratio adjusting device for adjusting an air ratio of the premixed burner, in which: the premixed burner and the water pipe group have such characteristics that when the air ratio is a set air ratio, a concentration ratio of oxygen, nitrogen oxides, and carbon monoxide in the gas on a primary side of the oxidation catalyst becomes a predetermined concentration ratio; the oxidation catalyst has such characteristics that when the concentration ratio is a predetermined concentration ratio, a concentration of nitrogen oxides on a secondary side of the oxidation catalyst is substantially zero while a concentration of carbon monoxide is decreased to substantially zero or a predetermined value or less; and the predetermined concentration ratio is kept to be constant by being controlled to the set air ratio by the air-ratio adjusting device.
    • 首先,尽可能地将氮氧化物的排放量减少到零,一氧化碳的排放量降低到容许范围。 其次,实现了以低空气比燃烧的接近1.0的节能。 第三,在燃烧区域以低空气比稳定地进行空气比控制。 提供锅炉,包括:预混燃烧器; 通过与由预混合燃烧器产生的气体进行热交换的水管组,抑制气体的温度从而将氮氧化物的浓度抑制在预定值以下; 氧化催化剂,用于氧化通过水管组后的气体中包含的一氧化碳,并通过一氧化碳还原氮氧化物; 以及用于调节预混燃烧器的空气比的空气比调节装置,其中:预混合燃烧器和水管组具有这样的特性,即当空气比是设定空气比时,氧,氮氧化物的浓度比 ,氧化催化剂的初级侧的气体中的一氧化碳成为规定的浓度比; 氧化催化剂具有以下特性:当浓度比为预定浓度比时,氧化催化剂的二次侧的氮氧化物的浓度基本为零,同时一氧化碳的浓度基本为零或预定值以下 ; 并且通过由空气比调节装置控制到设定空气比,预定浓度比保持恒定。
    • 7. 发明申请
    • BOILER
    • 锅炉
    • US20110088636A1
    • 2011-04-21
    • US12997362
    • 2009-04-09
    • Soji SumiYukihiro Tokunaga
    • Soji SumiYukihiro Tokunaga
    • F22B37/10
    • F22B21/065F22B37/101
    • The present invention relates to a various kinds of boilers including a steam boiler, a hot water boiler, a waste-heat boiler and an exhaust gas boiler. Projections are provided on a heat-transfer tube which connects an upper header and a lower header with each other such that a heat-transfer area pet unit length of the heat-transfer tube becomes smaller in an upstream region than that in a downstream region of combustion gas. It is preferable that installation pitches between adjacent upper and lower projections and/or projecting lengths of the projections from the heat-transfer tube are changed such that the heat-transfer area per unit length of the heat-transfer tube becomes smaller in the upstream region than those in the downstream region of the combustion gas.
    • 本发明涉及包括蒸汽锅炉,热水锅炉,废热锅炉和废气锅炉的各种锅炉。 在将上部集管和下部集管彼此连接的传热管上设置投影,使得传热管的传热区域宠物单位长度在上游区域比在下游区域 燃烧气体。 优选地,相邻的上下突起之间的安装间距和/或来自传热管的突起的突出长度改变,使得传热管的每单位长度的传热面积在上游区域变小 比在燃烧气体的下游区域。
    • 9. 发明授权
    • Combustion method and combustion apparatus
    • 燃烧方法和燃烧装置
    • US08113822B2
    • 2012-02-14
    • US12281556
    • 2007-04-13
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • F23N1/02F23N5/00F01N3/00F01N3/10B01D53/56
    • F23N1/022F23J2219/10F23N5/006F23N2035/06F23N2035/10F23N2035/12F23N2041/04
    • First, to decrease an amount of emitted nitrogen oxides to zero as much as possible and also decrease an amount of emitted carbon monoxide to a permissible level. Second, to save energy on combustion at a low air ratio close to 1.0. Third, to attain a stable air ratio control in a low air ratio combustion region.Included are a combustion step in which hydrocarbon-containing fuel is burned by the burner to generate gas free of hydrocarbons but containing oxygen, nitrogen oxides and carbon monoxide, an endothermic step in which endothermic device is used to absorb heat from gas generated in the combustion step, a hazardous-substance decreasing step in which the gas is brought into contact with an oxidation catalyst after the endothermic step to oxidize carbon monoxide contained in the gas by oxygen and reduce nitrogen oxides by carbon monoxide, and a concentration ratio adjusting step in which a concentration ratio of oxygen, nitrogen oxides and carbon monoxide in gas on the primary side of the oxidation catalyst is adjusted to a predetermined concentration ratio on the basis of concentration ratio characteristics of the burner and the endothermic device by using the air-ratio adjusting device of the burner.
    • 首先,将排出的氮氧化物的量尽可能多地减少到零,并且将排放的一氧化碳的量减少到允许的水平。 二是以低空气比接近1.0来节约能源燃烧。 第三,为了在低空气比燃烧区域中获得稳定的空气比控制。 包括燃烧步骤,其中含烃燃料由燃烧器燃烧以产生不含烃,但含有氧气,氮氧化物和一氧化碳的气体,吸热装置用于吸收燃烧产生的气体的吸热步骤 步骤,其中在吸热步骤之后气体与氧化催化剂接触以使氧气中的一氧化碳氧化并通过一氧化碳还原氮氧化物的危险物质减少步骤,以及浓缩比调节步骤,其中 基于燃烧器和吸热装置的浓度比特性,通过使用空气比调节装置将氧化催化剂的初级侧的气体中的氧气,氮氧化物和一氧化碳的浓度比调节至规定的浓度比 的燃烧器。
    • 10. 发明申请
    • COMBUSTION METHOD AND COMBUSTION APPARATUS
    • 燃烧方法和燃烧装置
    • US20090042152A1
    • 2009-02-12
    • US12281556
    • 2007-04-13
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • Osamu TanakaYukihiro TokunagaYusuke OkamotoKenji Yasui
    • F23N1/02F23N5/00F23C13/00F23C99/00
    • F23N1/022F23J2219/10F23N5/006F23N2035/06F23N2035/10F23N2035/12F23N2041/04
    • First, to decrease an amount of emitted nitrogen oxides to zero as much as possible and also decrease an amount of emitted carbon monoxide to a permissible level. Second, to save energy on combustion at a low air ratio close to 1.0. Third, to attain a stable air ratio control in a low air ratio combustion region.Included are a combustion step in which hydrocarbon-containing fuel is burned by the burner to generate gas free of hydrocarbons but containing oxygen, nitrogen oxides and carbon monoxide, an endothermic step in which endothermic device is used to absorb heat from gas generated in the combustion step, a hazardous-substance decreasing step in which the gas is brought into contact with an oxidation catalyst after the endothermic step to oxidize carbon monoxide contained in the gas by oxygen and reduce nitrogen oxides by carbon monoxide, and a concentration ratio adjusting step in which a concentration ratio of oxygen, nitrogen oxides and carbon monoxide in gas on the primary side of the oxidation catalyst is adjusted to a predetermined concentration ratio on the basis of concentration ratio characteristics of the burner and the endothermic device by using the air-ratio adjusting device of the burner.
    • 首先,将排出的氮氧化物的量尽可能多地减少到零,并且将排放的一氧化碳的量减少到允许的水平。 二是以低空气比接近1.0来节约能源燃烧。 第三,为了在低空气比燃烧区域中获得稳定的空气比控制。 包括燃烧步骤,其中含烃燃料由燃烧器燃烧以产生不含烃,但含有氧气,氮氧化物和一氧化碳的气体,吸热装置用于吸收燃烧产生的气体的吸热步骤 步骤,其中在吸热步骤之后气体与氧化催化剂接触以使氧气中的一氧化碳氧化并通过一氧化碳还原氮氧化物的危险物质减少步骤,以及浓缩比调节步骤,其中 基于燃烧器和吸热装置的浓度比特性,通过使用空气比调节装置将氧化催化剂的初级侧的气体中的氧气,氮氧化物和一氧化碳的浓度比调节至规定的浓度比 的燃烧器。