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    • 2. 发明授权
    • Conjugated diene-based polymer, conjugated diene-based polymer composition, and process for producing conjugated diene-based polymer
    • 共轭二烯系聚合物,共轭二烯类聚合物组合物,以及共轭二烯类聚合物的制造方法
    • US08367765B2
    • 2013-02-05
    • US13206167
    • 2011-08-09
    • Mana ItoKatsunari InagakiMayumi Oshima
    • Mana ItoKatsunari InagakiMayumi Oshima
    • C08L43/04C08F230/08C08F36/04
    • C08F236/10C08K3/36C08F4/48C08L9/06
    • Disclosed are a conjugated diene-based polymer from which a polymer composition excellent in fuel cost-saving properties and elongation at break can be obtained, a polymer composition containing the conjugated diene-based polymer and a reinforcing agent, and a process for producing the conjugated diene-based polymer. There is provided a conjugated diene-based polymer having a conjugated diene unit, a monomer unit based on a compound represented by the following formula (1) and a monomer unit based on a compound represented by the following formula (2). wherein R11 represents a hydrogen atom or a hydrocarbyl group, m is 0 or 1, R12 represents a hydrocarbylene group, and X1, X2 and X3 each independently represent a substituted amino group, or a hydrocarbyl group optionally having a substituent, provided that at least one of X1, X2 and X3 is a substituted amino group. wherein R21 represents a hydrogen atom or a hydrocarbyl group, n is 0 or 1, R22 represents a hydrocarbylene group, and A represents a substituted amino group, or a nitrogen-containing heterocyclic group.
    • 公开了一种共轭二烯类聚合物,其中可以获得具有优异的燃料成本节约性能和断裂伸长率的聚合物组合物,含有共轭二烯系聚合物和增强剂的聚合物组合物,以及制备共轭二烯系聚合物的方法 二烯基聚合物。 提供具有共轭二烯单元的共轭二烯系聚合物,基于下述式(1)所示的化合物的单体单元和基于下述式(2)表示的化合物的单体单元。 其中R11表示氢原子或烃基,m为0或1,R12表示亚烃基,X1,X2和X3各自独立地表示取代的氨基或任选具有取代基的烃基,条件是至少 X 1,X 2和X 3中的一个是取代的氨基。 其中R21表示氢原子或烃基,n为0或1,R22表示亚烃基,A表示取代氨基或含氮杂环基。
    • 3. 发明授权
    • Conjugated diene-based polymer, conjugated diene-based polymer composition, and process for producing conjugated diene-based polymer
    • 共轭二烯系聚合物,共轭二烯类聚合物组合物,以及共轭二烯类聚合物的制造方法
    • US08299179B2
    • 2012-10-30
    • US13206171
    • 2011-08-09
    • Mana ItoKatsunari Inagaki
    • Mana ItoKatsunari Inagaki
    • C08F8/42C08F8/30C08K3/36C08F236/04
    • C08C19/44C08C19/25
    • Disclosed are a conjugated diene-based polymer from which a polymer composition excellent in fuel cost-saving properties and elongation at break can be obtained, a polymer composition containing the conjugated diene-based polymer and a reinforcing agent, and a process for producing the conjugated diene-based polymer. A conjugated diene-based polymer obtained by reacting one end of a polymer having a monomer unit based on a conjugated diene, a monomer unit based on a compound represented by the following formula (1), and a monomer unit based on a compound represented by the following formula (2) with an alkoxysilane compound. V1—S1  (1) wherein V1 represents a hydrocarbyl group having a polymerizable carbon-carbon double bond, and S1 represents a substituted silyl group. V2-A2  (2) wherein V2 represents a hydrocarbyl group having a polymerizable carbon-carbon double bond, and A2 represents a substituted amino group, or a nitrogen-containing heterocyclic group.
    • 公开了一种共轭二烯类聚合物,其中可以获得具有优异的燃料成本节约性能和断裂伸长率的聚合物组合物,含有共轭二烯系聚合物和增强剂的聚合物组合物,以及制备共轭二烯系聚合物的方法 二烯基聚合物。 一种共轭二烯类聚合物,其通过使具有基于共轭二烯的单体单元的聚合物的一端,基于由下式(1)表示的化合物的单体单元和基于由下式(1)表示的化合物的单体单元) 下述式(2)表示烷氧基硅烷化合物。 V1-S1(1)其中V1表示具有可聚合碳 - 碳双键的烃基,S1表示取代甲硅烷基。 V2-A2(2)其中V2表示具有可聚合碳 - 碳双键的烃基,A2表示取代的氨基或含氮杂环基。
    • 4. 发明授权
    • Conjugated diene-based polymer, conjugated diene-based polymer composition, and process for producing conjugated diene-based polymer
    • 共轭二烯系聚合物,共轭二烯类聚合物组合物,以及共轭二烯类聚合物的制造方法
    • US08334339B2
    • 2012-12-18
    • US13206166
    • 2011-08-09
    • Mana ItoKatsunari InagakiMayumi Oshima
    • Mana ItoKatsunari InagakiMayumi Oshima
    • C08L43/04C08F230/08C08F8/32C08F8/34C08K3/36
    • C08F236/04C08F4/48C08F226/00C08F230/08
    • Disclosed are a conjugated diene-based polymer from which a polymer composition excellent in fuel cost-saving properties and a tensile strength at break can be obtained. There is provided a conjugated diene-based polymer having a monomer unit based on a conjugated diene, a monomer unit based on a compound represented by the following formula (1), and a monomer unit based on a compound represented by the following formula (2), in which at least one end of the polymer is modified with the following compound (G). V1-S1  (1) wherein V1 represents a hydrocarbyl group having a polymerizable carbon-carbon double bond, and S1 represents a substituted silyl group.) V2-A2  (2) wherein V2 represents a hydrocarbyl group having a polymerizable carbon-carbon double bond, and A2 represents a substituted amino group, or a nitrogen-containing heterocyclic group. Compound (G): at least one kind of compound selected from the compound group consisting of a compound having an amino group optionally having a substituent and a carbonyl group, and a compound having an amino group optionally having a substituent and a thiocarbonyl group.
    • 公开了一种共轭二烯类聚合物,可以获得燃料成本节约性和断裂拉伸强度优异的聚合物组合物。 提供一种共轭二烯类聚合物,其具有基于共轭二烯的单体单元,基于下式(1)表示的化合物的单体单元和基于下式(2)表示的化合物的单体单元 ),其中聚合物的至少一端用以下化合物(G)修饰。 V1-S1(1)其中V1表示具有可聚合碳 - 碳双键的烃基,S1表示取代甲硅烷基)V2-A2(2)其中V2表示具有可聚合碳 - 碳双键的烃基 A2表示取代氨基或含氮杂环基。 化合物(G):选自具有任选具有取代基的氨基的化合物和羰基的化合物中的至少一种化合物和具有任选具有取代基的氨基的化合物和硫代羰基。
    • 5. 发明申请
    • CONJUGATED DIENE POLYMER, CONJUGATED DIENE POLYMER COMPOSITION, AND METHOD FOR PRODUCING CONJUGATED DIENE POLYMER
    • 连接二烯聚合物,连接二烯聚合物组合物和生产连接二烯聚合物的方法
    • US20110207874A1
    • 2011-08-25
    • US13033322
    • 2011-02-23
    • Mana ItoKatsunari Inagaki
    • Mana ItoKatsunari Inagaki
    • C08F8/30C08F236/10C08L9/00C08F4/46
    • C08C19/44C08F236/10C08K3/36C08F4/48C08L15/00
    • A conjugated diene polymer is provided that includes a conjugated diene-based monomer unit and a monomer unit based on a compound represented by Formula (1) below, the monomer unit based on a compound represented by Formula (1) below being between a conjugated diene-based monomer unit-containing partial chain and a conjugated diene-based monomer unit-containing partial chain (said partial chain not comprising a monomer unit based on a compound represented by Formula (1) below), and the polymer having at least one terminus modified by a compound represented by Formula (2) below, wherein r is 0 or 1, R1 denotes a hydrocarbyl group or a group containing at least one atom selected from the atomic group consisting of a nitrogen atom, an oxygen atom, and a sulfur atom, and R2 denotes a group containing at least one atom selected from the atomic group consisting of a nitrogen atom, an oxygen atom, and a sulfur atom, wherein X denotes an oxygen atom or a sulfur atom, R3 denotes a nitrogen atom- and/or oxygen atom-containing group, a hydrocarbyl group, or a hydrogen atom, R4 denotes a nitrogen atom- and/or oxygen atom-containing group, and R3 and R4 may be bonded to each other. There is also provided a method for producing a conjugated diene polymer.
    • 提供了共轭二烯聚合物,其包含基于由下式(1)表示的化合物的共轭二烯系单体单元和单体单元,基于下述通式(1)表示的化合物的单体单元为共轭二烯 基于单体单元的部分链和含共轭二烯系单体单元的部分链(所述部分链不包含基于下述通式(1)表示的化合物的单体单元),所述聚合物具有至少一个末端 由下式(2)表示的化合物修饰,其中r为0或1,R1表示烃基或含有至少一个选自由氮原子,氧原子和硫原子组成的原子的基团 原子,R2表示含有选自由氮原子,氧原子和硫原子构成的原子团中的至少一个原子的基团,其中,X表示氧原子或硫原子,R3表示氮原子 - 和/或含氧原子的基团,烃基或氢原子,R4表示含氮原子和/或含氧原子的基团,并且R 3和R 4可以彼此键合。 还提供了一种生产共轭二烯聚合物的方法。