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1. 发明申请

US20090065398A1 Solid acid assisted deep desulfurization of diesel boiling range feeds 有权
标题翻译：固体酸辅助深度脱硫柴油沸腾饲料
公开(公告)号：US20090065398A1
公开(公告)日：2009-03-12
申请号：US11900449
申请日：2007-09-11
申请人： Jonathan M. McConnachie , Catalina L. Coker , Madhav Acharya
发明人： Jonathan M. McConnachie , Catalina L. Coker , Madhav Acharya
IPC分类号： C10G17/06
CPC分类号： C10G65/04 , C10G2400/04
摘要： The instant invention relates to a process to produce low sulfur diesel products through the hydrodesulfurization of low nitrogen diesel boiling range feedstreams in the presence of solid acidic materials.
摘要翻译：本发明涉及一种在固体酸性物质存在下通过低氮柴油沸程进料流的加氢脱硫生产低硫柴油产品的方法。

2. 发明授权

US07731838B2 Solid acid assisted deep desulfurization of diesel boiling range feeds 有权
标题翻译：固体酸辅助深度脱硫柴油沸腾饲料
公开(公告)号：US07731838B2
公开(公告)日：2010-06-08
申请号：US11900449
申请日：2007-09-11
申请人： Jonathan M. McConnachie , Catalina L. Coker , Madhav Acharya
发明人： Jonathan M. McConnachie , Catalina L. Coker , Madhav Acharya
IPC分类号： C10G17/06
CPC分类号： C10G65/04 , C10G2400/04
摘要： The instant invention relates to a process to produce low sulfur diesel products through the hydrodesulfurization of low nitrogen diesel boiling range feedstreams in the presence of solid acidic materials.
摘要翻译：本发明涉及一种在固体酸性物质存在下通过低氮柴油沸程进料流的加氢脱硫生产低硫柴油产品的方法。

3. 发明授权

US07446216B2 Halogen substituted metallocene compounds for olefin polymerization 有权
公开(公告)号：US07446216B2
公开(公告)日：2008-11-04
申请号：US11300054
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryahov , Mikhail V. Nikulin , Alexander V. Lygin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryahov , Mikhail V. Nikulin , Alexander V. Lygin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/6392 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound is represented by the formula (1): A2YyMXn-2 wherein: M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; each A is independently a substituted polycyclic arenyl ligand pi-bonded to M, each A ligand includes at least one halogen substituent directly bonded to an sp2 carbon at a bondable ring position and, when each A is a substituted indenyl ligand and y is equal to one and the ligand includes at least one chloro, bromo or iodo substituent at the 4, 5, or 6 position of the indenyl ligand, then A also includes at least one other substituent in the indenyl ligand selected from hydrocarbyl, substituted hydrocarbyl, halogen, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, substituted germylcarbyl, or other heteroatom substituents wherein the heteroatom is bonded directly to a ring carbon of the ring structure ligand and is boron, a Group 15 atom, or a Group 16 atom, preferably boron, nitrogen, oxygen, phosphorus, or sulfur; Y is an optional bridging group containing at least one Group 13, 14, 15, or 16 element and is bonded to any single position of the ring structure of A, y is zero or 1, indicating the absence (y=0) or presence (y=1) of Y; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when y is equal to 1, then A is not 5,6-dichloroindenyl or an indenyl group having a fluoro- or chloro substituent at the 7 position and a hydrocarbyl or substituted hydrocarbyl substituent at the 4 position, and provided further that when y is equal to 0, then A is not 5,6-difluoroindenyl.

4. 发明申请

US20130245213A1 Catalysts For Producing Polyaplha-Olefins 有权
标题翻译：用于生产Polyaplha-Olefins的催化剂
公开(公告)号：US20130245213A1
公开(公告)日：2013-09-19
申请号：US13423686
申请日：2012-03-19
申请人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
发明人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
IPC分类号： C08F4/76 , C08F110/14
CPC分类号： C08F110/14 , C08F210/16 , C08F10/00 , C08F4/6592 , C08F2500/02 , C08F2500/03 , C08F2500/17
摘要： This invention is directed to new mono-cyclopentadienyl (“mono-Cp”) metallocene catalyst compounds useful for producing high viscosity PAOs with narrow molecular weight distribution and good shear stability. Specifically, this invention relates to a group of bridged mono-Cp catalysts wherein, in an embodiment of the invention, the aromatic ring structure is substituted with: 1) at least one phenyl group, 2) at least one alkyl group, and 3) at least one other group, such as a hydrocarbyl group, a heteroatom, or a heteroatom-containing group.
摘要翻译：本发明涉及用于生产具有窄分子量分布和良好剪切稳定性的高粘度PAO的新单环戊二烯（“一Cp”）茂金属催化剂化合物。具体地，本发明涉及一组桥连的单Cp催化剂，其中在本发明的一个实施方案中，芳环结构被以下物质取代：1）至少一个苯基，2）至少一个烷基，和3）至少一个其它基团，例如烃基，杂原子或含杂原子的基团。

5. 发明申请

US20130158307A1 Low Viscosity Poly-Alpha-Olefins 有权
标题翻译：低粘度聚α-烯烃
公开(公告)号：US20130158307A1
公开(公告)日：2013-06-20
申请号：US13476686
申请日：2012-05-21
申请人： Margaret May-Som Wu , Catalina L. Coker , John F. Walzer, JR. , Peijun Jiang
发明人： Margaret May-Som Wu , Catalina L. Coker , John F. Walzer, JR. , Peijun Jiang
IPC分类号： C07C2/02 , C07C11/02
CPC分类号： C07C11/02 , C07C2/02 , C07C2/34 , C07C5/05 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/14 , C08F110/14 , C08F210/04 , C08F210/14 , C10M107/10 , C10M143/08 , C10M2205/026 , C10M2205/0265 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2220/025 , C10N2220/026 , C10N2220/028 , C10N2220/033 , C10N2270/00 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2500/02
摘要： A low viscosity poly(apha-olefin) (PAO) is produced by contacting one or more C3 to C24 alpha-olefins with an unbridged, substituted bis cyclopentadienyl transition metal compound, a non-coordinating anion activator, and an alkyl-aluminum compound. The molar ratio of transition metal compound to activator is 10:1 to 0.1:1, and the molar ratio of alkyl aluminum compound to transition metal compound is 1:4 to 4000:1. The transition metal compound has either (a) at least one non-isoolefin substitution on both cyclopentadienyl rings, or (b) at least two substitutions on at least one cyclopentadienyl ring. The PAO is comprised of at least 50 mole % of C3 to C24 alpha-olefins and has a kinematic viscosity at 100° C. of 20 cSt or less.
摘要翻译：通过使一个或多个C 3至C 24α-烯烃与未桥连的取代的双环戊二烯基过渡金属化合物，非配位阴离子活化剂和烷基铝化合物接触来制备低粘度聚（对苯二甲酸烯丙酯）（PAO）。过渡金属化合物与活化剂的摩尔比为10：1至0.1：1，烷基铝化合物与过渡金属化合物的摩尔比为1：4至4000：1。过渡金属化合物具有（a）在两个环戊二烯基环上至少一个非异构烯烃取代，或（b）至少一个环戊二烯基环上的至少两个取代基。 PAO由至少50摩尔％的C3至C24α-烯烃组成，并且在100℃下的运动粘度为20cSt或更低。

6. 发明授权

US07868197B2 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US07868197B2
公开(公告)日：2011-01-11
申请号：US11300240
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6192 , C08F4/6592 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

7. 发明授权

US07763562B2 Heteroatom bridged metallocene compounds for olefin polymerization 有权
标题翻译：异质桥接金属茂化合物用于烯烃聚合
公开(公告)号：US07763562B2
公开(公告)日：2010-07-27
申请号：US11302998
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/6392 , C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , B01J31/2295 , B01J2231/12 , B01J2531/48 , C08F4/65912 , C08F10/06 , C08F110/02 , C08F210/16 , C08F2420/06 , Y10S526/943 , C08F2500/03 , C08F210/14 , C08F2500/01 , C08F110/06 , C08F2500/20 , C08F210/06 , C08F10/00 , C08F4/65927
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）通过茚基环的4,5,6或7位与Y键合的取代或未取代的茚基配体，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

8. 发明申请

US20100113717A1 Process For Producing Substituted Metallocene Compounds For Olefin Polymerization 有权
标题翻译：用于生产用于烯烃聚合的取代茂金属化合物的方法
公开(公告)号：US20100113717A1
公开(公告)日：2010-05-06
申请号：US12641123
申请日：2009-12-17
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/16 , C07F17/00 , B01J31/12 , B01J31/14
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

9. 发明授权

US07709670B2 Process for producing substituted metallocene compounds for olefin polymerization 失效
标题翻译：制备用于烯烃聚合的取代茂金属化合物的方法
公开(公告)号：US07709670B2
公开(公告)日：2010-05-04
申请号：US11302997
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C07F7/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

10. 发明授权

US08664461B2 Catalysts for producing polyalpha-olefins and processes related thereto 有权
标题翻译：用于生产聚α-烯烃的催化剂及其相关工艺
公开(公告)号：US08664461B2
公开(公告)日：2014-03-04
申请号：US13423686
申请日：2012-03-19
申请人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
发明人： Bruce A. Harrington , Abhimanyu O. Patil , Donna J. Crowther , Phillip T. Matsunaga , Kevin B. Stavens , Catalina L. Coker
IPC分类号： C07C2/08 , C07C2/34 , C08F4/6592
CPC分类号： C08F110/14 , C08F210/16 , C08F10/00 , C08F4/6592 , C08F2500/02 , C08F2500/03 , C08F2500/17
摘要： This invention is directed to new mono-cyclopentadienyl (“mono-Cp”) metallocene catalyst compounds useful for producing high viscosity PAOs with narrow molecular weight distribution and good shear stability. Specifically, this invention relates to a group of bridged mono-Cp catalysts wherein, in an embodiment of the invention, the aromatic ring structure is substituted with: 1) at least one phenyl group, 2) at least one alkyl group, and 3) at least one other group, such as a hydrocarbyl group, a heteroatom, or a heteroatom-containing group.
摘要翻译：本发明涉及用于生产具有窄分子量分布和良好剪切稳定性的高粘度PAO的新单环戊二烯（“一Cp”）茂金属催化剂化合物。具体地，本发明涉及一组桥连的单Cp催化剂，其中在本发明的一个实施方案中，芳环结构被以下物质取代：1）至少一个苯基，2）至少一个烷基，和3）至少一个其它基团，例如烃基，杂原子或含杂原子的基团。

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