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1. 发明授权

US08785702B2 Turbine and diesel fuels and methods for making the same 有权
标题翻译：汽轮机和柴油燃料及其制造方法
公开(公告)号：US08785702B2
公开(公告)日：2014-07-22
申请号：US12769757
申请日：2010-04-29
申请人： Benjamin G. Harvey , Roxanne L. Quintana , Michael E. Wright
发明人： Benjamin G. Harvey , Roxanne L. Quintana , Michael E. Wright
IPC分类号： C07C2/14 , C07C5/03
CPC分类号： C10L1/04 , C07C2/16 , C07C2/34 , C07C5/03 , C07C2527/054 , C07C2531/14 , C07C2531/38 , C10G69/126 , C07C11/02 , C07C9/14 , C07C9/22
摘要： A process for making diesel and turbine fuels including, providing an effective amount of branched olefins, adding active heterogeneous acid catalyst(s) to said branched olefins to produce a solvent-free mixture, heating said solvent-free mixture greater than about 100° C. for a desired amount of time depending on various conditions, to produce C16 dimers/catalyst mixture, removing said catalysts from said dimers/catalyst mixture, and adding hydrogenation catalyst(s) to said dimers under hydrogen atmosphere to produce a mixture of stable fuels.
摘要翻译：一种制备柴油和涡轮燃料的方法，包括提供有效量的支链烯烃，向所述支链烯烃中加入活性多相酸催化剂以产生无溶剂的混合物，加热大于约100℃的无溶剂混合物根据各种条件的期望的时间量，生产C16二聚体/催化剂混合物，从所述二聚体/催化剂混合物中除去所述催化剂，并在氢气氛下向所述二聚体中加入氢化催化剂以产生稳定燃料的混合物。

2. 发明授权

US08697925B2 Turbine and diesel fuels and methods for making the same 有权
公开(公告)号：US08697925B2
公开(公告)日：2014-04-15
申请号：US12769757
申请日：2010-04-29
申请人： Benjamin G. Harvey , Roxanne L. Quintana , Michael E. Wright
发明人： Benjamin G. Harvey , Roxanne L. Quintana , Michael E. Wright
IPC分类号： C07C2/14 , C07C5/03
摘要： A process for making diesel and turbine fuels including, providing an effective amount of branched olefins, adding active heterogeneous acid catalyst(s) to said branched olefins to produce a solvent-free mixture, heating said solvent-free mixture greater than about 100° C. for a desired amount of time depending on various conditions, to produce C16 dimers/catalyst mixture, removing said catalysts from said dimers/catalyst mixture, and adding hydrogenation catalyst(s) to said dimers under hydrogen atmosphere to produce a mixture of stable fuels.

3. 发明申请

US20120209045A1 Diesel and Jet Fuels Based on the Oligomerization of Butene 有权
标题翻译：基于丁烯低聚的柴油和喷气燃料
公开(公告)号：US20120209045A1
公开(公告)日：2012-08-16
申请号：US12511796
申请日：2009-07-29
申请人： Michael E. Wright , Benjamin G. Harvey , Roxanne L. Quintana
发明人： Michael E. Wright , Benjamin G. Harvey , Roxanne L. Quintana
IPC分类号： C07C2/08 , B01J31/14
CPC分类号： B01J31/189 , B01J31/143 , B01J31/2295 , B01J2531/48 , C10G45/00 , C10G50/00 , C10G69/126 , C10G2300/1011 , C10G2300/1092 , C10G2300/302 , C10G2300/308 , C10G2300/44 , C10G2300/703 , C10G2400/04 , C10G2400/22 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： A renewable biofuel based on a highly efficient batch catalysis methodology for conversion of 1-butene to a new class of potential jet fuel blends. By tuning the catalyst and then using the dimer produced, the carbon use is about 95% or greater. This latter point will be particularly important in the future, where the source of raw materials (i.e., biomass/biofeedstock) is limited. Also noteworthy, the batch catalysis approach disclosed requires a minimal input of energy and hydrogen to make fuels that possess useful flash points, coldflow properties, and solution density/energy content. This new process affords a saturated hydrocarbon fuel that has a high solution density and thus possesses a higher calculated power density (per volume) than similar fuels made by the GTL Fischer-Tropsch processes. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.
摘要翻译：基于用于将1-丁烯转化为新型潜在喷气燃料混合物的高效批量催化方法的可再生生物燃料。通过调节催化剂然后使用所生产的二聚体，碳的使用量约为95％或更高。后一点在未来将是特别重要的，其中原料来源（即生物质/生物饲料）是有限的。还值得注意的是，所公开的批量催化方法需要能量和氢的最小输入以制备具有有用闪点，冷流特性和溶液密度/能量含量的燃料。该新方法提供了具有高溶液密度的饱和烃燃料，因此具有比由GTL费 - 托方法制备的类似燃料更高的计算功率密度（每体积）。要强调的是，该摘要被提供以符合要求抽象的规则，允许搜索者或其他读者快速确定技术公开内容的主题。提交它的理解是，它不会用于解释或限制权利要求的范围。

4. 发明申请

US20120205284A1 HIGH DENSITY RENEWABLE FUELS BASED ON THE SELECTIVE DIMERIZATION OF PINENES 有权
标题翻译：高密度可再生能源燃料基于PINENES的选择性二次化
公开(公告)号：US20120205284A1
公开(公告)日：2012-08-16
申请号：US12550973
申请日：2009-08-31
申请人： Benjamin G. Harvey , Michael E. Wright , Roxanne L. Quintana
发明人： Benjamin G. Harvey , Michael E. Wright , Roxanne L. Quintana
IPC分类号： C10L1/04 , C10G63/04
CPC分类号： C07C2/28 , B01J21/16 , B01J23/42 , B01J31/10 , C07C2/08 , C07C5/03 , C07C2521/16 , C07C2523/42 , C07C2531/10 , C07C2602/42 , C10G29/205 , C10G2400/08 , C10L1/04 , C07C13/39
摘要： An effective method for producing high density fuel candidates from pinenes is provided. MMT-K10 is an efficient catalyst for the reaction, although significant amounts of p-cymene and camphene produced as byproducts limit the overall yield to about 80%. Nafion is also an excellent catalyst for pinene dimerization and was capable of producing dimers in up to 90% yield. Pinene dimers synthesized with these heterogenous catalysts have a density and net heat of combustion comparable to JP-10. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.
摘要翻译：提供了从蒎烯生产高密度燃料候选物的有效方法。 MMT-K10是用于反应的有效催化剂，尽管作为副产物产生的显着量的对甲基异丙基苯和camp烯将总产率限制在约80％。 Nafion也是蒎烯二聚化的优异催化剂，能够以高达90％的产率生产二聚体。与这些异质催化剂合成的蒎烯二聚体具有与JP-10相当的密度和净燃烧热。要强调的是，该摘要被提供以符合要求抽象的规则，允许搜索者或其他读者快速确定技术公开内容的主题。提交它的理解是，它不会用于解释或限制权利要求的范围。

5. 发明授权

US08227651B1 High density renewable fuels based on the selective dimerization of pinenes 有权
标题翻译：基于蒎烯选择性二聚的高密度可再生燃料
公开(公告)号：US08227651B1
公开(公告)日：2012-07-24
申请号：US12550973
申请日：2009-08-31
申请人： Benjamin G. Harvey , Michael E. Wright , Roxanne L. Quintana
发明人： Benjamin G. Harvey , Michael E. Wright , Roxanne L. Quintana
IPC分类号： C07C13/28
CPC分类号： C07C2/28 , B01J21/16 , B01J23/42 , B01J31/10 , C07C2/08 , C07C5/03 , C07C2521/16 , C07C2523/42 , C07C2531/10 , C07C2602/42 , C10G29/205 , C10G2400/08 , C10L1/04 , C07C13/39
摘要： An effective method for producing high density fuel candidates from pinenes is provided. MMT-K10 is an efficient catalyst for the reaction, although significant amounts of p-cymene and camphene produced as byproducts limit the overall yield to about 80%. Nafion is also an excellent catalyst for pinene dimerization and was capable of producing dimers in up to 90% yield. Pinene dimers synthesized with these heterogenous catalysts have a density and net heat of combustion comparable to JP-10. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.
摘要翻译：提供了从蒎烯生产高密度燃料候选物的有效方法。 MMT-K10是用于反应的有效催化剂，尽管作为副产物产生的显着量的对甲基异丙基苯和camp烯将总产率限制在约80％。 Nafion也是蒎烯二聚化的优异催化剂，能够以高达90％的产率生产二聚体。与这些异质催化剂合成的蒎烯二聚体具有与JP-10相当的密度和净燃烧热。要强调的是，该摘要被提供以符合要求抽象的规则，允许搜索者或其他读者快速确定技术公开内容的主题。提交它的理解是，它不会用于解释或限制权利要求的范围。

6. 发明授权

US08395007B2 Diesel and jet fuels based on the oligomerization of butene 有权
标题翻译：基于丁烯低聚的柴油和喷气燃料
公开(公告)号：US08395007B2
公开(公告)日：2013-03-12
申请号：US12511796
申请日：2009-07-29
申请人： Michael E. Wright , Benjamin G. Harvey , Roxanne L. Quintana
发明人： Michael E. Wright , Benjamin G. Harvey , Roxanne L. Quintana
IPC分类号： C07C2/22
CPC分类号： B01J31/189 , B01J31/143 , B01J31/2295 , B01J2531/48 , C10G45/00 , C10G50/00 , C10G69/126 , C10G2300/1011 , C10G2300/1092 , C10G2300/302 , C10G2300/308 , C10G2300/44 , C10G2300/703 , C10G2400/04 , C10G2400/22 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： A renewable biofuel based on a highly efficient batch catalysis methodology for conversion of 1-butene to a new class of potential jet fuel blends. By tuning the catalyst and then using the dimer produced, the carbon use is about 95% or greater.
摘要翻译：基于用于将1-丁烯转化为新型潜在喷气燃料混合物的高效批量催化方法的可再生生物燃料。通过调节催化剂然后使用所生产的二聚体，碳的使用量约为95％或更高。

7. 发明授权

US08975463B1 Efficient conversion of pure and mixed terpene feedstocks to high density fuels 有权
标题翻译：将纯萜原料和混合萜烯原料高效转化为高密度燃料
公开(公告)号：US08975463B1
公开(公告)日：2015-03-10
申请号：US13605436
申请日：2012-09-06
申请人： Benjamin G. Harvey , Heather A. Meylemans , Roxanne L. Quintana
发明人： Benjamin G. Harvey , Heather A. Meylemans , Roxanne L. Quintana
IPC分类号： C07C403/00 , C07C403/02
CPC分类号： C10L1/08 , B01J21/16 , B01J23/42 , B01J31/10 , C07C2/04 , C07C2/08 , C07C2/28 , C07C2/38 , C07C5/03 , C07C2521/16 , C07C2521/18 , C07C2523/42 , C07C2523/44 , C07C2523/72 , C07C2523/755 , C07C2529/04 , C07C2531/10 , C07C2601/14 , C07C2601/16 , C07C2602/42 , C10G3/00 , C10G29/205 , C10G2300/1003 , C10G2300/1014 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/04 , C10L1/06 , C10L2200/0469 , C10L2270/023 , C10L2270/026 , C10L2270/04 , C10L2290/543 , C10L2290/547 , Y02P30/20 , C07C13/39
摘要： A process for making high density fuels from mixed terpene feedstocks and the resulting high density fuel products.
摘要翻译：从混合萜烯原料制备高密度燃料和所得到的高密度燃料产品的方法。

8. 发明申请

US20120209036A1 TURBINE AND DIESEL FUELS AND METHODS FOR MAKING THE SAME 有权
标题翻译：涡轮和柴油燃料及其制造方法
公开(公告)号：US20120209036A1
公开(公告)日：2012-08-16
申请号：US12769757
申请日：2010-04-29
申请人： Benjamin G. Harvey , Roxanne L. Quintana
发明人： Benjamin G. Harvey , Roxanne L. Quintana
IPC分类号： C10L1/16 , C07C2/00
CPC分类号： C10L1/04 , C07C2/16 , C07C2/34 , C07C5/03 , C07C2527/054 , C07C2531/14 , C07C2531/38 , C10G69/126 , C07C11/02 , C07C9/14 , C07C9/22
摘要： A process for making diesel and turbine fuels including, providing an effective amount of branched olefins, adding active heterogeneous acid catalyst(s) to said branched olefins to produce a solvent-free mixture, heating said solvent-free mixture greater than about 100° C. for a desired amount of time depending on various conditions, to produce C16 dimers/catalyst mixture, removing said catalysts from said dimers/catalyst mixture, and adding hydrogenation catalyst(s) to said dimers under hydrogen atmosphere to produce a mixture of stable fuels.
摘要翻译：一种制备柴油和涡轮燃料的方法，包括提供有效量的支链烯烃，向所述支链烯烃中加入活性多相酸催化剂以产生无溶剂的混合物，加热大于约100℃的无溶剂混合物根据各种条件的期望的时间量，生产C16二聚体/催化剂混合物，从所述二聚体/催化剂混合物中除去所述催化剂，并在氢气氛下向所述二聚体中加入氢化催化剂以产生稳定燃料的混合物。

9. 发明授权

US09327279B2 Methods for the production of renewable dimethyl JP10 有权
标题翻译：生产可再生二甲基铵的方法JP10
公开(公告)号：US09327279B2
公开(公告)日：2016-05-03
申请号：US13604115
申请日：2012-09-05
申请人： Benjamin G. Harvey , Heather A. Meylemans , Roxanne L. Quintana
发明人： Benjamin G. Harvey , Heather A. Meylemans , Roxanne L. Quintana
IPC分类号： C10L1/16 , C07C1/22 , C07C1/24 , C07C13/32 , C07C9/00 , B01J31/18 , B01J31/14 , B01J31/22 , C10G45/00 , C10G50/00 , C10G69/12 , C10L1/08 , C10G45/32 , C10G45/58 , C10G65/04 , C10G65/06 , C10L1/04 , C10L1/06 , C10G3/00
CPC分类号： C07C1/20 , B01J31/143 , B01J31/189 , B01J31/2265 , B01J31/2273 , B01J31/2278 , B01J31/2295 , B01J2231/20 , B01J2531/48 , B01J2531/821 , C07C1/24 , C07C2/08 , C07C5/03 , C07C29/00 , C07C2523/42 , C07C2527/167 , C07C2531/22 , C07C2601/10 , C07C2603/68 , C08F110/10 , C10G3/42 , C10G45/00 , C10G45/32 , C10G45/58 , C10G50/00 , C10G65/043 , C10G65/06 , C10G69/126 , C10G2300/1011 , C10G2300/1092 , C10G2300/302 , C10G2300/308 , C10G2300/44 , C10G2300/703 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/22 , C10L1/04 , C10L1/06 , C10L1/08 , C10L2200/0469 , C10L2270/023 , C10L2270/04 , Y02E50/13 , Y02P30/20 , C07C13/15 , C07C13/32 , C07C35/06
摘要： A highly efficient method for the conversion of a natural product into the high density fuel RJ-4 with concomitant evolution of isobutylene for conversion to fuels and polymers, more specifically, embodiments of the invention relate to efficient methods for the conversion of the renewable, linear terpene alcohol, linalool into a drop-in, high density fuel suitable for ramjet or missile propulsion.
摘要翻译：用于将天然产物转化为高密度燃料RJ-4的高效方法，同时伴随着异丁烯的转化转化成燃料和聚合物，更具体地说，本发明的实施方案涉及转化可再生的，线性的萜烯醇，芳樟醇成为适用于冲压式或导弹推进的滴灌，高密度燃料。

10. 发明申请

US20150011807A1 METHODS FOR THE PRODUCTION OF RENEWABLE DIMETHYL JP10 有权
标题翻译：生产可再生二甲基丙烯酸酯的方法JP10
公开(公告)号：US20150011807A1
公开(公告)日：2015-01-08
申请号：US13604115
申请日：2012-09-05
申请人： Benjamin G. Harvey , Heather A. Meylemans , Roxanne L. Quintana
发明人： Benjamin G. Harvey , Heather A. Meylemans , Roxanne L. Quintana
IPC分类号： C10L1/16 , C07C1/22 , C07C1/24 , C07C9/00 , C07C13/32
CPC分类号： C07C1/20 , B01J31/143 , B01J31/189 , B01J31/2265 , B01J31/2273 , B01J31/2278 , B01J31/2295 , B01J2231/20 , B01J2531/48 , B01J2531/821 , C07C1/24 , C07C2/08 , C07C5/03 , C07C29/00 , C07C2523/42 , C07C2527/167 , C07C2531/22 , C07C2601/10 , C07C2603/68 , C08F110/10 , C10G3/42 , C10G45/00 , C10G45/32 , C10G45/58 , C10G50/00 , C10G65/043 , C10G65/06 , C10G69/126 , C10G2300/1011 , C10G2300/1092 , C10G2300/302 , C10G2300/308 , C10G2300/44 , C10G2300/703 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/22 , C10L1/04 , C10L1/06 , C10L1/08 , C10L2200/0469 , C10L2270/023 , C10L2270/04 , Y02E50/13 , Y02P30/20 , C07C13/15 , C07C13/32 , C07C35/06
摘要： A highly efficient method for the conversion of a natural product into the high density fuel RJ-4 with concomitant evolution of isobutylene for conversion to fuels and polymers, more specifically, embodiments of the invention relate to efficient methods for the conversion of the renewable, linear terpene alcohol, linalool into a drop-in, high density fuel suitable for ramjet or missile propulsion.
摘要翻译：用于将天然产物转化为高密度燃料RJ-4的高效方法，同时伴随着异丁烯的转化转化成燃料和聚合物，更具体地说，本发明的实施方案涉及转化可再生的，线性的萜烯醇，芳樟醇成为适用于冲压式或导弹推进的滴灌，高密度燃料。

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