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1. 发明申请

US20080085973A1 Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
标题翻译：用于最小化可交联组合物焦烧的硝酸化合物
公开(公告)号：US20080085973A1
公开(公告)日：2008-04-10
申请号：US11539815
申请日：2006-10-09
申请人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
发明人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
IPC分类号： C07D211/00 , C08F2/38
CPC分类号： C08F2/38 , C08F4/00 , C08K5/0025 , C08K5/3435
摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.
摘要翻译：在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制，例如4-羟基 - 四氢环丁基哌啶-1-基。在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性，聚合物组合物内迁移少。

2. 发明授权

US07842759B2 Nitroxide compounds for minimizing scorch in crosslinkable compositions 失效
标题翻译：用于最小化可交联组合物中焦化的硝酸氧化物
公开(公告)号：US07842759B2
公开(公告)日：2010-11-30
申请号：US12267909
申请日：2008-11-10
申请人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
发明人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
IPC分类号： C08F8/30
CPC分类号： C08F2/38 , C08F4/00 , C08K5/0025 , C08K5/3435
摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.
摘要翻译：在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制，例如4-羟基 - 四氢环丁基哌啶-1-基。在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性，聚合物组合物内迁移少。

3. 发明申请

US20090069469A1 Nitroxide Compounds for Minimizing Scorch in Crosslinkable Compositions 失效
标题翻译：用于最小化可交联组合物焦烧的硝酸化合物
公开(公告)号：US20090069469A1
公开(公告)日：2009-03-12
申请号：US12267909
申请日：2008-11-10
申请人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
发明人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
IPC分类号： C08K5/3435 , C07D211/94
CPC分类号： C08F2/38 , C08F4/00 , C08K5/0025 , C08K5/3435
摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.
摘要翻译：在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制，例如4-羟基 - 四氢环丁基哌啶-1-基。在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性，聚合物组合物内迁移少。

4. 发明授权

US07465769B2 Nitroxide compounds for minimizing scorch in crosslinkable compositions 失效
标题翻译：用于最小化可交联组合物中焦化的硝酸氧化物
公开(公告)号：US07465769B2
公开(公告)日：2008-12-16
申请号：US11539815
申请日：2006-10-09
申请人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
发明人： Mohamed Esseghir , Bharat I. Chaudhary , Jeffrey M. Cogen , John Klier , Jinder Jow , Robert F. Eaton , Suzanne M. Guerra
IPC分类号： C08F8/30
CPC分类号： C08F2/38 , C08F4/00 , C08K5/0025 , C08K5/3435
摘要： Scorch is inhibited during the free-radical crosslinking of a crosslinkable polymer, e.g., an EPDM, by incorporating into the polymer before melt processing and crosslinking a scorch inhibiting amount of a derivative, preferably an ether, ester or urethane derivative, of a TEMPO compound, e.g., 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl. The scorch inhibitors of this invention perform as well, if not better, than their 4-hydroxy-tetrahydrocarbylpiperidin-1-oxyl counterparts in similar polymer compositions and under similar conditions in terms of scorch inhibition and ultimate degree of crosslinking, but exhibit less volatility and less migration within the polymer composition.
摘要翻译：在可交联聚合物（例如EPDM）的自由基交联期间，通过在熔融加工和交联焦烧抑制量的TEMPO化合物的衍生物，优选醚，酯或氨基甲酸酯衍生物的交联之前引入聚合物中，焦烧被抑制，例如4-羟基 - 四氢环丁基哌啶-1-基。在类似的聚合物组合物和类似的条件下，本发明的焦烧抑制剂（如果不是更好）也与其4-羟基 - 四烃基哌啶-1-氧基对应物一样，在焦烧抑制和最终交联度方面也表现出较低的挥发性，聚合物组合物内迁移少。

5. 发明申请

US20140343201A1 Plasticizer for Low Temperature Unwind with Weight Retention During Heat Aging 有权
标题翻译：增塑剂用于低温退火，重量保持在热老化期间
公开(公告)号：US20140343201A1
公开(公告)日：2014-11-20
申请号：US14344421
申请日：2012-09-13
申请人： Caroline H. Laufer , Robert F. Eaton , Abhijit Ghosh-Dastidar , Manish Mundra , Bharat I. Chaudhary , Jeffrey M. Cogen , Lin Fu
发明人： Caroline H. Laufer , Robert F. Eaton , Abhijit Ghosh-Dastidar , Manish Mundra , Bharat I. Chaudhary , Jeffrey M. Cogen , Lin Fu
IPC分类号： C08K5/1515
CPC分类号： C08K5/1515 , C08K5/0016 , C08K2201/014 , C09D127/06 , H01B3/443 , C08L27/06
摘要： The present disclosure is directed to a plasticizer, polymeric compositions containing the plasticizer, and conductors coated with the polymeric composition. The plasticizer includes (i) an epoxidized fatty acid methyl ester, (ii) an epoxidized natural oil, and (iii) an epoxidized tallate ester. Polymeric compositions containing a polymeric resin and the plasticizer exhibit a weight loss less than 50 mg/cm2 after exposure to 100° C. for seven days. Conductors coated with the polymeric composition (containing the plasticizer) pass the low temperature unwind test of UL719 and exhibit a weight loss less than 50 mg/cm2 after exposure to 100° C. for seven days.
摘要翻译：本公开涉及含增塑剂的增塑剂，聚合物组合物和涂覆有聚合物组合物的导体。增塑剂包括（i）环氧化脂肪酸甲酯，（ii）环氧化天然油，和（iii）环氧化的酯酸酯。含有聚合物树脂和增塑剂的聚合物组合物在暴露于100℃下显示重量损失小于50mg / cm 2，持续7天。用聚合物组合物（含增塑剂）涂覆的导体通过UL719的低温退火试验，并且在暴露于100℃下显示出低于50mg / cm 2的重量减少7天。

6. 发明授权

US09403965B2 Plasticizer for low temperature unwind with weight retention during heat aging 有权
标题翻译：用于低温退火的增塑剂，在热老化期间具有重量保持性
公开(公告)号：US09403965B2
公开(公告)日：2016-08-02
申请号：US14344421
申请日：2012-09-13
申请人： Caroline H. Laufer , Robert F. Eaton , Abhijit Ghosh-Dastidar , Manish Mundra , Bharat I. Chaudhary , Jeffrey M. Cogen , Lin Fu
发明人： Caroline H. Laufer , Robert F. Eaton , Abhijit Ghosh-Dastidar , Manish Mundra , Bharat I. Chaudhary , Jeffrey M. Cogen , Lin Fu
IPC分类号： C08K5/15 , C08K5/1515 , C08K5/00 , C09D127/06 , H01B3/44
CPC分类号： C08K5/1515 , C08K5/0016 , C08K2201/014 , C09D127/06 , H01B3/443 , C08L27/06
摘要： The present disclosure is directed to a plasticizer, polymeric compositions containing the plasticizer, and conductors coated with the polymeric composition. The plasticizer includes (i) an epoxidized fatty acid methyl ester, (ii) an epoxidized natural oil, and (iii) an epoxidized tallate ester. Polymeric compositions containing a polymeric resin and the plasticizer exhibit a weight loss less than 50 mg/cm2 after exposure to 100° C. for seven days. Conductors coated with the polymeric composition (containing the plasticizer) pass the low temperature unwind test of UL719 and exhibit a weight loss less than 50 mg/cm2 after exposure to 100° C. for seven days.
摘要翻译：本公开涉及含增塑剂的增塑剂，聚合物组合物和涂覆有聚合物组合物的导体。增塑剂包括（i）环氧化脂肪酸甲酯，（ii）环氧化天然油，和（iii）环氧化的酯酸酯。含有聚合物树脂和增塑剂的聚合物组合物在暴露于100℃下显示重量损失小于50mg / cm 2，持续7天。用聚合物组合物（含增塑剂）涂覆的导体通过UL719的低温退火试验，并且在暴露于100℃下显示出低于50mg / cm 2的重量减少7天。

7. 发明申请

US20130206450A1 PLASTICIZER SYSTEM WITH IMPROVED ELECTRICAL PROPERTIES 审中-公开
标题翻译：具有改善电性能的增塑剂系统
公开(公告)号：US20130206450A1
公开(公告)日：2013-08-15
申请号：US13878858
申请日：2011-11-03
申请人： Robert F. Eaton , Abhijit Ghosh-Dastidar , Jeffrey M. Cogen , Bharat I. Chaudhary , Caroline H. Laufer
发明人： Robert F. Eaton , Abhijit Ghosh-Dastidar , Jeffrey M. Cogen , Bharat I. Chaudhary , Caroline H. Laufer
IPC分类号： C08K5/1515 , H01B3/30
CPC分类号： C08K5/1515 , C08K2201/014 , H01B3/308 , C08L27/06
摘要： The disclosure is directed to a plasticizer system with improved electrical properties. The plasticizer system includes (a) a primary plasticizer consisting of an epoxidized vegetable oil and (b) a secondary plasticizer consisting of an epoxidized fatty acid ester, where the primary plasticizer is present in an amount greater than 50% by weight of the total plasticizer system weight.
摘要翻译：本公开涉及具有改善的电性能的增塑剂体系。增塑剂体系包括（a）由环氧化植物油组成的主要增塑剂和（b）由环氧化脂肪酸酯组成的二次增塑剂，其中主要增塑剂的存在量大于总增塑剂的50重量％系统重量。

8. 发明申请

US20120172510A1 MOISTURE CROSSLINKABLE POLYETHYLENE COMPOSITION 审中-公开
标题翻译：水分可交联聚乙烯组合物
公开(公告)号：US20120172510A1
公开(公告)日：2012-07-05
申请号：US12981639
申请日：2010-12-30
申请人： Mohamed Esseghir , Jeffrey M. Cogen , Robert F. Eaton , Michael B. Biscoglio , Salvatore F. Shurott
发明人： Mohamed Esseghir , Jeffrey M. Cogen , Robert F. Eaton , Michael B. Biscoglio , Salvatore F. Shurott
IPC分类号： C08L23/02 , C08K5/14 , C08K5/5425
CPC分类号： C08L23/02 , C08L23/08 , C08L23/14 , C08L2205/02 , C08L23/0846
摘要： The present invention is a moisture crosslinkable composition. It may be (i) a blend of a nonpolar polyolefin and a second highly polar or amorphous polyolefin or (ii) a copolymer of a nonpolar polyolefin and the second polar or amorphous polyolefin. The present invention is useful for the preparation of moisture-cured wires, cables, film, pipe, hot melt adhesives, and other extruded or injection molded articles. The present invention is also useful in the preparation of media for fast transport of selective species, including film membranes.
摘要翻译：本发明是水分交联组合物。其可以是（i）非极性聚烯烃和第二高极性或无定形聚烯烃的共混物，或（ii）非极性聚烯烃和第二极性或无定形聚烯烃的共聚物。本发明可用于制备湿固化线，电缆，薄膜，管，热熔粘合剂和其它挤出或注模制品。本发明还可用于制备用于快速输送选择性物质（包括膜膜）的培养基。

9. 发明申请

US20110112250A1 MOISTURE CROSSLINKABLE POLYETHYLENE COMPOSITION 审中-公开
标题翻译：水分可交联聚乙烯组合物
公开(公告)号：US20110112250A1
公开(公告)日：2011-05-12
申请号：US13002059
申请日：2009-06-29
申请人： Mohamed Esseghir , Jeffrey M. Cogen , Robert F. Eaton , Michael B. Biscoglio , Salvatore F. Shurott
发明人： Mohamed Esseghir , Jeffrey M. Cogen , Robert F. Eaton , Michael B. Biscoglio , Salvatore F. Shurott
IPC分类号： C08J3/24 , C08L23/02
CPC分类号： C08L23/04 , C08K5/14 , C08K5/5425 , C08L23/0853 , C08L23/0869 , C08L23/0884 , C08L23/10 , H01B3/441 , H01B3/448 , C08L2666/06 , C08L2666/04
摘要： The present invention is a moisture crosslinkable composition. It may be (i) a blend of a nonpolar polyolefin and a second highly polar or amorphous polyolefin or (ii) a copolymer of a nonpolar polyolefin and the second polar or amorphous polyolefin. The present invention is useful for the preparation of moisture-cured wires, cables, film, pipe, hot melt adhesives, and other extruded or injection molded articles. The present invention is also useful in the preparation of media for fast transport of selective species, including film membranes.
摘要翻译：本发明是水分交联组合物。其可以是（i）非极性聚烯烃和第二高极性或无定形聚烯烃的共混物，或（ii）非极性聚烯烃和第二极性或无定形聚烯烃的共聚物。本发明可用于制备湿固化线，电缆，薄膜，管，热熔粘合剂和其它挤出或注模制品。本发明还可用于制备用于快速输送选择性物质（包括膜膜）的培养基。

10. 发明申请

US20100120955A1 Isocyanate, Diisocyanate and (Meth) Acrylate Compounds for Minimizing Scorch and Diisocyanate Compounds for Promoting Cure in Crosslinkable Compositions 审中-公开
标题翻译：用于最小化焦化和二异氰酸酯化合物的异氰酸酯，二异氰酸酯和（甲基）丙烯酸酯化合物，用于促进可交联组合物中的固化
公开(公告)号：US20100120955A1
公开(公告)日：2010-05-13
申请号：US12529494
申请日：2008-03-11
申请人： Bharat I. Chaudhary , Robert F. Eaton
发明人： Bharat I. Chaudhary , Robert F. Eaton
IPC分类号： C08K5/29 , C08K5/10
CPC分类号： C08K5/0025 , C08K5/14 , C08K5/29 , C08K5/3435 , C08L23/04
摘要： Thermally activated, free-radical initiator-containing polymer compositions comprise a (i) free radical initiator, (ii) free radical crosslinkable polymer, (iii) scorch inhibiting amount and/or a cure-boosting amount of at least one of isocyanate, diiso-cyanate, e.g., MDI, or hydroxyalkyl(meth)acrylate compound, e.g., hydroxyethyl(meth)acrylate, and, optionally, (iv) other scorch retardants and/or cure boosters, e.g., a TEMPO compound, a hindered phenol, alpha-methyl styrene dimer, etc. The free radical initiator can be any thermally activated compound that is relatively unstable and easily breaks into at least two radicals, e.g., a peroxide or azo initiator. The crosslinkable polymer is a thermoplastic and/or elastomeric polymer that can be crosslinked (cured) through the action of a crosslinking agent, e.g., LDPE. The isocyanate, diisocyanate and (meth)acrylate scorch inhibitors and/or cure boosters can be used alone, or in combination with one another, or, optionally, in combination with a TEMPO compound, e.g., 4-hydroxy-TEMPO.
摘要翻译：热活化的含自由基引发剂的聚合物组合物包含（i）自由基引发剂，（ii）自由基交联聚合物，（iii）焦化抑制量和/或固化促进量的至少一种异氰酸酯，二异氰酸酯 - 氰酸酯，例如MDI或（甲基）丙烯酸羟烷基酯化合物，例如（甲基）丙烯酸羟乙酯，和任选的（iv）其它焦烧延迟剂和/或固化促进剂，例如TEMPO化合物，受阻酚，α 甲基苯乙烯二聚体等。自由基引发剂可以是任何相对不稳定的热活化化合物，并且易于分解成至少两个基团，例如过氧化物或偶氮引发剂。可交联聚合物是可以通过交联剂例如LDPE的作用进行交联（固化）的热塑性和/或弹性聚合物。异氰酸酯，二异氰酸酯和（甲基）丙烯酸酯焦化抑制剂和/或固化促进剂可以单独使用或彼此组合使用，或任选与TEMPO化合物如4-羟基-TEMPO组合使用。

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