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    • 3. 发明授权
    • α+beta-type titanium alloy part and method of production of same
    • α+β型钛合金零件及其制造方法
    • US09187807B2
    • 2015-11-17
    • US13513026
    • 2010-12-02
    • Kazuhiro TakahashiAkira KawakamiTomonori KuniedaMotomi Masaki
    • Kazuhiro TakahashiAkira KawakamiTomonori KuniedaMotomi Masaki
    • C22C14/00C22F1/18
    • C22C14/00C22F1/183F16B33/00F16C7/02F16C2204/42
    • A method of production of an α+β-type titanium alloy part for a motorcycle, car, or bicycle which has a high Young's modulus (rigidity) in the axial direction of the shaped product and a bolt, engine valve, or connecting rod made of an α+β-type titanium alloy and a method of production of the same, wherein an α+β-type titanium alloy is heated at the temperatures giving the β-single phase, then is uni-directionally hot rolled, the plate is machined so that a direction vertical to both the hot rolling direction and thickness direction (width direction) corresponds to the direction in which high rigidity is demanded in the finished part, that is, the axial direction of the bolt, engine valve, or connecting rod, and the X-ray diffraction intensities I(0002), I(10-10), and I(10-11), of the (0002) plane, (10-10) plane, and (10-11) plane of the titanium α-phase measured at the cross-sections vertical to the longitudinal axial direction of the parts satisfy I(0002)/[I(10-10)+I(10-11)]≧1.
    • 一种在成形制品的轴向上具有高杨氏模量(刚性)的摩托车,汽车或自行车的α+ / bgr型型钛合金部件的制造方法以及螺栓,发动机气门或连杆 由α+ / bgr型钛合金制成,其制造方法为α+ b型钛合金,在单相温度下加热,然后单向热轧 加工板,使得与热轧方向和厚度方向(宽度方向)垂直的方向对应于成品部件中要求高刚性的方向,即螺栓,发动机阀门的轴向方向 (10-10)面的X射线衍射强度I(0002),I(10-10)和I(10-11),(10-10)面和(10- 11)在垂直于部件的纵向轴向的横截面处测量的钛α相的面积满足I(0002)/ [I(10-10 )+ I(10-11)]≥1。
    • 4. 发明授权
    • Process for producing 2,3,3,3-tetrafluoropropene
    • 制备2,3,3,3-四氟丙烯的方法
    • US09040760B2
    • 2015-05-26
    • US13879668
    • 2011-10-27
    • Kazuhiro TakahashiYuzo KomatsuAkinori Ueda
    • Kazuhiro TakahashiYuzo KomatsuAkinori Ueda
    • C07C17/25C07C17/20C07C17/087
    • C07C17/25C07C17/087C07C17/20C07C17/206C12Q1/686G01N21/6428G01N21/6486G01N2021/6439G01N2201/061Y02P20/582C07C21/18
    • This invention provides a process for producing 2,3,3,3-tetrafluoropropene, the process comprising: (1) a first reaction step of reacting hydrogen fluoride with at least one chlorine-containing compound selected from the group consisting of a chloropropane represented by Formula (1): CClX2CHClCH2Cl, wherein each X is the same or different and is CI or F, a chloropropene represented by Formula (2): CClY2CCl═CH2, wherein each Y is the same or different and is CI or F, and a chloropropene represented by Formula (3): CZ2═CClCH2Cl, wherein each Z is the same or different and is CI or F in a gas phase in the absence of a catalyst while heating; and (2) a second reaction step of reacting hydrogen fluoride with a reaction product obtained in the first reaction step in a gas phase in the presence of a fluorination catalyst while heating. According to the process of this invention, 2,3,3,3-tetrafluoropropene (HFO-1234yf) can be obtained with high selectivity, and catalyst deterioration can be suppressed.
    • 本发明提供一种生产2,3,3,3-四氟丙烯的方法,该方法包括:(1)使氟化氢与至少一种选自以下的含氯化合物反应的第一反应步骤:选自由 式(1):CClX 2 CHClCH 2 Cl,其中每个X相同或不同,为Cl或F,式(2)表示的氯丙烯:CClY 2 CCl = CH 2,其中每个Y相同或不同,为Cl或F, 由式(3)表示的氯丙烯:CZ2 = CClCH2Cl,其中每个Z相同或不同,并且在加热时不存在催化剂的气相中为Cl或F; 和(2)在加热下在氟化催化剂存在下,在气相中使氟化氢与第一反应步骤中得到的反应产物反应的第二反应步骤。 根据本发明的方法,可以高选择性地获得2,3,3,3-四氟丙烯(HFO-1234yf),并且可以抑制催化剂劣化。
    • 10. 发明申请
    • PURIFICATION METHOD OF 2,3,3,3-TETRAFLUOROPROPENE
    • 2,3,3,3-四氯丙烯的纯化方法
    • US20130105296A1
    • 2013-05-02
    • US13808358
    • 2011-07-21
    • Takehiro ChakiKazuhiro Takahashi
    • Takehiro ChakiKazuhiro Takahashi
    • C07C17/386
    • C07C17/386C01B7/196C07C17/38C07C17/383Y02P20/582C07C21/18
    • This invention provides a method for purifying HFO-1234yf by removing HF from a mixture of HFO-1234yf and HF under simple and economically advantageous conditions. According to the present invention, this is a purification method for 2,3,3,3-tetrafluoropropene, (1) the purification method comprising the step of subjecting a mixture comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride to extractive distillation in a distillation column A using an extractant, thereby obtaining a fraction I that contains 2,3,3,3-tetrafluoropropene and has a lower ratio of hydrogen fluoride to 2,3,3,3-tetrafluoropropene than that of the mixture, while obtaining a fraction II that contains hydrogen fluoride and has a lower ratio of 2,3,3,3-tetrafluoropropene to hydrogen fluoride than that of the mixture; (2) the extractant comprising at least one member selected from the group consisting of: (i) alcohols represented by ROH, wherein R is a C1-5 alkyl group, (ii) ethers represented by ROR′, wherein R and R′ are the same or different, and each is a C1-4 alkyl group, (iii) fluorinated alcohols represented by RfOH, wherein Rf is a C1-3 fluoroalkyl group, (iv) ketones represented by RCOR′, wherein R and R′ are the same or different, and each is a C1-4 alkyl group, (v) esters represented by RCOOR′, wherein R and R′ are the same or different, and each is a C1-4 alkyl group, (vi) polyols represented by R(OH)n, wherein R is a C1-4 alkyl group, and n is an integer of 2 to 3, and (vii) ethylene glycols represented by R1O(CH2CH2O)nR2, wherein R1 and R2 are the same or different, and each is hydrogen or a C1-4 alkyl group, and n is an integer of 1 to 3.
    • 本发明提供了一种通过在简单且经济有利的条件下从HFO-1234yf和HF的混合物中除去HF来净化HFO-1234yf的方法。 根据本发明,这是2,3,3,3-四氟丙烯的纯化方法,(1)纯化方法,其包括将包含2,3,3,3-四氟丙烯和氟化氢的混合物进行萃取 在使用萃取剂的蒸馏塔A中进行蒸馏,从而获得含有2,3,3,3-四氟丙烯的馏分I,并且氟化氢与2,3,3,3-四氟丙烯的比例低于混合物, 同时获得含有氟化氢并且比2,3混合物具有较低的2,3,3,3-四氟丙烯与氟化氢的比例II; (2)萃取剂,其包含选自以下的至少一种:(i)由ROH表示的醇,其中R为C 1-5烷基,(ii)由ROR'表示的醚,其中R和R'为 相同或不同,各自为C1-4烷基,(iii)由RfOH表示的氟化醇,其中Rf为C1-3氟代烷基,(iv)由RCOR'表示的酮,其中R和R'为 相同或不同,并且各自为C 1-4烷基,(v)由RCOOR'表示的酯,其中R和R'相同或不同,并且各自为C 1-4烷基,(vi)由 R(OH)n,其中R是C 1-4烷基,n是2至3的整数,和(vii)由R 10(CH 2 CH 2 O)n R 2表示的乙二醇,其中R 1和R 2相同或不同, 各自为氢或C 1-4烷基,n为1〜3的整数。