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1. 发明授权

US4455438A Cyclobutanone oximes 失效
标题翻译：环丁酮肟
公开(公告)号：US4455438A
公开(公告)日：1984-06-19
申请号：US376988
申请日：1982-05-10
申请人： Laurenz Gsell , Jean-Claude Gehret
发明人： Laurenz Gsell , Jean-Claude Gehret
IPC分类号： A01N47/24 , C07C131/00
CPC分类号： A01N47/24
摘要： Cyclobutanone oxime carbamates of the formula ##STR1## wherein n is 1 to 5 and X.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio. A process for obtaining the compounds of the formula I and their use in pest control as well as the cyclobutanone oximes used as intermediates are described.
摘要翻译：式（I）的环丁酮肟氨基甲酸酯，其中n为1至5，X 1为氢，卤素，C 1 -C 4烷氧基或C 1 -C 4烷硫基。描述了获得式I化合物及其在病虫害防治中的用途以及用作中间体的环丁酮肟的方法。

2. 发明授权

US4348414A Cyclobutanone oxime carbamates, and use thereof in pest control 失效
标题翻译：环丁酮肟氨基甲酸酯，以及其在害虫防治中的用途
公开(公告)号：US4348414A
公开(公告)日：1982-09-07
申请号：US252527
申请日：1981-04-09
申请人： Laurenz Gsell , Jean-Claude Gehret
发明人： Laurenz Gsell , Jean-Claude Gehret
IPC分类号： A01N47/24 , A01N33/24
CPC分类号： A01N47/24
摘要： Cyclobutanone oxime carbamates of the formula ##STR1## wherein n is 1 to 5 and X.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio.A process for obtaining the compounds of the formula I and their use in pest control as well as the cyclobutanone oximes used as intermediates are described.
摘要翻译：式（I）的环丁酮肟氨基甲酸酯，其中n为1至5，X 1为氢，卤素，C 1 -C 4烷氧基或C 1 -C 4烷硫基。描述了获得式I化合物及其在病虫害防治中的用途以及用作中间体的环丁酮肟的方法。

3. 发明授权

US5081125A Anthelmintics 失效
标题翻译： ANTHELMINTICS
公开(公告)号：US5081125A
公开(公告)日：1992-01-14
申请号：US586176
申请日：1990-09-19
申请人： Peter Maienfisch , Christor Hildenbrand , Jean-Claude Gehret
发明人： Peter Maienfisch , Christor Hildenbrand , Jean-Claude Gehret
IPC分类号： A23K1/16 , A61K31/44 , A61K31/4402 , A61K31/4418 , A61K31/505 , A61P33/00 , C07D213/64 , C07D213/643 , C07D213/70 , C07D213/84 , C07D213/85 , C07D239/34 , C07D239/38 , C07D239/56
CPC分类号： C07D213/643 , C07D213/85 , C07D239/34 , C07D239/38
摘要： Anthelmintically active compounds of formula I are described ##STR1## in which R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 thioalkyl, C.sub.1 -C.sub.2 haloalkyl, nitro, C.sub.1 -C.sub.2 alkoxy, or the group SO.sub.n R in which R is C.sub.1 -C.sub.2 alkyl or phenyl and n is 0, 1 or 2;R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy or C.sub.1 -C.sub.2 alkoxy;R.sub.3 is hydrogen or C.sub.1 -C.sub.2 alkyl;R.sub.4 is hydrogen or C.sub.1 -C.sub.2 alkyl;R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.5 alkyl;R.sub.6 is hydrogen, halogen or C.sub.1 -C.sub.5 alkyl;R.sub.7 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, nitro, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy or C.sub.1 -C.sub.2 alkoxy;R.sub.8 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy or C.sub.1 -C.sub.2 alkoxy;R.sub.9 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy or C.sub.1 -C.sub.2 alkoxy;R.sub.10 is hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 alkylthio, C.sub.3 -C.sub.6 cycloalkyl or cyano;R.sub.11 is hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 alkylthio or C.sub.3 -C.sub.6 cycloalkyl;R.sub.12 is hydrogen or halogen; and Y is .dbd.CH-- or .dbd.N-; including the physiologically tolerable acid additon salts thereof, and also the preparatin and use thereof and novel intermediates.
摘要翻译：式Ⅰ的驱虫活性化合物描述为其中R 1是氢，卤素，C 1 -C 2烷基，C 1 -C 2硫代烷基，C 1 -C 2卤代烷基，硝基，C 1 -C 2烷氧基或其中R是C 1 -C 2烷基的基团SO n R或苯基，n为0,1或2; R 2是氢，卤素，C 1 -C 2烷基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基或C 1 -C 2烷氧基; R3是氢或C1-C2烷基; R4是氢或C1-C2烷基; R5是氢，卤素或C1-C5烷基; R6是氢，卤素或C1-C5烷基; R 7是氢，卤素，C 1 -C 2烷基，硝基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基或C 1 -C 2烷氧基; R 8是氢，卤素，C 1 -C 2烷基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基或C 1 -C 2烷氧基; R 9是氢，卤素，C 1 -C 2烷基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基或C 1 -C 2烷氧基; R 10是氢，卤素，C 1 -C 6烷基，C 1 -C 2卤代烷基，C 1 -C 2烷硫基，C 3 -C 6环烷基或氰基; R 11是氢，卤素，C 1 -C 6烷基，C 1 -C 2卤代烷基，C 1 -C 2烷硫基或C 3 -C 6环烷基; R 12是氢或卤素; 且Y为= CH-或= N-; 包括其生理上可耐受的酸加成盐，以及其制备及其用途和新型中间体。

4. 发明授权

US4946854A 3-aminobenzoylphenylureas useful for controlling parasites and insects that attack domestic animals and livestock 失效
标题翻译： 3-氨基苯甲酰苯胺可用于控制攻击家畜和牲畜的寄生虫和昆虫
公开(公告)号：US4946854A
公开(公告)日：1990-08-07
申请号：US280061
申请日：1988-12-05
申请人： Peter Maienfisch , Jean-Claude Gehret , Bruno Frei
发明人： Peter Maienfisch , Jean-Claude Gehret , Bruno Frei
IPC分类号： C07D213/64 , A01N47/34 , C07C67/00 , C07C233/58 , C07C233/65 , C07C241/00 , C07C265/16 , C07D213/643 , C07D213/70 , C07D213/74
CPC分类号： C07D213/643 , C07C233/58 , C07C265/16 , C07D213/70 , C07D213/74
摘要： Novel compounds of formula I ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.7, R.sup.8 and R.sup.9, independently of the others, is H or halogen,R.sup.4 is H, R.sup.10 CO-- or R.sup.11 NHCO-- wherein R.sup.10 is a C.sub.1 -C.sub.4 alkyl group which is unsubstituted or substituted by one to three identical or different substituents selected from the group consisting of halogen, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 - acyloxy and --COOG, wherein G is H, an alkali metal cation or an alkaline earth metal cation, and R.sup.11 is an unsubstituted or halo-substituted C.sub.1 -C.sub.4 alkyl or phenyl group,each of R.sup.5 and R.sup.6, independently of the other, is H, halogen, alkyl or haloalkyl andX is O, S(O)n or NH wherein n is 0, 1 or 2, the preparation of the novel compounds and their use against parasites in and on productive livestock and against insect pests, and novel starting materials and their preparation.
摘要翻译：式I的新型化合物其中R 1，R 2，R 3，R 7，R 8和R 9各自独立地为H或卤素，R 4为H，R 10 CO-或R 11 NHCO-，其中R 10为C 1 -C 1-4烷基，其被未取代或被一至三个相同或不同的选自卤素，C 1 -C 4烷氧基，C 1 -C 4 - 酰氧基和-COOG的取代基取代，其中G为H，碱金属阳离子或碱土金属金属阳离子，R11为未取代或卤素取代的C1-C4烷基或苯基，R5和R6各自独立地为H，卤素，烷基或卤代烷基，X为O，S（O）n或NH 其中n为0,1或2，新化合物的制备及其在生产性家畜和害虫中的寄生虫的用途，以及新的起始原料及其制备方法。

5. 发明授权

US4559357A Insecticidal and acaricidal phenylhydrazono- and phenylhydrazino-pyrrolidines 失效
标题翻译：杀虫和杀螨苯肼和苯肼基吡咯烷
公开(公告)号：US4559357A
公开(公告)日：1985-12-17
申请号：US501456
申请日：1983-06-06
申请人： Jean-Claude Gehret , Walter Traber
发明人： Jean-Claude Gehret , Walter Traber
IPC分类号： A01N43/36 , A01N47/36 , A01N47/38 , C07D207/22 , C07D207/14
CPC分类号： C07D207/22 , A01N43/36 , A01N47/36 , A01N47/38
摘要： Compounds of the formula ##STR1## and of the isomeric formulae ##STR2## wherein R is alkyl or halogen, R.sub.1 is hydrogen, optionally substituted alkyl or optionally substituted alkenyl, R.sub.2 is hydrogen or methyl, R.sub.3 is hydrogen, alkyl or alkenyl, and X is oxygen or sulfur, including their acid salts, are insecticidally and acaricidally active.
摘要翻译：其中R是烷基或卤素，R 1是氢，任选取代的烷基或任选被取代的链烯基，R 2是（Ⅰa）化合物及其异构体式氢或甲基，R3是氢，烷基或烯基，X是氧或硫，包括它们的酸盐，具有杀虫和杀螨活性。

6. 发明授权

US5077300A Anthelmintics 失效
标题翻译： ANTHELMINTICS
公开(公告)号：US5077300A
公开(公告)日：1991-12-31
申请号：US586096
申请日：1990-09-19
申请人： Peter Maienfisch , Christof Hildenbrand , Jean-Claude Gehret
发明人： Peter Maienfisch , Christof Hildenbrand , Jean-Claude Gehret
IPC分类号： A61K31/425 , A61K31/428 , A61P33/10 , C07D277/68 , C07D513/04
CPC分类号： C07D277/68 , C07D513/04
摘要： Anthelmintically active compounds of formula I are described ##STR1## in which R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 haloalkyl, nitro, C.sub.1 -C.sub.2 alkoxy, or the group SO.sub.n R in which R is C.sub.1 -C.sub.2 alkyl or phenyl and n is 0, 1 or 2;R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy or C.sub.1 -C.sub.2 alkoxy;R.sub.3 is hydrogen or C.sub.1 -C.sub.2 alkyl;R.sub.4 is hydrogen or C.sub.1 -C.sub.2 alkyl;R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.5 alkyl;R.sub.6 is hydrogen, halogen or C.sub.1 -C.sub.5 alkyl;R.sub.7 is hydrogen, halogen, or C.sub.1 -C.sub.2 alkyl, nitro, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy or C.sub.1 -C.sub.2 alkoxy;R.sub.8 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy or C.sub.1 -C.sub.2 alkoxy;R.sub.9 is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy or C.sub.1 -C.sub.2 alkoxy;R.sub.10 is hydrogen, halogen, nitro, NCS, OCF.sub.3, C.sub.1 -C.sub.2 alkyl or C.sub.1 -alkoxy;R.sub.11 is hydrogen, halogen, nitro, NCS, OCF.sub.3, C.sub.1 -C.sub.2 alkyl or C.sub.1 -C.sub.2 alkoxy; orR.sub.10 and R.sub.11 together form a --O(CH.sub.2).sub.m O-- bridge in which m is 1, 2 or 3, including the physiologically tolerable acid addition salts thereof, and also the preparation and use thereof and novel intermediates.
摘要翻译：式Ⅰ的驱虫活性化合物描述为其中R 1是氢，卤素，C 1 -C 2烷基，C 1 -C 2卤代烷基，硝基，C 1 -C 2烷氧基或其中R是C 1 -C 2烷基或苯基的基团SO n R和 n为0,1或2; R 2是氢，卤素，C 1 -C 2烷基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基或C 1 -C 2烷氧基; R3是氢或C1-C2烷基; R4是氢或C1-C2烷基; R5是氢，卤素或C1-C5烷基; R6是氢，卤素或C1-C5烷基; R 7是氢，卤素或C 1 -C 2烷基，硝基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基或C 1 -C 2烷氧基; R 8是氢，卤素，C 1 -C 2烷基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基或C 1 -C 2烷氧基; R 9是氢，卤素，C 1 -C 2烷基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基或C 1 -C 2烷氧基; R 10是氢，卤素，硝基，NCS，OCF 3，C 1 -C 2烷基或C 1 - 烷氧基; R 11是氢，卤素，硝基，NCS，OCF 3，C 1 -C 2烷基或C 1 -C 2烷氧基; 或R 10和R 11一起形成其中m为1,2或3的-O（CH 2）m O-桥，包括其生理上可耐受的酸加成盐，以及其制备和用途以及新型中间体。

7. 发明授权

US4824845A Pesticidal compositions 失效
标题翻译：杀虫剂组合物
公开(公告)号：US4824845A
公开(公告)日：1989-04-25
申请号：US233870
申请日：1988-08-17
申请人： Jean-Claude Gehret , Odd Kristiansen
发明人： Jean-Claude Gehret , Odd Kristiansen
IPC分类号： A01N43/68 , C07D251/70
CPC分类号： A01N43/68 , C07D251/70
摘要： Novel substituted acylamino-s-triazine compounds of the formula ##STR1## wherein R is C.sub.1 -C.sub.4 -alkyl, R.sub.1 is hydrogen, or C.sub.2 --C.sub.12 -acyl which is unsubstituted or substituted by halogen or C.sub.1 --C.sub.4 -alkoxy, and R.sub.2 is C.sub.2 --C.sub.12 -acyl which is unsubstituted or substituted by halogen or C.sub.1 --C.sub.4 -alkoxy, including the salts thereof. The novel compounds have valuable insecticidal and laryicidal properties, and can be used as active substances for controlling phytoparasitic and zooparasitic insects, expecially the larvae thereof, amongst these in particular ectoparasites.
摘要翻译：新型取代的酰基氨基-s-三嗪化合物，其中R为C 1 -C 4 - 烷基，R 1为氢，或未被取代或被卤素或C 1 -C 4 - 烷氧基取代的C 2 -C 12 - 酰基，R 2为未被取代或被卤素或C 1 -C 4烷氧基取代的C 2 -C 12酰基，包括其盐。这些新颖化合物具有有价值的杀虫和杀虫性能，可用作控制植物寄生虫和寄生虫的昆虫，特别是其幼虫，特别是外寄生虫的活性物质。

8. 发明授权

US4560770A Pesticidal compositions based on N-pyrrolylphenyl-N'-benzoylurea compounds 失效
标题翻译：基于N-吡咯基苯基-N'-苯甲酰脲化合物的杀虫组合物
公开(公告)号：US4560770A
公开(公告)日：1985-12-24
申请号：US574798
申请日：1984-01-30
申请人： Jean-Claude Gehret , Kurt Gubler
发明人： Jean-Claude Gehret , Kurt Gubler
IPC分类号： A01N47/34 , A01N47/36 , C07D207/32 , C07D207/325 , C07D207/34 , C07D207/04 , C08K5/21
CPC分类号： C07D207/325 , A01N47/36
摘要： Novel substituted N-pyrrolylphenyl-N'-benzoylurea compounds of the formula ##STR1## in which X and Y independently of one another are each hydrogen or halogen,R is hydrogen or halogen, andZ is hydrogen, halogen or methyl.The compounds have valuable properties for controlling pests, such as phytoparasitic and zooparasitic insects and members of the order Acarina, including in particular ectoparasites.
摘要翻译：新颖的取代的N-吡咯基苯基-N'-苯甲酰脲化合物，其中X和Y彼此独立地为氢或卤素，R为氢或卤素，Z为氢，卤素或甲基。这些化合物具有有价值的性质，用于防治害虫，如植物寄生虫和寄生虫，以及蜱螨属，特别是外寄生虫。

9. 发明授权

US4978677A C(29)-carbonyloxymilbemycin derivatives for controlling parasitic pets of animals and plants 失效
标题翻译： C（29） - 羰氧基米尔伯霉素衍生物，用于控制动物和植物的寄生宠物
公开(公告)号：US4978677A
公开(公告)日：1990-12-18
申请号：US432297
申请日：1989-11-06
申请人： Jean-Claude Gehret
发明人： Jean-Claude Gehret
IPC分类号： C07D493/22 , A01N43/90 , A01N53/00 , A61K31/365 , A61K31/70 , A61K31/7042 , A61K31/7048 , A61P33/00 , A61P33/10 , C07F7/18 , C07H17/08 , C07H19/01
CPC分类号： C07H19/01 , A01N43/90 , A01N53/00
摘要： the invention relates to novel C(29)-carbonyloxymilbemycin derivatives of formula I, to the preparation thereof and to the use thereof ffor controlling pests, as well as to pesticidal compositions which contain as active ingredient at least one of these compounds., Said novel compounds are of the general formula I ##STR1## wherein X is --CH(OR.sub.1)--, --C(O)-- or --C(.dbd.N--OH)--,R.sub.1 is hydrogen, a silyl group, an acyl group or a sugar residue,R.sub.2 is methyl, ethyl, isopropyl or sec-butyl andR is hydrogen unsubstituted or substituted straight chain or branched C.sub.1 -C.sub.18 alkyl, unsubstituted or substituted C.sub.3 -C.sub.10 cycloalkyl, unsubstituted or substituted C.sub.2 -C.sub.6 alkenyl, unsubstituted or substituted C.sub.2 -C.sub.6 alkynyl or unsubstituted or substituted phenyl.
摘要翻译：本发明涉及式I的新型C（29） - 羰氧基米尔贝霉素衍生物及其制备方法及其用于防治害虫的用途，以及含有这些化合物中的至少一种作为活性成分的杀虫组合物。化合物具有通式I（I）其中X是-CH（OR 1） - ， - C（O） - 或-C（= N-OH） - ，R 1是氢，甲硅烷基，酰基基团或糖残基，R 2是甲基，乙基，异丙基或仲丁基，R是未取代的或取代的直链或支链C 1 -C 18烷基，未取代或取代的C 3 -C 10环烷基，未取代或取代的C 2 -C 6烯基，未取代或取代的C 2 -C 1-6炔基或未取代或取代的苯基。

10. 发明授权

US4920148A Insecticides and parasiticides 失效
标题翻译：杀虫剂和杀寄生虫剂
公开(公告)号：US4920148A
公开(公告)日：1990-04-24
申请号：US369436
申请日：1989-06-21
申请人： Jean-Claude Gehret
发明人： Jean-Claude Gehret
IPC分类号： C07D493/22 , A01N43/90 , A61K31/365 , A61P33/00 , C07H19/01
CPC分类号： C07H19/01 , A01N43/90 , Y02P20/55
摘要： The present invention relates to novel C(29)-oximinomilbemycin derivatives of formula I, to their preparation and to the use thereof for controlling pests. The invention further relates to pesticidal compositions which contain at least one of these compounds as active ingredient.The novel compounds have the general formula I ##STR1## wherein X is a group selected from --CH(OR.sub.1)--, --C(O)--or --C(.dbd.N--OR)--,R.sub.1 is hydrogen or a OH protective group,R is hydrogen, a OH protective group, an alkyl, cycloakyl or acyl group,R.sub.2 is methyl, ethyl, isopropyl, sec-butyl or the ##STR2## group, wherein A is methyl, ethyl or isopropyl; and R.sub.3 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl, a radical selected from the group consisting of phenyl and benzyl which is unsubstituted or substituted by one or more members selected from the group consisting of halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 haloalkyl, nitro or cyano, or is the group U ##STR3## wherein n is 0, 1, 2, 3, 4 or 5, E is oxygen or --CH(R.sub.d)-- and R.sub.z is hydrogen, R.sub.a is hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or 2-tetrahydropyranyl, and R.sub.b, R.sub.c and R.sub.d are each independently hydrogen, halogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, which group U may also be in unsaturated form.

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