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    • 2. 发明授权
    • Oxygen assisted organosolv process, system and method for delignification of lignocellulosic materials and lignin recovery
    • 氧辅助有机溶剂法,木质纤维素材脱木质素和木质素回收系统及方法
    • US09382283B2
    • 2016-07-05
    • US14449812
    • 2014-08-01
    • American Science and Technology Corporation
    • Ali ManeshJohn H. GuentherEdwin G. ZoborowskiWalter BraennerMohammad Ali ManeshLee J. Hawk
    • C07G1/00C08L97/00D21C3/00C08H8/00D21C1/00C08H7/00
    • C07G1/00C08H6/00C08H8/00C08L97/005D21C1/00D21C3/00
    • An oxygen assisted Organosolv process for a more efficient delignification and producing bio-products by decomposing lignocellulosic materials comprises providing a lignin solvent with water, an acid, an oxidant and one or more lignin dissolving chemicals. The process also includes placing biomass in contact with oxidant, acid, water, the lignin solvent in any order or combined to form a recyclable solvent, and recycling at least a portion of the recyclable solvent by circulating the recyclable solvent back into contact with the biomass. The circulating of the recyclable solvent occurs for a period of time, during which, acid and oxidant may be added if necessary as they may be consumed by the process, after which, the process then includes separating material such as chemicals and lignin from the recyclable solvent. The chemicals can be recycled as new lignin dissolving solvent or sold, while lignin can be used as natural and renewable colorant for polymers such as poly lactic acid, or mixed with other polymers as an additive and extruded or injected to consumable polymeric parts, or can be used and the natural source of renewable aromatics. Application of an oxidant will help the overall fractionation process by changing the chemical characteristics of the lignin and therefore allows more lignin to be removed from biomass. At the end, the lignin is separated from the lignin dissolving solvent by a separation process to also reclaim the lignin dissolving solvent for the next fractionation process.
    • 用于通过分解木质纤维素材料更有效脱木质素和生产生物产物的氧辅助有机溶剂法包括提供木质素溶剂与水,酸,氧化剂和一种或多种木质素溶解化学品。 该方法还包括将生物质以任何顺序与氧化剂,酸,水,木质素溶剂接触,或者组合形成可再循环溶剂,并通过使可回收利用的溶剂循环回生物质而回收至少一部分可再循环溶剂 。 可回收溶剂的循环发生一段时间,在此期间,如果需要,可以加入酸和氧化剂,因为它们可能被该方法消耗,之后,该方法包括从可再循环的方法分离诸如化学品和木质素的材料 溶剂。 化学品可以作为新的木质素溶解溶剂再循环或出售,而木质素可以用作聚合物如聚乳酸的天然和可再生着色剂,或与其他聚合物作为添加剂混合并挤出或注入消耗性聚合物部件,或者可以 被使用和再生芳烃的天然来源。 氧化剂的应用将通过改变木质素的化学特性来帮助整个分馏过程,从而允许从生物质中除去更多的木质素。 最后,通过分离方法将木质素与木质素溶解溶剂分离,还回收木质素溶解溶剂用于下一分馏过程。