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1. 发明授权

US08749868B2 Electrochromic devices 有权
公开(公告)号：US08749868B2
公开(公告)日：2014-06-10
申请号：US13610684
申请日：2012-09-11
申请人： Zhongchun Wang , Anshu Pradhan , Robert Rozbicki
发明人： Zhongchun Wang , Anshu Pradhan , Robert Rozbicki
IPC分类号： G02F1/15
CPC分类号： G02F1/155 , C23C14/083 , C23C14/34 , C23C14/5806 , G02F1/1508 , G02F1/1523 , G02F1/153 , G02F2001/1555 , H01J37/3426
摘要： Conventional electrochromic devices frequently suffer from poor reliability and poor performance. Improvements are made using entirely solid and inorganic materials. Electrochromic devices are fabricated by forming an ion conducting electronically insulating interfacial region that serves as an IC layer. In some methods, the interfacial region is formed after formation of an electrochromic and a counter electrode layer. The interfacial region contains an ion conducting electronically insulating material along with components of the electrochromic and/or the counter electrode layer. Materials and microstructure of the electrochromic devices provide improvements in performance and reliability over conventional devices.

2. 发明授权

US08389715B1 Method for forming cooperative binary ionic solids 有权
标题翻译：形成合成二元离子固体的方法
公开(公告)号：US08389715B1
公开(公告)日：2013-03-05
申请号：US12756744
申请日：2010-04-08
申请人： John A. Shelnutt , Kathleen E. Martin , Zhongchun Wang , Craig J. Medforth
发明人： John A. Shelnutt , Kathleen E. Martin , Zhongchun Wang , Craig J. Medforth
IPC分类号： C07D487/00 , C07B47/00
CPC分类号： C07D487/22
摘要： A nanostructured molecular unit and method for forming is described where a cationic porphyrin having an ethanolic substituent species and a metal in the porphyrin cavity is combined with an anionic porphyrin having a sulfonate substituent species and a metal in the porphyrin cavity to form by self-assembly a nanostructured molecular unit with a morphology comprising four dendritic elements connected at a central node.
摘要翻译：描述了纳米结构分子单元和形成方法，其中在卟啉空腔中具有乙醇取代基物质和金属的阳离子卟啉与卟啉空穴中具有磺酸盐取代基物质和金属的阴离子卟啉与自组装形成具有形式的纳米结构分子单元，其包含在中心节点处连接的四个树突状元件。

3. 发明授权

US08228592B2 Electrochromic devices 有权
公开(公告)号：US08228592B2
公开(公告)日：2012-07-24
申请号：US13166537
申请日：2011-06-22
申请人： Zhongchun Wang , Anshu Pradhan , Robert T Rozbicki
发明人： Zhongchun Wang , Anshu Pradhan , Robert T Rozbicki
IPC分类号： G02F1/153
CPC分类号： G02F1/155 , C23C14/083 , C23C14/34 , C23C14/5806 , G02F1/1508 , G02F1/1523 , G02F1/153 , G02F2001/1555 , H01J37/3426
摘要： Conventional electrochromic devices frequently suffer from poor reliability and poor performance. Improvements are made using entirely solid and inorganic materials. Electrochromic devices are fabricated by forming an ion conducting electronically insulating interfacial region that serves as an IC layer. In some methods, the interfacial region is formed after formation of an electrochromic and a counter electrode layer. The interfacial region contains an ion conducting electronically insulating material along with components of the electrochromic and/or the counter electrode layer. Materials and microstructure of the electrochromic devices provide improvements in performance and reliability over conventional devices.

4. 发明申请

US20100079845A1 Reflection-Controllable Electrochromic Device Using A Base Metal As A Transparent Conductor 有权
标题翻译：使用基础金属作为透明导体的可反射控制电致变色装置
公开(公告)号：US20100079845A1
公开(公告)日：2010-04-01
申请号：US12242917
申请日：2008-10-01
申请人： Zhongchun Wang , Paul P. Nguyen
发明人： Zhongchun Wang , Paul P. Nguyen
IPC分类号： G02F1/153
CPC分类号： G02F1/155 , G02F1/19
摘要： An all-solid-state electrochromic device comprises a transparent base material, and an electrochromic multilayer-stack structure formed on the transparent base material. The electrochromic multilayer-stack structure comprises a first transparent-conductive film formed on the transparent base material, an ion-storage layer formed on the first transparent-conductive film, a solid-electrolyte layer formed on the ion-storage layer, and an electrochromic layer formed on the solid-electrolyte layer. The electrochromic layer comprises a reflection-controllable electrochromic layer. In one exemplary embodiment, the electrochromic layer comprises a reflection-controllable layer that comprises at least one of antimony and an antimony-based alloy. A second transparent-conductive film can be formed on the reflection-controllable layer, or between the reflection-controllable layer and the solid-electrolyte layer. In one exemplary embodiment, the second transparent-conductive layer comprises a base metal and/or a base metal alloy.
摘要翻译：全固体电致变色装置包括透明基材和形成在透明基材上的电致变色多层堆叠结构。电致变色多层堆叠结构包括形成在透明基材上的第一透明导电膜，形成在第一透明导电膜上的离子存储层，形成在离子保存层上的固体电解质层和电致变色层，形成在固体电解质层上。电致变色层包括反射可控电致变色层。在一个示例性实施例中，电致变色层包括反射可控层，其包含锑和锑基合金中的至少一种。第二透明导电膜可以形成在反射可控层上，或反射可控层和固体电解质层之间。在一个示例性实施例中，第二透明导电层包括贱金属和/或贱金属合金。

5. 发明授权

US08582193B2 Electrochromic devices 有权
公开(公告)号：US08582193B2
公开(公告)日：2013-11-12
申请号：US12772075
申请日：2010-04-30
申请人： Zhongchun Wang , Anshu Pradhan , Robert Rozbicki
发明人： Zhongchun Wang , Anshu Pradhan , Robert Rozbicki
IPC分类号： G02F1/153
CPC分类号： G02F1/155 , C23C14/083 , C23C14/34 , C23C14/5806 , G02F1/1508 , G02F1/1523 , G02F1/153 , G02F2001/1555 , H01J37/3426
摘要： Conventional electrochromic devices frequently suffer from poor reliability and poor performance. Improvements are made using entirely solid and inorganic materials. Electrochromic devices are fabricated by forming an ion conducting electronically insulating interfacial region that serves as an IC layer. In some methods, the interfacial region is formed after formation of an electrochromic and a counter electrode layer. The interfacial region contains an ion conducting electronically insulating material along with components of the electrochromic and/or the counter electrode layer. Materials and microstructure of the electrochromic devices provide improvements in performance and reliability over conventional devices.

6. 发明申请

US20130003157A1 ELECTROCHROMIC DEVICES 有权
标题翻译：电致发光器件
公开(公告)号：US20130003157A1
公开(公告)日：2013-01-03
申请号：US13610684
申请日：2012-09-11
申请人： Zhongchun Wang , Anshu Pradhan , Robert Rozbicki
发明人： Zhongchun Wang , Anshu Pradhan , Robert Rozbicki
IPC分类号： G02F1/153 , C23C14/06 , C23C14/34
CPC分类号： G02F1/155 , C23C14/083 , C23C14/34 , C23C14/5806 , G02F1/1508 , G02F1/1523 , G02F1/153 , G02F2001/1555 , H01J37/3426
摘要： Conventional electrochromic devices frequently suffer from poor reliability and poor performance. Improvements are made using entirely solid and inorganic materials. Electrochromic devices are fabricated by forming an ion conducting electronically insulating interfacial region that serves as an IC layer. In some methods, the interfacial region is formed after formation of an electrochromic and a counter electrode layer. The interfacial region contains an ion conducting electronically insulating material along with components of the electrochromic and/or the counter electrode layer. Materials and microstructure of the electrochromic devices provide improvements in performance and reliability over conventional devices.
摘要翻译：常规的电致变色器件经常具有差的可靠性和差的性能。使用完全固体和无机材料进行改进。通过形成用作IC层的离子传导电绝缘界面区域来制造电致变色器件。在一些方法中，在形成电致变色剂和对电极层之后形成界面区域。界面区域包含离子传导电绝缘材料以及电致变色和/或对电极层的组分。与常规设备相比，电致变色器件的材料和微结构提供了性能和可靠性的改进。

7. 发明授权

US08324342B1 Porphyrin coordination polymer nanospheres and nanorods 有权
标题翻译：卟啉配位聚合物纳米球和纳米棒
公开(公告)号：US08324342B1
公开(公告)日：2012-12-04
申请号：US11762512
申请日：2007-06-13
申请人： Zhongchun Wang , John A. Shelnutt , Craig J. Medforth
发明人： Zhongchun Wang , John A. Shelnutt , Craig J. Medforth
IPC分类号： C08G79/00 , C09B62/00 , C09B47/04 , C07D487/22
CPC分类号： C07D487/22 , C09B47/00
摘要： A porphyrin coordination polymer nanostructure comprising a network of pyridyl porphyrin molecules and coordinating metal ions coordinatively bound through the pyridyl groups. In some embodiments, the porphyrins are metalloporphyrins. A variety of nanostructures are formed by the network polymer, including nanospheres, polygonal nanostructures, nanorods, and nanofibers, depending on a variety of factors including coordination metal ion, porphyrin type, metal of the metalloporphyrin, and degree of agitation during nanostructure formation. Reduction of coordinating metal ions may be used to form metal nanoparticles on the coordination polymer nanostructure.
摘要翻译：卟啉配位聚合物纳米结构，其包含吡啶基卟啉分子网络和通过吡啶基配位结合的配位金属离子。在一些实施方案中，卟啉是金属卟啉。取决于多种因素，包括配位金属离子，卟啉型，金属卟啉金属和纳米结构形成过程中的搅拌程度，由网络聚合物形成多种纳米结构，包括纳米球，多边形纳米结构，纳米棒和纳米纤维。配位金属离子的还原可用于在配位聚合物纳米结构上形成金属纳米颗粒。

8. 发明申请

US20110249314A1 ELECTROCHROMIC DEVICES 有权
标题翻译：电致发光器件
公开(公告)号：US20110249314A1
公开(公告)日：2011-10-13
申请号：US13166537
申请日：2011-06-22
申请人： Zhongchun Wang , Anshu Pradhan , Robert Rozbicki
发明人： Zhongchun Wang , Anshu Pradhan , Robert Rozbicki
IPC分类号： G02F1/153
CPC分类号： G02F1/155 , C23C14/083 , C23C14/34 , C23C14/5806 , G02F1/1508 , G02F1/1523 , G02F1/153 , G02F2001/1555 , H01J37/3426
摘要： Conventional electrochromic devices frequently suffer from poor reliability and poor performance. Improvements are made using entirely solid and inorganic materials. Electrochromic devices are fabricated by forming an ion conducting electronically insulating interfacial region that serves as an IC layer. In some methods, the interfacial region is formed after formation of an electrochromic and a counter electrode layer. The interfacial region contains an ion conducting electronically insulating material along with components of the electrochromic and/or the counter electrode layer. Materials and microstructure of the electrochromic devices provide improvements in performance and reliability over conventional devices.
摘要翻译：常规的电致变色器件经常具有差的可靠性和差的性能。使用完全固体和无机材料进行改进。通过形成用作IC层的离子传导电绝缘界面区域来制造电致变色器件。在一些方法中，在形成电致变色剂和对电极层之后形成界面区域。界面区域包含离子传导电绝缘材料以及电致变色和/或对电极层的组分。与常规设备相比，电致变色器件的材料和微结构提供了性能和可靠性的改进。

9. 发明授权

US07338590B1 Water-splitting using photocatalytic porphyrin-nanotube composite devices 有权
标题翻译：使用光催化卟啉 - 纳米管复合器件进行水分解
公开(公告)号：US07338590B1
公开(公告)日：2008-03-04
申请号：US11256808
申请日：2005-10-25
申请人： John A. Shelnutt , James E. Miller , Zhongchun Wang , Craig J. Medforth
发明人： John A. Shelnutt , James E. Miller , Zhongchun Wang , Craig J. Medforth
IPC分类号： C25B1/02
CPC分类号： C25B1/003 , B01J31/003 , B01J31/1815 , B01J35/004 , B01J2231/62 , B01J2531/025 , B01J2531/824 , B01J2531/828 , B01J2531/845 , B01J2531/847 , B82Y30/00 , Y02E60/368
摘要： A method for generating hydrogen by photocatalytic decomposition of water using porphyrin nanotube composites. In some embodiments, both hydrogen and oxygen are generated by photocatalytic decomposition of water.
摘要翻译：一种使用卟啉纳米管复合材料通过光催化分解水生产氢的方法。在一些实施方案中，通过水的光催化分解产生氢和氧。

10. 发明申请

US20210320324A1 MULTILAYER SOLID-STATE ELECTROLYTE, BATTERY CELLS INCLUDING THE SAME, AND METHODS OF MAKING THE SAME 有权
公开(公告)号：US20210320324A1
公开(公告)日：2021-10-14
申请号：US17185159
申请日：2021-02-25
申请人： Zhongchun WANG , Arvind KAMATH
发明人： Zhongchun WANG , Arvind KAMATH
IPC分类号： H01M10/0562 , H01M10/0525 , H01M10/0585 , H01M4/36 , H01M4/62
摘要： A multilayer solid-state electrolyte, solid-state battery cells including the same, and methods of making the electrolyte and the battery cells are disclosed. The multi-layer solid-state electrolyte includes a solid bulk electrolyte layer comprising carbon-doped lithium phosphorus oxynitride (LiPON) or WO3+x (where 0≤x≤1), and a solid anode interface layer comprising LiPON or a metal oxide that forms a stable complex oxide with lithium oxide and conducts lithium ions when lithiated. The anode interface layer has a thickness less than that of the bulk electrolyte layer. The method of making the multi-layer solid-state electrolyte includes depositing one of the solid bulk electrolyte layer and the solid anode interface layer on an active layer of a battery cell, then depositing the other layer on the one layer. As for the solid-state electrolyte, the anode interface layer has a thickness less than that of the bulk electrolyte layer.

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