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1. 发明申请

US20060279019A1 Post-treatment for polymer pellets 有权
标题翻译：聚合物颗粒的后处理
公开(公告)号：US20060279019A1
公开(公告)日：2006-12-14
申请号：US10559259
申请日：2004-05-27
申请人： Pier Luigi Di Federico , Carlo Ciccarone , Luciano Michielin , Giuseppe Penzo
发明人： Pier Luigi Di Federico , Carlo Ciccarone , Luciano Michielin , Giuseppe Penzo
IPC分类号： B29C71/00 , B28B11/00 , D01D5/00
CPC分类号： B29B9/16 , B29B9/065 , B29B13/045 , B29B2009/165
摘要： A continuous process for minimizing the agglomeration of freshly manufactured polyolefin pellets comprising the steps of: feeding an aqueous stream containing polyolefin pellets to a tower, cooling said polyolefin pellets during their upward flow along said tower by means of a downward flow of a cooling agent having a density higher than said polyolefin, collecting the cooled pellets from the top of said tower after a residence time in the tower comprised between 2 and 20 minutes.
摘要翻译：一种用于最小化新制造的聚烯烃粒料团聚的连续方法，其包括以下步骤：将含有聚烯烃粒料的含水物流送入塔中，通过向下流动的冷却剂将所述聚烯烃粒料向上流动，冷却所述聚烯烃粒料，所述冷却剂具有密度高于所述聚烯烃，在塔中的停留时间为2至20分钟之后，从所述塔的顶部收集冷却的颗粒。

2. 发明授权

US07732551B2 Post-treatment for polymer pellets 有权
标题翻译：聚合物颗粒的后处理
公开(公告)号：US07732551B2
公开(公告)日：2010-06-08
申请号：US10559259
申请日：2004-05-27
申请人： Pier Luigi Di Federico , Carlo Ciccarone , Luciano Michielin , Giuseppe Penzo
发明人： Pier Luigi Di Federico , Carlo Ciccarone , Luciano Michielin , Giuseppe Penzo
IPC分类号： C08F210/00 , D01D5/40 , B28B11/00 , B29C71/00
CPC分类号： B29B9/16 , B29B9/065 , B29B13/045 , B29B2009/165
摘要： A continuous process for minimizing the agglomeration of freshly manufactured polyolefin pellets comprising the steps of: feeding an aqueous stream containing polyolefin pellets to a tower, cooling said polyolefin pellets during their upward flow along said tower by means of a downward flow of a cooling agent having a density higher than said polyolefin, collecting the cooled pellets from the top of said tower after a residence time in the tower comprised between 2 and 20 minutes.
摘要翻译：一种用于最小化新制造的聚烯烃粒料团聚的连续方法，其包括以下步骤：将含有聚烯烃粒料的含水物流送入塔中，通过向下流动的冷却剂将所述聚烯烃粒料向上流动，冷却所述聚烯烃粒料，所述冷却剂具有密度高于所述聚烯烃，在塔中的停留时间为2至20分钟之后，从所述塔的顶部收集冷却的颗粒。

3. 发明申请

US20070213481A1 Method of Discharging a Polymer from a Polymerization Reactor 有权
标题翻译：从聚合反应器中排出聚合物的方法
公开(公告)号：US20070213481A1
公开(公告)日：2007-09-13
申请号：US11632745
申请日：2005-07-04
申请人： Luciano Michielin , Maurizio Dorini , Giuseppe Penzo , Riccardo Rinaldi
发明人： Luciano Michielin , Maurizio Dorini , Giuseppe Penzo , Riccardo Rinaldi
IPC分类号： C08F2/00 , B01J4/00
CPC分类号： B01J8/002 , B01J8/003 , B01J8/1809 , B01J8/20 , B01J19/2435 , B01J2208/00539 , B01J2208/00761 , Y10S526/901
摘要： A method of discharging polymer from a continuously operated polymerization reactor, wherein at least a monomer is polymerized to form polymer particles, the method comprising adjusting the discharge rate of the polymer particles by means of a piston valve having a piston element connected to an actuator, said actuator being able to modulate the piston stroke inside said piston valve.
摘要翻译：一种从连续操作的聚合反应器中排出聚合物的方法，其中至少单体聚合以形成聚合物颗粒，所述方法包括通过具有连接到致动器的活塞元件的活塞阀来调节聚合物颗粒的排出速率，所述致动器能够调节所述活塞阀内的活塞行程。

4. 发明授权

US07763685B2 Method of discharging a polymer from a polymerization reactor 有权
标题翻译：从聚合反应器中排出聚合物的方法
公开(公告)号：US07763685B2
公开(公告)日：2010-07-27
申请号：US11632745
申请日：2005-07-04
申请人： Luciano Michielin , Maurizio Dorini , Giuseppe Penzo , Riccardo Rinaldi
发明人： Luciano Michielin , Maurizio Dorini , Giuseppe Penzo , Riccardo Rinaldi
IPC分类号： C08F2/00 , B01J4/00
CPC分类号： B01J8/002 , B01J8/003 , B01J8/1809 , B01J8/20 , B01J19/2435 , B01J2208/00539 , B01J2208/00761 , Y10S526/901
摘要： A method of discharging polymer from a continuously operated polymerization reactor, wherein at least a monomer is polymerized to form polymer particles, the method comprising adjusting the discharge rate of the polymer particles by means of a piston valve having a piston element connected to an actuator, said actuator being able to modulate the piston stroke inside said piston valve.
摘要翻译：一种从连续操作的聚合反应器中排出聚合物的方法，其中至少单体聚合以形成聚合物颗粒，所述方法包括通过具有连接到致动器的活塞元件的活塞阀来调节聚合物颗粒的排出速率，所述致动器能够调节所述活塞阀内的活塞行程。

5. 发明申请

US20100317811A1 PROCESS FOR THE GAS-PHASE POLYMERIZATION OF OLEFINS 有权
标题翻译：油相的气相聚合方法
公开(公告)号：US20100317811A1
公开(公告)日：2010-12-16
申请号：US12735090
申请日：2008-12-17
申请人： Antonio Mazzucco , Riccardo Rinaldi , Silvia Soffritti , Enrico Balestra , Giuseppe Penzo , Gabriele Mei
发明人： Antonio Mazzucco , Riccardo Rinaldi , Silvia Soffritti , Enrico Balestra , Giuseppe Penzo , Gabriele Mei
IPC分类号： C08F2/01
CPC分类号： B01J19/2435 , B01J2219/00164 , B01J2219/00166 , B01J2219/00173 , C08F10/00 , C08F110/06 , C08F210/06 , C08F2/34 , C08F2/001 , C08F2500/05 , C08F210/16
摘要： A process for the gas-phase polymerization of α-olefins carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate Fp of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.
摘要翻译：一种用于在两个相互连接的聚合区中进行的α-烯烃的气相聚合的方法，其中生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区（提升管），离开所述提升管并进入所述聚合区（降液管），通过它们以致密化形式向下流动，该方法的特征在于：（a）通过引入所述降液管的上部，存在于提升管中的气体混合物被全部或部分地防止进入降液管具有与提升管中存在的气体混合物不同的组成的液体流LB; （b）在所述降液管和所述提升管之间循环的聚合物的流量Fp与所述液体的流量LB之间的比R调节在10至50的范围内。

6. 发明授权

US08198383B2 Process for the gas-phase polymerization of olefins 有权
标题翻译：烯烃气相聚合方法
公开(公告)号：US08198383B2
公开(公告)日：2012-06-12
申请号：US12735090
申请日：2008-12-17
申请人： Antonio Mazzucco , Riccardo Rinaldi , Silvia Soffritti , Enrico Balestra , Giuseppe Penzo , Gabriele Mei
发明人： Antonio Mazzucco , Riccardo Rinaldi , Silvia Soffritti , Enrico Balestra , Giuseppe Penzo , Gabriele Mei
IPC分类号： C08F2/00 , C08F210/00 , C08F110/02 , B01J19/18 , B01J8/18
CPC分类号： B01J19/2435 , B01J2219/00164 , B01J2219/00166 , B01J2219/00173 , C08F10/00 , C08F110/06 , C08F210/06 , C08F2/34 , C08F2/001 , C08F2500/05 , C08F210/16
摘要： A process for the gas-phase polymerization of α-olefins carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate Fp of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.
摘要翻译：一种用于在两个相互连接的聚合区中进行的α-烯烃的气相聚合的方法，其中生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区（提升管），离开所述提升管并进入所述聚合区（降液管），通过它们以致密化形式向下流动，该方法的特征在于：（a）通过引入所述降液管的上部，存在于提升管中的气体混合物被全部或部分地防止进入降液管具有与提升管中存在的气体混合物不同的组成的液体流LB; （b）在所述降液管和所述提升管之间循环的聚合物的流量Fp与所述液体的流量LB之间的比R调节在10至50的范围内。

7. 发明申请

US20050234217A1 Method for removing volatile components from polymer compositions 有权
标题翻译：从聚合物组合物中除去挥发性组分的方法
公开(公告)号：US20050234217A1
公开(公告)日：2005-10-20
申请号：US10518693
申请日：2003-06-17
申请人： Daniele Bigiavi , Nicolo Arich De Finetti , Gabriele Mei , Giuseppe Penzo , Massimo Covezzi , Pietro Baita , Maria Silvia Tonti
发明人： Daniele Bigiavi , Nicolo Arich De Finetti , Gabriele Mei , Giuseppe Penzo , Massimo Covezzi , Pietro Baita , Maria Silvia Tonti
IPC分类号： C08F6/06 , C08F6/00 , C08F6/10 , C08G2/00
CPC分类号： C08F6/003 , Y02P20/544 , C08L23/20
摘要： Method for continuously removing the unreacted butene-1, and optionally other volatile components, from a polymeric solution obtained by liquid phase (co)polymerization of butene-1, the method comprising the steps of: subjecting the polymeric solution to heating and mixing conditions such that a mixture is formed consisting substantially of: (1) a polybutene melt containing entrapped butene-1 and (2) supercritical gaseous butene-1; subjecting the above mixture to a sequence of devolatilization steps operating at decreasing pressures.
摘要翻译：从通过丁烯-1的液相（共）聚合获得的聚合物溶液中连续除去未反应的丁烯-1和任选的其它挥发性组分的方法，所述方法包括以下步骤：将聚合物溶液加热和混合条件如形成的混合物基本上由以下组成：（1）含有截留的丁烯-1和（2）超临界气态丁烯-1的聚丁烯熔体; 使上述混合物经历在降低的压力下操作的一系列脱挥发分步骤。

8. 发明申请

US20100305283A1 MULTISTAGE PROCESSF FOR THE POLYMERIZATION OF OLEFINS 有权
标题翻译：烯烃聚合的多种方法
公开(公告)号：US20100305283A1
公开(公告)日：2010-12-02
申请号：US12733773
申请日：2008-08-27
申请人： Maurizio Dorini , Giuseppe Penzo , Riccardo Rinaldi
发明人： Maurizio Dorini , Giuseppe Penzo , Riccardo Rinaldi
IPC分类号： C08F2/00 , B01J19/18
CPC分类号： B01J8/1809 , B01J19/2435 , B01J2208/00212 , B01J2208/0061 , B01J2219/0004 , C08F10/06 , C08F110/06 , C08F210/16 , C08F2/34 , C08F2/001 , C08F2500/12 , C08F210/08
摘要： A process for the multistage polymerization of olefins in a sequence of an upstream slurry reactor and a downstream gas-phase reactor, the transfer of polymer from the upstream reactor to the downstream reactor comprising the following steps: a) heating the slurry of polyolefin particles to evaporate the liquid polymerization medium; b) separating the polyolefin particles from the obtained gaseous phase in at least a separation chamber; c) transferring the polyolefin particles to said downstream reactor by means of a couple of lock hoppers working intermittently in parallel, where one of said lock hoppers is continuously filled with the polymer coming from said separation chamber, while simultaneously the other one is continuously pressurized by means of a gas comprising the reaction mixture coming from said downstream reactor.
摘要翻译：一种用于上游浆料反应器和下游气相反应器的顺序的烯烃多段聚合的方法，聚合物从上游反应器转移到下游反应器，包括以下步骤：a）将聚烯烃颗粒的浆料加热至蒸发液体聚合介质; b）在至少分离室中从所获得的气相中分离聚烯烃颗粒; c）通过一对间歇地并行工作的一对锁定料斗将聚烯烃颗粒转移到所述下游反应器，其中一个所述锁定料斗连续地填充有来自所述分离室的聚合物，同时另一个由包括来自所述下游反应器的反应混合物的气体的方法。

9. 发明申请

US20090234083A1 Polymerization Process for Preparing Polyolefins 审中-公开
标题翻译：制备聚烯烃的聚合方法
公开(公告)号：US20090234083A1
公开(公告)日：2009-09-17
申请号：US11989384
申请日：2006-07-18
申请人： Daniele Bigiavi , Giuseppe Penzo
发明人： Daniele Bigiavi , Giuseppe Penzo
IPC分类号： C08F2/04
CPC分类号： C08F10/00 , C08F110/08 , C08F2/06
摘要： A solution process for polymerizing one or more α-olefins of formula CH2═CHR, where R is H or an alkyl radical C1-12, to produce a polymer that is soluble in the reaction medium, the process comprising: (a) polymerization in a solution phase of one or more α-olefins in the presence of an organo-aluminum compound and a catalyst system comprising a transition metal compound as the catalyst component; (b) the polymeric solution obtained from step a) is then pressurized and transferred by means of a screw pump to a successive step for removing the unreacted monomers from the polymer; wherein the pumping capacity of said screw pump is kept constant by adding the polymeric solution with water at a feeding point upstream the screw pump.
摘要翻译：用于聚合一种或多种式CH 2 -CHR的α-烯烃（其中R是H或烷基C1-12）以产生可溶于反应介质的聚合物的溶液方法，该方法包括：（a）在有机铝化合物存在下的一种或多种α-烯烃的溶液相和包含过渡金属化合物作为催化剂组分的催化剂体系; （b）然后通过螺杆泵将从步骤a）获得的聚合物溶液加压并转移到从聚合物中除去未反应单体的连续步骤; 其中所述螺杆泵的泵送能力通过在螺杆泵上游的进料点处加入聚合物溶液而保持恒定。

10. 发明申请

US20080177012A1 Process and Apparatus For the Polymerization of Ethylene 有权
标题翻译：用于聚合乙烯的方法和装置
公开(公告)号：US20080177012A1
公开(公告)日：2008-07-24
申请号：US11883713
申请日：2006-01-30
申请人： Giuseppe Penzo , Cyrus Ahmadzade-Youssefi , Rainer Karer , Ulrich Nieken
发明人： Giuseppe Penzo , Cyrus Ahmadzade-Youssefi , Rainer Karer , Ulrich Nieken
IPC分类号： C08F2/34 , B01J8/00
CPC分类号： C08F10/02 , B01J8/0035 , B01J8/006 , B01J8/24 , B01J2208/00274 , B01J2208/00761 , B01J2219/00006 , C08F6/005 , C08F10/00 , C08F110/02 , C08F210/16 , Y02P20/582 , Y10S526/92 , C08L23/06 , C08L23/0815 , C08F4/69 , C08F2/34 , C08F2/01 , C08F210/08 , C08F210/14
摘要： Process for the polymerization of ethylene or of ethylene with further 1-olefins, in which the ethylene is polymerized in the presence of a catalyst in a gas-phase reactor and reaction gas comprising propane and unpolymerized ethylene is circulated to remove the heat of polymerization, wherein the polymer particles are discharged continuously or discontinuously from the reactor, the polymer particles are separated from the major part of the concomitantly discharged gas and the polymer particles are degassed, the gas is freed of entrained fine particles and is separated from a low-boiling fraction comprising ethylene or from a high boiling fraction containing further 1-olefins or alkanes having from 4 to 12 carbon atoms in a first separation stage, a propane fraction is separated off in a second separation stage and this propane fraction is used for degassing the polymer particles discharged from the reactor, with the proportion of ethylene in the propane fraction being less than 1 mol % and the proportion of 1-olefins and alkanes having from 4 to 12 carbon atoms in the propane fraction being less than 4 mol %, in each case based on the total propane fraction. Furthermore, an apparatus for carrying out the process. In this way, a high heat discharge from the reactor, satisfactory degassing of the discharged polymer particles and recovery of the reaction gas discharged together with the polymer particles and also the gas used for degassing the polymer particles are made possible.
摘要翻译：乙烯或乙烯与进一步的1-烯烃聚合的方法，其中乙烯在催化剂存在下在气相反应器和包含丙烷和未聚合乙烯的反应气体中聚合循环以除去聚合热，其中聚合物颗粒从反应器中连续或不连续地排出，聚合物颗粒与伴随排出气体的主要部分分离，聚合物颗粒脱气，气体不含夹带的细颗粒，并从低沸点在第一分离阶段，包含乙烯或含有另外的具有4至12个碳原子的1-烯烃或烷烃的高沸点馏分的馏分在第二分离阶段分离出丙烷馏分，该丙烷馏分用于使聚合物脱气从反应器排出的颗粒，丙烷馏分中乙烯的比例小于1mol ％，丙烷馏分中具有4至12个碳原子的1-烯烃和烷烃的比例小于4mol％，基于总丙烷馏分。此外，一种用于执行该过程的装置。以这种方式，可以从反应器的高热放电，排出的聚合物颗粒的令人满意的脱气和与聚合物颗粒一起排放的反应气体的回收以及用于使聚合物颗粒脱气的气体成为可能。

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