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1. 发明授权

US07928170B2 Cyanate ester, epoxy resin and curing agent of phenol resin and epoxy compound-modified polyamine 有权
标题翻译：氰酸酯，环氧树脂和酚醛树脂和环氧化合物改性多胺的固化剂
公开(公告)号：US07928170B2
公开(公告)日：2011-04-19
申请号：US12665472
申请日：2008-06-06
申请人： Ryo Ogawa , Yoko Masamune , Shinsuke Yamada
发明人： Ryo Ogawa , Yoko Masamune , Shinsuke Yamada
IPC分类号： C08K3/22 , C08L63/02
CPC分类号： C08G59/5073 , C08G59/623 , C08L63/00 , C08L79/04 , C08L2666/20
摘要： The present invention is one liquid type cyanate-epoxy composite resin composition comprised of cyanate ester resin (A), epoxy resin (B), and potential curing agent (C), characterized in that the above potential curing agent is the potential curing agent containing phenol resin (b) as well as modified amine (a) which has one or more amino groups having an active hydrogen within a molecule obtained by reacting polyamine compound (a-1) with epoxy compound (a-2). The one liquid type cyanate-epoxy composite resin composition having storage stability, curing properties and high heat resistance properties at the same time can be realized by this composition.
摘要翻译：本发明是由氰酸酯树脂（A），环氧树脂（B）和电位固化剂（C）构成的一种液体型氰酸酯 - 环氧复合树脂组合物，其特征在于，上述潜在的固化剂是含有酚醛树脂（b）以及在多胺化合物（a-1）与环氧化合物（a-2）反应得到的分子内具有一个或多个具有活性氢的氨基的改性胺（a）。通过该组合物可以实现具有保存稳定性，固化性和高耐热性的一液型氰酸酯 - 环氧复合树脂组合物。

2. 发明申请

US20120123082A1 ONE LIQUID TYPE CYANATE ESTER-EPOXY COMPOSITE RESIN COMPOSITION 有权
标题翻译：一种液态氰化物环氧复合树脂组合物
公开(公告)号：US20120123082A1
公开(公告)日：2012-05-17
申请号：US13203586
申请日：2009-11-19
申请人： Ryo Ogawa , Shinsuke Yamada
发明人： Ryo Ogawa , Shinsuke Yamada
IPC分类号： C08G65/42
CPC分类号： C08G59/184 , C08G59/4007 , C08G59/4014 , C08G2650/50 , C08L63/00 , C09J163/00 , C08L79/04
摘要： The present invention discloses one liquid type cyanate ester-epoxy composite resin composition comprised of (A) cyanate ester resin, (B) epoxy resin and (C) latent curing agent. The present one liquid type cyanate ester-epoxy composite resin composition is characterized in that the above (C) latent curing agent is comprised of a modified amine (a), which has one or more amino group having active hydrogen within a molecule, obtained by a reaction of a polyamine compound (a-1) with an epoxy compound (a-2), and a phenol resin (b), and that the above polyamine compound (a-1) is a polyether polyamine compound and/or the above epoxy compound (a-2) is a polyether polyepoxy compound.
摘要翻译：本发明公开了一种液体型氰酸酯 - 环氧复合树脂组合物，其由（A）氰酸酯树脂，（B）环氧树脂和（C）潜在性固化剂组成。本发明的一种液态氰酸酯 - 环氧复合树脂组合物的特征在于，上述（C）潜伏性固化剂由在分子内具有一个或多个具有活性氢的氨基的改性胺（a）多胺化合物（a-1）与环氧化合物（a-2）和酚醛树脂（b）的反应，上述多胺化合物（a-1）是聚醚多胺化合物和/或上述环氧化合物（a-2）是聚醚多环氧化合物。

3. 发明申请

US20110095453A1 ONE LIQUID TYPE CYANATE-EPOXY COMPOSITE RESIN COMPOSITION 有权
标题翻译：一种液态氰基 - 环氧复合树脂组合物
公开(公告)号：US20110095453A1
公开(公告)日：2011-04-28
申请号：US13001461
申请日：2009-06-12
申请人： Ryo Ogawa , Shinsuke Yamada , MItsunori Ide
发明人： Ryo Ogawa , Shinsuke Yamada , MItsunori Ide
IPC分类号： B28B1/00 , C08L63/00
CPC分类号： C08G73/0655 , C08G59/184 , C08G59/4014 , C08G2261/312 , C08K5/16 , C08L63/00 , C08L79/04 , C08L2666/20 , C09J163/00
摘要： The present invention is one liquid type cyanate-epoxy composite resin composition that is comprised of cyanate ester resin (A), epoxy resin (B) and latent curing agent (C) and has high thermal resistance as well as excellent fast curing properties and storage stability, characterized in that the above latent curing agent is comprised of a modified amine compound (a) and a phenol resin (b). Where, the modified-amine compound (a) is obtained by the reaction of at least one kind of amine compounds (a-1), selected from amine compounds having one or more tertiary amino groups and one or more primary and/or secondary amino groups, with an epoxy compound (a-2), in particular. It is preferable that one liquid type cyanate-epoxy composite resin composition of the present invention contains 1-10,000 mass parts of the epoxy resin component of the component (B) relative to 100 mass parts of cyanate-ester resin component of the component (A). The using amount of the latent curing agent of the component (C) is preferred to be 1-100 mass parts relative to 100 mass parts of the whole components (A) and (B).
摘要翻译：本发明是一种由氰酸酯树脂（A），环氧树脂（B）和潜在性固化剂（C）组成的一种液体型氰酸酯 - 环氧复合树脂组合物，具有高耐热性和优异的快速固化性能和储存性其特征在于上述潜在性固化剂由改性胺化合物（a）和酚醛树脂（b）组成。其中，所述改性胺化合物（a）通过使至少一种胺化合物（a-1）与选自具有一个或多个叔氨基的胺化合物和一个或多个伯和/或仲氨基具有环氧化合物（a-2）。本发明的一种液体型氰酸酯 - 环氧复合树脂组合物相对于组分（A）的100质量份的氰酸酯 - 酯树脂组分，优选包含1-10质量份的组分（B）的环氧树脂组分）。组分（C）的潜在性固化剂的使用量相对于100质量份全部组分（A）和（B）优选为1-100质量份。

4. 发明授权

US07923516B2 One liquid type cyanate-epoxy composite resin composition, its hardened material, manufacturing method thereof, and materials for sealing and adhesive agents using the same 有权
标题翻译：一种液体型氰酸酯 - 环氧复合树脂组合物，其硬化材料，其制造方法，以及用于密封的材料和使用其的粘合剂
公开(公告)号：US07923516B2
公开(公告)日：2011-04-12
申请号：US12682052
申请日：2008-09-30
申请人： Ryo Ogawa , Mitsunori Ide , Shinsuke Yamada
发明人： Ryo Ogawa , Mitsunori Ide , Shinsuke Yamada
IPC分类号： C08K3/22 , C08L63/02
CPC分类号： H01L23/293 , C08G59/184 , C08G59/4007 , C08G59/58 , C09D163/00 , C09J163/00 , C09K2200/0647 , H01L2924/0002 , H01L2924/00
摘要： The present invention is a cyanate-epoxy composite resin composition comprised of a cyanate ester resin (A), an epoxy resin (B), and a latent curing agent (C), characterized in that the latent curing agent (C) is composed of a modified polyamine (c1), a phenol resin (c2) and one or more kind of polycarboxylic acid (c3). The above modified polyamine (c1) is a modified polyamine, which is obtained by the reaction of polyamine compound (c1-1) with epoxy compound (c1-2), containing one or more amino group having an active hydrogen within a molecule.
摘要翻译：本发明是一种由氰酸酯树脂（A），环氧树脂（B）和潜在性固化剂（C）组成的氰酸酯 - 环氧复合树脂组合物，其特征在于潜在性固化剂（C）由改性聚胺（c1），酚醛树脂（c2）和一种或多种多元羧酸（c3）。上述改性多胺（c1）是通过在分子内含有一个以上具有活性氢的氨基的多胺化合物（c1-1）与环氧化合物（c1-2）反应得到的改性多胺。

5. 发明申请

US20100204410A1 ONE LIQUID TYPE CYANATE-EPOXY COMPOSITE RESIN COMPOSITION 有权
标题翻译：一种液态氰基 - 环氧复合树脂组合物
公开(公告)号：US20100204410A1
公开(公告)日：2010-08-12
申请号：US12665472
申请日：2008-06-06
申请人： Ryo Ogawa , Yoko Masamune , Shinsuke Yamada
发明人： Ryo Ogawa , Yoko Masamune , Shinsuke Yamada
IPC分类号： C08L63/00
CPC分类号： C08G59/5073 , C08G59/623 , C08L63/00 , C08L79/04 , C08L2666/20
摘要： The present invention is one liquid type cyanate-epoxy composite resin composition comprised of cyanate ester resin (A), epoxy resin (B), and potential curing agent (C), characterized in that the above potential curing agent is the potential curing agent containing phenol resin (b) as well as modified amine (a) which has one or more amino groups having an active hydrogen within a molecule obtained by reacting polyamine compound (a-1) with epoxy compound (a-2). The one liquid type cyanate-epoxy composite resin composition having storage stability, curing properties and high heat resistance properties at the same time can be realized by this composition.
摘要翻译：本发明是由氰酸酯树脂（A），环氧树脂（B）和电位固化剂（C）构成的一种液体型氰酸酯 - 环氧复合树脂组合物，其特征在于，上述潜在的固化剂是含有酚醛树脂（b）以及在多胺化合物（a-1）与环氧化合物（a-2）反应得到的分子内具有一个或多个具有活性氢的氨基的改性胺（a）。通过该组合物可以实现具有保存稳定性，固化性和高耐热性的一液型氰酸酯 - 环氧复合树脂组合物。

6. 发明申请

US20100210793A1 ONE LIQUID TYPE CYANATE-EPOXY COMPOSITE RESIN COMPOSITION, ITS HARDENED MATERIAL, MANUFACTURING METHOD THEREOF, AND MATERIALS FOR SEALING AND ADHESIVE AGENTS USING THE SAME 有权
标题翻译：一种液态氰基 - 环氧复合树脂组合物，其硬化材料及其制造方法，以及使用其的密封和粘合剂的材料
公开(公告)号：US20100210793A1
公开(公告)日：2010-08-19
申请号：US12682052
申请日：2008-09-30
申请人： Ryo Ogawa , Mitsunori Ide , Shinsuke Yamada
发明人： Ryo Ogawa , Mitsunori Ide , Shinsuke Yamada
IPC分类号： C08L63/00
CPC分类号： H01L23/293 , C08G59/184 , C08G59/4007 , C08G59/58 , C09D163/00 , C09J163/00 , C09K2200/0647 , H01L2924/0002 , H01L2924/00
摘要： The present invention is a cyanate-epoxy composite resin composition comprised of a cyanate ester resin (A), an epoxy resin (B), and a latent curing agent (C), characterized in that the latent curing agent (C) is composed of a modified polyamine (c1), a phenol resin (c2) and one or more kind of polycarboxylic acid (c3). The above modified polyamine (c1) is a modified polyamine, which is obtained by the reaction of polyamine compound (c1-1) with epoxy compound (c1-2), containing one or more amino group having an active hydrogen within a molecule.
摘要翻译：本发明是一种由氰酸酯树脂（A），环氧树脂（B）和潜在性固化剂（C）组成的氰酸酯 - 环氧复合树脂组合物，其特征在于潜在性固化剂（C）由改性聚胺（c1），酚醛树脂（c2）和一种或多种多元羧酸（c3）。上述改性多胺（c1）是通过在分子内含有一个以上具有活性氢的氨基的多胺化合物（c1-1）与环氧化合物（c1-2）反应得到的改性多胺。

7. 发明授权

US09601401B2 Solventless one liquid type cyanate ester-epoxy composite resin composition 有权
公开(公告)号：US09601401B2
公开(公告)日：2017-03-21
申请号：US13497811
申请日：2010-07-23
申请人： Ryo Ogawa , Shinsuke Yamada
发明人： Ryo Ogawa , Shinsuke Yamada
IPC分类号： C08L63/00 , C09J163/00 , C08G59/02 , C08G59/56 , C08G59/62 , C08G59/50 , C09J11/04 , C09J11/06 , C09J11/08 , H01L23/29 , H01L23/31 , C08K5/00 , C08K5/13 , C08K5/31 , C08K5/315 , C08K3/22 , C08K3/36 , C08G59/68 , C08G73/06 , C08K3/00 , C08K7/02 , C08L79/04
CPC分类号： H01L23/295 , C08G59/686 , C08G73/0655 , C08K3/013 , C08K3/22 , C08K3/36 , C08L63/00 , C08L79/04 , H01L23/293 , H01L2924/0002 , C08L2666/20 , H01L2924/00
摘要： The present invention is a solventless one liquid type cyanate ester-epoxy resin composition having high thermal resistance as well as excellent storage stability and curing properties, which contains (A) cyanate ester, (B) epoxy resin, (C) guanidine compounds and (D) at least one kind of phenol compounds selected from a group consisting of phenol compounds represented by the following general formulae. In the general formulae, 1 is an integer selected from 0 to 4, R1 represents an unsubstituted or fluorine-substituted monovalent hydrocarbon group.General formula:

8. 发明授权

US09303114B2 One liquid type cyanate ester-epoxy composite resin composition 有权
标题翻译：一种液体型氰酸酯 - 环氧复合树脂组合物
公开(公告)号：US09303114B2
公开(公告)日：2016-04-05
申请号：US13203586
申请日：2009-11-19
申请人： Ryo Ogawa , Shinsuke Yamada
发明人： Ryo Ogawa , Shinsuke Yamada
IPC分类号： C08L63/00 , C08G59/14 , C08G18/00 , C08G65/40 , C08G65/38 , C08G75/00 , C08G73/00 , C08G59/18 , C08G59/40 , C09J163/00
CPC分类号： C08G59/184 , C08G59/4007 , C08G59/4014 , C08G2650/50 , C08L63/00 , C09J163/00 , C08L79/04
摘要： The present invention discloses one liquid type cyanate ester-epoxy composite resin composition comprised of (A) cyanate ester resin, (B) epoxy resin and (C) latent curing agent. The present one liquid type cyanate ester-epoxy composite resin composition is characterized in that the above (C) latent curing agent is comprised of a modified amine (a), which has one or more amino group having active hydrogen within a molecule, obtained by a reaction of a polyamine compound (a-1) with an epoxy compound (a-2), and a phenol resin (b), and that the above polyamine compound (a-1) is a polyether polyamine compound and/or the above epoxy compound (a-2) is a polyether polyepoxy compound.
摘要翻译：本发明公开了一种液体型氰酸酯 - 环氧复合树脂组合物，其由（A）氰酸酯树脂，（B）环氧树脂和（C）潜在性固化剂组成。本发明的一种液态氰酸酯 - 环氧复合树脂组合物的特征在于，上述（C）潜伏性固化剂由在分子内具有一个或多个具有活性氢的氨基的改性胺（a）多胺化合物（a-1）与环氧化合物（a-2）和酚醛树脂（b）的反应，上述多胺化合物（a-1）是聚醚多胺化合物和/或上述环氧化合物（a-2）是聚醚多环氧化合物。

9. 发明授权

US08911586B2 One liquid type cyanate-epoxy composite resin composition 有权
标题翻译：一种液体型氰酸酯 - 环氧复合树脂组合物
公开(公告)号：US08911586B2
公开(公告)日：2014-12-16
申请号：US13001461
申请日：2009-06-12
申请人： Ryo Ogawa , Shinsuke Yamada , Mitsunori Ide
发明人： Ryo Ogawa , Shinsuke Yamada , Mitsunori Ide
IPC分类号： B28B1/00 , C08L63/00
CPC分类号： C08G73/0655 , C08G59/184 , C08G59/4014 , C08G2261/312 , C08K5/16 , C08L63/00 , C08L79/04 , C08L2666/20 , C09J163/00
摘要： The present invention is one liquid type cyanate-epoxy composite resin composition that is comprised of cyanate ester resin (A), epoxy resin (B) and latent curing agent (C) and has high thermal resistance as well as excellent fast curing properties and storage stability, characterized in that the above latent curing agent is comprised of a modified amine compound (a) and a phenol resin (b). Where, the modified-amine compound (a) is obtained by the reaction of at least one kind of amine compounds (a-1), selected from amine compounds having one or more tertiary amino groups and one or more primary and/or secondary amino groups, with an epoxy compound (a-2), in particular. It is preferable that one liquid type cyanate-epoxy composite resin composition of the present invention contains 1-10,000 mass parts of the epoxy resin component of the component (B) relative to 100 mass parts of cyanate-ester resin component of the component (A). The using amount of the latent curing agent of the component (C) is preferred to be 1-100 mass parts relative to 100 mass parts of the whole components (A) and (B).
摘要翻译：本发明是一种由氰酸酯树脂（A），环氧树脂（B）和潜在性固化剂（C）组成的一种液体型氰酸酯 - 环氧复合树脂组合物，具有高耐热性和优异的快速固化性能和储存性其特征在于上述潜在性固化剂由改性胺化合物（a）和酚醛树脂（b）组成。其中，所述改性胺化合物（a）通过使至少一种胺化合物（a-1）与选自具有一个或多个叔氨基的胺化合物和一个或多个伯和/或仲氨基具有环氧化合物（a-2）。本发明的一种液体型氰酸酯 - 环氧复合树脂组合物相对于组分（A）的100质量份的氰酸酯 - 酯树脂组分，优选包含1-10质量份的组分（B）的环氧树脂组分）。组分（C）的潜在性固化剂的使用量相对于100质量份全部组分（A）和（B）优选为1-100质量份。

10. 发明申请

US20120178853A1 SOLVENTLESS ONE LIQUID TYPE CYANATE ESTER-EPOXY COMPOSITE RESIN COMPOSITION 有权
标题翻译：无溶剂一液型氰基酯环氧复合树脂组合物
公开(公告)号：US20120178853A1
公开(公告)日：2012-07-12
申请号：US13497811
申请日：2010-07-23
申请人： Ryo Ogawa , Shinsuke Yamada
发明人： Ryo Ogawa , Shinsuke Yamada
IPC分类号： C08G59/02 , C09J163/00 , C08K3/22 , C08L63/00 , C08K3/36
CPC分类号： H01L23/295 , C08G59/686 , C08G73/0655 , C08K3/013 , C08K3/22 , C08K3/36 , C08L63/00 , C08L79/04 , H01L23/293 , H01L2924/0002 , C08L2666/20 , H01L2924/00
摘要： The present invention is a solventless one liquid type cyanate ester-epoxy resin composition having high thermal resistance as well as excellent storage stability and curing properties, which contains (A) cyanate ester, (B) epoxy resin, (C) guanidine compounds and (D) at least one kind of phenol compounds selected from a group consisting of phenol compounds represented by the following general formulae. In the general formulae, 1 is an integer selected from 0 to 4, R1 represents an unsubstituted or fluorine-substituted monovalent hydrocarbon group.General formula:
摘要翻译：本发明是具有高耐热性和优异的储存稳定性和固化性能的无溶剂一液型氰酸酯 - 环氧树脂组合物，其含有（A）氰酸酯，（B）环氧树脂，（C）胍化合物和（ D）选自由以下通式表示的酚化合物组成的组中的至少一种酚化合物。在通式中，1是选自0至4的整数，R1表示未取代或氟取代的一价烃基。通式：

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