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    • 8. 发明申请
    • Methods and Apparatus for Ultrathin Catalyst Layer for Photoelectrode
    • 用于光电极的超薄催化剂层的方法和装置
    • US20130008495A1
    • 2013-01-10
    • US13544940
    • 2012-07-09
    • Kimin JunJoseph Jacobson
    • Kimin JunJoseph Jacobson
    • H01L31/0264H01L31/0376H01L31/0352H01L31/02H01G9/20
    • C25B1/003C25B11/02C25B11/0452H01G9/2031H01G9/2036Y02E10/542Y02P20/135
    • In exemplary implementations of this invention, a photoelectrode includes a semiconductor for photocarrier generation, and a catalyst layer for altering the reaction rate in an adjacent electrolyte. The catalyst layer covers part of the semiconductor. The thickness of the catalyst layer is less than 60% of its minority carrier diffusion distance. If the photoelectrode is a photoanode, it has an OEP that is more than the potential of the valance band edge but less than the potential of the Fermi level of the semiconductor. If it is a photocathode, it has an RHE potential that is less than the potential of the conduction band edge but more than the potential of the Fermi level of the semiconductor. The absolute value of difference (OEP minus potential of valence band edge, or RHE potential minus potential of conduction band edge) is greater than zero and less than or equal to 0.2V.
    • 在本发明的示例性实施方案中,光电极包括用于光载体产生的半导体和用于改变相邻电解质中的反应速率的催化剂层。 催化剂层覆盖半导体的一部分。 催化剂层的厚度小于其少数载流子扩散距离的60%。 如果光电极是光电阳极,则其具有超过有效带边缘的电位但小于半导体的费米能级的电位的OEP。 如果它是一个光电阴极,它的RHE电位小于导带边缘的电位,但大于半导体费米能级的电位。 差值的绝对值(OEP减去价带边缘的电位,或RHE电位减去导带边缘的电位)大于零且小于或等于0.2V。