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    • 3. 发明授权
    • Reinforced calcium aluminosilicate glass-ceramics
    • 增强铝硅酸铝玻璃陶瓷
    • US4755489A
    • 1988-07-05
    • US943072
    • 1986-12-18
    • Kenneth ChyungKishor P. GadkareeRonald L. StewartMark P. Taylor
    • Kenneth ChyungKishor P. GadkareeRonald L. StewartMark P. Taylor
    • C03C3/062C03C3/097C03C10/00C03C10/06C03C14/00C04B35/56
    • C03C14/002C03C10/0036C03C2214/02C03C2214/06C03C2214/20
    • The present invention is directed to the production of SiC whisker- and/or fiber-reinforced, internally-nucleated glass-ceramic matrix composite articles consisting essentially of 0.5-60% by weight SiC whiskers and/or 15-70% by volume ceramic fibers substantially uniformly distributed in a glass-ceramic matrix consisting essentially, in weight percent on the oxide basis, of 16-20%, CaO, 38.5-46% Al.sub.2 O.sub.3, 35-42% SiO.sub.2, and up to 10% total of at least one nucleating agent in the indicated proportion selected from the group consisting of 0.1-3% Cr.sub.2 O.sub.3, 0.25-3% HfO.sub.2, 2-5% MoO.sub.3, 0.25-3% Nb.sub.2 O.sub.5, 0.25-3% Ta.sub.2 O.sub.5, 0.25-3% WO.sub.3, and 1-10% ZrO.sub.2, wherein Al.sub.2 O.sub.3 is present in an amount which is at least 5 mole percent and up to 50 mole percent in excess of that present in stoichiometric triclinic anorthite, and wherein the predominant crystal phases in the glass-ceramic are triclinic anorthite and mullite and/or .alpha.-Al.sub.2 O.sub.3. Up to 1.5% As.sub.2 O.sub.3 may advantageously be included in the composition.
    • 本发明涉及生产基本上由0.5-60%(重量)SiC晶须和/或15-70%(体积)陶瓷纤维组成的SiC晶须和/或纤维增强的,内部成核的玻璃 - 陶瓷基复合材料 基本上均匀分布在基本上以氧化物为基准重量百分比为16-20%,CaO,38.5-46%Al2O3,35-42%SiO2和至多10%总共的至少一种 指定比例的成核剂选自0.1-3%Cr2O3,0.25-3%HfO2,2.5%MoO3,0.25-3%Nb2O5,0.25-3%Ta2O5,0.23%WO3和1% -10%的ZrO 2,其中Al 2 O 3以至少5摩尔%且高达50摩尔%的量存在于化学计量的三斜钙石中存在,并且其中玻璃 - 陶瓷中的主要结晶相是三斜长岩和 莫来石和/或α-Al2O3。 高达1.5%的As2O3可以有利地包括在组合物中。