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    • 3. 发明授权
    • Method for producing silicone rubber compound and silicone rubber composition
    • 硅橡胶组合物和硅橡胶组合物的制备方法
    • US08754160B2
    • 2014-06-17
    • US13457828
    • 2012-04-27
    • Yutaka HagiwaraMinoru Igarashi
    • Yutaka HagiwaraMinoru Igarashi
    • C08K3/34C08L83/00
    • C08J3/24C08J2383/04C08K3/36C08K5/5419C08L83/04
    • A method for producing a silicone rubber compound in a reduced blending time, and which imparts excellent resistance to plasticity reversion and the cured silicone rubber prepared without heat treatment has excellent resistance to compression set. (A) an organopolysiloxane with polymerization degree of at least 100 represented by the following average compositional formula (I): R1aSiO(4-a)/2  (I) (R1: a substituted or unsubstituted monovalent hydrocarbon group, a: 1.95 to 2.05), (B) a reinforcing silica having a specific surface area (BET) of at least 50 m2/g, and (C) a preliminary hydrolysis product of (C-1) an alkoxysilane represented by the following formula (II): R2mSi(OR3)4-m  (II) (R2: hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group, R3: a substituted or unsubstituted alkyl group, m: 0, 1, 2, or 3), and (C-2) water at a molar amount 0.3 to 5 times the alkoxy group in the alkoxysilane of component (C-1) are mixed and heated.
    • 缩短混合时间制造硅橡胶化合物的方法,具有优异的耐回缩性和不经热处理制备的固化的硅橡胶具有优异的耐压缩变形性。 (A)由以下平均组成式(I)表示的聚合度为至少100的有机聚硅氧烷:R1aSiO(4-a)/ 2(I)(R1:取代或未取代的单价烃基,a:1.95〜2.05 ),(B)比表面积(BET)为50m 2 / g以上的增强二氧化硅,(C)由下式(II)表示的(C-1)烷氧基硅烷的预水解产物:R2mSi (OR 3)4-m(II)(R 2:氢原子或取代或未取代的一价烃基,R 3:取代或未取代的烷基,m:0,1,2或3)和(C-2) 将组分(C-1)的烷氧基​​硅烷中的烷氧基的摩尔量为0.3至5倍的水混合并加热。
    • 9. 发明申请
    • METHOD FOR PRODUCING SILICONE RUBBER COMPOUND AND SILICONE RUBBER COMPOSITION
    • 生产硅橡胶化合物和硅橡胶组合物的方法
    • US20120277362A1
    • 2012-11-01
    • US13458845
    • 2012-04-27
    • Minoru IGARASHIYutaka Hagiwara
    • Minoru IGARASHIYutaka Hagiwara
    • C08K3/34
    • C08J3/24C08G77/20C08J2383/04C08K3/36C08K5/5419C08L83/04
    • A method for producing a silicone rubber compound in a reduced blending time and which imparts excellent resistance to plasticity reversion, and the cured silicone rubber prepared without heat treatment has excellent resistance to compression set. The method comprises mixing components: (A) an organopolysiloxane having a polymerization degree of at least 100 represented by the following average compositional formula (I): R1aSiO(4−a)/2   (I) wherein R1 is independently a substituted or unsubstituted monovalent hydrocarbon group, and a is 1.95 to 2.05; (B) a reinforcing silica having a specific surface area as measured by BET absorption method of at least 50 m2/g, (C) an alkoxysilane represented by the following formula (II): R2mSi(OR3)4−m   (II) wherein R2 is independently hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group, R3 is independently a substituted or unsubstituted alkyl group, and m is 0, 1, 2, or 3, and (D) water, and the heat treatment.
    • 一种缩短混合时间制备硅橡胶化合物的方法,其具有优异的耐回缩性,并且不经热处理制备的固化的硅橡胶具有优异的耐压缩变形性。 该方法包括混合组分:(A)聚合度为至少为100的由以下平均组成式(I)表示的聚合度的有机聚硅氧烷:R1aSiO(4-a)/ 2(I)其中R1独立地为取代或未取代的单价 烃基,a为1.95〜2.05; (B)通过BET吸收法测定的比表面积为至少50m 2 / g的增强二氧化硅,(C)由下式(II)表示的烷氧基硅烷:R2mSi(OR3)4-m(II)其中 R2独立地为氢原子或取代或未取代的单价烃基,R3独立地为取代或未取代的烷基,m为0,1,2或3,(D)水和热处理。