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1. 发明授权

US6063857A Solubilized hydrophobically-modified alkali-soluble emulsion polymers 失效
标题翻译：溶解的疏水改性的碱溶性乳液聚合物
公开(公告)号：US6063857A
公开(公告)日：2000-05-16
申请号：US119500
申请日：1998-07-20
申请人： Gary David Greenblatt , Willie Lau , Andrew Gordon Batzell, 3rd
发明人： Gary David Greenblatt , Willie Lau , Andrew Gordon Batzell, 3rd
IPC分类号： C09K3/00 , C08F2/22 , C08F2/44 , C08F246/00 , C08L101/00 , C09D133/06 , C08L5/16 , C08F220/26 , C08L33/04
CPC分类号： C08F2/22 , C09D133/064
摘要： Aqueous solutions of hydrophobically-modified alkali-soluble emulsion polymers which exhibit relatively low solution viscosity are disclosed. Such solutions are particularly useful for controlling the viscosity of aqueous systems to which the solutions are added.
摘要翻译：公开了具有较低溶液粘度的疏水改性的碱溶性乳液聚合物的水溶液。这种溶液对于控制加入溶液的水性体系的粘度特别有用。

2. 发明授权

US07235603B2 Ambient curable polymer 有权
标题翻译：环境固化聚合物
公开(公告)号：US07235603B2
公开(公告)日：2007-06-26
申请号：US10802638
申请日：2004-03-17
申请人： Thomas Glenn Madle , Matthew Stewart Gebhard , Chao-Jen Chung , Gary David Greenblatt
发明人： Thomas Glenn Madle , Matthew Stewart Gebhard , Chao-Jen Chung , Gary David Greenblatt
IPC分类号： C08G18/82 , C08G2/32
CPC分类号： C08F290/046 , C08F8/00 , C08F285/00 , C08F2800/20 , C08F220/14 , C08F2220/325
摘要： An ambient curable aqueous dispersion of polymer particles containing pendant ethylenically unsaturated side chains; a method of applying to a substrate a coating composition containing the aqueous dispersion of polymer particles; and a method of making the aqueous dispersion of polymer particles are provided.
摘要翻译：含有侧链烯属不饱和侧链的聚合物颗粒的环境固化水分散体; 向基材施加含有聚合物颗粒的水性分散体的涂料组合物的方法; 并提供制备聚合物颗粒的水性分散体的方法。

3. 发明授权

US06248826B1 Emulsion copolymers from terminally unsaturated acrylic acid oligomers 失效
标题翻译：来自末端不饱和丙烯酸低聚物的乳液共聚物
公开(公告)号：US06248826B1
公开(公告)日：2001-06-19
申请号：US09357176
申请日：1999-07-16
申请人： Robert David Solomon , Gary David Greenblatt
发明人： Robert David Solomon , Gary David Greenblatt
IPC分类号： C08F226
CPC分类号： C08F290/046 , C01P2004/62 , C08F220/04 , C08F265/02 , C08F265/04 , C08F265/06
摘要： An aqueous dispersion of a copolymer formed by the emulsion polymerization of a monomer mixture including from 0.1 to 20% by weight of one or more terminally unsaturated carboxylic acid oligomers; from 80 to 99.9% by weight of at least two monomers selected from esters and amides of (meth)acrylic acid, vinyl esters of carboxylic acids, vinyl aromatic compounds, ethylenically unsaturated nitrites, vinyl halides, and non-aromatic hydrocarbons; and 0 to 10% by weight of other copolymerisable monomers is provided. The aqueous copolymer dispersion is polymerized in the presence of anionic surfactant and at an acid pH. Also provided is a method of preparing the aqueous copolymer dispersion. Aqueous copolymer dispersions including the terminally unsaturated carboxylic acid oligomers have low viscosities over a broad pH range and are useful in coating compositions, as binders for nonwovens, textiles, paper coatings, and as adhesives.
摘要翻译：通过包含0.1至20重量％的一种或多种末端不饱和羧酸低聚物的单体混合物的乳液聚合形成的共聚物的水分散体; 80至99.9重量％的选自（甲基）丙烯酸的酯和酰胺，羧酸的乙烯基酯，乙烯基芳族化合物，烯键式不饱和亚硝酸酯，乙烯基卤化物和非芳族烃的至少两种单体; 并提供0至10重量％的其它可共聚单体。含水共聚物分散体在阴离子表面活性剂的存在下和在酸性pH下聚合。还提供了制备水性共聚物分散体的方法。包括末端不饱和羧酸低聚物的水性共聚物分散体在宽的pH范围内具有低粘度，并且可用于涂料组合物，作为无纺布，纺织品，纸涂料和粘合剂的粘合剂。

4. 发明授权

US06645562B2 Method of preparing a curable coating and curing thereof 失效
标题翻译：制备可固化涂层及其固化方法
公开(公告)号：US06645562B2
公开(公告)日：2003-11-11
申请号：US10183307
申请日：2002-06-27
申请人： Gary David Greenblatt , Ward Thomas Brown , Michael Damian Bowe , Richard Foster Merritt , Ronald Scott Beckley , Barry Clifford Lange , Robert Wilczynski , David William Whitman , Martha Harbaugh Wolfersberger
发明人： Gary David Greenblatt , Ward Thomas Brown , Michael Damian Bowe , Richard Foster Merritt , Ronald Scott Beckley , Barry Clifford Lange , Robert Wilczynski , David William Whitman , Martha Harbaugh Wolfersberger
IPC分类号： C09D500
CPC分类号： C08F2/02 , C08F2/18 , C08F8/14 , C08F20/04 , C08F290/046 , C08F2220/281 , C08F2800/10 , C08F2810/20 , C08F2810/30 , C08F2810/50 , C08K5/0016 , C08K5/0025 , C08L21/00 , C08L101/00 , C11D3/373 , C11D3/3746 , C11D3/3757 , C08L2666/02 , C08L2666/04 , C08F2220/1808 , C08F2220/1825
摘要： A method of preparing a curable coating and a method of curing the curable coating are disclosed. The curable composition from which the curable coating is prepared may be applied to the surface of a substrate in neat form or in aqueous medium to produce the coating. Curing of the curable coating may be accomplished by chemical generation of free radicals, by electrochemical generation of free radicals, by electron beam, by photochemical generation of free radicals, or by other electromagnetic irradiation.
摘要翻译：公开了一种制备可固化涂层的方法和一种固化可固化涂层的方法。制备可固化涂层的可固化组合物可以以纯形式或在水性介质中施加到基材的表面以产生涂层。可固化涂层的固化可以通过化学生成自由基，通过电化学生成自由基，电子束，通过光化学生成自由基或通过其它电磁辐射来实现。

5. 发明授权

US06566549B1 Continuous polymerization process and products therefrom 有权
标题翻译：连续聚合工艺及其产品
公开(公告)号：US06566549B1
公开(公告)日：2003-05-20
申请号：US09212038
申请日：1998-12-15
申请人： Gary David Greenblatt , Barry Clifford Lange , Michael Damian Bowe , Richard Foster Merritt , Robert Wilczynski , Gary Robert Larson , Lori Marie Petrovich , David William Whitman
发明人： Gary David Greenblatt , Barry Clifford Lange , Michael Damian Bowe , Richard Foster Merritt , Robert Wilczynski , Gary Robert Larson , Lori Marie Petrovich , David William Whitman
IPC分类号： C08F428
CPC分类号： C07C43/196 , C07C67/347 , C07C2603/68 , C08F2/02 , C08F2/18 , C08F20/04 , C08F290/046 , C08F2220/281 , C08K5/0016 , C08K5/0025 , C08L21/00 , C08L101/00 , C11D3/3757 , C08L2666/02 , C08L2666/04 , C07C69/604
摘要： A continuous process for oligomers which do not contain, as polymerized units, carboxylic acid-containing monomers and their salts, including the steps of: (1) forming a reaction mixture, substantially free of carboxylic acid-containing monomers and their salts, containing: (i) 0.5 to 99.95% by weight of the reaction mixture of at least one ethylenically unsaturated monomer; and (ii) 0.05 to 25% by weight, based on the weight of the ethylenically unsaturated monomer, of at least one free-radical initiator; and (2) continuously passing the reaction mixture through a heated zone wherein the reaction mixture is maintained at a temperature of at least 150° C. and a pressure of at least 30 bars for from 0.1 seconds to 4 minutes to form terminally-unsaturated oligomers. In addition, processes for forming oligomers of vinyl acetate and oligomers of vinyl alcohol are disclosed. Mixtures of fully saturated and terminally unsaturated oligomers are also disclosed.
摘要翻译：不含作为聚合单元的含羧酸单体及其盐的低聚物的连续方法，包括以下步骤：（1）形成基本上不含羧酸的单体及其盐的反应混合物，其含有：（i）至少一种烯属不饱和单体的反应混合物的0.5至99.95重量％; 和（ii）至少一种自由基引发剂的0.05至25重量％，基于烯键式不饱和单体的重量; 和（2）连续地将反应混合物通过加热区，其中将反应混合物保持在至少150℃的温度和至少30巴的压力0.1秒至4分钟以形成末端不饱和低聚物此外，公开了形成乙酸乙烯酯的低聚物和乙烯醇的低聚物的方法。还公开了完全饱和和末端不饱和低聚物的混合物。

6. 发明授权

US06362301B1 Curable composition 失效
标题翻译：可固化组合物
公开(公告)号：US06362301B1
公开(公告)日：2002-03-26
申请号：US09418937
申请日：1999-10-15
申请人： Michael Damian Bowe , Linda Louise Graham , Gary David Greenblatt , Barry Clifford Lange , Richard Foster Merritt
发明人： Michael Damian Bowe , Linda Louise Graham , Gary David Greenblatt , Barry Clifford Lange , Richard Foster Merritt
IPC分类号： C08G7220
CPC分类号： C08F230/08 , C08F2/02 , C08F2/18 , C08F20/04 , C08F290/046 , C08F2220/281 , C08K5/0016 , C08K5/0025 , C08L21/00 , C08L101/00 , C09D143/04 , C11D3/373 , C11D3/3746 , C08L2666/28 , C08F218/08 , C08F2220/1808 , C08F212/08 , C08F2220/1825 , C08F2220/1858 , C08L2666/02 , C08L2666/04
摘要： The present invention relates to a curable composition including an acryloxysilane- or acyloxysilane-containing oligomer prepared by a continuous process. In addition, photocurable composition including an alkoxysilane or acyloxysilane oligomer is provided. Methods are provided for curing the curable and photocurable compositions.
摘要翻译：本发明涉及包含通过连续方法制备的含有丙烯酰氧基硅烷或酰氧基硅烷的低聚物的可固化组合物。另外，提供了包含烷氧基硅烷或酰氧基硅烷低聚物的光固化性组合物。提供了用于固化可固化和光固化组合物的方法。

7. 发明授权

US06890983B2 Aqueous composite particle composition 有权
标题翻译：水性复合颗粒组合物
公开(公告)号：US06890983B2
公开(公告)日：2005-05-10
申请号：US10166928
申请日：2002-06-11
申请人： William Joseph Rosano , Gary Robert Larson , Leo Joseph Procopio , Albert Mulligan Dager , Gary David Greenblatt
发明人： William Joseph Rosano , Gary Robert Larson , Leo Joseph Procopio , Albert Mulligan Dager , Gary David Greenblatt
IPC分类号： C08F290/00 , C08F246/00 , C09C1/36 , C09C3/10 , C09D7/12 , C09D17/00 , C08J3/00 , C08K3/20 , C08K9/00 , C08L41/00 , C08L43/00
CPC分类号： B82Y30/00 , C01P2002/84 , C01P2004/03 , C01P2004/20 , C01P2004/32 , C01P2004/38 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/33 , C01P2006/60 , C08F230/02 , C08K3/22 , C08K9/12 , C08L41/00 , C08L43/02 , C09C1/3669 , C09C1/3676 , C09C1/3684 , C09C1/3692 , C09D7/62 , C09D133/02
摘要： An aqueous composite particle composition containing composite particles and polyvalent metal ion is provided. The composite particles contain pigment particle with adsorbed polymer particles. The polymer particles contain pendant acid functional groups and has a molecular weight in a select range. Also provided are methods of preparing the aqueous composite particle composition. The aqueous composite particle composition is useful for preparing coating with high gloss and improved solvent resistance.
摘要翻译：提供含有复合粒子和多价金属离子的水性复合粒子组合物。复合颗粒含有吸附有聚合物颗粒的颜料颗粒。聚合物颗粒含有侧链酸官能团并且分子量在选择范围内。还提供了制备水性复合颗粒组合物的方法。水性复合颗粒组合物可用于制备具有高光泽度和改善耐溶剂性的涂层。

8. 发明授权

US06376600B1 Aqueous composition 有权
标题翻译：水性成分
公开(公告)号：US06376600B1
公开(公告)日：2002-04-23
申请号：US09719462
申请日：2000-12-11
申请人： Robert David Solomon , Bradley Keith Hageman , Leo Joseph Procopio , Margo Raate Schaefer , Gary David Greenblatt , Stephen Scott Edwards , Gary Robert Larson , Alvin Michael Maurice , Stewart Orlyn Williams , Patricia Marie Lesko , Peter Reeves Sperry
发明人： Robert David Solomon , Bradley Keith Hageman , Leo Joseph Procopio , Margo Raate Schaefer , Gary David Greenblatt , Stephen Scott Edwards , Gary Robert Larson , Alvin Michael Maurice , Stewart Orlyn Williams , Patricia Marie Lesko , Peter Reeves Sperry
IPC分类号： C08J302
CPC分类号： C08F265/06 , C01P2004/62 , C08F220/04 , C08F265/02 , C08F265/04 , C08F290/046
摘要： Aqueous dispersion of copolymers formed by the polymerization of a monomer mixture containing 0.05% to less than 4.5% by weight of certain terminally unsaturated oligomers are useful for improving the scrub resistance, corrosion resistance, opacifying capacity and/or efflorescence resistance of a coating.
摘要翻译：通过聚合含有0.05重量％至小于4.5重量％的某些末端不饱和低聚物的单体混合物形成的共聚物的水分散体可用于改善涂层的耐擦洗性，耐腐蚀性，不透明性和/或防风化性。

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