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    • 10. 发明申请
    • POLY(ARYL ETHER SULFONE) COMPOSITION AND METHOD OF MAKING
    • POLY(ARYL ETHER SUFFONE)组合物及其制备方法
    • US20140350207A1
    • 2014-11-27
    • US14263063
    • 2014-04-28
    • Eric Lee LutzWilliam Hoy HeathRoy Ray OdleThomas Link GuggenheimJuan Justino Rodriguez OrdonezJose Roman Galdamez Pena
    • Eric Lee LutzWilliam Hoy HeathRoy Ray OdleThomas Link GuggenheimJuan Justino Rodriguez OrdonezJose Roman Galdamez Pena
    • C08G75/23
    • C08G75/23C08G65/00C08G65/40C08G65/4056
    • A poly(aryl ether sulfone) comprises units of formula (I): wherein Ar1 is a divalent C6-C15 aromatic group, Ar2 is a divalent C6-C15 aromatic group, Ar3 is a divalent C6-C15 aromatic group, and n is greater than 1;and a terminal group of formula (II) derived from a monofunctional phenoxide wherein is X is a hydrogen atom or an organic substituent having from 1 to 20 carbon atoms; wherein the poly(aryl ether sulfone) has a hydroxyl group content greater than 0 and less than 50 parts per million (ppm), based on the poly(aryl ether sulfone) weight, a glass transition temperature of 180 to 290° C., a weight average molecular weight of 20,000 to 100,000, a halogen content of greater than 0 and less than 3000 ppm based on the poly(aryl ether sulfone) weight. The poly(aryl ether sulfone) can have a thermal stability factor greater than or equal to 90%. The poly(aryl ether sulfone) can have a yellowness index (YI) less than 120 after an article made from the poly(aryl ether sulfone) is exposed to a temperature of 200° C. in ambient air for 28 days. The poly(aryl ether sulfone) is free of methoxy groups. Methods of making the polymer are also disclosed.
    • 聚(芳基醚砜)包括式(I)的单元:其中Ar1是二价C 6 -C 15芳族基团,Ar 2是二价C 6 -C 15芳族基团,Ar 3是二价C 6 -C 15芳族基团,n大于 比1; 和衍生自单官能酚盐的式(II)的末端基团,其中X为氢原子或具有1至20个碳原子的有机取代基; 其中聚(芳基醚砜)的羟基含量大于0且小于50ppm(ppm),基于聚(芳基醚砜)重量,玻璃化转变温度为180-290℃, 重均分子量为20,000至100,000,卤素含量大于0且小于3000ppm,基于聚(芳基醚砜)重量。 聚(芳基醚砜)可以具有大于或等于90%的热稳定性因子。 在由聚(芳基醚砜)制成的制品在环境空气中暴露于200℃的温度下,聚(芳基醚砜)可以具有小于120的黄色指数(YI)28天。 聚(芳基醚砜)不含甲氧基。 还公开了制备聚合物的方法。