专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

US20090292085A1 Polymerization processes for broadened molecular weight distribution 有权
标题翻译：用于扩大分子量分布的聚合方法
公开(公告)号：US20090292085A1
公开(公告)日：2009-11-26
申请号：US12454514
申请日：2009-05-19
申请人： Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Patrick Brant , James Richardson Lattner
发明人： Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Patrick Brant , James Richardson Lattner
IPC分类号： C08F2/01
CPC分类号： C08F10/00 , C08F110/06 , C08F2/06 , C08F2/01 , C08F2500/04
摘要： Provided are methods of producing polymers with broadened molecular weight and/or composition distribution in a continuous homogeneous polymerization system utilizing reactor temperature gradients, reactor polymer concentration gradients, monomer concentration gradients, catalyst concentration gradients, and combinations thereof in the polymerization reactor. Such methods are particularly suitable when utilizing metallocene catalysts and other single-site catalysts, which generally produce polymers with narrow molecular weight and composition distribution.
摘要翻译：提供了在聚合反应器中使用反应器温度梯度，反应器聚合物浓度梯度，单体浓度梯度，催化剂浓度梯度及其组合的连续均匀聚合体系中制备具有更宽分子量和/或组成分布的聚合物的方法。当使用茂金属催化剂和其它通常产生具有窄分子量和组成分布的聚合物的其它单中心催化剂时，这些方法是特别合适的。

2. 发明申请

US20110196115A1 POLYMERIZATION PROCESSES FOR BROADENED MOLECULAR WEIGHT DISTRIBUTION 有权
标题翻译：广泛分子量分布的聚合方法
公开(公告)号：US20110196115A1
公开(公告)日：2011-08-11
申请号：US13088622
申请日：2011-04-18
申请人： Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Patrick Brant , James Richardson Lattner
发明人： Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Patrick Brant , James Richardson Lattner
IPC分类号： C08F4/00 , C08F4/42
CPC分类号： C08F10/00 , C08F110/06 , C08F2/06 , C08F2/01 , C08F2500/04
摘要： Provided are methods of producing polymers with broadened molecular weight and/or composition distribution in a continuous homogeneous polymerization system utilizing reactor temperature gradients, reactor polymer concentration gradients, monomer concentration gradients, catalyst concentration gradients, and combinations thereof in the polymerization reactor. Such methods are particularly suitable when utilizing metallocene catalysts and other single-site catalysts, which generally produce polymers with narrow molecular weight and composition distribution.
摘要翻译：提供了在聚合反应器中使用反应器温度梯度，反应器聚合物浓度梯度，单体浓度梯度，催化剂浓度梯度及其组合的连续均匀聚合体系中制备具有更宽分子量和/或组成分布的聚合物的方法。当使用茂金属催化剂和其它通常产生具有窄分子量和组成分布的聚合物的其它单中心催化剂时，这些方法是特别合适的。

3. 发明申请

US20110196116A1 POLYMERIZATION PROCESSES FOR BROADENED MOLECULAR WEIGHT DISTRIBUTION 审中-公开
公开(公告)号：US20110196116A1
公开(公告)日：2011-08-11
申请号：US13088642
申请日：2011-04-18
申请人： Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Patrick Brant , James Richardson Lattner
发明人： Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Patrick Brant , James Richardson Lattner
IPC分类号： C08F4/00 , C08F4/42
CPC分类号： C08F10/00 , C08F110/06 , C08F2/06 , C08F2/01 , C08F2500/04
摘要： Provided are methods of producing polymers with broadened molecular weight and/or composition distribution in a continuous homogeneous polymerization system utilizing reactor temperature gradients, reactor polymer concentration gradients, monomer concentration gradients, catalyst concentration gradients, and combinations thereof in the polymerization reactor. Such methods are particularly suitable when utilizing metallocene catalysts and other single-site catalysts, which generally produce polymers with narrow molecular weight and composition distribution.

4. 发明授权

US07939610B2 Polymerization processes for broadened molecular weight distribution 有权
标题翻译：用于扩大分子量分布的聚合方法
公开(公告)号：US07939610B2
公开(公告)日：2011-05-10
申请号：US12454514
申请日：2009-05-19
申请人： Gabor Kiss , Robert Patrick Reynolds, Jr. , John W. Chu , Patrick Brant , James Richardson Lattner
发明人： Gabor Kiss , Robert Patrick Reynolds, Jr. , John W. Chu , Patrick Brant , James Richardson Lattner
IPC分类号： C08F2/00 , C08F4/00 , C08F110/06
CPC分类号： C08F10/00 , C08F110/06 , C08F2/06 , C08F2/01 , C08F2500/04
摘要： Provided are methods of producing polymers with broadened molecular weight and/or composition distribution in a continuous homogeneous polymerization system utilizing reactor temperature gradients, reactor polymer concentration gradients, monomer concentration gradients, catalyst concentration gradients, and combinations thereof in the polymerization reactor. Such methods are particularly suitable when utilizing metallocene catalysts and other single-site catalysts, which generally produce polymers with narrow molecular weight and composition distribution.
摘要翻译：提供了在聚合反应器中使用反应器温度梯度，反应器聚合物浓度梯度，单体浓度梯度，催化剂浓度梯度及其组合的连续均匀聚合体系中制备具有更宽分子量和/或组成分布的聚合物的方法。当使用茂金属催化剂和其它通常产生具有窄分子量和组成分布的聚合物的其它单中心催化剂时，这些方法是特别合适的。

5. 发明授权

US08410230B2 Polymerization processes for broadened molecular weight distribution 有权
公开(公告)号：US08410230B2
公开(公告)日：2013-04-02
申请号：US13088622
申请日：2011-04-18
申请人： Gabor Kiss , Robert Patrick Reynolds, Jr. , John W. Chu , Patrick Brant , James Richardson Lattner
发明人： Gabor Kiss , Robert Patrick Reynolds, Jr. , John W. Chu , Patrick Brant , James Richardson Lattner
IPC分类号： C08F2/00
CPC分类号： C08F10/00 , C08F110/06 , C08F2/06 , C08F2/01 , C08F2500/04
摘要： Provided are methods of producing polymers with broadened molecular weight and/or composition distribution in a continuous homogeneous polymerization system utilizing reactor temperature gradients, reactor polymer concentration gradients, monomer concentration gradients, catalyst concentration gradients, and combinations thereof in the polymerization reactor. Such methods are particularly suitable when utilizing metallocene catalysts and other single-site catalysts, which generally produce polymers with narrow molecular weight and composition distribution.

6. 发明申请

US20090163678A1 Bulk homogeneous polymerization process for ethylene propylene copolymers 有权
标题翻译：乙烯丙烯共聚物的均匀聚合方法
公开(公告)号：US20090163678A1
公开(公告)日：2009-06-25
申请号：US12291898
申请日：2008-11-14
申请人： Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Steven P. Rucker , James Richardson Lattner
发明人： Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Steven P. Rucker , James Richardson Lattner
IPC分类号： C08F2/01 , C08F4/06 , C08F210/02
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65927 , C08F210/06 , Y10S526/902 , C08F2/02 , C08F2/14 , C08F2500/03 , C08F2500/12
摘要： Provided are bulk homogeneous polymerization processes for producing ethylene propylene random copolymers. The process includes contacting in a reactor or in a series of reactors propylene monomer, ethylene comonomer with one or more catalyst systems and optional solvent (present at less than 40 wt %), wherein the reactor train is at a temperature of between 65° C. and 180° C. and at a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, and wherein the polymerization system for the reactor train is in its dense fluid state to form a polymer reactor effluent including a homogeneous fluid phase polymer-monomer mixture in the reactor train; and wherein the resultant copolymer product comprises between 10 wt % and 20 wt % randomly distributed ethylene and the concentration of total region defects in the continuous propylene segments of the random EP copolymer is between 40 and 150% greater than in a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.
摘要翻译：提供用于生产乙烯丙烯无规共聚物的本体均相聚合方法。该方法包括使反应器或一系列反应器中的丙烯单体，乙烯共聚单体与一种或多种催化剂体系和任选的溶剂（以小于40wt％存在）接触，其中反应器系在65℃ 并且在低于聚合体系的浊点压力不低于10MPa的压力下低于1500MPa，并且其中反应器系列的聚合系统处于其致密的流体状态以形成聚合物反应器流出物包括在反应器系列中的均相流体相聚合物 - 单体混合物; 并且其中所得共聚物产物包含10重量％至20重量％的随机分布的乙烯，并且随机EP共聚物的连续丙烯链段中总区域缺陷的浓度比当量熔体流动的共聚物中的区域间缺陷的浓度高40至150％速率和wt％乙烯通过溶液聚合方法聚合。

7. 发明授权

US08399586B2 Process for feeding ethylene to polymerization reactors 有权
标题翻译：将乙烯供给聚合反应器的方法
公开(公告)号：US08399586B2
公开(公告)日：2013-03-19
申请号：US12584338
申请日：2009-09-03
申请人： Gabor Kiss , Robert Patrick Reynolds, Jr. , John W. Chu , James Richardson Lattner , Gary D. Mohr
发明人： Gabor Kiss , Robert Patrick Reynolds, Jr. , John W. Chu , James Richardson Lattner , Gary D. Mohr
IPC分类号： C08F2/00 , C08F4/00 , C08F36/00 , C08F110/06 , C08F110/02
CPC分类号： C08F10/02 , C08F110/02 , C08F210/16 , Y02P20/544 , C08F2/06 , C08F2/01 , C08F2500/12 , C08F210/06 , C08F2/00
摘要： A process for feeding ethylene into a polymerization system includes providing a low-pressure ethylene stream, one or more low-pressure C3 to C20 monomer streams, an optional low-pressure inert solvent/diluent stream, and one or more reactors; metering the low-pressure ethylene stream, the one or more low-pressure C3 to C20 monomer streams, and the optional low-pressure inert solvent/diluent stream; blending the metered low-pressure ethylene stream, the metered one or more low-pressure C3 to C20 monomer streams, and the metered low-pressure optional inert solvent/diluent stream to form an ethylene-carrying low-pressure blended liquid feed stream; pressurizing the ethylene-carrying low-pressure blended liquid feed stream to the polymerization system pressure with one or more high-pressure pumps to thrm an ethylene-carrying high-pressure blended reactor feed stream; and feeding the ethylene-carrying high-pressure blended reactor feed stream to the one or more reactors.
摘要翻译：将乙烯进料到聚合体系中的方法包括提供低压乙烯流，一种或多种低压C3至C20单体流，任选的低压惰性溶剂/稀释剂流和一个或多个反应器; 计量低压乙烯流，一个或多个低压C3至C20单体流和任选的低压惰性溶剂/稀释剂流; 混合计量的低压乙烯流，计量的一个或多个低压C3至C20单体流和计量的低压可选惰性溶剂/稀释剂流，以形成携带乙烯的低压混合液体进料流; 使用一个或多个高压泵将携带乙烯的低压混合液体进料流加压至聚合系统压力以加入携带乙烯的高压共混反应器进料流; 并将含乙烯的高压共混反应器进料流输送到一个或多个反应器。

8. 发明授权

US07910679B2 Bulk homogeneous polymerization process for ethylene propylene copolymers 有权
标题翻译：乙烯丙烯共聚物的均匀聚合方法
公开(公告)号：US07910679B2
公开(公告)日：2011-03-22
申请号：US12291898
申请日：2008-11-14
申请人： Gabor Kiss , Robert Patrick Reynolds, Jr. , John W. Chu , Steven P. Rucker , James Richardson Lattner
发明人： Gabor Kiss , Robert Patrick Reynolds, Jr. , John W. Chu , Steven P. Rucker , James Richardson Lattner
IPC分类号： C08F2/02 , C08F210/06 , C08F4/643
CPC分类号： C08F210/16 , C08F4/65908 , C08F4/65927 , C08F210/06 , Y10S526/902 , C08F2/02 , C08F2/14 , C08F2500/03 , C08F2500/12
摘要： Provided are bulk homogeneous polymerization processes for producing ethylene propylene random copolymers. The process includes contacting in a reactor or in a series of reactors propylene monomer, ethylene comonomer with one or more catalyst systems and optional solvent (present at less than 40 wt %), wherein the reactor train is at a temperature of between 65° C. and 180° C. and at a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa, and wherein the polymerization system for the reactor train is in its dense fluid state to form a polymer reactor effluent including a homogeneous fluid phase polymer-monomer mixture in the reactor train; and wherein the resultant copolymer product comprises between 10 wt % and 20 wt % randomly distributed ethylene and the concentration of total region defects in the continuous propylene segments of the random EP copolymer is between 40 and 150% greater than in a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.
摘要翻译：提供用于生产乙烯丙烯无规共聚物的本体均相聚合方法。该方法包括使反应器或一系列反应器中的丙烯单体，乙烯共聚单体与一种或多种催化剂体系和任选的溶剂（以小于40wt％存在）接触，其中反应器系在65℃ 并且在低于聚合体系的浊点压力不低于10MPa的压力下低于1500MPa，并且其中反应器系列的聚合系统处于其致密的流体状态以形成聚合物反应器流出物包括在反应器系列中的均相流体相聚合物 - 单体混合物; 并且其中所得共聚物产物包含10重量％至20重量％的随机分布的乙烯，并且随机EP共聚物的连续丙烯链段中总区域缺陷的浓度比当量熔体流动的共聚物中的区域间缺陷的浓度高40至150％速率和wt％乙烯通过溶液聚合方法聚合。

9. 发明授权

US07928162B2 In-line process for producing plasticized polymers and plasticized polymer blends 有权
标题翻译：用于生产增塑聚合物和增塑聚合物共混物的在线方法
公开(公告)号：US07928162B2
公开(公告)日：2011-04-19
申请号：US12283045
申请日：2008-09-09
申请人： Gabor Kiss , Alan Anthony Galuska , Robert Patrick Reynolds, Jr. , John W. Chu , Bryan R. Chapman , Patrick Brant , Sudhin Datta
发明人： Gabor Kiss , Alan Anthony Galuska , Robert Patrick Reynolds, Jr. , John W. Chu , Bryan R. Chapman , Patrick Brant , Sudhin Datta
IPC分类号： C08F2/12 , C08F6/00 , C08L23/02
CPC分类号： C08F10/00 , B01J2219/00038 , B01J2219/0004 , C08F210/16 , C08J3/18 , C08F2/01 , C08F2/001 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/20
摘要： A process for fluid phase in-line blending of plasticized polymers is provided. The process includes providing two or more reactor trains configured in parallel and a separator for product blending and product-feed separation, wherein one or more of the reactor trains produces one or more polymers and one or more of the reactor trains produces one or more plasticizers; contacting in at least one of the parallel reactor trains olefin monomers, catalyst systems, optional comonomers, optional scavengers, and optional diluents or solvents, at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa; forming a reactor effluent including a homogeneous fluid phase polymer-monomer mixture and plasticizer-monomer mixture in each parallel reactor train; passing the reactor effluents through the separator; maintaining the temperature and pressure within the separator above the solid-fluid phase transition point but below the cloud point pressure and temperature to form a fluid-fluid two-phase system including a plasticized polymer-rich blend phase and a monomer-rich phase; and separating the monomer-rich phase from the plasticized polymer-rich blend phase. The polymer-rich blend phase is conveyed to a downstream finishing stage for further monomer stripping, drying and/or pelletizing to form a plasticized polymer product blend. Suitable plasticizers for in-line production and blending include polyalphaolefin oligomers, polybutenes, low glass transition temperature polymers and combinations thereof.
摘要翻译：提供了一种用于增塑聚合物的流体相在线共混的方法。该方法包括提供并联配置的两个或多个反应器列和用于产物共混和产物 - 进料分离的分离器，其中一个或多个反应器列产生一种或多种聚合物，并且一个或多个反应器列产生一种或多种增塑剂 ; 在高于聚合体系的固体 - 流体相转变温度的温度下，在至少一个平行反应器系列烯烃单体，催化剂体系，任选的共聚单体，任选的清除剂和任选的稀释剂或溶剂中接触，并且压力不低于10 MPa低于聚合体系的浊点压力，小于1500MPa; 在每个平行的反应器列中形成包含均相流体相聚合物 - 单体混合物和增塑剂 - 单体混合物的反应器流出物; 使反应器流出物通过分离器; 将分离器内的温度和压力保持在固体 - 流体相转变点之上但低于浊点压力和温度，以形成包括增塑的富含聚合物的共混相和富单体相的流体 - 流体两相系统; 并将富单体相与增塑的富聚合物相分离。富含聚合物的共混相被输送到下游整理阶段以用于进一步的单体汽提，干燥和/或造粒以形成增塑的聚合物产物混合物。用于在线生产和共混的合适的增塑剂包括聚α-烯烃低聚物，聚丁烯，低玻璃化转变温度聚合物及其组合。

10. 发明授权

US08614277B2 Polypropylene ethylene-propylene copolymer blends and in-line process to produce them 有权
标题翻译：聚丙烯乙烯 - 丙烯共聚物共混物和在线方法生产它们
公开(公告)号：US08614277B2
公开(公告)日：2013-12-24
申请号：US13371733
申请日：2012-02-13
申请人： Gabor Kiss , Patrick Brant , Robert Patrick Reynolds, Jr. , Aspy K. Mehta , Manika Varma-Nair , John W. Chu , Steven P. Rucker
发明人： Gabor Kiss , Patrick Brant , Robert Patrick Reynolds, Jr. , Aspy K. Mehta , Manika Varma-Nair , John W. Chu , Steven P. Rucker
IPC分类号： C08F2/01 , C08F6/06 , C08L23/16
CPC分类号： C08L23/0815 , C08F110/06 , C08F210/06 , C08L23/10 , C08L2314/02 , C08L2314/06 , Y02P20/544 , C08L2666/06 , C08F2500/12 , C08F2500/20 , C08F2500/03 , C08F210/16
摘要： Isotactic polypropylene ethylene-propylene copolymer blends and in-line processes for producing. The blends may have between 1 and 50 wt % of isotactic polypropylene with a melt flow rate of between 0.5 and 20,000 g/10 min and a melting peak temperature of 145° C. or higher, and wherein the difference between the DSC peak melting and the peak crystallization temperatures is less than or equal to 0.5333 times the melting peak temperature minus 41.333° C., and between 50 and 99 wt % of ethylene-propylene copolymer including between 10 wt % and 20 wt % randomly distributed ethylene with a melt flow rate of between 0.5 and 20,000 g/10 min, wherein the copolymer is polymerized by a bulk homogeneous polymerization process, and wherein the total regio defects in the continuous propylene segments of the copolymer is between 40 and 150% greater than a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.
摘要翻译：全同立构聚丙烯乙烯 - 丙烯共聚物共混物和在线生产方法。共混物可以具有1至50重量％的全同立构聚丙烯，熔体流动速率为0.5至20,000g / 10min，熔融峰温度为145℃或更高，并且其中DSC峰值熔融和峰值结晶温度小于或等于熔融峰温度减去41.333℃的0.5333倍，和包含10重量％至20重量％的乙烯 - 丙烯共聚物的50至99重量％之间，随机分布的乙烯和熔体流动速率为0.5至20,000g / 10min，其中共聚物通过本体均相聚合方法聚合，并且其中共聚物的连续丙烯链段中的总区域缺陷比等同熔体的共聚物大40至150％流速和wt％乙烯通过溶液聚合方法聚合。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式